EP0563313A1 - Selectively weakened cores for core wound paper products. - Google Patents

Selectively weakened cores for core wound paper products.

Info

Publication number
EP0563313A1
EP0563313A1 EP92904115A EP92904115A EP0563313A1 EP 0563313 A1 EP0563313 A1 EP 0563313A1 EP 92904115 A EP92904115 A EP 92904115A EP 92904115 A EP92904115 A EP 92904115A EP 0563313 A1 EP0563313 A1 EP 0563313A1
Authority
EP
European Patent Office
Prior art keywords
core
weakening
flattened
compressive forces
flattened core
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP92904115A
Other languages
German (de)
French (fr)
Other versions
EP0563313B1 (en
Inventor
Donald David Dearwester
Stephen Kreg Newby
James Lee Swanson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of EP0563313A1 publication Critical patent/EP0563313A1/en
Application granted granted Critical
Publication of EP0563313B1 publication Critical patent/EP0563313B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65HHANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H75/00Storing webs, tapes, or filamentary material, e.g. on reels
    • B65H75/02Cores, formers, supports, or holders for coiled, wound, or folded material, e.g. reels, spindles, bobbins, cop tubes, cans, mandrels or chucks
    • B65H75/18Constructional details
    • B65H75/22Constructional details collapsible; with removable parts
    • B65H75/2209Constructional details collapsible; with removable parts collapsible by use of hinged or slidable parts; foldable without removing parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65HHANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H75/00Storing webs, tapes, or filamentary material, e.g. on reels
    • B65H75/02Cores, formers, supports, or holders for coiled, wound, or folded material, e.g. reels, spindles, bobbins, cop tubes, cans, mandrels or chucks
    • B65H75/04Kinds or types
    • B65H75/08Kinds or types of circular or polygonal cross-section
    • B65H75/10Kinds or types of circular or polygonal cross-section without flanges, e.g. cop tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65HHANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H2701/00Handled material; Storage means
    • B65H2701/50Storage means for webs, tapes, or filamentary material
    • B65H2701/51Cores or reels characterised by the material
    • B65H2701/511Cores or reels characterised by the material essentially made of sheet material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65HHANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H2701/00Handled material; Storage means
    • B65H2701/50Storage means for webs, tapes, or filamentary material
    • B65H2701/53Adaptations of cores or reels for special purposes
    • B65H2701/532Tearable or frangible cores or reels

