EP0499138B1 - An assembly for controlling a voltage pulse feeder in a electrostatic precipitator - Google Patents
An assembly for controlling a voltage pulse feeder in a electrostatic precipitator Download PDFInfo
- Publication number
- EP0499138B1 EP0499138B1 EP92101961A EP92101961A EP0499138B1 EP 0499138 B1 EP0499138 B1 EP 0499138B1 EP 92101961 A EP92101961 A EP 92101961A EP 92101961 A EP92101961 A EP 92101961A EP 0499138 B1 EP0499138 B1 EP 0499138B1
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- EP
- European Patent Office
- Prior art keywords
- voltage
- direct voltage
- base
- pulse
- generator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C3/00—Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
- B03C3/34—Constructional details or accessories or operation thereof
- B03C3/66—Applications of electricity supply techniques
- B03C3/68—Control systems therefor
Definitions
- This present invention relates to an assembly for controlling a voltage pulse feeder in an electrostatic precipitator, in particular in an electrostatic precipitator in a coal combustion plant and, anyway, in a plant wherein particles are to be collected which have an high resistivity, from 108 ⁇ . cm and over.
- the prior art comprises in said precipitators voltage pulse feeders (which will be referred to only as - feeder(s) - in the following description) by means of which the insulated electrode is given a negative polarity direct voltage of some tens of kV, to which direct voltage, voltage pulses are added which range from tens to hundreds of microseconds (»s) with a convenient frequency and peak values of some tens of kV (said negative polarity direct voltage will be referred to only as - base direct voltage - in the following description).
- the voltage pulses having short life and proper voltage give the ash particles in the smokes remarkable electric charges, so that the electric field generated by the base direct voltage works to collect the particles by electrostatic action.
- the prior art comprises feeders made according to two different assemblies :
- the peculiarity of both said assemblies is to afford manually or automatically an independent control of the base direct voltage and voltage pulse amplitude.
- document EP-A-0044488 discloses a procedure for operating a precipitator fed by variable direct voltage and superposed pulses wherein at least one of the parameters (pulse height, frequency, rise velocity) is variable, still wherein the direct voltage and/or one of the pulse parameters is iteratively varied in such a way that the sum of the electrical energies in the direct voltage and in the pulses as absorbed by the precipitator are lead to a minimum value in order to maintain a predetermined average value according to the amount of ashes in the gas. It appears that the scope of this invention is rather to minimize the energy without affording an efficiency improvement.
- a drawback in the prior art is that the efficiency in collecting the solid particles is much jeopardized by unsteadyness of said voltages and, particularly after a discharge in a precipitator, is jeopardized on resetting the base direct voltage and the amplitude of the voltage pulses.
- the base direct voltage and the pulse voltage added thereto are interdependent in other words, when one of said voltages rises the other lows, and vice versa.
- the object of this invention is to obviate the low efficiency caused by said interdependency between said voltages in the assemblies according to the prior art.
- the invention as characterized in the claims, provides an assembly which automatically keeps steady the base direct voltage on varying the pulse amplitudes added thereto and, similarly, automatically keeps steady the auxiliary direct voltage in order to generate the pulse on varying the base direct voltage.
- This assembly works to generate the base current voltage and/or the pulse voltage irrespective of the control being manual or automatic.
- Fig. 1 shows an assembly comprising: a feeder 1 comprising a base direct voltage generator 2; an auxiliary direct voltage generator 3 which generates voltage pulses; a precipitator 4 comprising an insulated filiform sender electrode 5, and a collecting electrode 6 for collecting solid particles; a couple of electronic controllers 7A, 7B made by the firm SIATEM in Padova (Italy) with components type L141 and » A747, respectively adapted to control automatically the base direct voltage and the auxiliary direct voltage for generating pulses and to balance for both voltages all the variations caused by said interdependency; a voltage divider 8 which shows continuously the value of the base direct voltage; a voltage divider 9 which shows continuously the value of the direct voltage associated with the voltage pulses; a voltage divider 10 which shows continuously the value of total voltage on the precipitator 4; wires 11A, 11B; 12A, 12B respectively connecting said generators with said electronic controllers 7A, 7B; wires 13A, 13B respectively connecting said generators with the voltage dividers 8, 9 and said send
- the collecting highest efficiency in the electrostatic precipitator is obtained by setting and keeping steady a predetermined value of the base direct voltage selected depending on the amount and quality of the solid particles in the precipitator; to the base direct voltage a voltage pulse is added whose amplitude is increased gradually until a discharge occurs in the precipitator.
