EP0522650A3 - Procedure for the preparation of a solid component of catalyst for the (co)polymerization of ethylene - Google Patents

Procedure for the preparation of a solid component of catalyst for the (co)polymerization of ethylene Download PDF

Info

Publication number
EP0522650A3
EP0522650A3 EP19920202059 EP92202059A EP0522650A3 EP 0522650 A3 EP0522650 A3 EP 0522650A3 EP 19920202059 EP19920202059 EP 19920202059 EP 92202059 A EP92202059 A EP 92202059A EP 0522650 A3 EP0522650 A3 EP 0522650A3
Authority
EP
European Patent Office
Prior art keywords
polymerization
catalyst
ethylene
procedure
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19920202059
Other versions
EP0522650A2 (en
EP0522650B1 (en
Inventor
Francesco Masi
Renzo Invernizzi
Angelo Moalli
Cesare Ferrero
Francesco Menconi
Lia Barazzoni
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Versalis SpA
Original Assignee
ECP Enichem Polimeri SRL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ECP Enichem Polimeri SRL filed Critical ECP Enichem Polimeri SRL
Publication of EP0522650A2 publication Critical patent/EP0522650A2/en
Publication of EP0522650A3 publication Critical patent/EP0522650A3/en
Application granted granted Critical
Publication of EP0522650B1 publication Critical patent/EP0522650B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/658Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in a single group of groups C08F4/653 - C08F4/657
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
EP92202059A 1991-07-12 1992-07-07 Procedure for the preparation of a solid component of catalyst for the (CO)polymerization of ethylene Expired - Lifetime EP0522650B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI911933A IT1251785B (en) 1991-07-12 1991-07-12 PROCEDURE FOR THE PREPARATION OF A SOLID COMPONENT OF CATALYST FOR THE (CO) POLYMERIZATION OF ETHYLENE
ITMI911933 1991-07-12

Publications (3)

Publication Number Publication Date
EP0522650A2 EP0522650A2 (en) 1993-01-13
EP0522650A3 true EP0522650A3 (en) 1993-03-03
EP0522650B1 EP0522650B1 (en) 1995-09-13

Family

ID=11360336

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92202059A Expired - Lifetime EP0522650B1 (en) 1991-07-12 1992-07-07 Procedure for the preparation of a solid component of catalyst for the (CO)polymerization of ethylene

Country Status (24)

Country Link
US (1) US5382557A (en)
EP (1) EP0522650B1 (en)
JP (1) JP3310696B2 (en)
KR (1) KR950001279B1 (en)
CN (1) CN1030082C (en)
AR (1) AR248411A1 (en)
AT (1) ATE127811T1 (en)
AU (1) AU652456B2 (en)
BR (1) BR9202660A (en)
CA (1) CA2073657C (en)
DE (1) DE69204768T2 (en)
DK (1) DK0522650T3 (en)
DZ (1) DZ1594A1 (en)
EG (1) EG20533A (en)
ES (1) ES2077342T3 (en)
FI (1) FI104081B1 (en)
GR (1) GR3017820T3 (en)
IT (1) IT1251785B (en)
MX (1) MX9204063A (en)
NO (1) NO179330C (en)
RU (1) RU2081884C1 (en)
SA (1) SA92130164B1 (en)
TN (1) TNSN92057A1 (en)
ZA (1) ZA925064B (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1252069B (en) * 1991-11-25 1995-05-29 Enichem Elastomers PROCESS FOR THE PREPARATION OF ETHYLENE ELASTOMERIC COPOLYMERS
DE4417475A1 (en) * 1994-05-19 1995-11-23 Hoechst Ag Process for the preparation of a catalyst component for the polymerization of ethylene and 1-olefins to form ultra-high molecular weight ethylene polymers
IT1269805B (en) * 1994-05-20 1997-04-15 Enichem Spa CATALYST FOR THE (CO) POLYMERIZATION OF ETHYLENE AND PROCEDURE FOR ITS OBTAINMENT
WO2000075197A1 (en) * 1999-06-04 2000-12-14 Lg Chemical Ltd. Process for preparing polyolefin polymerization catalysts
JP4934898B2 (en) * 2000-03-30 2012-05-23 住友化学株式会社 Solid catalyst component for olefin polymerization, catalyst for olefin polymerization, and method for producing olefin polymer
CN1119354C (en) * 2000-05-19 2003-08-27 中国石油化工集团公司 Magnesium chlorid-alcohol carrier and olefine polymerizing catalyst component prepared with it
DE60120389T2 (en) * 2001-06-20 2007-06-14 Borealis Technology Oy Preparation of a catalyst component for olefin polymerization
KR20050025120A (en) 2002-07-23 2005-03-11 바셀 폴리올레핀 이탈리아 에스.피.에이. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
WO2004085495A1 (en) * 2003-03-27 2004-10-07 Basell Poliolefine Italia S.R.L. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
CN1315885C (en) * 2005-04-26 2007-05-16 浙江大学 Catalast for polymerizing propylene with low carried titanium MgCl2/AlCl3 composite carrier and its preparation process
CN100513438C (en) * 2005-10-31 2009-07-15 中国石油化工股份有限公司 Catalyst in use for polymerization or combined polymerization of ethylene, preparation and application
US7388060B2 (en) * 2006-01-04 2008-06-17 China Petroleum & Chemical Corporation Catalyst component for olefin (co)polymerization, preparation thereof, a catalyst comprising the same and use thereof
FI121820B (en) 2006-05-15 2011-04-29 Ramtec Oy Screening bucket and screening transmission module