Definitions

  • This invention relates to a core for core wound products, particularly to a core which has been flattened or compressed to minimize its void space, and more particularly to a flattened core having a means for rerounding the core to more nearly its
  • Core wound paper products such as toilet tissue and paper towels, are well known in the art and are highly useful consumer products. Such products comprise a core about which layers of the
  • the core may be, and frequently is, inserted onto a spindle for convenient temporary storage of the paper product and for removal of the paper product from the core and from the balance of the roll on demand.
  • the spindle is inserted through the center of the core and, thus, requires the
  • a preferred core shape is a cylinder having a geometrically
  • Patent 4,909,388 issued March 20, 1990, to Watanabe disclose rolls of paper product compressed to one-half to one-fifth of the original diameter of the product.
  • the cores of these products are taught to be provided with a slight elasticity to allow the cores to return from the flattened shapes, attained under compression, to the original cylindrical shape. It is generally desired, per these patents, that the flattened rolls be easily returned to their original shape.
  • U.S. Patent 1,005,787 issued October 1911 to Sibley discloses a flattened toilet paper package wound onto a hollow core made of flexible and axially corrugated paper stock.
  • the corrugated core holds the fabric and results in an oscillatory motion as the paper is removed from the roll.
  • European Patent Specification 709,363 published May 19, 1954, to Samson discloses a web of paper or pliable sheet material wound upon a core which is diametrically flattened and is said to readily resume its tubular shape when the roll is unpacked.
  • the core consists of spirally wound strips of kraft sheet material and is flexible. The flexibility is said to permit the core to be flattened without cracking and to later recover its cylindrical shape after flattening.
  • U.S. Patent 4,886,167 issued December 12, 1989, to Dearwester discloses unilaterally compressed toilet tissue having flattened cores with little to no void space illustrated between the diametrically opposed faces of the flattened core cross-section.
  • the Dearwester patent is incorporated herein by reference for the purpose of showing particularly preferred compact, compressed rolls of toilet tissue and paper towels.
  • the foregoing teachings suffer from the drawback that upon rerounding, diametrically opposed creases frequently occur throughout the core and prevent the desired cylindrical shape from being obtained. These creases frequently cause the core to fit poorly on a spindle, and thereby, results in an inconvenience to the user each time such a core is inserted onto, used whileon, or removed from a spindle.
  • non-round cross-section of such a core may prevent easy removal of the paper product from the remainder of the roll, resulting in further inconvenience to the user each time a sheet or a larger portion of the paper product is desired.
  • a core having a nonround cross section is also typically noisier during dispensing.
  • One attempt to overcome the problems associated with core flattening is to prevent such flattening, as disclosed in U.S. Patent 2,659,543 issued November 17, 1953, to Guyer, which patent suggests a way to maintain the original core shape.
  • This patent teaches a core for tape products having at least one axially oriented groove or slot disposed along the outside of the core at uniform intervals around its circumference.
  • the subject of this invention to provide a core having a means for flattening and rerounding the core in a manner more convenient to the user and which will precisely and repeatedly cause the core to more nearly resume its original shape.
  • the present invention comprises a flattened core about which a core wound paper product is wound to comprise a roll of the paper product.
  • the flattened core has an inner circumference, an outer circumference, and two oppositely disposed ends defining a longitudinal axis.
  • the flattened core is capable of approximating a circular cross section, upon rerounding.
  • the core further comprises at least one axially oriented means for weakening the resistance of the core to applied compressive forces.
  • the weakening means is disposed on at least one of the inner circumference, the outer circumference, or may intercept both the inner and outer circumferences by being through the entire thickness of the core.
  • the weakening means comprises a plurality of axially oriented continuous score lines.
  • the weakening means comprises a plurality of axially oriented perforations.
  • the weakening means comprises a plurality of axially oriented holes.
  • the score lines, perforations, or holes may either be blind - so that only one circumference of the core is affected by the weakening means or may pass through the entire thickness of the core to intercept both the inner and outer circumferences of the core.
  • Figure 1 is a perspective view of a fl ttened core and paper product according to the present invention
  • Figure 2 is a perspective view of a core according to the present invention prior to flattening, and having a plurality of various types of axially oriented score lines disposed about the inner and outer circumferences of the core;
  • Figure 3 is a schematic plan view of a core according to the present invention when unfolded, and having five circumferentially spaced axially offset holes;
  • Figure 4 is a schematic plan view of a core according to the present invention when unfolded, and having five circumferentially spaced holes inset from each end;
  • Figure 5 is a schematic plan view of a core according to the present invention when unfolded, and having five lines of equally sized cuts and lands extending inwardly about one inch from each end the core;
  • Figure 6 is a schematic plan view of a core according to the present invention when unfolded, and having five lines of equally siz cuts and lands penetrating only about one half the thickness of the core;
  • Figure 7 is a schematic plan view of a core according to the present invention when unfolded, and having five lines of perforations with cuts one-third the length of the lands;
  • Figure 8 is a schematic plan view of a core according to the present invention when unfolded, and having five lines of cuts terminating before intercepting either end of the core;
  • Figure 9 is a schematic plan view of a core according to the present invention when unfolded, and having five lines of cuts and lands, larger than those of either Figures 6 or 7;
  • Figure 10 is a schematic plan view of a core according to the present invention when unfolded, and having five lines of equally siz cuts and lands smaller than those of the preceding figures;
  • Figure 11 is a schematic plan view of a core according to the present invention when unfolded, and having five lines of alternately spaced cuts and lands with the cuts three times the size of the lands.
  • a "core” refers to a hollow tubular member about which another component is wound in a spiral for later dispensing and removal.
  • a “paper product” refers to a cellulosic base product wound onto the core 20 and is removed, typically, in batch form, i.e., one or more sheets at a time, for usage and eventual discard. Used paper product 24, when taken from the core 20, is not returned.