- Said collecting voltage pulse shall be of low frequency, from 1 Hz to 50 Hz.
- the base direct voltage and the pulse voltage are drawn to zero by the control assembly and, after a predetermined time period of some tens of milliseconds, the base direct voltage rapidly returns to the predetermined value, while the pulse voltage rapidly returns to that value which caused the discharge, reduced by a predetermined percentage, and then it increases along a low slope until a further discharge occurs in the precipitator.
- Fig. 2 shows an assembly comprising:
- Fig. 3 shows an assembly comprising
- Fig. 4 is a diagram of an electronic controller which may be used for automatically keeping steady, in the illustrated case, the base direct voltage for the feeder as illustrated in Figures 1, 2 and 3.
- a similar electronic controller is used for automatically keeping steady the auxiliary direct voltage associated with the pulses.
- Said controller comprises:
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- Engineering & Computer Science (AREA)
- Automation & Control Theory (AREA)
- Electrostatic Separation (AREA)
- Elimination Of Static Electricity (AREA)
- Printers Or Recording Devices Using Electromagnetic And Radiation Means (AREA)
- Networks Using Active Elements (AREA)
Abstract
Description
- This present invention relates to an assembly for controlling a voltage pulse feeder in an electrostatic precipitator, in particular in an electrostatic precipitator in a coal combustion plant and, anyway, in a plant wherein particles are to be collected which have an high resistivity, from 10⁸ Ω . cm and over.
- The prior art comprises in said precipitators voltage pulse feeders (which will be referred to only as - feeder(s) - in the following description) by means of which the insulated electrode is given a negative polarity direct voltage of some tens of kV, to which direct voltage, voltage pulses are added which range from tens to hundreds of microseconds (»s) with a convenient frequency and peak values of some tens of kV (said negative polarity direct voltage will be referred to only as - base direct voltage - in the following description). As known, the voltage pulses having short life and proper voltage give the ash particles in the smokes remarkable electric charges, so that the electric field generated by the base direct voltage works to collect the particles by electrostatic action.
- In particular, the prior art comprises feeders made according to two different assemblies :
- a) an assembly that generates the voltage pulses starting from an auxiliary direct voltage source of relatively low voltage and adds said pulses to the base direct voltage through a step-up transformer and the interpositioning of a capacitor having capacity suitable for said auxiliary direct voltage.
- b) an assembly that generates the voltage pulses starting from an auxiliary direct voltage source of high voltage and adds said voltage pulses to the base direct voltage, still by the interpositioning of a capacitor of capacity suitable for said auxiliary direct voltage , but without using a step-up transformer.
- The peculiarity of both said assemblies is to afford manually or automatically an independent control of the base direct voltage and voltage pulse amplitude.
- Finally, document EP-A-0044488 discloses a procedure for operating a precipitator fed by variable direct voltage and superposed pulses wherein at least one of the parameters (pulse height, frequency, rise velocity) is variable, still wherein the direct voltage and/or one of the pulse parameters is iteratively varied in such a way that the sum of the electrical energies in the direct voltage and in the pulses as absorbed by the precipitator are lead to a minimum value in order to maintain a predetermined average value according to the amount of ashes in the gas. It appears that the scope of this invention is rather to minimize the energy without affording an efficiency improvement.
- A drawback in the prior art is that the efficiency in collecting the solid particles is much jeopardized by unsteadyness of said voltages and, particularly after a discharge in a precipitator, is jeopardized on resetting the base direct voltage and the amplitude of the voltage pulses. After investigating about the reasons of such drawback, the inventor found that the base direct voltage and the pulse voltage added thereto are interdependent in other words, when one of said voltages rises the other lows, and vice versa. It is just this interdependency that makes unsteady the working of the voltage pulse feeder and prevents from optimizing its control assembly, the nature of this drawback being well realized if one considers that the ashes produced from coals of different kinds present different resistivities and consequently the precipitators installed in a combustion plant should fit with different ashes.
