EP0519942A1 - Cosmetic cleansing agent. - Google Patents

Cosmetic cleansing agent.

Info

Publication number
EP0519942A1
EP0519942A1 EP91905070A EP91905070A EP0519942A1 EP 0519942 A1 EP0519942 A1 EP 0519942A1 EP 91905070 A EP91905070 A EP 91905070A EP 91905070 A EP91905070 A EP 91905070A EP 0519942 A1 EP0519942 A1 EP 0519942A1
Authority
EP
European Patent Office
Prior art keywords
betaine
group
weight
surfactants
general formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP91905070A
Other languages
German (de)
French (fr)
Other versions
EP0519942B1 (en
Inventor
Uwe Schoenrock
Heike Lerg
Wolfgang Pape
Klaus-Michael Steiger
Petra Osthof
Kerstin Gerlach
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beiersdorf AG
Original Assignee
Beiersdorf AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beiersdorf AG filed Critical Beiersdorf AG
Publication of EP0519942A1 publication Critical patent/EP0519942A1/en
Application granted granted Critical
Publication of EP0519942B1 publication Critical patent/EP0519942B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/06—Ether- or thioether carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates

Definitions

  • the present invention relates to cosmetic cleaning agents.
  • Such means are known per se. These are essentially surface-active substances or mixtures of substances that are offered to the consumer in various preparations.
  • Preparations of this type are, for example, foam and shower baths, solid and liquid soaps or so-called “syndets” (synthetic detergents), shampoos, hand-washing pastes, intimate detergents, special cleaning agents for small children and the like.
  • synthetic detergents synthetic detergents
  • shampoos hand-washing pastes
  • intimate detergents special cleaning agents for small children and the like.
  • the most common surfactant for cosmetic compositions is sodium lauryl ether sulfate. Although it has good washing power and is reasonably compatible with the skin and mucous membranes, should be sensitive
  • this object is achieved by a cleaning agent containing
  • sulfoacetate surfactants 0.5 - 15 wt .-% of one or more sulfoacetate surfactants and optionally one or more of the surfactants selected from the group of sarcosinates, betaines, the
  • Sulfobetaines the amidosulfobetaines, the sulfosuccinates and the ethoxylated alcohol carboxylates.
  • compositions to be used in cosmetic, cleaning agents.
  • compositions according to the invention are surfactants from the group of the sulfosuccinates, betaines, sarcosinates and / or carboxylated alcohol ethoxylates
  • compositions according to the invention give an extremely fine-bubble, creamy foam when used.
  • Amidoamine-amphoteric surfactants are understood to mean compounds of the following general formulas:
  • R is a saturated hydrocarbon residue with 6 - 25
  • Z ', Z' ' can be selected independently from the group OH,
  • H + , Na + , K + , NH 4 + , H m N + (-CH 2 -CH 2 -OH) 4-m , H m N + (-CH 2 -CH 3 ) 4-m or H m N + (CH 3 ) 4-m means, p, q, r, s independently of one another are numbers from 1 to 5,
  • n 0, 1, 2 or 3.
  • R is a saturated hydrocarbon residue with 6 - 25
  • H m N + (-CH 2 -CH 3 ) 4-m or H m N + (CH 3 ) 4-m means, p, q, r, s independently of one another are numbers from 1 to 5,
  • n 0, 1, 2 or 3
  • Lauryl sulfate Lauryl ether sulfate means.
  • R is a saturated hydrocarbon residue with 6 - 25
  • Z ', Z' ' can be selected independently from the group OH,
  • H m N + (-CH 2 -CH 3 ) 4-m or H m N + (CH 3 ) 4-m means, p, q, r, independently of one another, numbers from 1-5
