EP0524282A1 - Device for use in installations for preparing gas mixtures for analysis - Google Patents

Device for use in installations for preparing gas mixtures for analysis

Info

Publication number
EP0524282A1
EP0524282A1 EP92903568A EP92903568A EP0524282A1 EP 0524282 A1 EP0524282 A1 EP 0524282A1 EP 92903568 A EP92903568 A EP 92903568A EP 92903568 A EP92903568 A EP 92903568A EP 0524282 A1 EP0524282 A1 EP 0524282A1
Authority
EP
European Patent Office
Prior art keywords
gas
filter
coagulation
container
vessel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP92903568A
Other languages
German (de)
French (fr)
Inventor
Eckhard Aidam
Günter Meister
Klaus Wendt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Original Assignee
Siemens AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens AG filed Critical Siemens AG
Publication of EP0524282A1 publication Critical patent/EP0524282A1/en
Withdrawn legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004—Gaseous mixtures, e.g. polluted air
    • G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0011—Sample conditioning
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/02—Devices for withdrawing samples
    • G01N1/22—Devices for withdrawing samples in the gaseous state
    • G01N1/2247—Sampling from a flowing stream of gas
    • G01N1/2258—Sampling from a flowing stream of gas in a stack or chimney
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/02—Devices for withdrawing samples
    • G01N1/22—Devices for withdrawing samples in the gaseous state
    • G01N1/2202—Devices for withdrawing samples in the gaseous state involving separation of sample components during sampling
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/02—Devices for withdrawing samples
    • G01N1/22—Devices for withdrawing samples in the gaseous state
    • G01N1/24—Suction devices
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
    • G01N1/40—Concentrating samples
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/02—Devices for withdrawing samples
    • G01N1/22—Devices for withdrawing samples in the gaseous state
    • G01N1/2202—Devices for withdrawing samples in the gaseous state involving separation of sample components during sampling
    • G01N2001/222—Other features
    • G01N2001/2223—Other features aerosol sampling devices
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/02—Devices for withdrawing samples
    • G01N1/22—Devices for withdrawing samples in the gaseous state
    • G01N1/2247—Sampling from a flowing stream of gas
    • G01N1/2258—Sampling from a flowing stream of gas in a stack or chimney
    • G01N2001/2261—Sampling from a flowing stream of gas in a stack or chimney preventing condensation (heating lines)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Definitions

