EP0522161B1

EP0522161B1 - Corrosion inhibitor for steam and condenser system and corrosion inhibition method therefor

Info

Publication number: EP0522161B1
Application number: EP91906425A
Authority: EP
Inventors: Shunichi C/O Aquas Corporation Akama; Takanobu C/O Aquas Corporation Sasa; Tokuko C/O Aquas Corporation Yanagisawa
Original assignee: Aquas Corp
Current assignee: Aquas Corp
Priority date: 1990-03-30
Filing date: 1991-03-28
Publication date: 1995-02-15
Anticipated expiration: 2011-03-28
Also published as: EP0522161A1; AU643796B2; AU7848991A; WO1991015612A1; DE69107449D1; EP0522161A4; ATE118559T1; CA2069952A1; DE69107449T2

Abstract

The invention relates to a method of inhibiting corrosion in steam or the piping and equipment of a condenser system. In general, hygienic safety of steam generated by boilers or the like is urgently required when it is used in the processing of food, production of pharmaceuticals, or air conditioning of buildings. However there has not been any corrosion inhibitor which can be used safely irrespective of the purpose of the use of steam or the concentration of the inhibitor in steam. Therefor the use of a corrosion inhibitor has often been refrained from even though there has been a possibility of corrosion in steam or the piping and equipment of a condenser system, when there has been a need for hygienically safe steam. Under these circumstances the invention provides a method of inhibiting corrosion of steam and a condenser system by adding thereto a corrosion inhibitor containing at least one of vitamins A and E as the active ingredient, whereby hygienically safe steam can be used for the processing of food or the like without any fear of the pollution of steam and corrosion of piping due to chemicals. <IMAGE>

Description

Field of Invention

The present invention relates to a method of preventing the occurrence of corrosion in pipes and devices of steam and condenser systems and the use of vitamin A or a combination of vitamin A and vitamin E and/or their derivatives as anticorrosive agents.

Background Art

In steam generating apparatuses, such as boilers and concentration cans, the metal in contact with steam and condensed water may corrode due to feed water-containing oxygen and components of M-alkalinity. Regarding to condenser systems in particular, carbon dioxide generated together with steam in boilers and the like dissolves again in water at condensation of steam, leading to the decrease in pH of condensed water (condensation), which frequently causes severe corrosion of pipes and devices. As the methods to prevent such corrosion, there has been conventionally carried out the chemical process with strong basic-type amines such as morpholine and long-chain aliphatic amines such as octadecyl amine, besides the processes of ion exchange and degassing for the objective to degass carbonate in feed water.
In case that the steam generated in boilers is to be used for food processing and the production process of pharmaceutical agents and for humidification of air conditioning of buildings, a high degree of hygienic safety is required for steam. Some of the amine-type chemical agents described above have got approval of their use as the additives for boilers from US FDA Standards, but the objectives of the utility of generated steam have been limited and the concentration of the agents in steam has also limitation. Additionally, they are not necessarily satisfactory in terms of safety. Hence, even in the case that some concerns about the corrosion of pipes and devices of steam and condenser systems may be present, steam is used without chemical processing, in order to ensure safety.
JP-A-49 058 084 discloses a method for controlling redox reaction with a system obtained by combining one or more compound(s) selected from the group (A) and one or more compound(s) selected from the group (B). Examples for the compounds of group (A) are coenzyme Q, vitamin K₂ and plastoquinones; examples for the compounds of group (B) are ubichromenol, ubichromanol and tocopherol (vitamin E). Vitamin A is not mentioned in this document.
EP 0 039 130 discloses the use of dioxo aromatic compounds as oxygen scavengers in an aqueous medium. Examples for such dioxo aromatic compounds are hydroquinone, benzoquinone, naphthoquinone, catechol, and dihydroxybenzaldehyde. Vitamin A is not mentioned in EP 0 039 130.
US 3,149,037 discloses Vitamin compositions comprising Vitamin A or a combination of Vitamin A and Vitamin E for pharmaceutical use.

Disclosure of the invention

The present invention is thus to provide an anticorrosive method of steam and condenser systems, capable of providing sufficient ensuring of hygienic safety.
The present inventors have carried out investigations so as to achieve the above objectives, and have found that vitamin A or a combination of vitamin A and vitamin E and/or their derivatives among vitamins as the organic substances inevitable for maintaining normal growth and nutritious state of animals, have anticorrosive effects on steam and condenser systems. That is, the present invention provides the use of vitamin and/or its derivatives or a combination of vitamin A and vitamin E and/or their derivatives as anticorrosive agents for steam and condenser systems, and a method for preventing corrosion in steam and condenser systems, comprising the addition of Vitamin A and/or its derivatives or the addition of a combination of vitamin A and vitamin E and/or their derivatives as anticorrosive agents.
The vitamin A to be used in the present invention is ;

(a) vitamin A compounds including vitamin A₁ (retinol), vitamin A₂, vitamin A₃, etc., or
(b) the derivatives of the vitamin A compounds described above, including vitamin A aliphatic acid ester, vitamin A acid, vitamin A aldehyde, etc., and they may be natural products or synthetic products, or those containing such compounds or derivatives, for example, fatty oil obtained from liver and pyrolus uvula of marine animals.