  • n 0, 1, 2 or 3.
  • R is a saturated hydrocarbon residue with 6 - 25
  • M is a cation selected from the group
  • n 0, 1, 2 or 3.
  • Sulfosuccinates include compounds of
  • Betaines include compounds of the general formula
  • Sulfobetaines include compounds of the general formula
  • Amidosulfobetaines include compounds of the general formula
  • Sarcosinates include compounds of the general formula
  • R is a saturated hydrocarbon residue with 6 - 25
  • R ', R' 'and R' '' are independent of each other from the
  • Y, Z are selected independently from the group
  • M + means a cation selected from the group
  • n is a number from 1 to 5
  • n 0, 1, 2 or 3.
  • the cleaning agents according to the invention particularly preferably contain 2-8% by weight of one or more amidoamines
  • the total amount of surfactants should not exceed 50% by weight.
  • amidoamine amphoteric surfactants according to the invention are advantageously selected from the group bearing the names alkylamphodiacetates, alkylamphoacetates, alkylamphodipropionates and alkylamphopropionates according to the CTFA nomenclature.
  • Cocoamphodiacetate Cocoamphoacetate
  • Cocoamphopropionate Cocoamphodipropionate
  • the sulfoacetate surfactants are preferably selected from the group
  • the betaines are preferably selected from the group of higher alkyl betaines, sulfobetaines or
  • Amidosulfobetaine especially from the group
  • Coco amidopropyl betaine cocobetaine
  • the sulfosuccinates are preferably selected from the group of the N-acyl sulfosuccinates, preferably selected from the group
  • the carboxylated alcohol ethoxylates are preferably selected from the group
  • MEA Sodium lauroyl carboxyamide
  • compositions according to the invention contain water and, if appropriate, the additives customary in cosmetics, for example perfume, thickeners, dyes, deodorants,
  • Plant extracts Plant extracts, vitamins, active ingredients and the like.
  • compositions according to the invention according to Examples 1-6 are produced as follows:
  • the surfactants, the PEG-7-glyceryl cocoate, the pearlescent agent (glycol distearate) and about 10% by weight of water are heated to 70 ° C. with stirring and sodium lauryl sulfoacetate is added. The reaction mixture slowly opens up
  • Citric acid and sodium chloride are dissolved in a small amount of water and added to the mixture. Finally, the preservative, the perfume and the thickener as well as the remaining water are added and the composition is homogenized.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A cleansing agent, preferably for cosmetic purposes, contains 2 - 10 wt.% of one of more amidoamine amphoteric tensides, 0.5 - 15 wt.% of one or more sulphoacetate tensides and possibly one or more of tensides from the groups of sulphosuccinates of general formula (I), betaines of general formula RR'R''N?+(CH2?)m?-(CYZ)-COO?-, sulphobetaines of general formula RR'R''N?+(CH2?)m?-(CYZ)-SO3?, amidosulphobetaines of general formula (II), sarcosinates of general formula M?+-OOC-CH2?-N(CH3?)-COR, and ethoxylated alcohol carboxylates of general formula R-(O-CH2?-CH2?)n?-O-CH2?-COO?-M?+ where: R is a saturated hydrocarbon group with 6 - 25 C atoms; R',R'' and R''' are chosen independently from each other from the group H, -CH2?-CH2?-OH, -(CH2?)2?COO?-M?+; X is H or -(CH2?)2?COO?-M?+; M?+ is a cation from the group H?+, Na?+, K?+, NH4??+, Hm?N?+(-CH2?-CH2?-OH)4-m?, Hm?N?+(-CH2?-CH3?)4-m? or Hm?N?+(CH3?)4-m?; n is a number from 1 to 5; m is 0, 1, 2 or 3.