  • a “roll” refers to the aggregation of a "core” and a “paper product” wound thereon. The roll 28 may further comprise a wrapping 32 to maintain the configuration illustrated by Figure 1.
  • a core 20, according to the present invention may advantageously be used for toilet tissue or for paper towels.
  • the core 20 is generally cylindrical prior to compression and flattening, has an axial length defined by two oppositely disposed ends.
  • the ends of the core 20 are circular in cross section prior to flattening.
  • the line connecting the centers of these circles is the "longitudinal axis" of the core 20.
  • axial refers to the longitudinal axis.
  • the resulting roll 28 of toilet tissue typically has a diameter of about 10.2 centimeters to about 12.7 centimeters (4.00 to 5.00 inches) and a length of about 11.4 centimeters (4.50 inches) between the ends.
  • the roll 28 of paper towels typically has a diameter of about 10.2 to about 15.2 centimeters (4.00 to 6.00 inches) and a length of about 27.9 centimeters (11.0 inches) for the embodiments described herein.
  • the typical core 20 may be made of two layers of a paper having any suitable combination of bleached krafts, sulfites, hardwoods, softwoods, and recycled fibers.
  • the core 20 should exhibit uniform strength without weak spots.
  • the core 20 is not calendered, so that it is relatively stiff and retains adhesive deposited thereon.
  • the core 20 should have a mullen strength of at least 60 and preferably at least 70 as measured according to ASTM Test Method D2529.
  • the core 20 may have a thickness of about 0.5 millimeters (0.020 inch).
  • the core 20 should be free of objectionable odor and impurities or contaminates which may cause irritation to the skin.
  • the core 20 may be made of paper having a basis weight of about 0.16 kilograms per square meter (0.032 pounds per square foot) and a ring crush strength of at least 6.79 kilograms per centimeter (38 pounds per inch) and preferably at least 8.93 kilograms per centimeter (50 pounds per inch) as measured according to Tappi Standard T8180M—87.
  • the core 20 according to the present invention is provided with at least one means 36 for selectively weakening the resistance of the core 20 to compressive forces, and more particularly to diametrically applied compressive forces.
  • the diametrically applied compressive forces may occur at any point along, or throughout the entire axis of, the core 20.
  • diametrically applied compressive forces refer to opposed compressive forces applied at any diameter of any cross section of the core 20. It is, of course, to be recognized that compressive forces may be applied, along a chord of the cross section and not be coincident a diameter. However, the principles involved in such application are substantially similar to those of diametrically applied compressive forces and, will not be further distinguished or repeated.
  • the cross section of the flattened core 20 of Figure 1 has a major axis a-a, and a mutually orthogonal minor axis i-i.
  • the major axis a-a and minor axis i-i of the cross section are transverse and orthogonal the longitudinal axis of the core 20.
  • the major axis a-a is aligned with the longest dimension of the cross section of the paper product 24 when flattened, and the minor axis i-i is the perpendicular bisector thereto. It has been found that at least one circumferentially disposed means 36 for weakening the resistance of the core 20 to applied compressive forces is required.
  • each means 36 for weakening the resistance of the core 20 to applied compressive forces is equally circumferentially spaced from the adjacent means 36 for weakening the resistance of the core 20 to applied compressive forces, so that the cross section of the core 20 more nearly approaches a circle than an irregular polygon upon rerounding.
  • the azimuthal orientation of the major and minor axes a-a and i-i of the flattened core 20 can be predetermined by the circumferential disposition and spacing of the means 36 for weakening the resistance of the core 20 to applied compressive forces. If the core 20 is provided with two diametrically opposed means 36 for weakening the resistance of the core 20 to applied compressive forces, and if the diameter along which the compressive forces are applied is about 90 * relative to the two means 36 for weakening the resistance of the core 20 to applied compressive forces, the core 20 will generally flatten at the two means 36 for weakening the resistance of the core 20 to applied compressive forces.
  • the resulting flattened core 20 will have a major axis a-a with two vertices, one located at each end of the major axis a-a and corresponding to the means 36 for weakening the resistance of the core 20 to applied compressive forces. Therefore, preferably, an even number of means 36 for weakening the resistance of the core 20 to applied compressive forces is provided, so that each means 36 for weakening the resistance of the core 20 to applied compressive forces is diametrically opposed to another means 36 for weakening the resistance of the core 20 to applied compressive forces.
  • the core 20 upon rerounding the core 20 will not approximate its original cylindrical shape, due to the two vertices maintain the cross section of the core 20 in a somewhat doubly convex shape. Additional circumferentially disposed means 36 for weakening the resistance of the core 20 to applied compressive forces are needed to provide additional vertices.
  • the core 20 Upon rerounding, the core 20 will assume a polygonal cross section, corresponding in number of sides to the number of vertices, each vertex corresponding to a particular individual means 36 for weakening the resistance of the core 20 to applied compressive forces.
  • At least one, and even a plurality of two means 36 for weakening the resistance of the core 20 to applied compressive forces is inadequate due to the resulting doubly convex shape upon attempted rerounding. If four means 36 for weakening the resistance of the core 20 to applied compressive forces are provided, the core 20 rerounds to a generally square cross section and has a hollow hexahedronal shape. Such a core 20, when attempted to be rerounded, suffers from excessive wobble and noise on the spindle and is, therefore, generally not preferred.
  • Two means 36 for weakening the resistance of the core 20 to applied compressive forces occur at each end of the major axis a-a of the core 20 when it is flattened.
  • Two means 36 for weakening the resistance of the-core 20 to applied compressive forces are disposed on each side of the flattened core 20, straddling the minor axis i-i and juxtaposed with the two means 36 for weakening the resistance of the core 20 to applied compressive forces on the other side of the flattened core 20.
  • This core 20 rerounds to a hexagonal cross section and exhibits less wobble and noise during dispensing.
  • a core 20 having eight, ten, or twelve equally spaced means 36 for weakening the resistance of the core 20 to applied compressive forces is undesirable due t ⁇ -natural tendency of the core 20 to reform to a quadrilaterally shaped cross section. Also this structure requires two stages of rerounding, further inconveniencing the user.
  • a particularly preferred means 36 for weakening the resistance of the core 20 to applied compressive forces is a continuous axially oriented score line.
  • the score line is preferably parallel to the axis of the core 20, but prophetically may wrap the core 20 in a helical shape, if desired.
