EP0516119B1

EP0516119B1 - Hollow trilobal cross-section filament and spinneret plate for the manufacture of it

Info

Publication number: EP0516119B1
Application number: EP19920109046
Authority: EP
Inventors: Ling Yeh; Richard Kotek
Original assignee: BASF Corp
Current assignee: BASF Corp
Priority date: 1991-05-31
Filing date: 1992-05-29
Publication date: 1998-01-21
Anticipated expiration: 2012-05-29
Also published as: CZ161992A3; YU56992A; EP0516119A2; SK161992A3; DE69224103D1; EP0516119A3; ES2111010T3; YU48646B; DE69224103T2

Description

The present invention relates to a trilobal synthetic polymeric filament having a single void extending approximately axially central, the total cross-sectional void area of the filament being between 3 and 10 percent void.

The present invention furthermore relates to a carpet made from these filaments and a spinneret plate for the manufacture of these filaments.

For many uses of fibrous synthetic polymers, it is desirable to minimize the weight of fiber needed to spread over an area. This qualitative property of a fiber is known as "cover". Another quality of fibers for certain end uses (like for carpet yarn) is the fiber's ability to hide soil. Yet, while for some end uses it is important to obtain high cover and good soil hiding, sparkle and/or luster should not be sacrificed. For example, carpet yarns should provide the greatest cover and hide soil well, yet remain lustrous. Efforts to achieve a fabric having these characteristics have largely failed since fiber properties leading to soil hiding tend to lessen luster. Presently, Applicants are unaware of any fiber which effectively achieves all these qualities.

Trilobal fibers are known to provide cover superior to round cross-sections and it is known to make trilobal and pseudo-trilobal filaments (e.g., deltas, T-shapes).Exemplary are U.S. Patent No. 3,981,948 to Phillips, U.S. Patent No. 3,194,002 to Raynolds et al., U.S. Patent No. 2,939,201 to Holland, U.S. Patent No. 4,492,731 to Bankar et al. and Japanese Kokai 42-22574.

It is also known to provide voids in filaments and that many times these voids result in improved soiling hiding performance. U.S. Patent No. 3,745,061 to Champaneria et al. and U.S. Patent No. 4,407,889 to Gintis et al. show non-round filaments having one or more voids.

It in known also to provide trilobal or pseudo-trilobal fibers which have one or more voids. Exemplary are U.S. Patent No. 3,095,258 to Scott, U.S. Patent No. 3,357,048 to Cobb, Jr., U.S. Patent No. 3,493,459 to McIntosh et al., U.S. Patent No. 3,558,420 to Opfell, U.S. Patent No. 4,279,053 to Payne et al., U.S. Patent No. 4,364,996 to Sugiyama, U.S. Patent No. 4,956,237 to Samuelson, British Patent No. 843,179 to Siemer et al., GB-A-1,160,263 and FR-A-1,497,744.

GB-A-1,160,263 does not disclose a modification ratio and an arm angle of the fiber and the void area of the filament is not defined.

FR-A-1,497,744 does not disclose a modification ratio and an arm angle of the fiber and the filament has a total cross-sectional void area of between 10 and 30%.

U.S. Patent No. 4,648,830 to Peterson et al. discloses a spinneret for manufacturing hollow trilobal cross-section filaments. The filaments disclosed therein have one extending hole in each lobe.

To address the foregoing deficiencies, the present invention concerns a multilobal synthetic polymeric filament having a single approximately axially extending central void. The total cross-sectional void area of the filament is between 3 and 10 percent void.

It is an object of the present invention to provide an improved hollow trilobal filament.

We have found that this object is achieved by the filaments definet at the outset.

We have also found a carpet made from these filaments and a spinneret plate for the manufacture of these filaments.

Related objects and advantages will be apparent to the ordinarily skilled artisan after reading the following detailed description of the invention.

FIG. 1 is a cross-sectional plan view of a filament according to the present invention.