Description

Beschreibung  description
Kosmetische Reinigungsmittel Cosmetic detergents
Die vorliegende Erfindung betrifft kosmetische Reinigungsmittel. The present invention relates to cosmetic cleaning agents.
Derartige Mittel sind an sich bekannt. Es handelt sich dabei im wesentlichen um oberflächenaktive Substanzen oder Stoffgemische, die dem Verbraucher in verschiedenen Zubereitungen angeboten werden. Such means are known per se. These are essentially surface-active substances or mixtures of substances that are offered to the consumer in various preparations.
Zubereitungen dieser Art sind beispielsweise Schaumund Duschbäder, feste und flüssige Seifen oder sogenannte "Syndets" (synthetische Detergentien), Shampoos, Handwaschpasten, Intimwaschmittel, spezielle Reinigungsmittel für Kleinkinder und dergleichen. Preparations of this type are, for example, foam and shower baths, solid and liquid soaps or so-called "syndets" (synthetic detergents), shampoos, hand-washing pastes, intimate detergents, special cleaning agents for small children and the like.
Oberflächenaktive Stoffe - am bekanntesten die Alkalisalze der höheren Fettsäuren, also die klassischen "Seifen" - sind amphiphile Stoffe, die organische unpolare Substanzen in Wasser emulgieren können. Surface-active substances - best known are the alkali salts of higher fatty acids, ie the classic "soaps" - are amphiphilic substances that can emulsify organic non-polar substances in water.
Diese Stoffe schwemmen nicht nur Schmutz von Haut und Haaren, sie reizen, je nach Wahl des Tensids oder des Tensidgemisches, Haut und Schleimhäute mehr oder minder stark. These substances not only wash away dirt from the skin and hair, they irritate the skin and mucous membranes to a greater or lesser extent, depending on the choice of surfactant or mixture of surfactants.
Das gebräuchlichste Tensid für kosmetische Zusammensetzungen ist das Natriumlaurylethersulfat. Obwohl es gute Waschkraft besitzt und einigermaßen haut- und schleimhautverträglich ist, sollten empfindliche The most common surfactant for cosmetic compositions is sodium lauryl ether sulfate. Although it has good washing power and is reasonably compatible with the skin and mucous membranes, should be sensitive
Personen den häufigen Kontakt damit meiden. Avoid frequent contact with people.
Es ist zwar eine große Zahl recht milder Tenside erhältlich, jedoch sind die Tenside des Standes der Technik entweder mild, reinigen aber schlecht, oder aber sie reinigen gut, reizen jedoch Haut oder While a large number of fairly mild surfactants are available, the prior art surfactants are either mild, but clean poorly, or they clean well but irritate the skin or
Schleimhäute. Mucous membranes.
Es war somit die Aufgabe der vorliegenden Erfindung, den Mißständen des Standes der Technik abzuhelfen. It was therefore the object of the present invention to remedy the shortcomings of the prior art.
Erfindungsgemäß wird diese Aufgabe gelöst durch ein Reinigungsmittel, enthaltend According to the invention, this object is achieved by a cleaning agent containing
2 - 10 Gew.-% eines oder mehrerer Amidoamin-ampho- terer Tenside 2 - 10% by weight of one or more amidoamine amphoteric surfactants
0,5 - 15 Gew.-% eines oder mehrerer Sulfoacetat-Tenside und gegebenenfalls eines oder mehrerer der Tenside, gewählt aus der Gruppe der Sarcosinate, der Betaine, der  0.5 - 15 wt .-% of one or more sulfoacetate surfactants and optionally one or more of the surfactants selected from the group of sarcosinates, betaines, the
Sulfobetaine, der Amidosulfobetaine, der Sulfosuccinate und der ethoxylierten Alkoholcarboxylate. Sulfobetaines, the amidosulfobetaines, the sulfosuccinates and the ethoxylated alcohol carboxylates.
Es ist an sich bekannt, die beiden einzelnen It is known in itself, the two individual
Hauptbestandteile der erfindungsgemäßen Main components of the invention
Zusammensetzungen, Amidoamin-amphotere Tenside und Sulfoacetat-Tenside, in kosmetischer, Reinigungsmitteln einzusetzen. Compositions, amidoamine-amphoteric surfactants and sulfoacetate surfactants, to be used in cosmetic, cleaning agents.
Es ist auch bekannt, die einzelnen Hauptbestandteile mit anderen oberflächenaktiven Substanzen zu mischen. Es konnte aber nicht vorhergesehen werden, daß die Kombination der erfindungsgemäßen Hauptbestandteile zu Produkten führen würde, die sich gegenüber den It is also known to mix the individual main components with other surface-active substances. However, it could not have been foreseen that the combination of the main components according to the invention Would lead to products that are different from the
Einzelsubstanzen durch bessere Verträglichkeit mit Haut und Schleimhäuten auszeichnen und zudem überlegene Waschkraft aufweisen. Demnach liegt ein echter  Individual substances are characterized by better compatibility with skin and mucous membranes and also have superior washing power. So there is a real one