  • the invention relates to a device in units for measuring gas processing for gas analysis, with a heated gas extraction, a gas cooler with condensate drainage, an aerosol filter, pumps and fine dust filters.
  • the gas mixture (sample gas) must be fed to the analyzers free of dust and condensate.
  • Filters with Teflon or ceramic inserts with a pore size of approximately 1 ⁇ m are used to separate the aerosol still present in the measuring gas after the gas cooler. If the sample gas contains a high proportion of SO, it is shown in practice that after the gas cooler and the aerosol filter, an aerosol or acid precipitate forms in the gas-carrying parts, which is removed from gas lines, gas pumps, gas flow indicators and the analysis devices at relatively short intervals must be, which creates a significant maintenance.
  • the formation of the acid precipitate in the gas lines can be explained as follows: SO ⁇ - and f- ⁇ SO ⁇ .- molecules are contained in the molecular system of a combustion exhaust gas which is approx. 200 ° C
  • the result is a disperse system in which the dispersed substance is colloidally divided oleum (concentrated sulfuric acid with sulfur trioxide dissolved in it) in the dispersing agent, the colloidal particles become larger and larger until they finally become visible deposits of oleum on the walls of the gas-carrying parts
  • oleum is extremely hygroscopic, it absorbs water vapor from the residual moisture of the gas, so that acidic liquid is formed between a few thousandths of a micron and a few microns.
  • the proportion of smallest particles apparently predominates in the combustion exhaust gases, which is why the aerosol filters used with a pore size of 1 ⁇ m are not effective.
  • the flow velocity of the gas is reduced to such an extent that it remains in the filter for a sufficiently long time so that the large effective surface area of the inner wall of the vessel and the inert shaped bodies, preferably spheres made of quartz glass, a large part of the aerosols is already separated by coagulation with the formation of acid.
  • the measuring gas can flow through the free spaces between the molded bodies unhindered, so that falsified values due to absorption of the gas components to be measured are avoided.
  • the coagulation filter can be installed in a thermostated container and there at a temperature between 280 and 300 K. being held.
  • the proportion of aerosols that is transported by the gas flow at the filter outlet has the desired property of the acid mist. This acid mist is completely filtered out in the following aerosol pore filter.
  • FIG. 1 shows a coagulation filter
  • Figure 2 shows a sample gas processing system with the built-in coagulation filter.
  • the coagulation filter KF consists of an essentially cylindrical vessel 1, the diameter D of which is a multiple of the diameter of its inlet and outlet lines 4, 5 at the end.
  • the cylindrical vessel 1 is filled with inert shaped bodies 2, here quartz glass spheres with diameters between 3 and 10 mm.
  • the length L of the vessel 1 is approximately ten times its diameter D.
  • the condensate formed in the coagulation filter KF is discharged via the condensate drain 3.
  • the gas mixture to be analyzed is removed from the exhaust gas duct by means of the gas extraction GE and fed to the measuring gas processing unit via an extraction line EL.
  • the gas extraction GE and the extraction line EL can be heated to a temperature above the acid dew point.
  • the gas coolers MK with condensate drains and the condensate pumps KP are preceded by the coagulation filter KF in the flow path of the gas.
  • Its installation position is such that the longitudinal axis of the vessel of the coagulation filter encloses an angle of 0 to 45 ', here 0 * , with the horizontal, so that the pre-condensate produced can easily drain off via the condensate breakdown 3.
  • the Koagu ⁇ correlation filter KF is the ambient temperature at the installation more than 30 * C, this can in a thermostatically controlled vessel TG at an operating temperature be- see 280 K and 300 K are held.
  • the aerosol filters AF which are arranged after the gas coolers MK in the flow path and are designed as pore filters with a pore size in the order of magnitude of I ⁇ , the remaining aerosols are separated off, so that with the help of the membrane pumps MP and the fine dust filter FF, measuring gas with the to Analysis required purity can be supplied to the analyzers I, II and III, each measuring one of the components of the sample gas.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Pathology (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Molecular Biology (AREA)
  • Biomedical Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Food Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

Dans une installation composée essentiellement de refroidisseurs de gaz à conduits d'évacuation du condensat, de filtres à aérosols, de filtres à poussières et de pompes, un filtre par coagulation (KF) composé d'un récipient cylindrique (1) rempli de billes en quartz est placé dans le trajet d'écoulement. La longueur (L) et la section (D) du récipient (1) sont établies de sorte que la vitesse moyenne d'écoulement du gaz dans le récipient soit inférieure d'au moins un ordre de grandeur décimal à sa vitesse d'écoulement dans les conduits d'amenée et d'évacuation (4, 5). De l'oléum colloïdalement dispersé se forme, à la température ambiante, avec l'humidité qui se dégage des gaz de combustion à teneur élevée en SO3. Les particules colloïdales s'agrandissent toujours davantage par association (coagulation), de sorte qu'une grande partie des aérosols se précipite déjà dans le filtre par coagulation (KF) par acidification. Lorsque la température ambiante dépasse 30 °C, le filtre par coagulation (KF) est incorporé à un récipient thermostatisé. L'invention est appliquée lors de la préparation de gaz de mesure à des fins de contrôle des valeurs d'émission de gaz de combustion.In an installation mainly composed of gas coolers with condensate drainage pipes, aerosol filters, dust filters and pumps, a coagulation filter (KF) composed of a cylindrical container (1) filled with balls quartz is placed in the flow path. The length (L) and the section (D) of the container (1) are established so that the average speed of flow of the gas in the container is at least one decimal order less than its speed of flow in the supply and evacuation conduits (4, 5). Colloidally dispersed oleum is formed at room temperature with the moisture which is released from the combustion gases with a high SO3 content. The colloidal particles always grow larger by association (coagulation), so that a large part of the aerosols is already precipitated in the filter by coagulation (KF) by acidification. When the ambient temperature exceeds 30 ° C, the coagulation filter (KF) is incorporated into a thermostatically controlled container. The invention is applied during the preparation of sample gases for the purpose of checking the emission values of combustion gases.