  • a means 36 for weakening the resistance of the core 20 to applied compressive forces is considered to be "axially oriented" if a line drawn through the weakening means 36 forms an included angle less than ⁇ 45 * of the longitudinal axis of the core 20.
  • the score lines may be disposed on either the inner or outer circumference of the core 20. It will be apparent, that if a plurality of score lines is provided, the plurality may be divided between the inner and outer circumferences of the core 20.
  • score lines are inclusive of lines of compression, and, preferably, lines defined by material removed from the core 20.
  • the score lines may be made by a scoring rule or a rotary die and preferably penetrate about 25 percent to about 100 percent of the thickness of the core 20.
  • the score lines preferably extend between and to both ends of the core 20.
  • the means 36 for weakening the resistance of the core 20 to applied compressive forces such as a score line, may be continuous, discontinuous or intermittent and may resemble discrete holes or perforations. The discrete holes or perforations may, but need not, extend to each end of the core 20 and may be axial y offset from the ends, of the core 20.
  • Table I represents one sample, which was prepared from commercially available Charmin brand toilet tissue made and sold by the Procter & Gamble Company of Cincinnati, Ohio.
  • the cores 20 were removed from the roll 28 of paper product 24, provided with the designated means 36 for weakening the resistance of the core 20 to applied compressive forces, and inserted back into the center of the paper product 24 to complete the roll 28.
  • Each roll 28 of paper product 24 was then diametrically compressed along the minor axis i-i with a force of about 36 kilograms (80 pounds).
  • the rolled paper products 24 were then aged for a period of about four weeks at about 50% relative humidity and 72'F.
  • a minimum two week aging period is considered necessary to allow any memory or resiliency of the core 20 to be developed, so that storage and shipping conditions are approximated and accurate data are obtained when the sample is later rerounded.
  • An aging period of less than about two weeks is considered unsatisfactory, as the results obtained may not approximate that seen in actual practice when the product is made, warehoused, shipped to the point of purchase, purchased, taken to the consumer's home, and finally installed onto a spindle and used.
  • Each core 20 was made of the aforementioned materials and is about 11.43 centimeters (4.5 inches) in length. The samples of
  • Figures 3-10 were provided with six equally spaced means 36 for weakening the resistance of the core 20 to applied compressive forces, one through-cut for opening the core 20 and five means 36 for weakening the resistance of the core 20 to applied compressive forces as described below.
  • the first column of Table I provides a plan view illustration of the described means 36 for weakening the resistance of the core 20 to applied compressive forces.
  • the fifth means 36 for weakening the resistance of the core 20 to applied compressive forces are described.
  • the cores 20 had to be slit and opened as illustrated in the plan views of Figures 3-10 to install the described weakening means 36 for a total of six means 36 for selectively weakening the resistance of the core 20 to applied compressive forces.
  • the through slit was reclosed with adhesive tape and the core 20 compressed, so that upon flattening the major axis a-a intercepted the taped slit and one of the described weakening means 36.
  • the aforementioned through slit would be replaced by a means 36 for weakening the resistance of the core 20 to applied compressive forces which is similar to the other five as described, so that all six means 36 for weakening the resistance of the core 20 to applied compressive forces are identical.
  • the percentage of the perforated or cut surface area listed in the third column of Table I is the percentage of axial linear dimension affected by the means 36 for weakening the resistance of the core 20 to applied compressive forces.
  • Each core 20 had a total linear dimension of about 68.8 centimeters (27.1 inches) (6 lines x 4.5 inches).
  • the longitudinal axial distribution of the weakening means 36 is listed as either end-to-end and extending throughout the entire length of the core 20, centered and not intercepting the ends, or endwise and starting at both ends, but not meeting in the center.
  • the vertex forming effect of the weakening means 36 in the fifth column of Table I was judged to be low ("L"), medium (“M”), or high (“H"), based upon subjective judgment when trying to reround the core 20 to its original cylindrical condition.
  • a sample was judged to be low in vertex forming effect if no distinct vertices were observed upon rerounding.
  • a sample was judged to be medium in vertex forming effect if a change in the direction of curvature was apparent at one or more of the vertices.
  • a sample was judged to be high in vertex forming effect if the vertices formed corners at the means 36 for weakening the resistance of the core 20 to applied compressive forces.
  • the sample of Figure 3 was provided with five holes, approximately 6.4 millimeters diameter (0.25 inches). Each hole is axially offset from the circumferentially adjacent hole by approximately one-fifth of the length of the core 20.
  • the sample of Figure 4 was provided with ten circumferentially spaced holes having a diameter of approximately 6.4 mm (0.25 inch), five at each end of the core 20. Each of the five holes was in the same plane, and inset approximately one inch inward from the end of the core 20. The five holes at each end of the core 20 were axially aligned with the mutually opposite five holes at the other end of the core 20.
  • the sample of Figure 5 was perforated from each end towards the center of the core 20 with alternating one millimeter (0.04 inches) cuts 40 and one millimeter (0.04 inch) lands 44.
  • the perforations extended inwardly about 2.54 centimeters (1 inch) from each end of the core 20.
  • The_sample of Figure 6 was perforated with alternating one millimeter (0.04 inch) cuts 40 and one millimeter (0.04 inch) lands 44.
  • The. cuts 40 are made from the inside circumference through one half the thickness of the core 20.
  • the percentage of effective surface area for Figure 6 was halved, to account for the fact that the perforation only affects one half of the total thickness of the core 20.
  • the sample of Figure 7 was perforated with alternating two millimeter (0.08 inch) cuts 40 and six millimeter (0.24 inch) lands 44.
  • the cuts 40 and lands 44 extend throughout the entire length of the core 20.
  • the sample, of Figure 8 was provided with double cuts 40 about 2.54 centimeters (1.0 inch) in length.
  • the cuts 40 were axially ter inated about 1.27 centimeters (0.5 inch) inwardly from each end.
  • the sample of Figure 9 was perforated with alternating 9.6 millimeters (0.38 inch) cuts 40 and 9.6 millimeters (0.38 inch) lands 44.
  • the perforations extend -entirely from end to end of the core 20.
  • the sample of Figure 10 was perforated with alternating one millimeter (0.04 inch) cuts 40 and one millimeter (0.04 inch) lands 44. The perforations extend from end to end of the core 20.
  • the sample of Figure 11 was provided with alternating three millimeter (0.12 inch) cuts 40 and one millimeter (0.04 inch) lands 44. The perforations extend from end to end of the core 20.

