EP0518707A2 - Spark plug with a platinum tip on its outer electrode - Google Patents
Spark plug with a platinum tip on its outer electrode Download PDFInfo
- Publication number
- EP0518707A2 EP0518707A2 EP92305477A EP92305477A EP0518707A2 EP 0518707 A2 EP0518707 A2 EP 0518707A2 EP 92305477 A EP92305477 A EP 92305477A EP 92305477 A EP92305477 A EP 92305477A EP 0518707 A2 EP0518707 A2 EP 0518707A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- outer electrode
- spark plug
- tip
- core metal
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 229910052697 platinum Inorganic materials 0.000 title claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 claims abstract description 26
- 239000002184 metal Substances 0.000 claims abstract description 26
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011159 matrix material Substances 0.000 claims abstract description 12
- 239000000956 alloy Substances 0.000 claims abstract description 7
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 7
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 7
- 239000012212 insulator Substances 0.000 claims abstract description 6
- 238000002485 combustion reaction Methods 0.000 claims description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 238000003466 welding Methods 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 230000004323 axial length Effects 0.000 description 4
- 239000010953 base metal Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 230000008646 thermal stress Effects 0.000 description 4
- 241001600451 Chromis Species 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000007792 addition Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
- H01T13/00—Sparking plugs
- H01T13/20—Sparking plugs characterised by features of the electrodes or insulation
- H01T13/39—Selection of materials for electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
- H01T13/00—Sparking plugs
- H01T13/20—Sparking plugs characterised by features of the electrodes or insulation
- H01T13/32—Sparking plugs characterised by features of the electrodes or insulation characterised by features of the earthed electrode
Definitions
- This invention relates to a spark plug having a platinum tip welded to its outer electrode, and particularly concerns an improvement intended to avoid deterioration of the welded portion between the tip and the outer electrode.
- the outer electrode be made of a copper core cladded by a nickel-alloy matrix, while platinum tips are welded to the opposing ends of both outer and center electrodes so as to improve oxidation and corrosion-resistance.
- the outer electrode Compared to the center electrode, the outer electrode, however, is exposed to higher ambient temperature to such a degree that the platinum tip tends to fall off the outer electrode at the welded portion.
- the outer electrode is all the more exposed to higher ambient temperature, and successively cooled by newly introduced mixture of gasoline.
- a spark plug comprising a center electrode disposed within an insulator in a metallic shell so that the front end of the center electrode forms a spark gap with an outer electrode extending from the metallic shell, and a platinum tip welded to the outer electrode so as to oppose the front end of the center electrode;
- the outer electrode comprising a heat-conductive core metal cladded by a matrix metal which is made from nickel-based alloy containing 10 - 20% by weight of chromium; the tip being placed so that the distance between a circumferential edge of the weld between the outer electrode and the tip and the front end of the core metal is between 0.0 mm to 2.0 mm.
- a significant amount of heat is smoothly dissipated from a front end of the outer electrode to the metallic shell by way of the core metal.
- the core metal is liable to be softened, and the outer electrode to deform at the time of welding the tip to the outer electrode.
- the platinum tip begins to fall off the outer electrode when the spaced distance exceeds 2.0 mm.
- the spaced distance is determined to fall within the range from 0.0 mm to 2.0 mm.
- a spark plug shown in Fig. 1 there is shown a cylindrical metallic shell 2, to a front end of which a L-shaped outer electrode 1 is welded.
- a tubular insulator 3 is placed whose inner space acts as an axial bore 31.
- a middle axis 4 is placed whose rear and has a terminal 41 to which a high tension cord of an ignition circuit (not shown) is to be connected.
- a glass sealant resistor 42 and a center electrode 5 are in turn connected in linear relationship with each other.
- a front end 5A of the center electrode 5 extends from the metallic shell 2 to oppose a front end 1A of the outer electrode 1 so as to form a spark gap (Gp) therebetween.
- the spark plug is an extension-type one in which the front end 5A of the center electrode 5 extends from the metallic shell 2 by 1.5 ⁇ 15.0 mm so that the front end 5A projects into a combustion chamber (Ch) by 3.0 ⁇ 17.0 mm when the spark plug is mounted on an internal combustion engine.