Description

Einrichtung in Aggregaten zur Meßgasaufbereitung für die Gas¬ analyseDevice in units for sample gas processing for gas analysis
Die Erfindung bezieht sich auf eine Einrichtung in Aggregaten zur Meßgasaufbereitung für die Gasanalyse, mit einer beheizten Gasentnahme, einem Gaskühler mit Kondensatableitung, einem Aerosolfilter, Pumpen und Staubfeinfiltern.The invention relates to a device in units for measuring gas processing for gas analysis, with a heated gas extraction, a gas cooler with condensate drainage, an aerosol filter, pumps and fine dust filters.
Zur Analyse von Gasgemischen, insbesondere von Verbrennungs- abgasen, muß das Gasgemisch (Meßgas) den Analysegeräten staub- und kondensatfrei zugeführt werden.To analyze gas mixtures, especially combustion gases, the gas mixture (sample gas) must be fed to the analyzers free of dust and condensate.
Zur Abscheidung des nach dem Gaskühler noch im Meßgas vorhan¬ denen Aerosol werden Filter mit Teflon- bzw. Keramikeinsätzen mit einer Porenweite von etwa 1 μm eingesetzt. Enthält das Meßgas einen hohen SO,-Anteil, zeigt sich in der Praxis, daß sich nach dem Gaskühler und dem Aerosolfilter ein Aerosol¬ oder Säureniederschlag in den gasführenden Teilen bildet, der in relativ kurzen Zeitabständen aus Gasleitungen, Gaspumpen, Gasströmungsanzeigern sowie den Analysegeräten entfernt werden muß, wodurch ein erheblicher Wartungsaufwand entsteht.Filters with Teflon or ceramic inserts with a pore size of approximately 1 μm are used to separate the aerosol still present in the measuring gas after the gas cooler. If the sample gas contains a high proportion of SO, it is shown in practice that after the gas cooler and the aerosol filter, an aerosol or acid precipitate forms in the gas-carrying parts, which is removed from gas lines, gas pumps, gas flow indicators and the analysis devices at relatively short intervals must be, which creates a significant maintenance.
Die Bildung des Säureniederschlags in den Gasleitungen läßt sich folgendermaßen erklären: In dem molekularen System eines ca. 200 "C heißen Verbrennungsabgases sind SO^- und f-^SO^.- Moleküle enthalten, die beim Absenken der Temperatur auf Raum¬ temperatur zusammen mit der Gasfeuchte Kolloide bilden. Es ent¬ steht so ein disperses System, worin die dispergierte Substanz kolloid zerteiltes Oleum (konzentrierte Schwefelsäure mit darin gelöstem Schwefeltrioxyd) in dem Dispersionsmittel Meßgas ist. Durch Zusammenlagerung werden die kolloiden Teilchen immer größer, bis es schließlich zur sichtbaren Ablagerung von Oleum an den Wandungen der gasführenden Teile kommt. Da Oleum außer¬ ordentlich hygroskopisch ist, nimmt es Wasserdampf aus der Restfeuchte des Gases auf, so daß sich Säureflüssigkeit bildet. Kolloide Teilchen haben nach Literaturangaben Abmessungen zwischen einigen Tausendstel Mikrometern bis zu einigen Mikro¬ metern. Bei den Verbrennungsabgasen überwiegt offenbar der Anteil kleinster Teilchen, weshalb die eingesetzten Aerosol¬ filter mit 1 μm Porenweite nicht wirksam sind.The formation of the acid precipitate in the gas lines can be explained as follows: SO ^ - and f- ^ SO ^ .- molecules are contained in the molecular system of a combustion exhaust gas which is approx. 200 ° C The result is a disperse system in which the dispersed substance is colloidally divided oleum (concentrated sulfuric acid with sulfur trioxide dissolved in it) in the dispersing agent, the colloidal particles become larger and larger until they finally become visible deposits of oleum on the walls of the gas-carrying parts Since oleum is extremely hygroscopic, it absorbs water vapor from the residual moisture of the gas, so that acidic liquid is formed between a few thousandths of a micron and a few microns. The proportion of smallest particles apparently predominates in the combustion exhaust gases, which is why the aerosol filters used with a pore size of 1 μm are not effective.