- The object of this invention is to obviate the low efficiency caused by said interdependency between said voltages in the assemblies according to the prior art.
- The invention, as characterized in the claims, provides an assembly which automatically keeps steady the base direct voltage on varying the pulse amplitudes added thereto and, similarly, automatically keeps steady the auxiliary direct voltage in order to generate the pulse on varying the base direct voltage. This assembly works to generate the base current voltage and/or the pulse voltage irrespective of the control being manual or automatic.
- The invention will be described in detail herebelow with reference to the accompanying drawings which illustrate specific embodiments , in which:
- FIG. 1 is a much simplified diagram showing a control assembly,
- FIG. 2 is the diagram of pulse feeder assembly provided with a step-up transformer,
- FIG. 3 is the diagram of a pulse feeder assembly not provided with a step-up transformer and
- FIG. 4 is the diagram of an electronic controller for operating the feeders allustrated in Figures 1, 2 and 3 by a base current voltage kept steady automatically.
- Fig. 1 shows an assembly comprising: a
feeder 1 comprising a basedirect voltage generator 2; an auxiliarydirect voltage generator 3 which generates voltage pulses; aprecipitator 4 comprising an insulatedfiliform sender electrode 5, and a collectingelectrode 6 for collecting solid particles; a couple of 7A, 7B made by the firm SIATEM in Padova (Italy) with components type L141 and » A747, respectively adapted to control automatically the base direct voltage and the auxiliary direct voltage for generating pulses and to balance for both voltages all the variations caused by said interdependency; aelectronic controllers voltage divider 8 which shows continuously the value of the base direct voltage; avoltage divider 9 which shows continuously the value of the direct voltage associated with the voltage pulses; avoltage divider 10 which shows continuously the value of total voltage on theprecipitator 4; wires 11A, 11B; 12A, 12B respectively connecting said generators with said 7A, 7B;electronic controllers 13A, 13B respectively connecting said generators with thewires 8, 9 and saidvoltage dividers sender electrode 5; 14A, 14B respectively connecting saidwires 8, 9 with saidvoltage dividers 7A, 7B; aelectronic controllers wire 16 connecting saidsender electrode 5 with saidtotal voltage divider 10 and awire 17 connecting saidtotal voltage divider 10 with anoscilloscope 18 which continuously shows the value of the total voltage on thesender electrode 5. - In general, it was experienced that the collecting highest efficiency in the electrostatic precipitator is obtained by setting and keeping steady a predetermined value of the base direct voltage selected depending on the amount and quality of the solid particles in the precipitator; to the base direct voltage a voltage pulse is added whose amplitude is increased gradually until a discharge occurs in the precipitator. Said collecting voltage pulse shall be of low frequency, from 1 Hz to 50 Hz. Immediately after the discharge, the base direct voltage and the pulse voltage are drawn to zero by the control assembly and, after a predetermined time period of some tens of milliseconds, the base direct voltage rapidly returns to the predetermined value, while the pulse voltage rapidly returns to that value which caused the discharge, reduced by a predetermined percentage, and then it increases along a low slope until a further discharge occurs in the precipitator.