Synergismus vor. Synergism before.
Es konnte weiterhin überraschend festgestellt werden, daß dieser synergistische Effekt unterstützt wird, wenn die erfindungsgemäßen Zusammensetzungen Tenside aus der Gruppe der Sulfosuccinate, der Betaine, der Sarcosinate und/oder der carboxylierten Alkoholethoxylate It was also surprisingly found that this synergistic effect is supported if the compositions according to the invention are surfactants from the group of the sulfosuccinates, betaines, sarcosinates and / or carboxylated alcohol ethoxylates
enthalten. contain.
Besonders überraschend war, daß die erfindungsgemäßen Zusammensetzungen bei der Anwendung einen äußerst feinblasigen, cremigen Schaum ergeben. It was particularly surprising that the compositions according to the invention give an extremely fine-bubble, creamy foam when used.
Die Hauptbestandteile sind wie folgt charakterisiert: The main components are characterized as follows:
Unter Amidoamin-amphoteren Tensiden werden Verbindungen der folgenden allgemeinen Formeln verstanden: Amidoamine-amphoteric surfactants are understood to mean compounds of the following general formulas:
a) a)
wobei in which
R einen gesättigten Kohlenwasserstoffrest mit 6 - 25 R is a saturated hydrocarbon residue with 6 - 25
C-Atomen bedeutet, Carbon atoms means
Z', Z'' unabhängig gewählt werden aus der Gruppe OH ,Z ', Z' 'can be selected independently from the group OH,
-COO- M+ , -COO- M + ,
Z'''-COO- bedeutet, Z '' '- COO- means
M+ ein Kation, gewählt aus der Gruppe M + a cation selected from the group
H+, Na+, K+, NH4 +, HmN+(-CH2-CH2-OH)4-m , HmN+(-CH2-CH3)4-m oder HmN+(CH3)4-m bedeutet, p, q , r , s unabhängig voneinander Zahlen von 1 - 5 bedeuten, H + , Na + , K + , NH 4 + , H m N + (-CH 2 -CH 2 -OH) 4-m , H m N + (-CH 2 -CH 3 ) 4-m or H m N + (CH 3 ) 4-m means, p, q, r, s independently of one another are numbers from 1 to 5,
m 0, 1, 2 oder 3 bedeutet.  m means 0, 1, 2 or 3.
wobei  in which
R einen gesättigten Kohlenwasserstoffrest mit 6 - 25 R is a saturated hydrocarbon residue with 6 - 25
C-Atomen bedeutet, Carbon atoms means
M+ ein Kation, gewählt aus der Gruppe M + a cation selected from the group
H+, Na+, K+, NH4 +, HmN+(-CH2-CH2-OH)4-m , H + , Na + , K + , NH 4 + , H m N + (-CH 2 -CH 2 -OH) 4-m ,
HmN+(-CH2-CH3)4-m oder HmN+(CH3)4-m bedeutet, p , q , r , s unabhängig voneinander Zahlen von 1 - 5 bedeuten, H m N + (-CH 2 -CH 3 ) 4-m or H m N + (CH 3 ) 4-m means, p, q, r, s independently of one another are numbers from 1 to 5,
m 0, 1, 2 oder 3 bedeutet,  m denotes 0, 1, 2 or 3,
J- ein Anion , gewählt aus der Gruppe  J- an anion selected from the group
Laurylsulfat, Laurylethersulfat bedeutet.  Lauryl sulfate, Lauryl ether sulfate means.
wobei in which
R einen gesättigten Kohlenwasserstoffrest mit 6 - 25 R is a saturated hydrocarbon residue with 6 - 25
C-Atomen bedeutet, Carbon atoms means
Z', Z'' unabhängig gewählt werden aus der Gruppe OH , Z ', Z' 'can be selected independently from the group OH,
-COO- M+ , M+ ein Kation, gewählt aus der Gruppe -COO- M + , M + a cation selected from the group
H+, Na+, K+, NH4 +, HmN+(-CH2-CH2-OH)4-m , H + , Na + , K + , NH 4 + , H m N + (-CH 2 -CH 2 -OH) 4-m ,
HmN+(-CH2-CH3)4-m oder HmN+(CH3)4-m bedeutet, p , q , r unabhängig voneinander Zahlen von 1 - 5 H m N + (-CH 2 -CH 3 ) 4-m or H m N + (CH 3 ) 4-m means, p, q, r, independently of one another, numbers from 1-5
bedeuten,  mean,
m 0, 1, 2 oder 3 bedeutet. m means 0, 1, 2 or 3.
Unter Sulfoacetaten werden im folgenden Verbindungen der allgemeinen Formel Below, sulfoacetates are compounds of the general formula
verstanden, wobei understood, whereby
R einen gesättigten Kohlenwasserstoffrest mit 6 - 25 R is a saturated hydrocarbon residue with 6 - 25
C-Atomen bedeutet, Carbon atoms means
M ein Kation, gewählt aus der Gruppe  M is a cation selected from the group
H+, Na+, K+, NH4 +, HmN+(-CH2-CH2-OH)4-m , H + , Na + , K + , NH 4 + , H m N + (-CH 2 -CH 2 -OH) 4-m ,
Hm(-CH2-CH3)4-m oder Hm(CH3)4-m bedeutet, H m (-CH 2 -CH 3 ) 4-m or H m (CH 3 ) 4-m ,
m 0, 1, 2 oder 3 bedeutet.  m means 0, 1, 2 or 3.
Die Nebenbestandteile sind wie folgt charakterisiert: The minor components are characterized as follows:
Unter Sulfosuccinaten werden Verbindungen der Sulfosuccinates include compounds of
allgemeinen Formel .general formula ,
Unter Betainen werden Verbindungen der allgemeinen Formel Betaines include compounds of the general formula
..
Unter Sulfobetainen werden Verbindungen der allgemeinen Formel Sulfobetaines include compounds of the general formula
..
Unter Amidosulfobetainen werden Verbindungen der allgemeinen Amidosulfobetaines include compounds of the general
Formel formula