FIG. 2 is a plan view of a spinneret useful to prepare the filament of FIG. 1.

FIG. 3 is a plan view of another spinneret according to the present invention.

The term "modification ratio" (MR) means the ratio of the radius R₂ of the circumscribed circle to the radius R₁ of the inscribed circle as shown in FIG. 1. The term "arm angle" (AA) is the angle formed by extension of sides of an arm as shown in FIG. 1.

Depicted in FIG. 1 is an enlarged view of fiber 10 which is representative of the present invention. Filament 10 is trilobal having three (3) lobes, 11, 12 and 13 and axially extending, more or less central, void 15.

According to the present invention, filament 10 has a modification ratio of between 2 to 6, more preferably 2.0 to 3.5 and an arm angle between 7° and 35°. The single approximately central void represents 3 to 10 percent, preferably 5 to 8 percent, of the total fiber volume measured including the volume of the void.

FIG. 2 illustrates a spinneret usefull for preparing the filament of the present invention.

FIG. 2 is a plan view of one filament forming bore group of a spinneret of the present invention. Bore group 10 consists of three approximately "Y" shaped holes, 11, 11' and 11". Each Y-shaped hole has long legs, 12, 12' and 12", and short legs, 13, 13' and 13". The angle between legs 12 and 12' is typically 80° to 160°, preferably 100° to 140° and need not be uniform. R₂ is preferably from 0.5 to 6 mm, more preferably 1.5 to 3.0 mm. R₁ is preferably from 0.3 to 2.5 mm but more preferably from 0.5 to 1.5 mm. The width of each leg is typically between 0.005 to 0.15 mm, preferably 0.06 to 0.10 mm. The gap between legs 13 and 13' is 0.05 to 0.25 mm, preferably 0.08 to 0.20 mm.

Legs

13 and 12 are of sufficient length to meet the limitations of R₁ and R₂.

Although any filament count yarn can be manufactured, to illustrate the present invention a spinneret is cut with 58 filament bore groups arranged in a circular layout with 8 rows and 6 to 9 capillaries per row of filament forming capillaries. Nylon 6 polymer is extruded at normal conventional spinning conditions into a quench stack, drawn, and taken up onto the package where it is further processed into typical carpet yarn. This carpet yarn is then tufted into a carpet using conventional tufting methods and the face yarn of the carpet is observed to have improved apparent bulk, luster, soil hiding, resiliency and appearance retention compared to previously known trilobal carpet yarns having no central void.

FIG. 3 is an alternate form of the spinneret of the present invention.

Filaments of the present invention may be prepared from synthetic thermoplastic polymers which are melt spinnable. Exemplary polymers are polyamides such as poly(hexamethylene adipamide), polycaprolactam and polyamides of bis(4-aminocyclohexyl(methane and linear aliphatic dicarboxylic acids containing 9, 10 and 12 carbon atoms; copolyamides; polyester such as poly (ethylene) terephthalic acid and copolymers thereof; and polyolefins such as polyethylene and polypropylene. Both heterogeneous and homogeneous mixtures of such polymers may also be used.

As is apparent to one ordinarily skilled in the art, the filaments can be prepared by known methods of spinning filaments. Molten polymer is spun through spinneret orifices shaped to provide the desired void volume and filament cross-sections under spinning conditions which give the desired denier. Specific spinning conditions and spinneret orifices, shapes and dimensions will vary depending upon the particular polymer and filament product being spun.

To achieve the desired percent void, the spinning and quenching conditions are modified appropriately. For example, the present void can generally be increased by more rapid quenching of the molten filaments by increasing the polymer melt viscosity.

Test Methods Percent Void:

The filament ends of a length of yarn weighing from 6 to 8 grams are sealed by melting with a flame. The yarn is weighed. Using a conventional pycnometer the yarn density is determined. The density of a solid filament yarn is also determined with the same method as a control. Percent void is then calculated by subtracting the density of the hollow filament yarn from the density of the solid control, dividing the result by the density of the solid filament yarn and then multiplying by 100.