Landscapes

  • Sanitary Thin Papers (AREA)
  • Storage Of Web-Like Or Filamentary Materials (AREA)
  • Replacement Of Web Rolls (AREA)

Abstract

Mandrin pour rouleaux de produits en papier tels que le papier hygiénique ou essuie-tout. Le mandrin (20) est doté d'une pluralité de stries (36), de perforations ou de trous orientés dans le sens axial. Les stries (36), perforations ou trous sont continus et affaiblissent le mandrin de sorte que des arêtes soient formées lorsqu'on l'aplatit. Lorsque l'on restitue la forme cylindrique du mandrin (20), chaque strie (36), perforation ou trou forme une arête de manière à obtenir une section transversale prédéterminée de forme polygonale et sensiblement circulaire.Core for rolls of paper products such as toilet paper or paper towels. The mandrel (20) has a plurality of axially oriented ridges (36), perforations or holes. The ridges (36), perforations or holes are continuous and weaken the mandrel so that ridges are formed when it is flattened. When restoring the cylindrical shape of the mandrel (20), each groove (36), perforation or hole forms an edge so as to obtain a predetermined cross section of polygonal and substantially circular shape.

Description

SELECTIVELY WEAKENED CORES FOR CORE WOUND PAPER PRODUCTS
5 FIELD OF THE INVENTION
This invention relates to a core for core wound products, particularly to a core which has been flattened or compressed to minimize its void space, and more particularly to a flattened core having a means for rerounding the core to more nearly its
10 original condition.
BACKGROUND OF THE INVENTION Core wound paper products, such as toilet tissue and paper towels, are well known in the art and are highly useful consumer products. Such products comprise a core about which layers of the
15 paper product are wound. The core may be, and frequently is, inserted onto a spindle for convenient temporary storage of the paper product and for removal of the paper product from the core and from the balance of the roll on demand. The spindle is inserted through the center of the core and, thus, requires the
20 core to be open, so that the spindle may fit therethrough without encountering excessive friction or later causing difficulty in the
* dispensation of the desired paper product.
A A preferred core shape is a cylinder having a geometrically
* round cross-section, so that the core (and the paper product wound 25 thereon) freely rotates about the axis of the spindle and the paper product is easily removed from the roll. One improvement to rolls of core wound paper products is compression of the core, in a direction normal to the axis of the core, to reduce the void space in the core. This arrangement provides for convenient storage, handling and shipment of core wound paper products, due to the products may be stored and shipped more economically and in higher densities. Several attempts have been made in the art to capitalize on the benefits of compressed core wound paper products. For example, U.S. Patent 4,762,061 issued August 9, 1988, to Watanabe et al. and U. S. Patent 4,909,388 issued March 20, 1990, to Watanabe disclose rolls of paper product compressed to one-half to one-fifth of the original diameter of the product. The cores of these products are taught to be provided with a slight elasticity to allow the cores to return from the flattened shapes, attained under compression, to the original cylindrical shape. It is generally desired, per these patents, that the flattened rolls be easily returned to their original shape.
U.S. Patent 1,005,787 issued October 1911 to Sibley discloses a flattened toilet paper package wound onto a hollow core made of flexible and axially corrugated paper stock. The corrugated core holds the fabric and results in an oscillatory motion as the paper is removed from the roll. European Patent Specification 709,363 published May 19, 1954, to Samson discloses a web of paper or pliable sheet material wound upon a core which is diametrically flattened and is said to readily resume its tubular shape when the roll is unpacked. The core consists of spirally wound strips of kraft sheet material and is flexible. The flexibility is said to permit the core to be flattened without cracking and to later recover its cylindrical shape after flattening.
U.S. Patent 4,886,167 issued December 12, 1989, to Dearwester discloses unilaterally compressed toilet tissue having flattened cores with little to no void space illustrated between the diametrically opposed faces of the flattened core cross-section. The Dearwester patent is incorporated herein by reference for the purpose of showing particularly preferred compact, compressed rolls of toilet tissue and paper towels. The foregoing teachings suffer from the drawback that upon rerounding, diametrically opposed creases frequently occur throughout the core and prevent the desired cylindrical shape from being obtained. These creases frequently cause the core to fit poorly on a spindle, and thereby, results in an inconvenience to the user each time such a core is inserted onto, used whileon, or removed from a spindle. Furthermore, the non-round cross-section of such a core may prevent easy removal of the paper product from the remainder of the roll, resulting in further inconvenience to the user each time a sheet or a larger portion of the paper product is desired. A core having a nonround cross section is also typically noisier during dispensing. One attempt to overcome the problems associated with core flattening is to prevent such flattening, as disclosed in U.S. Patent 2,659,543 issued November 17, 1953, to Guyer, which patent suggests a way to maintain the original core shape. This patent teaches a core for tape products having at least one axially oriented groove or slot disposed along the outside of the core at uniform intervals around its circumference. When material is tightly wound onto the core, the grooves slightly collapse, providing relief of the compressive hoop stress induced by tight winding of the tape about the core. However, this teaching suffers from the drawback that the round cross-section of the core is maintained and the aforementioned advantages of a flattened core are lost.
What is needed, therefore, is a core which can be flattened as taught in the prior art, but more conveniently and accurately rerounded after the compressive stresses applied to the paper product are removed.
Accordingly, the subject of this invention to provide a core having a means for flattening and rerounding the core in a manner more convenient to the user and which will precisely and repeatedly cause the core to more nearly resume its original shape.
BRIEF SUMMARY OF THE INVENTION The present invention comprises a flattened core about which a core wound paper product is wound to comprise a roll of the paper product. The flattened core has an inner circumference, an outer circumference, and two oppositely disposed ends defining a longitudinal axis. The flattened core is capable of approximating a circular cross section, upon rerounding. The core further comprises at least one axially oriented means for weakening the resistance of the core to applied compressive forces. The weakening means is disposed on at least one of the inner circumference, the outer circumference, or may intercept both the inner and outer circumferences by being through the entire thickness of the core.
In one embodiment, the weakening means comprises a plurality of axially oriented continuous score lines. In a second embodiment, the weakening means comprises a plurality of axially oriented perforations. In a third embodiment, the weakening means comprises a plurality of axially oriented holes. The score lines, perforations, or holes may either be blind - so that only one circumference of the core is affected by the weakening means or may pass through the entire thickness of the core to intercept both the inner and outer circumferences of the core.
BRIEF DESCRIPTION OF THE DRAWINGS
While the Specification concludes with claims particularly pointing out and distinctly claiming the present invention, it is believed the same will be better understood from the following
Specification taken in conjunction with the associated drawings wherein like parts are given the same reference numeral, and:
Figure 1 is a perspective view of a fl ttened core and paper product according to the present invention; Figure 2 is a perspective view of a core according to the present invention prior to flattening, and having a plurality of various types of axially oriented score lines disposed about the inner and outer circumferences of the core;
Figure 3 is a schematic plan view of a core according to the present invention when unfolded, and having five circumferentially spaced axially offset holes;
Figure 4 is a schematic plan view of a core according to the present invention when unfolded, and having five circumferentially spaced holes inset from each end; Figure 5 is a schematic plan view of a core according to the present invention when unfolded, and having five lines of equally sized cuts and lands extending inwardly about one inch from each end the core;
Figure 6 is a schematic plan view of a core according to the present invention when unfolded, and having five lines of equally siz cuts and lands penetrating only about one half the thickness of the core;