Unter Sarcosinaten werden Verbindungen der allgemeinen Formel Sarcosinates include compounds of the general formula
..
Unter ethoxylierten Alkoholcarboxylaten werden Among ethoxylated alcohol carboxylates
Verbindungen der allgemeinen Formel Compounds of the general formula
Für die Nebenbestandteile bedeutet For the minor components means
R einen gesättigten Kohlenwasserstoffrest mit 6 - 25 R is a saturated hydrocarbon residue with 6 - 25
C-Atomen, Carbon atoms,
R', R'' und R''' werden unabhängig voneinander aus der R ', R' 'and R' '' are independent of each other from the
Gruppe group
H, -CH2-CH2-OH , -(CH2)2COO- M+ gewählt, H, -CH 2 -CH 2 -OH, - (CH 2 ) 2 COO- M + selected,
Y, Z werden unabhängig voneinander gewählt aus der Gruppe  Y, Z are selected independently from the group
H, Methyl  H, methyl
M+ bedeutet ein Kation, gewählt aus der Gruppe M + means a cation selected from the group
H+, Na+, K+, NH4 +, HmN+(-CH2-CH2-OH)4-m , H + , Na + , K + , NH 4 + , H m N + (-CH 2 -CH 2 -OH) 4-m ,
HmN+(-CH2-CH3)4-m oder HmN+(CH3)4-m , H m N + (-CH 2 -CH 3 ) 4-m or H m N + (CH 3 ) 4-m ,
n bedeutet eine Zahl von 1 - 5 ,  n is a number from 1 to 5,
m bedeutet 0, 1, 2 oder 3.  m means 0, 1, 2 or 3.
Bevorzugt enthalten die erfindungsgemäßen Preferably contain the invention
Reinigungsmittel  cleaning supplies
2 - 10 Gew.-% eines oder mehrerer  2 - 10 wt .-% of one or more
Amidoamin-amphoterer  Amidoamine amphoteric
Tenside  Surfactants
0,5 - 15 Gew.-% eines oder mehrerer Sulfoacetate und  0.5-15% by weight of one or more sulfoacetates and
0,5 - 8 Gew.-% eines oder mehrerer Sulfosuccinate, 5 - 15 Gew.-% eines oder mehrerer Betaine 0.5-8% by weight of one or more sulfosuccinates, 5-15% by weight of one or more betaines
2 - 20 Gew.-% eines oder mehrerer Sarcosinate  2 - 20% by weight of one or more sarcosinates
10 - 20 Gew.-% eines oder mehrerer carboxylierter  10-20% by weight of one or more carboxylated
Alkoholethoxylate,  Alcohol ethoxylates,
bezogen auf das Gesamtgewicht der Zusammensetzung.  based on the total weight of the composition.
Besonders bevorzugt enthalten die erfindungsgemäßen Reinigungsmittel 2 - 8 Gew.-% eines oder mehrerer Amidoamin The cleaning agents according to the invention particularly preferably contain 2-8% by weight of one or more amidoamines
amphoterer Tenside  amphoteric surfactants
0,5 - 5 Gew.-% eines oder mehrerer Sulfoacetate und 0,5 - 5 Gew.-% eines oder mehrerer Sulfosuccinate, 5 - 12 Gew.-% eines oder mehrerer Betaine 0.5-5% by weight of one or more sulfoacetates and 0.5-5% by weight of one or more sulfosuccinates, 5-12% by weight of one or more betaines
2 - 10 Gew.-% eines oder mehrerer Sarcosinate 2 - 10% by weight of one or more sarcosinates
10 - 15 Gew.-% eines oder mehrerer carboxylierter 10-15% by weight of one or more carboxylated
Alkoholethoxylate,  Alcohol ethoxylates,
bezogen auf das Gesamtgewicht der Zusammensetzung. Dabei sollte die Gesamtmenge der Tenside höchstens 50 Gew.-% betragen. based on the total weight of the composition. The total amount of surfactants should not exceed 50% by weight.
Vorteilhaft werden die erfindungsgemäßen Amidoamin- amphoteren Tenside gewählt aus der Gruppe die nach der CTFA-Nomenklatur die Bezeichnung Alkylamphodiacetate, Alkylamphoacetate, Alkylamphodipropionate sowie Alkyl- amphopropionate tragen. The amidoamine amphoteric surfactants according to the invention are advantageously selected from the group bearing the names alkylamphodiacetates, alkylamphoacetates, alkylamphodipropionates and alkylamphopropionates according to the CTFA nomenclature.
Besonders vorteilhaft werden die erfindungsgemäßen Amidoamin amphoteren Tenside gewählt aus der Gruppe, die nach der CTFA-Nomenklatur die Bezeichnungen The amidoamine amphoteric surfactants according to the invention are particularly advantageously selected from the group which has the names according to the CTFA nomenclature
Cocoamphodiacetate, Cocoamphoacetate, Cocoamphodiacetate, Cocoamphoacetate,
Cocoamphopropionate, Cocoamphodipropionate, Cocoamphopropionate, Cocoamphodipropionate,
Lauroamphodiacetate, Lauroamphodiacetate,
Lauroamphoacetate, Lauroamphodipropionate,  Lauroamphoacetate, Lauroamphodipropionate,
Caproamphodiacetate, Caproamphoacetate, Caproamphodiacetate, Caproamphoacetate,
Capryloamphodiacetate, Capryloamphoacetate, Capryloamphodiacetate, Capryloamphoacetate,
Capryloamphodipropionate, Stearoamphodiacetate, Capryloamphodipropionate, Stearoamphodiacetate,
Stearoamphoacetate, Isostearoamphoacetate, Stearoamphoacetate, isostearoamphoacetate,
Isostearoamphodipropionate tragen. Die Sulfoacetat-Tenside werden bevorzugt gewählt aus der Gruppe Wear isostearoamphodipropionate. The sulfoacetate surfactants are preferably selected from the group
Laurylsulfoacetat, Cocoylsulfoacetat, Oleylsulfoacetat, Lauryl sulfoacetate, cocoyl sulfoacetate, oleyl sulfoacetate,