- the outer electrode 1 consists a composite base metal 10 having a heat-conductive core metal 12 cladded by a nickel-alloyed matrix 11 which contains 10 ⁇ 20 wt% chrominum.
- a column platinum tip 6 is welded at a welded portion (WI) in a manner to oppose the front end 5A of the center electrode 5. It is noted that the tip 6 may contain 20 wt% iridium (Ir).
- the nickel-alloyed matrix 11 increases its oxidation-resistance with an increased addition of chromi um, while inviting an increased hardness and reduced thermal conductivity.
- the nickel-alloyed matrix 11 containing chromi um less than 10 wt% causes to deteriorate its oxidation-resistance.
- the chromi um content is 10 ⁇ 20 wt%.
- the core metal 12 is made from copper, silver, copper-based alloy or silver-based alloy, and having a front end 12a and a rear end 12b, the latter of which is placed in heat-transferable contact relationship with a front end of the metallic shell 2.
- the core metal 12 clads an innermost core 13 which is made of pure nickel or pure iron.
- the core metal 12 contributes to improving a weld-intensity of the outer electrode 1 to the metallic shell 2, and at the same time, preventing the deformation of the outer electrode 1 which arises from the heat-cool cycle of the internal combustion engine.
- the welded portion (WI) of the tip 6 is arranged to terminate slightly short of the core metal 12, so that a spaced distance (L) between a circumferential edge (Wx) of the welded portion (WI) and the front end 12a of the core metal 12 falls within a range from 0.0 mm to 2.0 mm as shown in Fig. 2.
- the nickel-alloyed matrix 11 which contains 10 ⁇ 20 wt% chronium, is somewhat inferior in thermal conductivity but superior in both high-temperature strength and oxidation -resistance compared to a nickel-alloyed outer electrode which usually contains more than 90 wt% nickel.
- the front end 12a of the core metal 12 is extended toward the circumferential edge (Wx) of the welded portion (WI) within a range from 0.0 mm to 2.0 mm.
- the spaced distance (L) makes it possible to prevent an excessive temperature rise of the front end 1A of the outer electrode 1, and thus prevents increased thermal stress from occurring at the welded portion (WI), keeping the tip 6 in place.
- the straight-type outer electrode is firstly welded to the metallic shell 2. Then, the insulator 3 is placed within the metallic shell 2. Before bending the outer electrode 1 into L-shaped configuration, the tip 6 is secured to the outer electrode 1 by means of resistance welding.
- the copper or silver core 12 may be softended and buckled during the resistance welding when the circumferential edge (Wx) of the welded portion (WI) partly overlaps with the front end 12a of the core metal 12.
- the lower limit of the spaced distance (L) is determined to be 0.0 mm, preventing an overlapping relationship between the circumferential edge (Wx) of the welded portion (WI) and the front end 12a of the core metal 12.
- the center electrode 5 consists a composite base metal 50 having a copper core 51 cladded by a nickel-alloyed matrix 52 which contains more than 90 wt% nickel.
- a nickel-alloyed layer 53 which contains 20 ⁇ 25 wt% chronium is secured by means of resistance welding.
- a platinum tip 7 is secured by means of resistance welding. The platinum tip 7 has a diameter-increased portion 71 welded to the nickel-alloyed layer 53, and a diameter-reduced portion 72 which opposes the platinum tip 6 across the spark gap (Gp).
- outer configuration of the nickel-alloyed layer 53 and the platinum tip 7 may be shaped after carrying out the resistance welding in order to prevent their unfavorable deformations during the welding operation.
- the nickel-alloyed layer 53 may be left out, and the platinum tip 7 may be welded directly to a front end of the diameter-reduced portion of the nickel-alloyed matrix 52 instead of the nickel-alloyed layer 53.
- Fig. 3 shows a graph showing how corrosion (S) of the welded portion (WI) changes with operating time (T) and the spaced distance (L) after carrying out an endurance experiment with the spark plug mounted on a four-cylinder, 2000 cc, four-cycle internal combustion engine which is alternately operated idling and full throttle at the heat-cool cycle process.
- Fig. 3a shows a partly broken outer electrode 1 to define an axial length (A) of the platinum tip 6 and an axial length (B) of the welded portion. (WI).
