EP0568920B1 - Inductively coupled plasma generator - Google Patents
Inductively coupled plasma generator Download PDFInfo
- Publication number
- EP0568920B1 EP0568920B1 EP19930106923 EP93106923A EP0568920B1 EP 0568920 B1 EP0568920 B1 EP 0568920B1 EP 19930106923 EP19930106923 EP 19930106923 EP 93106923 A EP93106923 A EP 93106923A EP 0568920 B1 EP0568920 B1 EP 0568920B1
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- EP
- European Patent Office
- Prior art keywords
- power
- inductively coupled
- coupled plasma
- plasma generator
- oscillator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
- H05H1/36—Circuit arrangements
Definitions
- the present invention relates to plasma emission sources for use in analytical instruments such as spectrometers.
- Plasma emission sources provide photons and ions which are used to excite a sample to cause emission of light at wavelengths representative of the atoms of the sample. The emitted light is then detected by a spectrometer to identify the sample.
- Apparatus which is used to generate or create plasma emission sources generally comprise radio frequency (RF) generators the output of which is inductively coupled to a load such as a plasma torch.
- RF radio frequency
- a problem associated with all such prior systems lies in their inability to adjust and control output power adequately for use in present day systems.
- the present invention substantially eliminates this problem.
- the present invention solves the mismatch problem without the need of such cumbersome arrangements.
- the present invention eliminated the need for such elaborate and cumbersome arrangements. Since impedance and frequency are functionally interrelated, the present invention overcomes the mismatch problem by permitting the RF frequency to vary to automatically adjust for impedance mismatch. At more fully set forth in the description, a signal representative of deviation of actual RF power from desired RF power is used to control the RF generator.
- plasma potential may be high relative to ground which often results in destructive parasitic discharge to the glass torch in atomic emission spectrography, or erosive damage to the sampler cone in mass spectrography.
- the present invention overcomes this problem by maintaining the plasma at or near ground potential during operation.
- the present invention also includes means for monitoring the parameters of the generator during operation and provides means for closing down operation to prevent damage to the circuitry, e.g., in inductively coupled plasma generators, non-ignitIon or bad ignition of the plasma can be a serious problem since such conditions may cause damage to circuitry or the glass torch.
- the present invention solves this problem by continuously monitoring generator parameters to detect such ignition problems and shut down the system before damage is incurred.
- the present invention relates to an inductively coupled plasma generator for generating plasma for use in analytical instruments, e.g., atomic emission or mass spectrometers. It comprises circuitry including a vacuum triode tube adapted to be used as a radio frequency oscillator for generating a plasma.
- the primary purpose of the present invention is the accurate adjustment and stable control of RF power to the load coil.
- the present invention comprises a closed loop feed back circuit wherein actual power generated is used to control oscillator output power.
- means are provided for measuring and multiplying RF voltage and current to provide an output representative of actual RF output power. This output is compared to commanded power to produce an error signal for application to the grid of the oscillator to control its output.
- the present invention also includes means for maintaining the plasma at or near zero potential as well as means for monitoring the running conditions of the generator.
- the condition of the plasma is continuously monitored by sensing the condition of circuit parameter in order to present damage caused by non-ignition or bad ignition of the plasma.
- the inductively coupled plasma generator 10 of the present invention comprises a triode vacuum tube 11 designed to operate as an oscillator, e.g., a Colpitts oscillator as shown in Fig. 2 in the radio frequency RF range.
- Plate voltage is supplied to generator 10 by means of a high voltage power supply 12.
- High voltage power supply 12 has the capability of supplying voltage at several discrete levels, e.g., four discrete values which correspond to low, medium, high, and ignite power ranges.
- Grid bias voltage is supplied to the generator 10 by means of grid control circuit 13.
- Oscillator or generator 11 is connected to plasma load coil 17 which is disposed about glass torch 18.
- Output power to the load coil 17 is delivered via oscillator resonant circuit 16 of which load coil 17 is a part.
- Resonant circuit 16 is shown in schematic detail in Fig. 2.
- Argon or a similar gas is introduced through glass torch 18 via, e.g., an opening 18a is ionized by the electromagnetic field caused by RF power circulating through resonant output circuit 16 of which load coil 17 is the inductive part thereof.
- the generated plasma is symbolically shown as a flame 18b. It should be noted, however, that the plasma which comprises photons and ions is used differently depending on its use in atomic emission spectrometry or mass spectrometry.