Stearylsulfoacetat und Isostearylsulfoacetat. Stearyl sulfoacetate and isostearyl sulfoacetate.
Die Betaine werden bevorzugt gewählt aus der Gruppe der höheren Alkylbetaine, der Sulfobetaine oder der The betaines are preferably selected from the group of higher alkyl betaines, sulfobetaines or
Amidosulfobetaine, insbesondere der Gruppe aus Amidosulfobetaine, especially from the group
Coco-dimethyl-carboxymethyl-betain, Coco-dimethyl-carboxymethyl-betaine,
Lauryl-carboxymethyl-betain, Lauryl-carboxymethyl-betaine,
Lauryl-dimethyl-(alpha-carboxyethyl)-betain, Lauryl-dimethyl- (alpha-carboxyethyl) betaine,
Cetyl-dimethyl-carboxymethyl-betain, Cetyl-dimethyl-carboxymethyl-betaine,
Lauryl-(bis-(2-hydroxyethyl))-carboxymethyl-betain, Stearyl-(bis-(2-hydroxypropyl))-carboxymethyl-betain, Oleyl-dimethyl-(gamma-carboxypropyl)-betain, Lauryl- (bis- (2-hydroxyethyl)) carboxymethyl-betaine, stearyl- (bis- (2-hydroxypropyl)) -carboxymethyl-betaine, oleyl-dimethyl- (gamma-carboxypropyl) betaine,
Lauryl-(bis-(2-hydroxypropyl)-(alpha-carboxymethyl)-betain, Lauryl- (bis- (2-hydroxypropyl) - (alpha-carboxymethyl) betaine,
Coco-dimethyl-sulfodimethyl-sulfoethyl-betain,  Coco-dimethyl-sulfodimethyl-sulfoethyl-betaine,
Lauryl-(bis-(2-hydroxyethyl))-sulfopropyl-betain, Lauryl- (bis- (2-hydroxyethyl)) sulfopropyl betaine,
Coco-amidopropyl-betain, Cocobetain, Coco amidopropyl betaine, cocobetaine,
Myristyl-amidopropyl-betain. Myristyl amidopropyl betaine.
Die Sulfosuccinate werden bevorzugt gewählt aus der Gruppe der N-acyl-sulfosuccinate, bevorzugt gewählt aus der Gruppe The sulfosuccinates are preferably selected from the group of the N-acyl sulfosuccinates, preferably selected from the group
der Lauryl-sulfosuccinate, der Cocoyl-sulfosuccinate, der Oleyl-sulfosuccinate, der Stearyl-sulfosuccinate, der Isostearyl-sulfosuccinate. the lauryl sulfosuccinate, the cocoyl sulfosuccinate, the oleyl sulfosuccinate, the stearyl sulfosuccinate, the isostearyl sulfosuccinate.
Die carboxylierten Alkoholethoxylate werden bevorzugt gewählt aus der Gruppe The carboxylated alcohol ethoxylates are preferably selected from the group
Natrium-cocoylcarboxyamid-(MEA)-carboxylat,  Sodium cocoylcarboxyamide (MEA) carboxylate,
Natrium-cocoylcarboxyamid-(MEA)-carboxylat,  Sodium cocoylcarboxyamide (MEA) carboxylate,
Natrium-lauroylcarboxyamid-(MEA)-carboxylat,  Sodium lauroyl carboxyamide (MEA) carboxylate,
Natrium-lauroylcarboxyamid-(MEA)-carboxylat. Dabei bedeutet MEA Monoethanolammonium Sodium lauroyl carboxyamide (MEA) carboxylate. MEA means monoethanolammonium
(H3N+(-CH2-CH2-OH) ). (H 3 N + (-CH 2 -CH 2 -OH)).
Die erfindungsgemäßen Zusammensetzungen enthalten außer den vorgenannten Tensiden Wasser und gegebenenfalls die in der Kosmetik üblichen Zusatzstoffe, beispielsweise Parfüm, Verdicker, Farbstoffe, Desodorantien, In addition to the aforementioned surfactants, the compositions according to the invention contain water and, if appropriate, the additives customary in cosmetics, for example perfume, thickeners, dyes, deodorants,
antimikrobielle Stoffe, Perlglanzagentien, antimicrobial agents, pearlescent agents,
Pflanzenextrakte, Vitamine, Wirkstoffe und dergleichen. Plant extracts, vitamins, active ingredients and the like.
Die folgenden Beispiele sollen die erfindungsgemäßen Zusammensetzungen erläutern, ohne daß aber The following examples are intended to illustrate the compositions according to the invention, but without
beabsichtigt ist, die Erfindung auf diese Beispiele zu beschränken. the intention is to limit the invention to these examples.
Die erfindungsgemäßen Zusammensetzungen gemäß den Beispielen 1 - 6 werden wie folgt hergestellt: The compositions according to the invention according to Examples 1-6 are produced as follows:
Die Tenside, das PEG-7-glycerylcocoat, das Perlglanzagens (Glycol-distearat) und etwa 10 Gew.-% Wasser werden unter Rühren auf 70°C erhitzt und mit Natriumlaurylsulfoacetat versetzt. Das Reaktionsgemisch wird langsam auf The surfactants, the PEG-7-glyceryl cocoate, the pearlescent agent (glycol distearate) and about 10% by weight of water are heated to 70 ° C. with stirring and sodium lauryl sulfoacetate is added. The reaction mixture slowly opens up
Raumtemperatur abgekühlt, so daß das Perlglanzagens Cooled to room temperature so that the pearlescent agent
auskristallisieren kann. Zitronensäure und Natriumchlorid werden in einer kleinen Menge Wasser aufgelöst und zu dem Gemisch gegeben. Zuletzt werden das Konservierungsmittel, das Parfüm und das Verdickungsmittel sowie das restliche Wasser zugegeben und die Zusammensetzung homogenisiert. can crystallize out. Citric acid and sodium chloride are dissolved in a small amount of water and added to the mixture. Finally, the preservative, the perfume and the thickener as well as the remaining water are added and the composition is homogenized.