- the amount of corrosion (S) of the welded portion (WI) is expressed by (A-B)/A for the purpose of convenience.
Landscapes
- Spark Plugs (AREA)
Abstract
Description
- This invention relates to a spark plug having a platinum tip welded to its outer electrode, and particularly concerns an improvement intended to avoid deterioration of the welded portion between the tip and the outer electrode.
- With the recent demand for cleaner emission gas and enhanced fuel consumption from internal combustion engines, it has been needed to run the engine with a leaner mixture of gasoline. With higher temperatures in the combustion chamber the outer electrode of the spark plug tends to be exposed to higher temperatures.
- With the further demand for continuous running of engines for more than 100,000 Km without replacing the spark plugs, it has been suggested that the outer electrode be made of a copper core cladded by a nickel-alloy matrix, while platinum tips are welded to the opposing ends of both outer and center electrodes so as to improve oxidation and corrosion-resistance.
- Compared to the center electrode, the outer electrode, however, is exposed to higher ambient temperature to such a degree that the platinum tip tends to fall off the outer electrode at the welded portion.
- In an extension-type spark plug in which a firing end of the spark plug is extended into the combustion chamber, the outer electrode is all the more exposed to higher ambient temperature, and successively cooled by newly introduced mixture of gasoline.
- As a result, a greater intensity of thermal stress occurs at the welded portion between the tip and the outer electrode so that the tip is liable to fall off the outer electrode.
- Therefore, it is an object of the invention to provide a spark plug having a platinum tip welded to an outer electrode which is capable of effectively reducing the effect of thermal stress between the platinum tip and the outer electrode, thus contributing to an extended period of service life with a relatively simple structure.
- According to the present invention, there is provided a spark plug comprising a center electrode disposed within an insulator in a metallic shell so that the front end of the center electrode forms a spark gap with an outer electrode extending from the metallic shell, and a platinum tip welded to the outer electrode so as to oppose the front end of the center electrode;
the outer electrode comprising a heat-conductive core metal cladded by a matrix metal which is made from nickel-based alloy containing 10 - 20% by weight of chromium;
the tip being placed so that the distance between a circumferential edge of the weld between the outer electrode and the tip and the front end of the core metal is between 0.0 mm to 2.0 mm. - Such is the dimensional arrangement between the platinum tip and the core metal that a significant amount of heat is smoothly dissipated from a front end of the outer electrode to the metallic shell by way of the core metal. Thus prevents the temperature of the front end of the outer electrode from rising excessively, and reduces the thermal stress occurring at the welded portion between the tip and the outer electrode, and at the same time, reduces oxidation of the welded portion so as to prevent the tip from falling off the outer electrode.
- When the welded portion is positioned so as partly to overlap with the front end of the core metal, the core metal is liable to be softened, and the outer electrode to deform at the time of welding the tip to the outer electrode.
- Meanwhile, the platinum tip begins to fall off the outer electrode when the spaced distance exceeds 2.0 mm. Hence the spaced distance is determined to fall within the range from 0.0 mm to 2.0 mm.
- The invention will be further understood from,the following description, when taken together with the attached drawings which are given by way of example only, and in which:
- Fig. 1 is a sectional view of a spark plug.
- Fig. 2 is an enlarged longitudinal cross sectional view of an outer electrode showing the front end portion of the spark plug;
- Fig. 3 is a graph showing how corrosion (S) changes with operating time (T) and a spaced distance (L); and
- Fig. 3a is a partly broken view of the outer electrode to define an axial length (A) of a platinum tip and an axial length (B) of a welded portion.