Es besteht demgemäß die Aufgabe, ein Aggregat der eingangs genannten Art so auszubauen, daß den Aerosolfiltern nur noch Säurenebel mit großen Teilchenabmessungen enthaltendes Gas¬ gemisch zugeführt wird.Accordingly, there is the task of expanding an assembly of the type mentioned at the outset in such a way that the aerosol filters are only supplied with a gas mixture containing acid mist with large particle dimensions.
Eine Lösung der Aufgabe wird in einer Einrichtung gesehen, die die Merkmale des Anspruchs 1 aufweist.A solution to the problem is seen in a device having the features of claim 1.
In dem in den Gasweg eingeschalteten Koagulationsfilter wird infolge des großen Querschnitts des zylindrischen Gefäßes, ver- glichen zum Querschnitt der Zu- und Ableitungen, die Strömungs¬ geschwindigkeit des Gases so weit verringert, daß es genügend lange in dem Filter verweilt, so daß an der großen wirksamen Oberfläche der Innenwand des Gefäßes und der inerten Formkör¬ per, vorzugsweise Kugeln aus Quarzglas, bereits ein großer Teil der Aerosole durch Koagulation unter Säurebildung abge¬ schieden wird. Durch die freien Räume zwischen den Formkδrpern kann das Meßgas ungehindert hindurchströmen, so daß Meßwert¬ verfälschungen durch Absorption der zu messenden Gaskomponenten vermieden werden. Da die Zusammenlagerung der kolloiden Teil- chen außer von der Zeit und der Gasgeschwindigkeit auch von der Temperatur abhängig ist und bei niedrigen Temperaturen be¬ günstigt wird, kann das Koagulationsfilter in einen thermosta- tisierten Behälter eingebaut und dort auf einer Temperatur zwischen 280 und 300 K gehalten werden. Der Anteil der Aerosole, der vom Gasstrom am Filteraustritt weitertransportiert wird, hat die gewünschte Eigenschaft des Säurenebels. Im nachfolgenden Aerosol-Porenfilter wird dieser Säurenebel vollständig ausgefiltert.In the coagulation filter switched into the gas path, owing to the large cross-section of the cylindrical vessel compared to the cross-section of the feed and discharge lines, the flow velocity of the gas is reduced to such an extent that it remains in the filter for a sufficiently long time so that the large effective surface area of the inner wall of the vessel and the inert shaped bodies, preferably spheres made of quartz glass, a large part of the aerosols is already separated by coagulation with the formation of acid. The measuring gas can flow through the free spaces between the molded bodies unhindered, so that falsified values due to absorption of the gas components to be measured are avoided. Since the colloidal particles are stored together not only with time and gas velocity but also with temperature and are favored at low temperatures, the coagulation filter can be installed in a thermostated container and there at a temperature between 280 and 300 K. being held. The proportion of aerosols that is transported by the gas flow at the filter outlet has the desired property of the acid mist. This acid mist is completely filtered out in the following aerosol pore filter.
Zur Erläuterung der Erfindung sind in den Figuren Ausführungs¬ beispiele dargestellt und im folgenden beschrieben. Figur 1 zeigt ein Koagulationsfilter,To explain the invention, exemplary embodiments are shown in the figures and described below. FIG. 1 shows a coagulation filter,
Figur 2 eine Meßgasaufbereitungsanlage mit dem eingebauten Koagulationsfilter.Figure 2 shows a sample gas processing system with the built-in coagulation filter.