Claims

Patentansprüche Claims
1. Reinigungsmittel, bevorzugt für kosmetische Zwecke, enthaltend 1. Containing cleaning agents, preferably for cosmetic purposes
2 - 10 Gew.-% eines oder mehrerer Amidoamin-amphoterer 2 - 10 wt .-% of one or more amidoamine amphoteric
Tenside  Surfactants
0,5 - 15 Gew.-% eines oder mehrerer Sulfoacetat-Tenside und gegebenenfalls eines oder mehrere der Tenside gewählt aus der Gruppe der Sulfosuccinate der allgemeinen Formel  0.5 - 15 wt .-% of one or more sulfoacetate surfactants and optionally one or more of the surfactants selected from the group of sulfosuccinates of the general formula
der Betaine der allgemeinen Formel  of betaines of the general formula
der Sulfobetaine der al lgemeinen Formel the sulfobetaines of the general formula
der Amidosulfobetaine der allgemeinen Formel the amidosulfobetaines of the general formula
der Sarcosinate der allgemeinen Formel sowie der ethoxylierten Alkoholcarboxylate der allgemeinen Formel the sarcosinate of the general formula and the ethoxylated alcohol carboxylates of the general formula
wobei  in which
R einen gesättigten Kohlenwasserstoffrest mit 6 - 25 R is a saturated hydrocarbon residue with 6 - 25
C-Atomen bedeutet, Carbon atoms means
R', R'' und R''' unabhängig voneinander aus der Gruppe R ', R' 'and R' '' independently of one another from the group
H, -CH2-CH2-OH , -(CH2)2COO- M+ gewählt werden, Y, Z unabhängig voneinander gewählt werden aus der GruppeH, -CH 2 -CH 2 -OH, - (CH 2 ) 2 COO- M + can be selected, Y, Z can be selected independently of one another from the group
H, Methyl, H, methyl,
M+ ein Kation, gewählt aus der Gruppe M + a cation selected from the group
H+, Na+, K+, NH4 +, HmN+(-CH2-CH2-OH)4-m , H + , Na + , K + , NH 4 + , H m N + (-CH 2 -CH 2 -OH) 4-m ,
HmN+(-CH2-CH3)4-m oder HmN+(CH3)4-m bedeutet, H m N + (-CH 2 -CH 3 ) 4-m or H m N + (CH 3 ) 4-m ,
n eine Zahl von 1 - 5 bedeutet,  n is a number from 1 to 5,
m 0, 1, 2 oder 3 bedeutet. 2. Reinigungsmittel nach Anspruch 1, enthaltend, bezogen auf die Gesamtzusammensetzung  m means 0, 1, 2 or 3. 2. Cleaning agent according to claim 1, containing, based on the total composition
0,5 - 8 Gew.-% eines oder mehrerer Sulfosuccinate, 0.5 - 8% by weight of one or more sulfosuccinates,
5 - 15 Gew.-% eines oder mehrerer Betaine  5 - 15% by weight of one or more betaines
2 - 20 Gew.-% eines oder mehrerer Sarcosinate  2 - 20% by weight of one or more sarcosinates
10 - 20 Gew.-% eines oder mehrerer ethoxylierter  10-20% by weight of one or more ethoxylated
Alkoholcarboxylate. Alcohol carboxylates.
3. Reinigungsmittel nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß das oder die Amidoamin-amphoteren 3. Cleaning agent according to claim 1 or 2, characterized in that the amido amine or amphoterics
Tenside gewählt werden aus der Gruppe der höheren Surfactants are selected from the group of higher ones
Alkylamphodiacetate, der höheren Alkylamphoacetate, der höheren Alkylamphodipropionate, der höheren Alkyl amphodiacetates, the higher alkyl amphoacetates, the higher alkyl amphodipropionates, the higher
Alkylamphopropionate. Alkyl amphopropionates.
4. Reinigungsmittel nach einem der Ansprüche 1 - 3 dadurch gekennzeichnet, daß das oder die 4. Cleaning agent according to one of claims 1-3, characterized in that the or
Amidoamin-amphoteren Tenside gewählt werden aus der Gruppe Amidoamine-amphoteric surfactants are selected from the group
Cocoamphodiacetate, Cocoamphoacetate, Cocoamphopropionate, Cocoamphodipropionate, Lauroamphodiacetate, Cocoamphodiacetate, Cocoamphoacetate, Cocoamphopropionate, Cocoamphodipropionate, Lauroamphodiacetate,
Lauroamphoacetate, Lauroamphodipropionate, Lauroamphoacetate, Lauroamphodipropionate,
Caproamphodiacetate, Caproamphoacetate, Caproamphodiacetate, Caproamphoacetate,
Capryloamphodiacetate, Capryloamphoacetate, Capryloamphodiacetate, Capryloamphoacetate,
Capryloamphodipropionate, Stearoamphodiacetate, Capryloamphodipropionate, Stearoamphodiacetate,
Stearoamphoacetate, Isostearoampnoacetate, Stearoamphoacetate, isostearoampnoacetate,
Isostearoamphodipropionate. Isostearoamphodipropionate.
5. Reinigungsmittel nach einem der Ansprüche 1 - 4 , dadurch gekennzeichnet, daß das oder die Sulfoacetat-Tenside gewählt werden aus der Gruppe 5. Cleaning agent according to one of claims 1-4, characterized in that the sulfoacetate or surfactants are selected from the group
Laurylsulfoacetat, Cocoylsulfoacetat, Oleylsulfoacetat, Stearylsulfoacetat und Isostearylsulfoacetat.  Laurylsulfoacetate, cocoylsulfoacetate, oleylsulfoacetate, stearylsulfoacetate and isostearylsulfoacetate.
6. Reinigungsmittel nach einem der Ansprüche 1 - 5 , dadurch gekennzeichnet, daß das oder die Betaine gewählt werden aus der Gruppe der höheren Alkyl-betaine, der 6. Cleaning agent according to one of claims 1-5, characterized in that the betaine or betaines are selected from the group of higher alkyl betaine, the
Sulfo-betaine oder der Amidosulfo-betaine. Sulfo-betaine or the Amidosulfo-betaine.