Soiling:

0.91 m x 1.83 m mock-dyned carpet samples, made from fibers with various cross-sections (of interest), are installed in a heavily traveled corridor for 50,000 passes. The samples are then cleaned with a standard vacuum cleaner and visually ranked for degree of soiling. Lower numbers represent less degree of soiling.

Arm Angle:

Fiber cross sections are magnified (300X) to determine the arm angle. Two tangent straight lines are drawn for each arm and the angle formed from the two straight lines is measured. The reported arm angle represents the average of ten measurements.

Luster: For carpet:

Cut pile carpets are made by standard tufting methods from cabled and heatset yarns. After mock dyeing, the carpets are visually ranked for luster. Lower numbers represent higher degree of luster.

For yarn:

A recording goniophotometer (HunterLab Goniophotometer GP-1R Serial 1050) is used to obtain reflectance readings. As illustrated in the following diagram, goniophotometers are used to take reflectance readings at varying angles. A fixed angle of incidence (60°) and varied angle of detection (-120 to 30°) is used. Yarn samples are wound in parallel on a 3.8 cm x 10.2 cm card. There are about four to five layers of yarn on each card. The measurement conditions are:

VS1-3

VS2-2

neutral density filter #25

incident angle -60°

scanned from -120 to -30°

Schematic diagram of the measurement components in a goniophotometer:

The actual specular peak for each sample is obtained from the recording chart. The angle is about 60°C. Luster L is calculated by the following equation: L = (1-D/S) X 100 Where D is percent reflectance reading of diffused light and S is percent reflectance reading of specular peak.

Cover:

Two types of samples, one heatset and one not, are bulked in hot water (99°C) for thirty minutes, dried an conditioned (20°C, 65% RH) overnight. A length of each yarn weighing about four grams is collected and its exact weight determined. Individual specimens are fluffed by hand and placed in a Teflon cylinder (d = 4 cm, H = 20 cm) loosely. An Instron instrument is used to measure the space a sample occupies at 9/10 full scale load (9,000 g). Specific volume of the sample is calculated and expressed in cc/g. This procedure is repeated three times for each sample. The average of the three measurements is reported.

Carpet Wear: Swivel chair test:

A carpet sample is cut to 134.6 cm x 121.9 cm. The carpet sample is taped to a platform with carpet tape. A metal chair with casters is filled with 45.4 kg weight and put onto the carpet. The chair is hooked to a motorized plunger rod and rotates on the carpet while the plunger rod cycles back and forth. The orientation of the carpet sample is periodically changed. At the end of 1,500 cycles, the degree of wear is assessed by a paired comparison.

Paired comparison:

A paired comparison test is conducted using eleven observers. The objective of the examination is to compare two carpets at a time and to select a carpet sample that has better overall appearance after a fixed amount of wear. The data received from the observers is processed by using a preference table. The observer's entry is treated in the following way:

S: represents the score
A_i: represents carpet sample i in a series
A_j: represents carpet sample j in a series
t: represents the total number of samples in the paired comparison evaluation

If A_i > A_j then S_ij = 1
If A_i = A_j then S_ij = 0,5
If A_i < A_j then S_ij = 0
If S_ij = 1 then S_ji = 0
If S_ij = 0,5 then S_ji = 0,5
If S_ij = 0 then S_ji = 1
Therefore S_ji = 1 - S_ij
S_ij = t (t-1)/2

The preference table for paired comparison evaluation of five samples:

(j)
(i)		A₁	A₂	A₃	A₄	A₅	Total Score
	A₁	-	S₁₂	S₁₃	S₁₄	S₁₅	Σ S_1j
	A₂	S₂₁	-	S₂₃	S₂₄	S₂₅	Σ S_2j
	A₃	S₃₁	S₃₂	-	S₃₄	S₃₅	Σ S_3j
	A₄	S₄₁	S₄₂	S₄₃	-	S₄₅	Σ S_4j
	A₅	S₅₁	S₅₂	S₅₃	S₅₄	-	Σ S_5j