Figure 7 is a schematic plan view of a core according to the present invention when unfolded, and having five lines of perforations with cuts one-third the length of the lands; Figure 8 is a schematic plan view of a core according to the present invention when unfolded, and having five lines of cuts terminating before intercepting either end of the core;
Figure 9 is a schematic plan view of a core according to the present invention when unfolded, and having five lines of cuts and lands, larger than those of either Figures 6 or 7;
Figure 10 is a schematic plan view of a core according to the present invention when unfolded, and having five lines of equally siz cuts and lands smaller than those of the preceding figures; and
Figure 11 is a schematic plan view of a core according to the present invention when unfolded, and having five lines of alternately spaced cuts and lands with the cuts three times the size of the lands.
DETAILED DESCRIPTION OF THE INVENTION As illustrated in Figure 1 and as used herein, a "core" refers to a hollow tubular member about which another component is wound in a spiral for later dispensing and removal. As used herein, a "paper product" refers to a cellulosic base product wound onto the core 20 and is removed, typically, in batch form, i.e., one or more sheets at a time, for usage and eventual discard. Used paper product 24, when taken from the core 20, is not returned. As used herein a "roll" refers to the aggregation of a "core" and a "paper product" wound thereon. The roll 28 may further comprise a wrapping 32 to maintain the configuration illustrated by Figure 1.
A core 20, according to the present invention, may advantageously be used for toilet tissue or for paper towels. The core 20 is generally cylindrical prior to compression and flattening, has an axial length defined by two oppositely disposed ends. The ends of the core 20 are circular in cross section prior to flattening. The line connecting the centers of these circles is the "longitudinal axis" of the core 20. As used herein "axial" refers to the longitudinal axis.
When toilet tissue is wound on the core 20, the resulting roll 28 of toilet tissue typically has a diameter of about 10.2 centimeters to about 12.7 centimeters (4.00 to 5.00 inches) and a length of about 11.4 centimeters (4.50 inches) between the ends. If a core 20 embodying the present invention is used for paper towels, the roll 28 of paper towels typically has a diameter of about 10.2 to about 15.2 centimeters (4.00 to 6.00 inches) and a length of about 27.9 centimeters (11.0 inches) for the embodiments described herein.
The typical core 20 may be made of two layers of a paper having any suitable combination of bleached krafts, sulfites, hardwoods, softwoods, and recycled fibers. The core 20 should exhibit uniform strength without weak spots. Preferably, the core 20 is not calendered, so that it is relatively stiff and retains adhesive deposited thereon. The core 20 should have a mullen strength of at least 60 and preferably at least 70 as measured according to ASTM Test Method D2529. The core 20 may have a thickness of about 0.5 millimeters (0.020 inch). The core 20 should be free of objectionable odor and impurities or contaminates which may cause irritation to the skin.
The core 20 may be made of paper having a basis weight of about 0.16 kilograms per square meter (0.032 pounds per square foot) and a ring crush strength of at least 6.79 kilograms per centimeter (38 pounds per inch) and preferably at least 8.93 kilograms per centimeter (50 pounds per inch) as measured according to Tappi Standard T8180M—87.
The core 20 according to the present invention is provided with at least one means 36 for selectively weakening the resistance of the core 20 to compressive forces, and more particularly to diametrically applied compressive forces. The diametrically applied compressive forces may occur at any point along, or throughout the entire axis of, the core 20.
As used herein, "diametrically applied compressive forces" refer to opposed compressive forces applied at any diameter of any cross section of the core 20. It is, of course, to be recognized that compressive forces may be applied, along a chord of the cross section and not be coincident a diameter. However, the principles involved in such application are substantially similar to those of diametrically applied compressive forces and, will not be further distinguished or repeated.
Upon application of the compressive forces, the core 20 will collapse into the flattened condition of Figure 1. The cross section of the flattened core 20 of Figure 1 has a major axis a-a, and a mutually orthogonal minor axis i-i. The major axis a-a and minor axis i-i of the cross section are transverse and orthogonal the longitudinal axis of the core 20. The major axis a-a is aligned with the longest dimension of the cross section of the paper product 24 when flattened, and the minor axis i-i is the perpendicular bisector thereto. It has been found that at least one circumferentially disposed means 36 for weakening the resistance of the core 20 to applied compressive forces is required. Preferably, but not necessarily, each means 36 for weakening the resistance of the core 20 to applied compressive forces is equally circumferentially spaced from the adjacent means 36 for weakening the resistance of the core 20 to applied compressive forces, so that the cross section of the core 20 more nearly approaches a circle than an irregular polygon upon rerounding.
The azimuthal orientation of the major and minor axes a-a and i-i of the flattened core 20 can be predetermined by the circumferential disposition and spacing of the means 36 for weakening the resistance of the core 20 to applied compressive forces. If the core 20 is provided with two diametrically opposed means 36 for weakening the resistance of the core 20 to applied compressive forces, and if the diameter along which the compressive forces are applied is about 90* relative to the two means 36 for weakening the resistance of the core 20 to applied compressive forces, the core 20 will generally flatten at the two means 36 for weakening the resistance of the core 20 to applied compressive forces.
The resulting flattened core 20 will have a major axis a-a with two vertices, one located at each end of the major axis a-a and corresponding to the means 36 for weakening the resistance of the core 20 to applied compressive forces. Therefore, preferably, an even number of means 36 for weakening the resistance of the core 20 to applied compressive forces is provided, so that each means 36 for weakening the resistance of the core 20 to applied compressive forces is diametrically opposed to another means 36 for weakening the resistance of the core 20 to applied compressive forces.
However, upon rerounding the core 20 will not approximate its original cylindrical shape, due to the two vertices maintain the cross section of the core 20 in a somewhat doubly convex shape. Additional circumferentially disposed means 36 for weakening the resistance of the core 20 to applied compressive forces are needed to provide additional vertices. Upon rerounding, the core 20 will assume a polygonal cross section, corresponding in number of sides to the number of vertices, each vertex corresponding to a particular individual means 36 for weakening the resistance of the core 20 to applied compressive forces.
As noted above, at least one, and even a plurality of two means 36 for weakening the resistance of the core 20 to applied compressive forces is inadequate due to the resulting doubly convex shape upon attempted rerounding. If four means 36 for weakening the resistance of the core 20 to applied compressive forces are provided, the core 20 rerounds to a generally square cross section and has a hollow hexahedronal shape. Such a core 20, when attempted to be rerounded, suffers from excessive wobble and noise on the spindle and is, therefore, generally not preferred.
A core 20 having six means 36 for weakening the resistance of the core 20 to applied compressive forces, each equally circumferentially spaced (on increments of about 60* or a multiple thereof) from the adjacent means 36 for weakening the resistance of the core 20 to applied compressive forces, works well. Two means 36 for weakening the resistance of the core 20 to applied compressive forces occur at each end of the major axis a-a of the core 20 when it is flattened. Two means 36 for weakening the resistance of the-core 20 to applied compressive forces are disposed on each side of the flattened core 20, straddling the minor axis i-i and juxtaposed with the two means 36 for weakening the resistance of the core 20 to applied compressive forces on the other side of the flattened core 20. This core 20 rerounds to a hexagonal cross section and exhibits less wobble and noise during dispensing.
A core 20 having eight, ten, or twelve equally spaced means 36 for weakening the resistance of the core 20 to applied compressive forces is undesirable due tσ-natural tendency of the core 20 to reform to a quadrilaterally shaped cross section. Also this structure requires two stages of rerounding, further inconveniencing the user.