- the capacitance of the oscillator resonant circuit 16 is split as shown in Fig. 2 to act as a voltage divider to cause a virtual ground to appear at the center of load coil 17. This permits the plasma to be operated at zero or near zero potential with its attendant advantage of eliminating parasitic discharges when used in an atomic emission spectrometer and discharges that erode the orifice of the sampler when used in a mass spectrometer.
- a capacitive voltage divider circuit 14 and a current transformer circuit 15 are connected between generator 11 and radio frequency multiplier circuit 19.
- Radio frequency multiplier circuit 19 provides an input to comparator circuit 19.
- Capacitive voltage divider circuit 14 provides an output representative of the RF voltage output of generator 11 to RF multiplier circuit 19 while current transformer 15 provides a signal representative of the RF current output of generator 11 to RF multiplier circuit 19.
- Voltage divider circuit 14 and current transformer circuit 15 are connected so as to not interfere with the RF power delivered to the load.
- RF voltage and current are in effect multiplied in RF multiplier circuit 19 to give an output signal representative of the RF power actually being delivered to the plasma 18b through the load coil 17.
- RF multiplier circuit 19 contains identical logarithmic response amplifiers and a summation circuit similar to the AD834 four-quadrant multiplier as shown and described on page 6-65 of Analog Devices, Inc., "Linear Products Databook” 1990/91 Edition. Since the RF voltage signal and the RF current signal are logarithmically amplified and then added together, they are arithmetically equivalent to being multiplied together. Since the arithmetic product of RF voltage and RF current is RF power, the output signal from RF multiplier circuit 19 is representative of the RF power being delivered to the plasma through the load coil 17.
- the signal representative of RF power is continuously applied to comparator circuit 21.
- a microprocessor 23 provides a second input to comparator circuit 21 indicative of desired or commanded RF power.
- a digital to analog converter is interposed between microprocessor 23 and comparator circuit 22 to convert the digital data from microprocessor to analog form to be compatible with the analog signal from RF multiplier circuit 19.
- the comparator circuit 21 provides an error signal to grid control circuit 13.
- This error signal is representative of the positive or negative deviation of actual RF power going to the load coil 17 from desired or commanded power provided by microprocessor 23. This value among others is provided by a host computer having a keyboard entry system or the like and a display and/or printer.
- the signal from the comparator circuit 21 fed back to the grid control circuit 13 and maintains RF power to the load coil 17 constant accurately adjusted and stable at the commanded power.
- Grid control circuit contains a power transistor, e.g., an FET transistor, to which the error signal is fed.
- the transistor controls the grid bias of triode vacuum tube 11 in accordance with the error signal.
- vacuum tube 11 of an oscillator In order to extend the range of vacuum tube 11 of an oscillator, its efficiency may be varied between approximately between 40% to 60% by varying grid current of vacuum tube 11 in accordance with actual output power, e.g., low efficiency for low grid current and high efficiency for high grid current.
- a meter circuit 25 has an input from generator 11.
- the meter circuit 25 has an output connected to comparator circuit 26 and analog to digital converter circuit 29 which, itself, provides an input to microprocessor 23.
- a monitor circuit 27 provides a second input to comparator circuit 26 whose output is provided as an input to protection circuit.
- the output of protection circuit 28 is connected to high voltage power supply.
- One purpose of this arrangement is to monitor the operating parameters of the generator 11 such as plate voltage, plate current, and grid current. Thus, if one of the parameters exceeds a critical value set by monitor circuit 27, protective circuit 28 will cause high voltage power supply 12 to shut down. This feature is particularly important when determining the operating conditions of the plasma by monitoring grid current. Prior to ignition of the plasma discharge, grid current is extremely high. This is so since very little power is being absorbed from the load coil and most of the power provided by RF generator 11 is fed back to the grid of the generator which, as aforesaid, is essentially a triode vacuum tube. If the grid current remains high beyond a predetermined time, it may be indicative of an ignition problem.
- protective circuit 28 shuts off high voltage from power supply 12 to generator 11.
- the grid current may be indicative of a good ignition by reverting from a high pre-ignition value to a stable lower running condition.
- Variation in grid current may also be indicative of a "bad" plasma that is one that comprises a destructive discharge. This is also detectable in time to shut off high voltage to the generator 11 before damage is incurred.