- Fig. 2 shows an assembly comprising:
- a set of
thyristors 20 in antiparallel which control the three-phase voltage applied to a step-up transformer 22 that feeds the circuit which generates the pulses; - a
group 21 controlling the starting step ofthyristors 20; - said step-up
transformer 22; - a
group 23 for rectifying the feeding of acapacitor 24 whose discharge causes the pulse generating voltage; - a block and
equalization inductance 25; - a step-
up transformer 26 for the pulse amplitude provided with aprimary winding 27 under a maximum voltage of about 8 kV, asecondary winding 28 under a high voltage with a maximum pulse amplitude of about 100 kV; -
thyristors 29 provided with diodes in antiparallel whose starting generates the oscillating voltage which causes the pulse; - an
inductance 30 that, added to the leakage inductance of the step-up transformer 26, defines the pulse life; - a set of
thyristors 31 in antiparallel for controlling the three-phase voltage applied to atransformer 33 which feeds the circuit of the base direct voltage; - a
group 32 which controls the starting step of thethyristors 31; - a step-
up transformer 33; - a
rectifier 34 for the base direct voltage; - a
block inductance 35; - a
capacitor 36 which separates the base direct voltage from the secondary winding of the pulse step-uptransformer 26; -
electrodes 37 receiving the sum of the base direct voltage and the pulse voltage; - a
voltage divider 38 detecting the value of the direct voltage associated with the pulse voltage; - a
voltage divider 39 for the base direct voltage; - an
electronic controller 40 receiving the voltage from the 38, 39 and from avoltage dividers voltage divider 41 which will be better described hereinafter; in particular, thisvoltage divider 41 receives the voltages from the 38, 39 and delivers to thevoltage dividers assemblies 42, 43 (defined hereinafter) separate signals proportional with the value of the base voltage and of the direct voltage associated with the pulses; - the above mentioned
assembly 42 that receives the signal of the direct voltage associated with the voltage pulse supplied from theelectronic controller 40 and delivers said signal to thephase control 21 which finally is the means that controls the pulse amplitude; - the above mentioned
assembly 43 that receives the signal of the base direct voltage supplied from theelectronic controller 40 and delivers said signal to thephase control 32 which finally is the means that controls the value of the base direct voltage; - the above mentioned
voltage divider 41 for detecting the peak value of the voltage applied to the node A ( base voltage plus pulse amplitude ), this node being connected withsaid electrodes 37 in theprecipitator 44. - Fig. 3 shows an assembly comprising;
- a set of
thyristors 50 in antiparallel for controlling the three-phase voltage applied to atransformer 52 which feeds the base direct voltage circuit; - a
group 51 which controls the starting-phase in thethyristors 50; - a step-
up transformer 52; - a
rectifier 53 for the base direct voltage; - a
block inductance 54; - a
capacitor 55 for separating the base direct voltage circuit from the pulse generating circuit; - a
voltage divider 56 for the base direct voltage; - a set of
thyristors 57 in antiparallel for controlling the three-phase voltage applied to a step-uptransformer 59 which feeds the pulse generating circuit; - a
group 58 for controlling the starting phase in thethyristors 57; - said step-up
transformer 59; - a
group 60 for rectifying the feeding to acapacitor 61 whose discharge causes the pulse generating voltage; - a
block inductance 62; - a voltage divider 63 for detecting the value of the direct voltage associated with the voltage pulse (because the life of the pulse is very short with respect to the time between two subsequent pulses);
-
thyristors 64 provided with diodes in antiparallel whose starting causes the oscillating voltage which generates the pulse; - a
voltage dividers 65 for detecting the peak voltage applied to node A (base voltage plus pulse amplitude); - an
inductance 66 for defining the pulse life by the capacity provided by 55, 61 and a precipitator 67 as mentioned hereinafter, in series;capacitors -
electrodes 68 that receive the sum of the base voltages and the pulse voltage, - said precipitator 67;
- an
electronic controller 69 which receives the voltages from the 56, 63 and 65. In particular, this controller takes the voltage values supplied from thevoltage dividers voltage dividers 56 and 63 and delivers to the below specifiedassemblies 70, 71 separate signals relevant to the base voltage value and to the direct voltage value associated with the pulses; - the above mentioned assembly 70 takes the signal from the base direct voltage as delivered by the
electronic controller 69 and supplies said signal to thecontrol group 51 that finally controls the value of the base direct voltage; - the above mentioned
assembly 71 takes the signal from the base direct voltage associated with the voltage pulse as delivered by theelectronic controller 69 and supplies said signal to thecontrol group 58 that controls the starting step which finally controls the voltage pulse amplitude. - Fig. 4 is a diagram of an electronic controller which may be used for automatically keeping steady, in the illustrated case, the base direct voltage for the feeder as illustrated in Figures 1, 2 and 3. A similar electronic controller is used for automatically keeping steady the auxiliary direct voltage associated with the pulses.