Das Koagulationsfilter KF besteht aus einem im wesentlichen zylindrischen Gefäß 1, dessen Durchmesser D ein Mehrfaches der Durchmesser seiner endseitigen Zu- und Ableitungen 4, 5 beträgt. Das zylindrische Gefäß 1 ist mit inerten Formkörpern 2, hier Quarzglaskugeln mit Durchmessern zwischen 3 und 10 mm gefüllt. Um die geforderte Verweilzeit des Meßgases für die Koagulation der kolloiden Teilchen zu erreichen, beträgt die Länge L des Gefäßes 1 etwa das Zehnfache seines Durchmessers D. Das sich in dem Koagulationsfilter KF bildende Kondensat wird über den Kondensatablaß 3 abgeführt.The coagulation filter KF consists of an essentially cylindrical vessel 1, the diameter D of which is a multiple of the diameter of its inlet and outlet lines 4, 5 at the end. The cylindrical vessel 1 is filled with inert shaped bodies 2, here quartz glass spheres with diameters between 3 and 10 mm. In order to achieve the required residence time of the measuring gas for the coagulation of the colloidal particles, the length L of the vessel 1 is approximately ten times its diameter D. The condensate formed in the coagulation filter KF is discharged via the condensate drain 3.
Wie in Figur 2 schematisch dargestellt, wird das zu analysie¬ rende Gasgemisch, also das Meßgas, mittels der Gasentnahme GE aus dem Abgaskanal entnommen und über eine Entnahmelei-ung EL dem Meßgasaufbereitungsaggregat zugeführt. Die Gasentnahme GE und die Entnahmeleitung EL sind auf eine Temperatur oberhalb des Säuretaupunkts beheizbar.As shown schematically in FIG. 2, the gas mixture to be analyzed, that is to say the measuring gas, is removed from the exhaust gas duct by means of the gas extraction GE and fed to the measuring gas processing unit via an extraction line EL. The gas extraction GE and the extraction line EL can be heated to a temperature above the acid dew point.
Den Gaskühlern MK mit Kondensatablässen und den Kondensat¬ pumpen KP ist im Strömungsweg des Gases das Koagulationsfilter KF vorgeschaltet. Seine Einbaulage ist so, daß die Längsachse des Gefäßes des Koagulationsfilters mit der Horizontalen einen Winkel von 0 bis 45', hier 0*, einschließt, damit das entste¬ hende Vorkondensat über den Kondensatabbau 3 leicht abfließen kann. Beträgt die Umgebungstemperatur am Einbauort des Koagu¬ lationsfilters KF mehr als 30 *C, so kann dieses in einem thermostatisierten Gefäß TG auf einer Arbeitstemperatur zwi- sehen 280 K und 300 K gehalten werden.The gas coolers MK with condensate drains and the condensate pumps KP are preceded by the coagulation filter KF in the flow path of the gas. Its installation position is such that the longitudinal axis of the vessel of the coagulation filter encloses an angle of 0 to 45 ', here 0 * , with the horizontal, so that the pre-condensate produced can easily drain off via the condensate breakdown 3. The Koagu¬ correlation filter KF is the ambient temperature at the installation more than 30 * C, this can in a thermostatically controlled vessel TG at an operating temperature be- see 280 K and 300 K are held.
In den nach den Gaskühlern MK im Strömungsweg angeordneten Aerosolfiltern AF, die als Porenfilter mit einer Porenweite in der Größenordnung von Iμ ausgebildet sind, werden die rest- liehen Aerosole abgeschieden, so daß mit Hilfe der Membran¬ pumpen MP und der Staubfeinfilter FF Meßgas mit dem zur Analyse erforderlichen Reinheitsgrad den Analysengeräten I, II und III zugeführt werden kann, die jeweils eine der Komponenten des Meßgases messen. In the aerosol filters AF, which are arranged after the gas coolers MK in the flow path and are designed as pore filters with a pore size in the order of magnitude of Iμ, the remaining aerosols are separated off, so that with the help of the membrane pumps MP and the fine dust filter FF, measuring gas with the to Analysis required purity can be supplied to the analyzers I, II and III, each measuring one of the components of the sample gas.