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2189429A1 (en) * 1972-06-22 1974-01-25 Solvay
EP0143339A1 (en) * 1983-10-28 1985-06-05 Phillips Petroleum Company Process for preparing a polyolefin polymerization catalyst
EP0281524A2 (en) * 1987-02-06 1988-09-07 ENICHEM ANIC S.p.A. A catalyst component for polymerizing ethylene or copolymerizing ethylene with an alpha-olefin

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA920299A (en) * 1968-08-01 1973-01-30 Mitsui Petrochemical Industries Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier
BE791676A (en) * 1971-12-08 1973-05-21 Solvay Process for the polymerization of olefins
LU64420A1 (en) * 1971-12-08 1973-07-16
IT1136627B (en) * 1981-05-21 1986-09-03 Euteco Impianti Spa SUPPORTED CATALYST FOR THE POLYMERIZATION OF ETHYLENE

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2189429A1 (en) * 1972-06-22 1974-01-25 Solvay
EP0143339A1 (en) * 1983-10-28 1985-06-05 Phillips Petroleum Company Process for preparing a polyolefin polymerization catalyst
EP0281524A2 (en) * 1987-02-06 1988-09-07 ENICHEM ANIC S.p.A. A catalyst component for polymerizing ethylene or copolymerizing ethylene with an alpha-olefin

Also Published As

Publication number Publication date
US5382557A (en) 1995-01-17
EP0522650A2 (en) 1993-01-13
KR930002385A (en) 1993-02-23
CA2073657C (en) 2002-12-10
SA92130164B1 (en) 2003-12-23
DE69204768T2 (en) 1996-04-11
ITMI911933A1 (en) 1993-01-12
ES2077342T3 (en) 1995-11-16
FI923150A0 (en) 1992-07-08
TNSN92057A1 (en) 1993-06-08
NO922708L (en) 1993-01-13
CA2073657A1 (en) 1993-01-13
DK0522650T3 (en) 1995-12-11
CN1068576A (en) 1993-02-03
JPH05194645A (en) 1993-08-03
FI923150A (en) 1993-01-13
AR248411A1 (en) 1995-08-18
AU652456B2 (en) 1994-08-25
BR9202660A (en) 1993-03-16
GR3017820T3 (en) 1996-01-31
RU2081884C1 (en) 1997-06-20
NO922708D0 (en) 1992-07-09
NO179330B (en) 1996-06-10
KR950001279B1 (en) 1995-02-15
FI104081B (en) 1999-11-15
DE69204768D1 (en) 1995-10-19
AU1948592A (en) 1993-01-14
ZA925064B (en) 1993-04-28
EP0522650B1 (en) 1995-09-13
JP3310696B2 (en) 2002-08-05
CN1030082C (en) 1995-10-18
ITMI911933A0 (en) 1991-07-12
FI104081B1 (en) 1999-11-15
EG20533A (en) 1999-07-31
NO179330C (en) 1996-09-18
DZ1594A1 (en) 2002-02-17
MX9204063A (en) 1993-07-01
IT1251785B (en) 1995-05-26
ATE127811T1 (en) 1995-09-15