- Referring to a spark plug shown in Fig. 1, there is shown a cylindrical
metallic shell 2, to a front end of which a L-shapedouter electrode 1 is welded. Within themetallic shell 2, atubular insulator 3 is placed whose inner space acts as anaxial bore 31. Within theaxial bore 31 of theinsulator 3, amiddle axis 4 is placed whose rear and has aterminal 41 to which a high tension cord of an ignition circuit (not shown) is to be connected. To a front end of themiddle axis 4, aglass sealant resistor 42 and acenter electrode 5 are in turn connected in linear relationship with each other. Afront end 5A of thecenter electrode 5 extends from themetallic shell 2 to oppose afront end 1A of theouter electrode 1 so as to form a spark gap (Gp) therebetween. - In this instance, the spark plug is an extension-type one in which the
front end 5A of thecenter electrode 5 extends from themetallic shell 2 by 1.5 ∼ 15.0 mm so that thefront end 5A projects into a combustion chamber (Ch) by 3.0 ∼ 17.0 mm when the spark plug is mounted on an internal combustion engine. - The
outer electrode 1 consists acomposite base metal 10 having a heat-conductive core metal 12 cladded by a nickel-alloyed matrix 11 which contains 10 ∼ 20 wt% chrominum. To thefront end 1A of the nickel-alloyed matrix 11, acolumn platinum tip 6 is welded at a welded portion (WI) in a manner to oppose thefront end 5A of thecenter electrode 5. It is noted that thetip 6 may contain 20 wt% iridium (Ir). - The nickel-
alloyed matrix 11 increases its oxidation-resistance with an increased addition of chromi um, while inviting an increased hardness and reduced thermal conductivity. The nickel-alloyed matrix 11 containing chromi um less than 10 wt% causes to deteriorate its oxidation-resistance. Hence the chromi um content is 10 ∼ 20 wt%. - The
core metal 12 is made from copper, silver, copper-based alloy or silver-based alloy, and having afront end 12a and arear end 12b, the latter of which is placed in heat-transferable contact relationship with a front end of themetallic shell 2. - In order to provide the
composite base metal 10 with three-layer structure, thecore metal 12 clads aninnermost core 13 which is made of pure nickel or pure iron. Thus contributes to improving a weld-intensity of theouter electrode 1 to themetallic shell 2, and at the same time, preventing the deformation of theouter electrode 1 which arises from the heat-cool cycle of the internal combustion engine. - The welded portion (WI) of the
tip 6 is arranged to terminate slightly short of thecore metal 12, so that a spaced distance (L) between a circumferential edge (Wx) of the welded portion (WI) and thefront end 12a of thecore metal 12 falls within a range from 0.0 mm to 2.0 mm as shown in Fig. 2. - The nickel-
alloyed matrix 11, which contains 10 ∼ 20 wt% chronium, is somewhat inferior in thermal conductivity but superior in both high-temperature strength and oxidation -resistance compared to a nickel-alloyed outer electrode which usually contains more than 90 wt% nickel. In order to compensate for the insufficient thermal conductivity of the nickel-alloyed matrix 11, thefront end 12a of thecore metal 12 is extended toward the circumferential edge (Wx) of the welded portion (WI) within a range from 0.0 mm to 2.0 mm. The spaced distance (L) makes it possible to prevent an excessive temperature rise of thefront end 1A of theouter electrode 1, and thus prevents increased thermal stress from occurring at the welded portion (WI), keeping thetip 6 in place. - In assembling the spark plug, the straight-type outer electrode is firstly welded to the
metallic shell 2. Then, theinsulator 3 is placed within themetallic shell 2. Before bending theouter electrode 1 into L-shaped configuration, thetip 6 is secured to theouter electrode 1 by means of resistance welding. The copper orsilver core 12 may be softended and buckled during the resistance welding when the circumferential edge (Wx) of the welded portion (WI) partly overlaps with thefront end 12a of thecore metal 12. Hence the lower limit of the spaced distance (L) is determined to be 0.0 mm, preventing an overlapping relationship between the circumferential edge (Wx) of the welded portion (WI) and thefront end 12a of thecore metal 12. - On the other hand, the
center electrode 5 consists acomposite base metal 50 having acopper core 51 cladded by a nickel-alloyed matrix 52 which contains more than 90 wt% nickel. To a front end of thecomposite base metal 50. A nickel-alloyed layer 53 which contains 20 ∼ 25 wt% chronium is secured by means of resistance welding. To a front end of the nickel-alloyedlayer 53, aplatinum tip 7 is secured by means of resistance welding. Theplatinum tip 7 has a diameter-increasedportion 71 welded to the nickel-alloyedlayer 53, and a diameter-reducedportion 72 which opposes theplatinum tip 6 across the spark gap (Gp). - It is noted that outer configuration of the nickel-alloyed
layer 53 and theplatinum tip 7 may be shaped after carrying out the resistance welding in order to prevent their unfavorable deformations during the welding operation. - It is noted that the nickel-
alloyed layer 53 may be left out, and theplatinum tip 7 may be welded directly to a front end of the diameter-reduced portion of the nickel-alloyed matrix 52 instead of the nickel-alloyedlayer 53. - Fig. 3 shows a graph showing how corrosion (S) of the welded portion (WI) changes with operating time (T) and the spaced distance (L) after carrying out an endurance experiment with the spark plug mounted on a four-cylinder, 2000 cc, four-cycle internal combustion engine which is alternately operated idling and full throttle at the heat-cool cycle process.