As illustrated in Figure 2, a particularly preferred means 36 for weakening the resistance of the core 20 to applied compressive forces is a continuous axially oriented score line. The score line is preferably parallel to the axis of the core 20, but prophetically may wrap the core 20 in a helical shape, if desired. A means 36 for weakening the resistance of the core 20 to applied compressive forces is considered to be "axially oriented" if a line drawn through the weakening means 36 forms an included angle less than ± 45* of the longitudinal axis of the core 20.
The score lines may be disposed on either the inner or outer circumference of the core 20. It will be apparent, that if a plurality of score lines is provided, the plurality may be divided between the inner and outer circumferences of the core 20.
As used herein, "score lines" are inclusive of lines of compression, and, preferably, lines defined by material removed from the core 20. The score lines may be made by a scoring rule or a rotary die and preferably penetrate about 25 percent to about 100 percent of the thickness of the core 20. The score lines preferably extend between and to both ends of the core 20. If desired, the means 36 for weakening the resistance of the core 20 to applied compressive forces, such as a score line, may be continuous, discontinuous or intermittent and may resemble discrete holes or perforations. The discrete holes or perforations may, but need not, extend to each end of the core 20 and may be axial y offset from the ends, of the core 20.
For example, referring to Figures 3-10, in turn, eight nonli iting examples are provided, illustrating various means 36 for weakening the resistance of the core 20 to applied compressive forces. One sample of each example is tabulated in Table I, to provide for easy comparison of the effect of the parameters listed in Table I on the attempted rerounding.
Each row in Table I represents one sample, which was prepared from commercially available Charmin brand toilet tissue made and sold by the Procter & Gamble Company of Cincinnati, Ohio. The cores 20 were removed from the roll 28 of paper product 24, provided with the designated means 36 for weakening the resistance of the core 20 to applied compressive forces, and inserted back into the center of the paper product 24 to complete the roll 28. Each roll 28 of paper product 24 was then diametrically compressed along the minor axis i-i with a force of about 36 kilograms (80 pounds).
The rolled paper products 24 were then aged for a period of about four weeks at about 50% relative humidity and 72'F. A minimum two week aging period is considered necessary to allow any memory or resiliency of the core 20 to be developed, so that storage and shipping conditions are approximated and accurate data are obtained when the sample is later rerounded. An aging period of less than about two weeks is considered unsatisfactory, as the results obtained may not approximate that seen in actual practice when the product is made, warehoused, shipped to the point of purchase, purchased, taken to the consumer's home, and finally installed onto a spindle and used.
Each core 20 was made of the aforementioned materials and is about 11.43 centimeters (4.5 inches) in length. The samples of
Figures 3-10 were provided with six equally spaced means 36 for weakening the resistance of the core 20 to applied compressive forces, one through-cut for opening the core 20 and five means 36 for weakening the resistance of the core 20 to applied compressive forces as described below.
The first column of Table I provides a plan view illustration of the described means 36 for weakening the resistance of the core 20 to applied compressive forces. In the second column of Table I, the five means 36 for weakening the resistance of the core 20 to applied compressive forces are described. However, for these samples the cores 20 had to be slit and opened as illustrated in the plan views of Figures 3-10 to install the described weakening means 36 for a total of six means 36 for selectively weakening the resistance of the core 20 to applied compressive forces.
Whenever five described weakening means 36 were utilized with one continuous through slit, the through slit was reclosed with adhesive tape and the core 20 compressed, so that upon flattening the major axis a-a intercepted the taped slit and one of the described weakening means 36. In practice, the aforementioned through slit would be replaced by a means 36 for weakening the resistance of the core 20 to applied compressive forces which is similar to the other five as described, so that all six means 36 for weakening the resistance of the core 20 to applied compressive forces are identical.
The percentage of the perforated or cut surface area listed in the third column of Table I is the percentage of axial linear dimension affected by the means 36 for weakening the resistance of the core 20 to applied compressive forces. Each core 20 had a total linear dimension of about 68.8 centimeters (27.1 inches) (6 lines x 4.5 inches). In the fourth column the longitudinal axial distribution of the weakening means 36 is listed as either end-to-end and extending throughout the entire length of the core 20, centered and not intercepting the ends, or endwise and starting at both ends, but not meeting in the center.
The vertex forming effect of the weakening means 36 in the fifth column of Table I was judged to be low ("L"), medium ("M"), or high ("H"), based upon subjective judgment when trying to reround the core 20 to its original cylindrical condition. A sample was judged to be low in vertex forming effect if no distinct vertices were observed upon rerounding. A sample was judged to be medium in vertex forming effect if a change in the direction of curvature was apparent at one or more of the vertices. A sample was judged to be high in vertex forming effect if the vertices formed corners at the means 36 for weakening the resistance of the core 20 to applied compressive forces.
The sample of Figure 3 was provided with five holes, approximately 6.4 millimeters diameter (0.25 inches). Each hole is axially offset from the circumferentially adjacent hole by approximately one-fifth of the length of the core 20.
The sample of Figure 4 was provided with ten circumferentially spaced holes having a diameter of approximately 6.4 mm (0.25 inch), five at each end of the core 20. Each of the five holes was in the same plane, and inset approximately one inch inward from the end of the core 20. The five holes at each end of the core 20 were axially aligned with the mutually opposite five holes at the other end of the core 20.
The sample of Figure 5 was perforated from each end towards the center of the core 20 with alternating one millimeter (0.04 inches) cuts 40 and one millimeter (0.04 inch) lands 44. The perforations extended inwardly about 2.54 centimeters (1 inch) from each end of the core 20.
The_sample of Figure 6 was perforated with alternating one millimeter (0.04 inch) cuts 40 and one millimeter (0.04 inch) lands 44. The. cuts 40 are made from the inside circumference through one half the thickness of the core 20. The percentage of effective surface area for Figure 6 was halved, to account for the fact that the perforation only affects one half of the total thickness of the core 20.
The sample of Figure 7 was perforated with alternating two millimeter (0.08 inch) cuts 40 and six millimeter (0.24 inch) lands 44. The cuts 40 and lands 44 extend throughout the entire length of the core 20. The sample, of Figure 8 was provided with double cuts 40 about 2.54 centimeters (1.0 inch) in length. The cuts 40 were axially ter inated about 1.27 centimeters (0.5 inch) inwardly from each end.
The sample of Figure 9 was perforated with alternating 9.6 millimeters (0.38 inch) cuts 40 and 9.6 millimeters (0.38 inch) lands 44. The perforations extend -entirely from end to end of the core 20.
The sample of Figure 10 was perforated with alternating one millimeter (0.04 inch) cuts 40 and one millimeter (0.04 inch) lands 44. The perforations extend from end to end of the core 20. The sample of Figure 11 was provided with alternating three millimeter (0.12 inch) cuts 40 and one millimeter (0.04 inch) lands 44. The perforations extend from end to end of the core 20.
TABLE I
Percentage of Axial
spaced inwardly 0.5 in. from ea. end
0.38 in. cut, 0.38 in. 50 end-to-end land
10 1 mm cut, 1 mm land 50 end-to-end
11 3 mm cut, 1 mm land 75 end-to-end As can be seen from- Table I, generally as the samples had less than about 20% of the axial dimension effected by the means 36 for weakening the resistance of the core 20 to applied compressive forces, the vertex forming effect was judged to be low. As the percentage of perforated or cut area affected by the means 36 for weakening the resistance of the core 20 to applied compressive forces approaches 20% to 45%, the vertex forming effect was judged to be medium, relative to the other samples. As the percentage of perforated or cut area effected by the means 36 for weakening the resistance of the core 20 to applied compressive forces increases above 50%, the vertex forming effect was judged to be high. However, all samples were placed on a spindle and then dispensed. All samples were judged to be superior to a control sample (having no means 36 for weakening the resistance of the core 20 to applied compressive forces) in both noise and in smooth, uninterrupted dispensing.