- Said controller comprises:
- a
potentiometer 80 located on the feeder control boards for setting the base direct voltage to be stabilized; - a terminal 81 in the
potentiometer 80 fed with a direct stabilized voltage of 15 V; - a
voltage divider 82; - a terminal 83 connected with the low voltage shunt in the
39, 56 respectively of Figures 2 and 3;voltage dividers - a
chart 84 containing all the components of the controller ; - an
input impedance 85; - an
operational amplifier 86; - an
integration grid 87 for generating rapid upward slopes after discharges; - an
input impedance 88; - an
operational amplifier 89 working as a reverser; - a
resistor 90 for adapting the signal; -
resistors 91 for comparing the signals coming frompotentiometer 80 andvoltage divider 82; - an
input impedance 92; - an
operational amplifier 93 working as error amplifier; - a
regulation grid 94 for the control system of the base direct voltage; - an
assembly 95, equivalent toassemblies 43 and 70 respectively in Figures 2 and 3, which receives the control signal at a terminal 96;
| - Base direct voltage: This voltage 19 steady since the control assembly which generates the voltage is set manual. Anyway, this voltage is inclined to lower while increasing the amplitude of the voltage pulse, but the assembly according to the invention keeps this voltage steady at the predetermined value. | about 30kV |
| - Voltage pulse value The control system for generating the pulses is set in automatic and the amplitude of the pulse increases until discharge is reached. | about 45kV |
| - Life of the voltage pulse | about 70»s |
| - Pulse frequency | about 10Hz |
| - Total voltage on the precipitator Such voltage value corresponds to the voltage level at which the discharge occurs and results from the addition of the base direct voltage with the voltage pulse. | about 75kV |
| - Current density in the precipitator | about 1-2 ηA/cm² |
| - Number of dicharges in a minute in the precipitator | 2 - 4 |
| - Collecting efficiency in the precipitator | about 99.9% |
Claims (4)
- An assembly for controlling voltage pulse feeders for an electrostatic precipitator (4) which is provided with insulated sender electrodes (5) and collecting electrodes (6) for collecting solid particles in the smokes and is associated with a generator of a base direct voltage (2) applied to said sender electrodes and to a generator of an auxiliary direct voltage (3) in order to generate voltage pulses applied to said sender electrodes (5), the assembly being characterized in that it comprises a first voltage controller (7A) which is connected to a first voltage divider (8), is connectable to said generator of the base direct voltage (2) and is adapted to automatically maintain steady the base direct voltage in order to balance all the variations of same base direct voltage due to the variations of the voltage pulses added thereto as well as it comprises a second voltage controller (7B) which is connected to a second voltage divider (9), is connectable to said generator of an auxiliary direct voltage (3) and is adapted to automatically maintain steady the auxiliary direct voltage in order to generate voltage pulses on varying the base direct voltage, the association of said first (7A) and second (7B) voltage controllers and dividers (8,9) drawing to zero all the variations of said two voltages caused by the interdependency of said same two voltages.
- An assembly according to claim 1 characterized in that the frequency of said voltage pulses ranges from between 1 Hz and 50 Hz.
- An assembly according to claims 1 or 2, characterized in that said first voltage divider (8) connected with said first voltage controller (7A) and with said generator of base direct voltage (2) is used to detect and indicate continuously the value of the base direct voltage to said voltage controller (7A) and to an operator; said second voltage divider (9) connected with said second voltage controller (7B) and with said generator of auxiliary direct voltage (3) is used to detect and indicate continuously the value of the auxiliary direct voltage associated with said pulses to said second voltage controller (7B); a third voltage divider (10) connected with said sender electrodes (5) is used to detect and indicate continuously the value of the total voltage in the precipitator (4).