- In this experiment, Fig. 3a shows a partly broken
outer electrode 1 to define an axial length (A) of theplatinum tip 6 and an axial length (B) of the welded portion. (WI). The amount of corrosion (S) of the welded portion (WI) is expressed by (A-B)/A for the purpose of convenience. - As a result, it is found that a rapid corrosion occurs at the welded portion (WI) in the cases when the spaced distance is 5.0 mm or 3.0 mm with the
innermost core 13 provided in thecore metal 12 to form the three-layer structure, and in the case when no core metal is provided. - It is also found that only small amount of corrosion (S) occurs at the welded portion (WI), but the outer electrode is subjected to an unfavorable deformation (the spark gap widens) when the spaced distance is 0.0 mm with no innermost core provided in the
core metal 12 to merely form a two-layer structure. Therefore it is desirable to exclude the case when the spaced distance is 0.0 mm upon putting the invention into practical use. - It is, however, understood that only small amount of corrosion (S) occurs at the welded portion (WI) when the spaced distance is kept within the range from 0.0 mm to 2.0 mm.
- It is appreciated that the invention is not restricted to the extension-type spark plug in which the
center electrode 5 projects into the combustion chamber (Ch). - While the invention has been described with reference to the specific embodiments, it is understood that this description is not to be construed in a limiting sense in as much as various modifications and additions to the specific embodiments may be made by skilled artisan without departing from the scope of the invention as defined in the appended claims.
Claims (4)
- A spark plug comprising a center electrode disposed within an insulator in a metallic shell so that the front end of the center electrode forms a spark gap with an outer electrode extending from the metallic shell, and a platinum tip welded to the outer electrode so as to oppose the front end of the center electrode;
the outer electrode comprising a heat-conductive core metal cladded by a matrix metal which is made from nickel-based alloy containing 10 ∼ 20% by weight of chromium;
the tip being placed so that the distance between a circumferential edge of the weld between the outer electrode and the tip and the front end of the core metal is between 0.0 mm to 2.0 mm. - A spark plug according to claim 1, wherein the core metal is made of one of the following: silver, copper, a silver-based alloy or a copper-based alloy.
- A spark plug according to claim 1 or 2, wherein an innermost core is provided to be cladded by the core metal, the innermost core being made of substantially pure nickel or substantially pure iron.