- microprocessor 23 controls the power level output of the generator 11 by adjusting amount of power provided by the power source 12. This may be accomplished, e.g., by turning on one of four triacs or similar devices that control the level of actual high voltage to the plate of triode vacuum tube 11.
- the oscillator of the present invention comprises triode vacuum tube 11 connected as a somewhat modified Colpitts oscillator.
- Resonant output circuit 16 essentially comprises the load coil 17 connected in parallel to capacitors C1 and C2 whose juncture is connected to the grounded cathode.
- the present Colpitts oscillator circuit differs from the conventional circuit in that in the present arrangement C1 and C2 are made equal in value to each other and reverse connected whereas in the conventional arrangement they are not equal.
- the ratio of C2 to C3 controls grid drive power whereas in the conventional setup, the ratio of C1 to C2 performs this function.
- the microprocessor 23 obtains information on the required or commanded RF power and other operational parameter, e.g., level of plate voltage from high voltage power supply 12 from host computer 24.
- the commanded RF power signal is provided to comparator circuit 22 via digital to analog converter 22 while the high voltage (low, medium, high or ignite) at which the oscillator is to be operated is provided via to high voltage power supply 12 via digital input output circuit 31.
- the grid current of the vacuum tube is constantly monitored to prevent the above-mentioned damage problems.
- the power adjustment range of the generator is expanded by varying the efficiency of the RF generator's vacuum tube oscillator.
Description
- The present invention relates to plasma emission sources for use in analytical instruments such as spectrometers. Plasma emission sources provide photons and ions which are used to excite a sample to cause emission of light at wavelengths representative of the atoms of the sample. The emitted light is then detected by a spectrometer to identify the sample.
- Apparatus which is used to generate or create plasma emission sources generally comprise radio frequency (RF) generators the output of which is inductively coupled to a load such as a plasma torch. Such systems are generally described in U.S. Patent. Nos. 4,629,940 and 4,935,596 issued to the inventor of the present invention.
- A problem associated with all such prior systems lies in their inability to adjust and control output power adequately for use in present day systems. The present invention substantially eliminates this problem.
- In such systems, the efficient transfer of power from the RF generator to the load is an important feature. Since RF generators are inductively coupled to the load, impedance mismatch between the load and RF generator is a serious problem to be overcome. This is so since impedance mismatch may result in extremely poor transfer of power as well as cause power to be reflected back which can damage or destroy the generator circuit.
- In fixed frequency RF systems such as described in U.S. Patent No. 4,629,940, above mentioned, the problem of mismatch is remedied by a rather elaborate electronic-mechanical hybrid arrangement for continuously matching the impedance between the RF generator and the plasma torch or load.
- The present invention solves the mismatch problem without the need of such cumbersome arrangements.
- Among other innovations and improvements, the present invention eliminated the need for such elaborate and cumbersome arrangements. Since impedance and frequency are functionally interrelated, the present invention overcomes the mismatch problem by permitting the RF frequency to vary to automatically adjust for impedance mismatch. At more fully set forth in the description, a signal representative of deviation of actual RF power from desired RF power is used to control the RF generator.
- Previous inductively coupled RF plasma generators were used without regard to plasma potential. Thus, in these prior systems, plasma potential may be high relative to ground which often results in destructive parasitic discharge to the glass torch in atomic emission spectrography, or erosive damage to the sampler cone in mass spectrography. The present invention overcomes this problem by maintaining the plasma at or near ground potential during operation.
- The present invention also includes means for monitoring the parameters of the generator during operation and provides means for closing down operation to prevent damage to the circuitry, e.g., in inductively coupled plasma generators, non-ignitIon or bad ignition of the plasma can be a serious problem since such conditions may cause damage to circuitry or the glass torch. The present invention solves this problem by continuously monitoring generator parameters to detect such ignition problems and shut down the system before damage is incurred.
- The present invention relates to an inductively coupled plasma generator for generating plasma for use in analytical instruments, e.g., atomic emission or mass spectrometers. It comprises circuitry including a vacuum triode tube adapted to be used as a radio frequency oscillator for generating a plasma. The primary purpose of the present invention is the accurate adjustment and stable control of RF power to the load coil. To this end, the present invention comprises a closed loop feed back circuit wherein actual power generated is used to control oscillator output power. To accomplish this, means are provided for measuring and multiplying RF voltage and current to provide an output representative of actual RF output power. This output is compared to commanded power to produce an error signal for application to the grid of the oscillator to control its output. This is accomplished in a manner which varies efficiency of the generator as well as eliminates the need for dynamic impedance matching. The present invention also includes means for maintaining the plasma at or near zero potential as well as means for monitoring the running conditions of the generator. The condition of the plasma is continuously monitored by sensing the condition of circuit parameter in order to present damage caused by non-ignition or bad ignition of the plasma.