- An assembly according to any of the preceding claims, characterized in that a voltage pulse is added which increases gradually until a discharge occurs in the precipitator (4) to a preselected value of the base direct voltage, the base direct voltage and the pulse direct voltage are drawn to zero after said discharge during a time period of some tens of millisecond and then the base direct voltage is rapidly drawn to said preselected value and the direct voltage associated with the pulse is rapidly drawn to that value it had before the discharge, but reduced by a predetermined percentage, and then it increases by a predetermined low rise slope until a value required for a further discharge is reached.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI910398A IT1245165B (en) | 1991-02-15 | 1991-02-15 | SYSTEM TO CONTROL AND REGULATE VOLTAGE PULSE POWER SUPPLIES FOR ELECTROSTATIC PRECIPITATORS |
| ITMI910398 | 1991-02-15 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0499138A2 EP0499138A2 (en) | 1992-08-19 |
| EP0499138A3 EP0499138A3 (en) | 1992-09-30 |
| EP0499138B1 true EP0499138B1 (en) | 1995-08-09 |
Family
ID=11358599
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP92101961A Revoked EP0499138B1 (en) | 1991-02-15 | 1992-02-06 | An assembly for controlling a voltage pulse feeder in a electrostatic precipitator |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0499138B1 (en) |
| AT (1) | ATE126100T1 (en) |
| DE (1) | DE69203876T2 (en) |
| DK (1) | DK0499138T3 (en) |
| ES (1) | ES2079086T3 (en) |
| GR (1) | GR3018054T3 (en) |
| IT (1) | IT1245165B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007014402A1 (en) * | 2005-07-25 | 2007-02-01 | Francoi Eberhardt Du Plessis | Method of and control system for controlling electrostatic separator |
| US8552326B2 (en) * | 2010-09-03 | 2013-10-08 | Separation Technologies Llc | Electrostatic separation control system |
| US9393573B2 (en) | 2014-04-24 | 2016-07-19 | Separation Technologies Llc | Continuous belt for belt-type separator devices |
| US9764332B2 (en) | 2015-02-13 | 2017-09-19 | Separation Technologies Llc | Edge air nozzles for belt-type separator devices |
| CN115916387A (en) | 2020-06-22 | 2023-04-04 | 分离技术有限责任公司 | Dry beneficiation process for fine and very fine iron ores by particle size and electrostatic separation |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3007364A1 (en) * | 1980-02-27 | 1981-09-10 | Siemens AG, 1000 Berlin und 8000 München | CONTROL FOR AN ELECTRIC FILTER |
| DE3027172A1 (en) * | 1980-07-17 | 1982-02-18 | Siemens AG, 1000 Berlin und 8000 München | METHOD FOR OPERATING AN ELECTROFILTER |
| DE3531025A1 (en) * | 1985-08-30 | 1987-03-05 | Bosch Gmbh Robert | CIRCUIT ARRANGEMENT FOR CONTROLLING THE HIGH VOLTAGE SUPPLY OF AN ELECTROSTATIC FILTER |
-
1991
- 1991-02-15 IT ITMI910398A patent/IT1245165B/en active IP Right Grant
-
1992
- 1992-02-06 EP EP92101961A patent/EP0499138B1/en not_active Revoked
- 1992-02-06 AT AT92101961T patent/ATE126100T1/en not_active IP Right Cessation
- 1992-02-06 DK DK92101961.8T patent/DK0499138T3/en active
- 1992-02-06 ES ES92101961T patent/ES2079086T3/en not_active Expired - Lifetime
- 1992-02-06 DE DE69203876T patent/DE69203876T2/en not_active Revoked
-
1995
- 1995-11-10 GR GR950403039T patent/GR3018054T3/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DK0499138T3 (en) | 1995-12-11 |
| IT1245165B (en) | 1994-09-13 |
| GR3018054T3 (en) | 1996-02-29 |
| ATE126100T1 (en) | 1995-08-15 |
| DE69203876D1 (en) | 1995-09-14 |
| EP0499138A2 (en) | 1992-08-19 |
| ES2079086T3 (en) | 1996-01-01 |
| EP0499138A3 (en) | 1992-09-30 |
| ITMI910398A0 (en) | 1991-02-15 |
| DE69203876T2 (en) | 1996-04-04 |
| ITMI910398A1 (en) | 1992-08-15 |
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