Claims

Patentansprüche Claims
1. Einrichtung in Aggregaten zur Meßgasaufbereitung für die Gasanalyse1. Installation in units for sample gas processing for gas analysis
- mit einer beheizten Gasentnahme, - einem Gaskühler mit Kondensatableitung,- with a heated gas extraction, - a gas cooler with condensate drain,
- einem Aerosolfilter, Pumpen und Staubfeinfiltern, d a d u r c h g e k e n n z e i c h n e t , daß- an aerosol filter, pumps and fine dust filters, which means that
- im Strömungsweg vor dem Gaskühler (MK) ein Koagulationsfilter (KF) eingeschaltet ist, bestehend aus einem zylindrischen Gefäß (1), dessen Durchmesser (D) ein Mehrfaches der Durch¬ messer seiner endseitigen Zu- und Ableitungen (4, 5) beträgt, mit einer Füllung aus inerten Formkörpern (2).a coagulation filter (KF) is switched on in the flow path upstream of the gas cooler (MK), consisting of a cylindrical vessel (1), the diameter (D) of which is a multiple of the diameter of its inlet and outlet lines (4, 5) at the end, with a filling of inert molded articles (2).
2. Einrichtung nach Anspruch 1, d a d u r c h g e k e n n - z e i c h n e t , daß der Durchmesser (D) des Gefäßes (1) um eine dezimale Größenordnung kleiner ist als dessen Länge (L).2. Device according to claim 1, d a d u r c h g e k e n n - z e i c h n e t that the diameter (D) of the vessel (1) is a decimal order of magnitude smaller than its length (L).
3. Einrichtung nach Anspruch 1, d a d u r c h g e k e n n ¬ z e i c h n e t , daß in der Mantelfläche des Gefäßes (1) ein Kondensatablaß (3) angeordnet ist.3. Device according to claim 1, d a d u r c h g e k e n n ¬ z e i c h n e t that a condensate drain (3) is arranged in the lateral surface of the vessel (1).
4. Einrichtung nach Anspruch 1, d a d u r c h g e k e n n ¬ z e i c h n e t , daß die Längsachse des Gefäßes (1) in Ein¬ baulage mit der Horizontalen einen Winkel zwischen 0* und 45* einschließt.4. Device according to claim 1, characterized in that the longitudinal axis of the vessel (1) in the installed position with the horizontal includes an angle between 0 * and 45 * .
5. Einrichtung nach Anspruch 1, d a d u r c h g e k e n n ¬ z e i c h n e t , daß das Koagulationsfilter (KF) in einem thermostatisierten Gehäuse (TG) angeordnet ist.5. Device according to claim 1, d a d u r c h g e k e n n ¬ z e i c h n e t that the coagulation filter (KF) is arranged in a thermostatted housing (TG).
6. Einrichtung nach Anspruch 5, d a d u r c h g e k e n n ¬ z e i c h n e t , daß die Temperatur im thermostatisierten Gehäuse (TG) zwischen 10 *C und 30 *C gehalten wird.6. Device according to claim 5, characterized in that the temperature in the thermostatted housing (TG) is kept between 10 * C and 30 * C.
7. Einrichtung nach Anspruch 1, d a d u r c h g e k e n n ¬ z e i c h n e t , daß die inerten Formkörper Glaskugeln mit Durchmessern zwischen 3 und 10 mm sind. 7. Device according to claim 1, characterized in that the inert shaped bodies are glass spheres with diameters between 3 and 10 mm.
8. Einrichtung nach Anspruch 1, d a d u r c h g e k e n n ¬ z e i c h n e t , daß dem Gaskühler (MK) nachgeschaltete Aerosolfilter (AF) ein Porenfilter mit einer Porenweite in der Größenordnung von Iμ ist. 8. Device according to claim 1, d a d u r c h g e k e n n ¬ z e i c h n e t that the gas cooler (MK) downstream aerosol filter (AF) is a pore filter with a pore size in the order of Iμ.
EP92903568A 1991-02-07 1992-01-23 Device for use in installations for preparing gas mixtures for analysis Withdrawn EP0524282A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE9101410U DE9101410U1 (en) 1991-02-07 1991-02-07 Installation in units for measuring gas preparation for gas analysis
DE9101410U 1991-02-07

Publications (1)

Publication Number Publication Date
EP0524282A1 true EP0524282A1 (en) 1993-01-27

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DE (1) DE9101410U1 (en)
WO (1) WO1992014130A1 (en)

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Publication number Priority date Publication date Assignee Title
DE4322923C2 (en) * 1993-07-05 1997-08-07 Hartmann & Braun Ag Equipment for the preparation and analysis of sample gases
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