Example

A spinneret having 58 filament capillaries is arranged in a circular layout with eight rows and 6 to 9 capillaries per row. The capillaries are formed generally according to FIG. 2 with appropriate design for the desired arm angle, percent void and modification ratio and are offset with respect to the capillaries of each next adjacent row. Commercial Nylon 6 polymer (with a relative viscosity of 2.7; measured at a concentration of 1 g per 100 ml in 96% by weight of sulfuric acid) is extruded with conventional spinning conditions into a quench stack, drawn, textured and taken up onto a package where it is further processed into typical carpet yarn. The spinning conditions were as follows: (1) extruder: melt temperature = 262°C, pressure = 1800 psig = 12.4 MPa; (2) throughput: 207 g/mi; (3) texture pressure: 94 psig = 648 kPa; (4) texture temperature = 250°C; (5) Duo 2 speed = 2109 m/min; (6) Duo 2 temperature = 160°C; (7) Duo 1 speed = 611 m/min; (8) Duo 1 temperature = 50°C; (9) Duo 3 speed = 1729 m/min; (10) FOY = 1.2%; (1) winding tension = 200 g; (12) winding speed = 1699 m/min; (13) denier = 1160. The carpet yarn is then tufted into a primary backing using conventional tuftin methods to make samples 6, 7, 8 and d in the following tables. Samples A and C are untufted carpet yarn. The face yarn of the carpet sample exhibits excellent bulk, luster, soiling hiding, resiliency and appearance retention.

Comparative Example

U.S. Patent No. 4,492,731 to Bankar et al. is followed to make samples 2, 3, 4, 5, C, b and c below. Samples 1 and a are other solid trilobal cross-sections.

ID	Twist (turn/ cm)	MR	Arm Angle	Denier	Cover (cc/g)	Void (%)	Luster	Soiling
1	0	2.6	21	16	4.2	0	2	3
2	0	3.3	19	16	4.6	0	4	4
3	0	3.6	14	16	4.9	0	4	4
4	0	2.8	28	16	4.6	0	2	3
5	0	3.5	20	16	4.8	0	4	4
6	0	2.5	35	20	5.2	6	1	1
7	0	3.1	11	20	6.2	5	3	2
8	0	5.7	7	20	6.7	5	4	3

ID	Twist (turn/cm)	MR	Cover (cc/g)	Luster By Photometer
A	0.6	2.6	4.9	67
	1.4		4.0
C	0.6	2.6	4.4	66
	1.4		3.7

The statistical analysis of total scores from the paired comparison test (11 observers) on the swivel chair worn (1,500 cycles) tufted carpet tiles (two-ply heatset, 3.75 tpi, 1/10 gauge tufter, 0.46 cm pile height, 881.6 g/m² is listed in the following Table 4.

ID	Twist (turn/cm)	MR	Arm Angle	Denier	Cover (cc/g)	Void (%)	Luster	Wear Score
a	1.5	2.5	21	19	4.3	0	2	2.45
b	1.5	3.0	14	19	5.0	0	3	2.59
c	1.5	3.1	21	19	5.2	0	2	1.64
d	1.5	2.8	24	19	5.7	6	1	7.09

Claims

A process for the manufacture of a multilobal synthetic polymeric filament having a single void extending approximately axially central, the total cross-sectional void area of the filament being between 3 and 10 percent void, obtainable by extruding a polymer at normal conventional spinning conditions through a spinneret plate, which has at least one filament forming bore group having a center and said bore group having three openings, each of said openings being approximately Y-shaped with one long leg defining an axis and the axis of each long leg converging on the center of the bore group and said opening having two shorter legs, each of the shorter legs of the same Y being divergent toward said center.