- Fig. 1 is a block diagram illustration of the inductively coupled plasma generator present invention; and
- Fig. 2 is a schematic representation of the oscillator of the present invention.
- Referring now to Fig. 1, there is shown the inductively coupled
plasma generator 10 of the present invention. It comprises atriode vacuum tube 11 designed to operate as an oscillator, e.g., a Colpitts oscillator as shown in Fig. 2 in the radio frequency RF range. Plate voltage is supplied togenerator 10 by means of a highvoltage power supply 12. Highvoltage power supply 12 has the capability of supplying voltage at several discrete levels, e.g., four discrete values which correspond to low, medium, high, and ignite power ranges. Grid bias voltage is supplied to thegenerator 10 by means ofgrid control circuit 13. - Oscillator or
generator 11 is connected toplasma load coil 17 which is disposed aboutglass torch 18. Output power to theload coil 17 is delivered via oscillatorresonant circuit 16 of whichload coil 17 is a part.Resonant circuit 16 is shown in schematic detail in Fig. 2. Argon or a similar gas is introduced throughglass torch 18 via, e.g., an opening 18a is ionized by the electromagnetic field caused by RF power circulating throughresonant output circuit 16 of whichload coil 17 is the inductive part thereof. The generated plasma is symbolically shown as aflame 18b. It should be noted, however, that the plasma which comprises photons and ions is used differently depending on its use in atomic emission spectrometry or mass spectrometry. - The capacitance of the oscillator
resonant circuit 16 is split as shown in Fig. 2 to act as a voltage divider to cause a virtual ground to appear at the center ofload coil 17. This permits the plasma to be operated at zero or near zero potential with its attendant advantage of eliminating parasitic discharges when used in an atomic emission spectrometer and discharges that erode the orifice of the sampler when used in a mass spectrometer. - A capacitive
voltage divider circuit 14 and acurrent transformer circuit 15 are connected betweengenerator 11 and radiofrequency multiplier circuit 19. Radiofrequency multiplier circuit 19 provides an input tocomparator circuit 19. Capacitivevoltage divider circuit 14 provides an output representative of the RF voltage output ofgenerator 11 toRF multiplier circuit 19 whilecurrent transformer 15 provides a signal representative of the RF current output ofgenerator 11 toRF multiplier circuit 19.Voltage divider circuit 14 andcurrent transformer circuit 15 are connected so as to not interfere with the RF power delivered to the load. - RF voltage and current are in effect multiplied in
RF multiplier circuit 19 to give an output signal representative of the RF power actually being delivered to theplasma 18b through theload coil 17. In one embodiment of the present invention,RF multiplier circuit 19 contains identical logarithmic response amplifiers and a summation circuit similar to the AD834 four-quadrant multiplier as shown and described on page 6-65 of Analog Devices, Inc., "Linear Products Databook" 1990/91 Edition. Since the RF voltage signal and the RF current signal are logarithmically amplified and then added together, they are arithmetically equivalent to being multiplied together. Since the arithmetic product of RF voltage and RF current is RF power, the output signal fromRF multiplier circuit 19 is representative of the RF power being delivered to the plasma through theload coil 17. - The signal representative of RF power is continuously applied to
comparator circuit 21. Amicroprocessor 23 provides a second input tocomparator circuit 21 indicative of desired or commanded RF power. A digital to analog converter is interposed betweenmicroprocessor 23 andcomparator circuit 22 to convert the digital data from microprocessor to analog form to be compatible with the analog signal fromRF multiplier circuit 19. - The
comparator circuit 21 provides an error signal togrid control circuit 13. This error signal is representative of the positive or negative deviation of actual RF power going to theload coil 17 from desired or commanded power provided bymicroprocessor 23. This value among others is provided by a host computer having a keyboard entry system or the like and a display and/or printer. The signal from thecomparator circuit 21 fed back to thegrid control circuit 13 and maintains RF power to theload coil 17 constant accurately adjusted and stable at the commanded power. - Grid control circuit contains a power transistor, e.g., an FET transistor, to which the error signal is fed. The transistor controls the grid bias of
triode vacuum tube 11 in accordance with the error signal. - In order to extend the range of
vacuum tube 11 of an oscillator, its efficiency may be varied between approximately between 40% to 60% by varying grid current ofvacuum tube 11 in accordance with actual output power, e.g., low efficiency for low grid current and high efficiency for high grid current. - A