Similar Documents

Publication Publication Date Title
AR244712A1 (en) A catalyst component for the polymerisation of olefins.
EG20314A (en) Process for the preparation of a solid component of catalyst for the (co)polymerization of ethylene
EP0748822A3 (en) Catalyst component useful for the polymerization of olefins
EP0459009A3 (en) A solid catalyst component for the polymerization of olefins and an olefin polymerization catalyst
EP0520811A3 (en) Catalyst components for polymerization of olefins
PH27289A (en) Catalyst for the polymerization of olefins
SG52625A1 (en) Process for the preparation of ethylene (co) polymers
PH27438A (en) Components and catalysts for the polymerization of olefins
EP0520816A3 (en) Catalyst components for polymerization of olefins
ZA917112B (en) Solid component of catalyst for the(co)-polymerization of ethylene
EP0589350A3 (en) Process for the preparation of a supported catalyst for the polymerisation of alpha - olefins.
EG20533A (en) Procedure for the preparation of a solid component of catalyst for the (co) polymerization of ethylene
GB9103656D0 (en) Catalyst for polymerisation
IL110886A0 (en) Catalyst for polymerization of ethylene
EP0419116A3 (en) Method for the preparation of a stabilized catalyst for the polymerization of olefins
EG20372A (en) Catalyst for the co (polymerization) of ethylene
AU3373193A (en) Olefins polymerization catalyst
SG52620A1 (en) Process for the preparation of ethylene (CO) polymers
CS7691A3 (en) Catalyst for ethylene polymerization
AR243553A1 (en) A catalyst component for polymerisation of olefines.
SG75090A1 (en) Preparing catalyst for olefin polymerization

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE CH DE DK ES FR GB GR IT LI LU MC NL PT SE

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE CH DE DK ES FR GB GR IT LI LU MC NL PT SE

17P Request for examination filed

Effective date: 19930714

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: ENICHEM S.P.A.

17Q First examination report despatched

Effective date: 19940324

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE DK ES FR GB GR IT LI LU MC NL PT SE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED.

Effective date: 19950913

Ref country code: BE

Effective date: 19950913

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19950913

REF Corresponds to:

Ref document number: 127811

Country of ref document: AT

Date of ref document: 19950915

Kind code of ref document: T

REF Corresponds to:

Ref document number: 69204768

Country of ref document: DE

Date of ref document: 19951019

ET Fr: translation filed
REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2077342

Country of ref document: ES

Kind code of ref document: T3

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

REG Reference to a national code

Ref country code: GR

Ref legal event code: FG4A

Free format text: 3017820

SC4A Pt: translation is available

Free format text: 951018 AVAILABILITY OF NATIONAL TRANSLATION

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
REG Reference to a national code

Ref country code: CH

Ref legal event code: PUE

Owner name: ENICHEM S.P.A. TRANSFER- POLIMERI EUROPA S.R.L.

Ref country code: CH

Ref legal event code: NV

Representative=s name: R. A. EGLI & CO. PATENTANWAELTE

REG Reference to a national code

Ref country code: GB

Ref legal event code: 732E

NLS Nl: assignments of ep-patents

Owner name: POLIMERI EUROPA S.R.L.

REG Reference to a national code

Ref country code: FR

Ref legal event code: TP

Free format text: PUBLIE A TORT DANS LE BOPI 98/03 SUIVANT LA NOTIFICATION DANS LE BOPI 98/07

REG Reference to a national code

Ref country code: FR

Ref legal event code: TP

REG Reference to a national code

Ref country code: ES

Ref legal event code: PC2A

REG Reference to a national code

Ref country code: PT

Ref legal event code: PC4A

Free format text: POLIMERI EUROPA S.R.L. IT

Effective date: 19990120

REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: LU

Payment date: 20040714

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DK

Payment date: 20040715

Year of fee payment: 13

Ref country code: CH

Payment date: 20040715

Year of fee payment: 13

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050707

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050731

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050801

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PT

Payment date: 20080620

Year of fee payment: 17

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GR

Payment date: 20080729

Year of fee payment: 17

REG Reference to a national code

Ref country code: PT

Ref legal event code: MM4A

Free format text: LAPSE DUE TO NON-PAYMENT OF FEES

Effective date: 20100107

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100107

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100204

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20110805

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20110727

Year of fee payment: 20

Ref country code: ES

Payment date: 20110726

Year of fee payment: 20

Ref country code: AT

Payment date: 20110621

Year of fee payment: 20

Ref country code: GB

Payment date: 20110725

Year of fee payment: 20

Ref country code: SE

Payment date: 20110727

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20110728

Year of fee payment: 20

REG Reference to a national code

Ref country code: DE

Ref legal event code: R071

Ref document number: 69204768

Country of ref document: DE

REG Reference to a national code

Ref country code: DE

Ref legal event code: R071

Ref document number: 69204768

Country of ref document: DE

REG Reference to a national code

Ref country code: NL

Ref legal event code: V4

Effective date: 20120707

REG Reference to a national code

Ref country code: GB

Ref legal event code: PE20

Expiry date: 20120706

REG Reference to a national code

Ref country code: SE

Ref legal event code: EUG

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK07

Ref document number: 127811

Country of ref document: AT

Kind code of ref document: T

Effective date: 20120707

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20120710

Ref country code: GB

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20120706

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20140827

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20120708