- An internal combustion engine comprising a spark plug according to any preceding claim.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14209491A JP3226294B2 (en) | 1991-06-13 | 1991-06-13 | Spark plug |
JP142094/91 | 1991-06-13 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0518707A2 true EP0518707A2 (en) | 1992-12-16 |
EP0518707A3 EP0518707A3 (en) | 1993-11-18 |
EP0518707B1 EP0518707B1 (en) | 1996-05-15 |
Family
ID=15307290
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92305477A Expired - Lifetime EP0518707B1 (en) | 1991-06-13 | 1992-06-15 | Spark plug with a platinum tip on its outer electrode |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0518707B1 (en) |
JP (1) | JP3226294B2 (en) |
DE (1) | DE69210686T2 (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5456624A (en) * | 1994-03-17 | 1995-10-10 | Alliedsignal Inc. | Spark plug with fine wire rivet firing tips and method for its manufacture |
EP0725463A1 (en) * | 1995-02-01 | 1996-08-07 | Ngk Spark Plug Co., Ltd | A spark plug for an internal combustion engine |
US5556315A (en) * | 1993-07-06 | 1996-09-17 | Ngk Spark Plug Co., Ltd. | Method of making a spark plug for an internal combustion engine |
EP1143587A2 (en) * | 2000-04-03 | 2001-10-10 | Denso Corporation | Spark plug for internal combustion engines and manufacturing method therof |
CZ297483B6 (en) * | 2001-11-29 | 2006-12-13 | BRISK Tábor a. s. | Spark plug |
CN103931065B (en) * | 2011-12-08 | 2015-12-23 | 日本特殊陶业株式会社 | Spark plug |
AT522986A1 (en) * | 2019-10-04 | 2021-04-15 | Brigitte Gruber | spark plug |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4261573B2 (en) | 2006-11-23 | 2009-04-30 | 日本特殊陶業株式会社 | Spark plug |
JP4405572B1 (en) | 2007-09-17 | 2010-01-27 | 日本特殊陶業株式会社 | Spark plug |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2296033A (en) * | 1941-01-18 | 1942-09-15 | Gen Motors Corp | Spark plug |
JPS61179837A (en) * | 1985-02-05 | 1986-08-12 | Toshiba Corp | Nickel-base alloy for spark plug electrode |
DE8811215U1 (en) * | 1987-09-17 | 1988-10-20 | Champion Spark Plug Europe S.A., Binche, Peronnes | Spark plug for an internal combustion engine |
EP0474351A1 (en) * | 1990-09-07 | 1992-03-11 | Ngk Spark Plug Co., Ltd | An outer electrode for spark plug and a method of manufacturing thereof |
-
1991
- 1991-06-13 JP JP14209491A patent/JP3226294B2/en not_active Expired - Lifetime
-
1992
- 1992-06-15 DE DE1992610686 patent/DE69210686T2/en not_active Expired - Lifetime
- 1992-06-15 EP EP92305477A patent/EP0518707B1/en not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2296033A (en) * | 1941-01-18 | 1942-09-15 | Gen Motors Corp | Spark plug |
JPS61179837A (en) * | 1985-02-05 | 1986-08-12 | Toshiba Corp | Nickel-base alloy for spark plug electrode |
DE8811215U1 (en) * | 1987-09-17 | 1988-10-20 | Champion Spark Plug Europe S.A., Binche, Peronnes | Spark plug for an internal combustion engine |
EP0474351A1 (en) * | 1990-09-07 | 1992-03-11 | Ngk Spark Plug Co., Ltd | An outer electrode for spark plug and a method of manufacturing thereof |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5556315A (en) * | 1993-07-06 | 1996-09-17 | Ngk Spark Plug Co., Ltd. | Method of making a spark plug for an internal combustion engine |
US5456624A (en) * | 1994-03-17 | 1995-10-10 | Alliedsignal Inc. | Spark plug with fine wire rivet firing tips and method for its manufacture |
EP0725463A1 (en) * | 1995-02-01 | 1996-08-07 | Ngk Spark Plug Co., Ltd | A spark plug for an internal combustion engine |
EP1143587A2 (en) * | 2000-04-03 | 2001-10-10 | Denso Corporation | Spark plug for internal combustion engines and manufacturing method therof |
EP1143587A3 (en) * | 2000-04-03 | 2001-12-19 | Denso Corporation | Spark plug for internal combustion engines and manufacturing method therof |
US6523515B2 (en) | 2000-04-03 | 2003-02-25 | Denso Corporation | Spark plug for internal combustion engines and manufacturing method thereof |
CZ297483B6 (en) * | 2001-11-29 | 2006-12-13 | BRISK Tábor a. s. | Spark plug |
CN103931065B (en) * | 2011-12-08 | 2015-12-23 | 日本特殊陶业株式会社 | Spark plug |
AT522986A1 (en) * | 2019-10-04 | 2021-04-15 | Brigitte Gruber | spark plug |
AT522986B1 (en) * | 2019-10-04 | 2023-06-15 | Brigitte Gruber | spark plug |
Also Published As
Publication number | Publication date |
---|---|
JPH04366581A (en) | 1992-12-18 |
EP0518707A3 (en) | 1993-11-18 |
EP0518707B1 (en) | 1996-05-15 |
DE69210686D1 (en) | 1996-06-20 |
JP3226294B2 (en) | 2001-11-05 |
DE69210686T2 (en) | 1996-09-19 |
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