meter circuit 25 has an input fromgenerator 11. Themeter circuit 25 has an output connected tocomparator circuit 26 and analog todigital converter circuit 29 which, itself, provides an input tomicroprocessor 23. Amonitor circuit 27 provides a second input tocomparator circuit 26 whose output is provided as an input to protection circuit. The output ofprotection circuit 28 is connected to high voltage power supply. - One purpose of this arrangement is to monitor the operating parameters of the
generator 11 such as plate voltage, plate current, and grid current. Thus, if one of the parameters exceeds a critical value set bymonitor circuit 27,protective circuit 28 will cause highvoltage power supply 12 to shut down. This feature is particularly important when determining the operating conditions of the plasma by monitoring grid current. Prior to ignition of the plasma discharge, grid current is extremely high. This is so since very little power is being absorbed from the load coil and most of the power provided byRF generator 11 is fed back to the grid of the generator which, as aforesaid, is essentially a triode vacuum tube. If the grid current remains high beyond a predetermined time, it may be indicative of an ignition problem. To prevent damage to the circuitry and/orglass torch 18,protective circuit 28 shuts off high voltage frompower supply 12 togenerator 11. Similarly, the grid current may be indicative of a good ignition by reverting from a high pre-ignition value to a stable lower running condition. Variation in grid current may also be indicative of a "bad" plasma that is one that comprises a destructive discharge. This is also detectable in time to shut off high voltage to thegenerator 11 before damage is incurred. - Dependent on the required RF power range, e.g., ignite or various running ranges,
microprocessor 23 controls the power level output of thegenerator 11 by adjusting amount of power provided by thepower source 12. This may be accomplished, e.g., by turning on one of four triacs or similar devices that control the level of actual high voltage to the plate oftriode vacuum tube 11. - Referring more particularly to Fig. 2, there is shown the oscillator of the present invention. As can be seen, it comprises
triode vacuum tube 11 connected as a somewhat modified Colpitts oscillator.Resonant output circuit 16 essentially comprises theload coil 17 connected in parallel to capacitors C₁ and C₂ whose juncture is connected to the grounded cathode. The present Colpitts oscillator circuit differs from the conventional circuit in that in the present arrangement C₁ and C₂ are made equal in value to each other and reverse connected whereas in the conventional arrangement they are not equal. In the present arrangement, the ratio of C₂ to C₃ controls grid drive power whereas in the conventional setup, the ratio of C₁ to C₂ performs this function. - By having capacitances C₁ and C₂ equal in reactances and reverse connected, the voltages across
load coil 17 are equal in magnitude but opposite in phase with respect to ground. The effect of this arrangement is to produce a virtual ground at the electrical midpoint ofload coil 17 which enables the plasma to operate with no indirect d.c. potential, i.e., at ground potential with the attendant advantage of eliminating damage to the glass torch in atomic emission spectrography or erosive damage to the sampler cone in mass spectrography. - The
microprocessor 23 obtains information on the required or commanded RF power and other operational parameter, e.g., level of plate voltage from highvoltage power supply 12 fromhost computer 24. - The commanded RF power signal is provided to
comparator circuit 22 via digital toanalog converter 22 while the high voltage (low, medium, high or ignite) at which the oscillator is to be operated is provided via to highvoltage power supply 12 via digitalinput output circuit 31. - There has above been described an inductively coupled plasma generator which provides novel means for the accurate adjustment and stable control of RF output power. Since the circuit measures true RMS power, it takes into account the phase shift of the RF current and RF voltage due to a change in the load impedance caused by different plasma operating conditions and the tube plate impedance charge due to varying the grid bias.
- In addition to maintaining the plasma at ground voltage, the grid current of the vacuum tube is constantly monitored to prevent the above-mentioned damage problems.
- Finally, as aforesaid, the power adjustment range of the generator is expanded by varying the efficiency of the RF generator's vacuum tube oscillator.
Claims (12)
- An inductively coupled plasma generator, comprising oscillator means for generating RF power,load means connected to said oscillator for generating a plasma,detector means for measuring actual RF power delivered to said load means,circuit means connected between said load means and said oscillator means for maintaining said RF power at a commanded level.