Claims

1. A flattened core about which a paper product may be wound, and having an inner surface, an outer surface, and two oppositely disposed ends defining a longitudinal axis, said flattened core being capable of approximating a tubular cross-section, the improve¬ ment comprising: an axially oriented means for weakening the resis¬ tance of said core to applied radially compressive forces, said weakening means being disposed on at least one of said inner surface and said outer surface of said flattened core and locally reducing the thickness thereof.
2. A flattened core about which a paper product may be wound, and having an inner surface, an outer surface, and two oppositely disposed ends defining a longitudinal axis, said flattened core being capable of approximating a tubular cross-section, the improve¬ ment comprising: means for weakening the resistance of said core to applied radially compressive forces, said weakening means comprising a plurality of axially oriented perforations on one said surface of said flattened core.
3. A flattened core about which a paper product may be wound, and having an inner surface, an outer surface, and two oppositely disposed ends defining a longitudinal axis, said fl-attened core being capable of approximating a tubular cross-section, the improve¬ ment comprising: means for weakening the resistance of the core to applied radially compressive forces, said weakening means comprising at least one axially oriented score line disposed along at least one of said inner surface and said outer surface of said flattened core.
4. A flattened core according to Claim 1 characterized in that said weakening means comprises a plurality of holes, said holes being distributed in a plurality of axially oriented lines.
5. A flattened core according to Claim 3 characterized in that said score lines are substantially continuous and disposed along said outer surface of said flattened core.
6. A flattened core according to Claims 1, 2 and 3 characterized in that said weakening means is oriented at an angle of 0* to 45* from said longitudinal axis.
7. A flattened core according to Claim 6 characterized in that said weakening means is substantially parallel said longitudinal axis.
8. A flattened core according to Claims 1, 2 and_3 having a weakening means intermediate said oppositely disposed ends and which do not intercept either end of said flattened core.
9. A flattened core according to Claims 1, 2, and 3 characterized in that each of said plurality of score lines is substantially equally circumferentially spaced about said longitudinal axis when said core is rerounded to a circular cross section.
10. A flattened core according to Claim 9 characterized in that said plurality of score lines is six.
EP92904115A 1990-12-19 1991-12-11 Selectively weakened cores for core wound paper products Expired - Lifetime EP0563313B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US62980890A 1990-12-19 1990-12-19
US629808 1990-12-19
PCT/US1991/009398 WO1992011196A1 (en) 1990-12-19 1991-12-11 Selectively weakened cores for core wound paper products

Publications (2)

Publication Number Publication Date
EP0563313A1 true EP0563313A1 (en) 1993-10-06
EP0563313B1 EP0563313B1 (en) 1995-02-15

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JP (1) JP3014449B2 (en)
CN (1) CN1029110C (en)
AR (1) AR247868A1 (en)
AT (1) ATE118457T1 (en)
AU (1) AU9174991A (en)
CA (1) CA2096976C (en)
DE (1) DE69107479T2 (en)
DK (1) DK0563313T3 (en)
ES (1) ES2068028T3 (en)
GR (1) GR3015070T3 (en)
HK (1) HK1006163A1 (en)
MX (1) MX9102674A (en)
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WO (1) WO1992011196A1 (en)

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Publication number Priority date Publication date Assignee Title
US5318235A (en) * 1992-12-08 1994-06-07 The Procter & Gamble Company Cores for compressed core wound paper products
US5255865A (en) * 1992-12-08 1993-10-26 The Procter & Gamble Company Cores providing reduced spindle clearance for core wound paper products
GB9606505D0 (en) * 1996-03-28 1996-06-05 Bpb Industries Plc Tube
IES78618B2 (en) * 1997-02-06 1998-02-25 Amakane Ltd Improvements in and relating to inserts for use with compressed core wound paper products
ITBO970416A1 (en) * 1997-07-08 1999-01-08 Goffredo Papeschi TUBULAR CORE FOR SUPPORTING PAPER REELS OR WINDABLE MATERIALS IN THE FORM OF FILM.
DE10119460B4 (en) * 2001-04-17 2004-09-16 Sca Hygiene Products Gmbh Method and device for winding a material web onto a sleeve serving as a winding core
JP5496447B2 (en) * 2007-09-19 2014-05-21 大王製紙株式会社 Toilet roll, toilet roll product, and method of manufacturing toilet roll
JPWO2018230629A1 (en) * 2017-06-14 2020-04-23 日立化成株式会社 Wrap film winding body, wrap film container, and manufacturing method thereof

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US1005787A (en) * 1909-06-02 1911-10-10 Stephen J Sibley Fabric-package.
US2659543A (en) * 1950-09-21 1953-11-17 Sonoco Products Co Winding core
GB709363A (en) * 1952-11-17 1954-05-19 Theodore Samson Improvements in or relating to toilet rolls or the like
US4909388A (en) * 1983-05-24 1990-03-20 Kouzou Watanabe Compressed roll paper, method of and apparatus for producing same
FI860416A (en) * 1986-01-29 1987-07-30 Spirolit Ab Oy HYLSA OCH FOERFARANDE FOER FRAMSTAELLNING AV DENSAMMA.
US4886167B1 (en) * 1989-04-14 1991-06-11 Compact,core-wound paper product

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CA2096976A1 (en) 1992-06-20
AU9174991A (en) 1992-07-22
JP3014449B2 (en) 2000-02-28
CN1063263A (en) 1992-08-05
MX9102674A (en) 1992-10-01
DK0563313T3 (en) 1995-04-10
EP0563313B1 (en) 1995-02-15
DE69107479D1 (en) 1995-03-23
ATE118457T1 (en) 1995-03-15
CN1029110C (en) 1995-06-28
AR247868A1 (en) 1995-04-28
JPH06503794A (en) 1994-04-28
ES2068028T3 (en) 1995-04-01
HK1006163A1 (en) 1999-02-12
GR3015070T3 (en) 1995-05-31
TR25560A (en) 1993-07-01
DE69107479T2 (en) 1995-08-17
CA2096976C (en) 1998-08-18
WO1992011196A1 (en) 1992-07-09

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