The vitamin E to be used in the present invention is represented by so-called tocopherol and its analogs, including for example, α-tocopherol, β-tocopherol, γ-tocopherol, δ-tocopherol, α-tocotorienol, β-tocotorienol, γ-tocotorienol, δ-tocotorienol, etc. As in vitamin A, oils containing such compounds, for example, germ oil and soybean oil, may be also included.
These vitamins A and E are those incorporated as nutritious components on daily basis into humans, and are substances in a wide range of general use as supplementary products for nutritious foods or additives for milk products, flour, baby foods, condensed and dried soup stocks, curry roux, confectioneries, etc. Vitamins A and E as such are thoroughly investigated of their safety including the effects on human body, so they can appropriately be used in the case that safety of steam is important as described above.
The anticorrosive mechanism is not clear in accordance with the present invention, but such anticorrosive property of vitamin A cannot be expected from the properties and utilities thereof, and the property is very surprising.
Vitamin A is used singly or in combination with vitamin E, or may be used as a pharmaceutical agent in which these vitamins are blended together. The method of adding vitamin A or the mixture of vitamin A and vitamin E, and the concentration thereof to be added should be appropriately determined, depending on equipment condition and the condition as to how to use, and it is generally preferable to directly inject and add them to the pipes of steam or condenser system. The longer the length of pipes of steam or condenser systems gets, the higher the concentration to be added should be. Vitamins A and E are also sparingly soluble in water, and in case that preliminary dilution of them is advantageous at their addition, they may be dispersed in emulsifiers or diluted with solvents, before adding and using them.

Brief Description of Drawings

Fig.1 is a figure representing the configuration of a testing apparatus to carry out the anticorrosive method of steam and condenser systems in accordance with the present invention.

Best Mode of carrying out the Invention

While supplying soft water f of the following water quality to autoclave a where as shown in Fig. 1, steam header b, water cooling type steam condenser c following the header b, and condensed water (condensation) pool d following the condenser c, were communicated together, and thermal electric heater e (conductive heat area 0.67 m²) was immersed in water, operation was effected at a steam pressure of 8 kg f/cm², a steam generation volume of 5.5 kg/h, a blower ratio of 10%, and the water temperature in the condensation water pool d of 70 °C, until the final accumulation of feed water reached 200 ℓ. The decrease in corrosion of a soft steel board of 15 mm x 40 mm x 2 mm, suspended in the condensed water pool d, was measured to calculate the corrosion degree (mdd). Chemical agents g used are as follows, and the agents were injected into the steam header b at their ratios to condensed water as shown in Fig.1. No chemical agents were injected into the autoclave a.
The results are shown as Fig.1, and excellent anticorrosive effect was obtained.

Quality of soft water

pH	7.5
Electric conductivity (»S/cm)	200
M-alkalinity (mg CaCO₃)	48
Silica (mg SiO₂)	24
Chloride ion (mg Cl/l)	13
Whole hardness (mg CaCO₃)	less than 1

Chemical agents used

Chemical agent A:
Vitamin A (Riken A palmitate 1000)	1 %
Benzyl alcohol	99 %

Chemical agent B:
Vitamin A (Riken A palmitate 1000)	4.1 %
Benzyl alcohol	95.9 %

Chemical agent D:
Benzyl alcohol	100 %

Chemical agent E:
Octadecyl amine	1.4 %
Polyoxyethylene stearylether	0.4
Water	98.2 %

Chemical agent F:
2-Amino-3-methyl propanol	17.5 %
Water	82.5 %

Table 1

Test No.	Chemical agent	Amount added (»g/litre)	Corrosion degree(mdd)	Note
1	blank		125
2	A	600	22	Example
3	B	600	34	Example
5	D	600	124	Comparative Example
6	E	600	41	Comparative Example
7	F	600	27	Comparative Example

Industrial Utilization of the Invention

Because an anticorrosive agent containing as the effective component vitamin A or a combination of vitamin A and vitamin E and/or their derivatives is injected into steam pipes or into boilers, the application of the anticorrosive method of steam and condenser systems in accordance with the present invention allows the use of the steam for food processing and the like, with no concerns about the occurrence of steam contamination and the corrosion of the pipes due to chemical agents and the like.

Claims

Use of vitamin A and/or its derivatives or a combination of vitamin A and vitamin E and/or their derivatives as anticorrosive agents.
Use according to claim 1 wherein the anticorrosive agents comprise additionally an emulsifier or a solvent.
Use according to claim 2 wherein said solvent is a benzyl alcohol.
A method for preventing corrosion in steam and condenser systems, comprising the addition of vitamin A and/or its derivatives as anticorrosive agents.
A method for preventing corrosion in steam and condenser systems, comprising the addition of a combination of vitamin A and vitamin E and/or their derivatives as anticorrosive agents.