- An inductively coupled plasma generator in accordance with claim 1, wherein said detector means comprisesfirst means connected to the output side of said oscillator means providing a voltage representative of the RF voltage output of said oscillator means,second means connected to the output side of said oscillator means providing a current representative of the RF current output of said oscillator means,third means connected to said first and second means for effectively multiplying the outputs of said first and second means providing an output voltage representative of actual RF power delivered by said oscillator means to said inductive load means.
- An inductively coupled plasma generator according to claim 2 wherein said circuit means comprisescomparator circuit means connected to said third means for receiving said voltage representative of said actual RF power,fourth means connected to said comparator circuit means for providing an input to said comparator circuit means representative of said commanded RF power,said comparator circuit means providing an error signal output representative of the difference between said actual RF power and said commanded RF power,control circuit means connected to said oscillator means and to said comparator circuit means for controlling the RF output power of said oscillator means in accordance with said error signal.
- An inductively coupled plasma generator in accordance with claim 3, wherein said oscillator means comprisesa triode vacuum tube having a plate, cathode and grid.
- An inductively coupled plasma generator in accordance with claim 4 wherein said control circuit means comprisesa grid control circuit connected to the grid of said triode vacuum tube for applying said error signal to said grid for maintaining RF output power at said commanded RF power.
- An inductively coupled plasma generator in accordance with claim 5 wherein said grid control circuit includespower transistor means which controls grid current to vary the efficiency of said oscillator means between limits determined by commanded RF output power.
- An inductively coupled plasma generator in accordance with claim 6 wherein said load means comprisesa glass torch,a load coil disposed about said glass torch,first and second series connected capacitors connected in parallel to said load coil to form a resonant circuit therewith connected between said plate and cathode of said triode.
- An inductively coupled plasma generator in accordance with claim 7 whereinsaid capacitors are of equal value and connected at their juncture to ground whereby plasma voltage is held a zero potential.
- An inductively coupled plasma generator in accordance with claim 8 wherein said fourth means is a microprocessor programmed to provide said commanded RF power.
- An inductively coupled plasma generator according to claim 9 further comprisingplate voltage supply means connected between said plate of said triode vacuum tube and said microprocessor for changing plate voltage in accordance with said commanded RF power.
- An inductively coupled plasma generator according to claim 10 wherein said first means and second means each comprise logarithmic response amplifiers and said third means comprises a summation circuit.
- An inductively coupled plasma generator according to claim 11 further comprisingprotective circuit means response to significant changes in grid current of said triode vacuum tube for disconnecting said power supply from said triode vacuum tube to prevent damage to said glass torch.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US87967892A | 1992-05-07 | 1992-05-07 | |
US879678 | 1992-05-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0568920A1 EP0568920A1 (en) | 1993-11-10 |
EP0568920B1 true EP0568920B1 (en) | 1996-03-27 |
Family
ID=25374663
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP19930106923 Expired - Lifetime EP0568920B1 (en) | 1992-05-07 | 1993-04-28 | Inductively coupled plasma generator |
Country Status (3)
Country | Link |
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EP (1) | EP0568920B1 (en) |
JP (1) | JP3167221B2 (en) |
DE (1) | DE69301952T2 (en) |
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US4500408A (en) * | 1983-07-19 | 1985-02-19 | Varian Associates, Inc. | Apparatus for and method of controlling sputter coating |
US4629940A (en) * | 1984-03-02 | 1986-12-16 | The Perkin-Elmer Corporation | Plasma emission source |
US4766287A (en) * | 1987-03-06 | 1988-08-23 | The Perkin-Elmer Corporation | Inductively coupled plasma torch with adjustable sample injector |
-
1993
- 1993-04-20 JP JP11516993A patent/JP3167221B2/en not_active Expired - Lifetime
- 1993-04-28 EP EP19930106923 patent/EP0568920B1/en not_active Expired - Lifetime
- 1993-04-28 DE DE1993601952 patent/DE69301952T2/en not_active Expired - Lifetime
Cited By (9)
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Also Published As
Publication number | Publication date |
---|---|
EP0568920A1 (en) | 1993-11-10 |
DE69301952D1 (en) | 1996-05-02 |
DE69301952T2 (en) | 1996-08-08 |
JP3167221B2 (en) | 2001-05-21 |
JPH0620793A (en) | 1994-01-28 |
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