7. Reinigungsmittel nach einem der Ansprüche 1 - 6 , dadurch gekennzeichnet, daß das oder die Betaine gewählt werden aus der Gruppe 7. Cleaning agent according to one of claims 1-6, characterized in that the betaine or betaines are selected from the group
Coco-dimethyl-carboxymethyl-betain, Coco-dimethyl-carboxymethyl-betaine,
Lauryl-carboxymethyl-betain, Lauryl-carboxymethyl-betaine,
Lauryl-dimethyl-(alpha-carboxyethyl)-betain, Cetyl-dimethyl-carboxymethyl-betain, Lauryl-dimethyl- (alpha-carboxyethyl) betaine, Cetyl-dimethyl-carboxymethyl-betaine,
Lauryl-(bis-(2-hydroxyethyl))-carboxymethyl-betain, Lauryl- (bis- (2-hydroxyethyl)) carboxymethyl betaine,
Stearyl-(bis-(2-hydroxypropyl))-carboxymethyl-betain, Stearyl- (bis- (2-hydroxypropyl)) carboxymethyl betaine,
01eyl-dimethyl-(gamma-carboxypropyl)-betain, 01eyl-dimethyl- (gamma-carboxypropyl) betaine,
Lauryl-(bis-(2-hydroxypropyl)-(alpha-carboxymethyl)-betain, Coco-dimethyl-sulfodimethyl-sulfoethyl-betain, Lauryl- (bis- (2-hydroxypropyl) - (alpha-carboxymethyl) betaine, coco-dimethyl-sulfodimethyl-sulfoethyl-betaine,
Lauryl-(bis-(2-hydroxyethyl))-sulfopropyl-betain, Lauryl- (bis- (2-hydroxyethyl)) sulfopropyl betaine,
Coco-amidopropyl-betain, Cocobetain, Coco amidopropyl betaine, cocobetaine,
Myristyl-amidopropyl-betain. Myristyl amidopropyl betaine.
8. Reinigungsmittel nach einem der Ansprüche 1 - 7 , dadurch gekennzeichnet, daß das oder die Sulfosuccinate gewählt werden aus der Gruppe der N-acyl-sulfosuccinate, bevorzugt gewählt aus der Gruppe 8. Cleaning agent according to one of claims 1-7, characterized in that the one or more sulfosuccinates are selected from the group of N-acylsulfosuccinates, preferably selected from the group
der Lauryl-sulfosuccinate, der Cocoyl-sulfosuccinate, der Oleyl-sulfosuccinate, der Stearyl-sulfosuccinate, der Isostearyl-sulfosuccinate. the lauryl sulfosuccinate, the cocoyl sulfosuccinate, the oleyl sulfosuccinate, the stearyl sulfosuccinate, the isostearyl sulfosuccinate.
9. Reinigungsmittel nach einem der Ansprüche 1 - 8 , dadurch gekennzeichnet, daß das oder die carboxylierten Alkoholethoxylate gewählt werden aus der Gruppe 9. Cleaning agent according to one of claims 1-8, characterized in that the carboxylated alcohol ethoxylate (s) are selected from the group
Natrium-cocoylcarboxyamid-(MEA-4)-carboxylat, Sodium cocoylcarboxyamide (MEA-4) carboxylate,
Natrium-cocoylcarboxyamid-(MEA-3)-carboxylat, Sodium cocoylcarboxyamide (MEA-3) carboxylate,
Natrium-lauroylcarboxyamid-(MEA-4)-carboxylat, Sodium lauroyl carboxyamide (MEA-4) carboxylate,
Natrium-lauroylcarboxyamid-(MEA-3)-carboxylat, Sodium lauroyl carboxyamide (MEA-3) carboxylate,
10. Reinigungsmittel nach einem der Ansprüche 1 - 9 , enthaltend 10. Cleaning agent according to one of claims 1-9, containing
2 - 8 Gew.-% eines oder mehrerer Amidoamin-amphoterer  2-8% by weight of one or more amidoamine amphoterics
Tenside  Surfactants
0,5 - 5 Gew.-% eines oder mehrerer Sulfoacetat-Tenside und 0,5 - 5 Gew.-% eines oder mehrerer Sulfosuccinate, 0.5-5% by weight of one or more sulfoacetate surfactants and 0.5-5% by weight of one or more sulfosuccinates,
5 - 12 Gew.-% eines oder mehrerer Betaine 5 - 12% by weight of one or more betaines
2 - 10 Gew.-% eines oder mehrerer Sarcosinate 2 - 10% by weight of one or more sarcosinates
10 - 15 Gew.-% eines oder mehrerer carboxylierter  10-15% by weight of one or more carboxylated
Alkoholethoxylate.  Alcohol ethoxylates.
mit der Maßgabe, daß die Gesamtmenge der Tenside höchstens 50 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung beträgt. with the proviso that the total amount of surfactants at most 50 wt .-%, based on the total weight of the composition.
EP91905070A 1990-03-10 1991-02-26 Cosmetic cleansing agent Expired - Lifetime EP0519942B1 (en)

Applications Claiming Priority (3)

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DE4007638 1990-03-10
DE4007638A DE4007638A1 (en) 1990-03-10 1990-03-10 COSMETIC DETERGENTS
PCT/DE1991/000163 WO1991013610A1 (en) 1990-03-10 1991-02-26 Cosmetic cleansing agent

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EP0519942A1 true EP0519942A1 (en) 1992-12-30
EP0519942B1 EP0519942B1 (en) 1994-10-05

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JP (1) JPH05504576A (en)
AT (1) ATE112485T1 (en)
DE (2) DE4007638A1 (en)
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FR2931666B1 (en) 2008-06-02 2010-05-28 Oreal SELF-FOAMING SOAP-FREE GEL BASED ON N-ACYLSARCOSINE; SHAVING METHOD; CLEANING PROCESS

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US11624041B2 (en) 2007-10-11 2023-04-11 Promega Corporation Cleavable surfactants

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JPH05504576A (en) 1993-07-15
DE4007638A1 (en) 1991-09-12
DE59103178D1 (en) 1994-11-10
ES2062771T3 (en) 1994-12-16
ATE112485T1 (en) 1994-10-15
DK0519942T3 (en) 1995-04-18
EP0519942B1 (en) 1994-10-05

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