EP0482882B1 - A process for flash spinning fiber-forming polymers - Google Patents
A process for flash spinning fiber-forming polymers Download PDFInfo
- Publication number
- EP0482882B1 EP0482882B1 EP19910309740 EP91309740A EP0482882B1 EP 0482882 B1 EP0482882 B1 EP 0482882B1 EP 19910309740 EP19910309740 EP 19910309740 EP 91309740 A EP91309740 A EP 91309740A EP 0482882 B1 EP0482882 B1 EP 0482882B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- process according
- mixture
- vinyl alcohol
- spin mixture
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 229920000642 polymer Polymers 0.000 title claims description 39
- 238000000034 method Methods 0.000 title claims description 32
- 238000009987 spinning Methods 0.000 title claims description 27
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 52
- 239000000203 mixture Substances 0.000 claims description 48
- -1 polypropylene Polymers 0.000 claims description 35
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 26
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 25
- 239000001569 carbon dioxide Substances 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 239000004698 Polyethylene Substances 0.000 claims description 19
- 229920000573 polyethylene Polymers 0.000 claims description 19
- 229920001903 high density polyethylene Polymers 0.000 claims description 15
- 239000004700 high-density polyethylene Substances 0.000 claims description 15
- 239000004743 Polypropylene Substances 0.000 claims description 14
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 12
- 229920000098 polyolefin Polymers 0.000 claims description 12
- 229920001155 polypropylene Polymers 0.000 claims description 10
- 239000005977 Ethylene Substances 0.000 claims description 6
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims description 6
- 229920000578 graft copolymer Polymers 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 239000004814 polyurethane Substances 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 2
- 239000004715 ethylene vinyl alcohol Substances 0.000 description 12
- 239000004751 flashspun nonwoven Substances 0.000 description 11
- 229920001474 Flashspun fabric Polymers 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 229920001684 low density polyethylene Polymers 0.000 description 7
- 239000004702 low-density polyethylene Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 229920003365 Selar® Polymers 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 description 6
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 150000008282 halocarbons Chemical class 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 239000004775 Tyvek Substances 0.000 description 2
- 229920000690 Tyvek Polymers 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 206010061592 cardiac fibrillation Diseases 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000002600 fibrillogenic effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 229920000136 polysorbate Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 229940029284 trichlorofluoromethane Drugs 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229950005499 carbon tetrachloride Drugs 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 229960001701 chloroform Drugs 0.000 description 1
- 238000010961 commercial manufacture process Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 210000000416 exudates and transudate Anatomy 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 229940073584 methylene chloride Drugs 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 229920006032 ungrafted co-polymer Polymers 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/11—Flash-spinning
Definitions
- the denier of the strand is determined from the weight of a 15 cm sample length of strand.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Artificial Filaments (AREA)
Description
- The invention relates to a process for flash-spinning plexifilamentary film-fibril strands of polymers that are substantially plasticizable in carbon dioxide and/or water, and have a melting point less than 300°C. More particularly, the invention relates to plexifilamentary film-fibril strands that are flash-spun from mixtures of carbon dioxide, water and the polymer.
- The disclosures of EP-A-0 431 801 falling under the terms of Art 54(3) EPC are a process for flash spinning plexifilamentary film-fibril strands of ethylene vinyl alcohol copolymer, optionally with 0 to 6 weight % of polyolefin, by the steps of forming a spin mixture of water, carbon dioxide and the copolymer at a temperature of at least 130°C, at a pressure that is greater than the autogenous pressure of the mixture and then flash spinning the mixture into a region of substantially lower temperature and pressure.
- Blades and White, United States Patent 3,081,519 describe flash-spinning plexifilamentary film-fibril strands from fiber-forming polymers. A solution of the polymer in a liquid, which is a non-solvent for the polymer at or below its normal boiling point, is extruded at a temperature above the normal boiling point of the liquid and at autogenous or higher pressure into a medium of lower temperature and substantially lower pressure. This flash spinning causes the liquid to vaporize and thereby cool the exudate which forms a plexifilamentary film-fibril strand of the polymer. According to Blades and White, the following liquids are useful in the flash-spinning process: aromatic hydrocarbons such as benzene, toluene, etc.; aliphatic hydrocarbons such as butane, pentane, hexane, heptane, octane, and their isomers and homologs; alicyclic hydrocarbons such as cyclohexane; unsaturated hydrocarbons; halogenated hydrocarbons such as methylene chloride, carbon tetrachloride, chloroform, ethyl chloride, methyl chloride; alcohols; esters; ethers; ketones; nitriles; amides; fluorocarbons; sulfur dioxide; carbon disulfide; nitromethane; water; and mixtures of the above liquids. The patent further states that the flash-spinning solution additionally may contain a dissolved gas, such as nitrogen, carbon dioxide, helium, hydrogen, methane, propane, butane, ethylene, propylene, butene, etc. Preferred for improving plexifilament fibrillation are the less soluble gases, i.e., those that dissolve to a less than 7% concentration in the polymer solution under the spinning conditions.
- Blades and White state that polymers which may be flash spun include those synthetic filament-forming polymers or polymer mixtures which are capable of having appreciable crystallinity and a high rate of crystallization. A preferred class of polymers is the crystalline, non-polar group consisting mainly of crystalline polyhydrocarbons, such as polyethylene and polypropylene.
- U.S. Patent 3,169,899 lists polyester, polyoxymethylene, polyacrylonitrile, polyamide, polyvinyl chloride, etc. as other polymers that may be flash spun. Still other polymers mentioned in the patent are flash spun as mixtures with polyethylene, including ethylene vinyl alcohol, polyvinyl chloride, polyurethane, etc. Example 18 of U.S. 3,169,899 illustrates flash spinning from methylene chloride of a mixture of polyethylene and ethylene vinyl alcohol in which polyethylene is the predominant component of the polymer mixture.
- Flash spun polyethylene products have achieved considerable commercial success. "Tyvek®" is a spunbonded polyethylene sheet product sold by E. I. du Pont de Nemours and Company. These sheets are used in the construction and packaging industries. "Tyvek®" is also used in protective apparel since the flash spun product provides a good barrier to particulate penetration. However, the hydrophobic nature of polyethylene results in a garment which tends to be uncomfortable during hot, humid weather. A more hydrophilic flash spun product is clearly desirable for garment and some other end uses. Additionally, flash spinning of any of the polymers would preferably be achieved from an environmentally safe, non-toxic solvent.
- Trichlorofluoromethane (Freon-11) has been a very useful solvent for commercial manufacture of plexifilamentary film-fibril strands of polyethylene. However, the escape of such a halocarbon into the atmosphere has been implicated as a serious source of depletion of the earth's ozone. A general discussion of the ozone-depletion problem is presented, for example by P.S. Zurer, "Search Intensifies for Alternatives to Ozone-Depleting Halocarbons", Chemical & Engineering News, pages 17-20 (February 8, 1988). The substitution of environmentally safe solvents for trichlorofluoromethane in a commercial flash spinning process should minimize the ozone depletion problem.
- There now has been discovered in accordance with this invention, flash spun polymer products desirable for uses such as garments, construction and packaging, which are flash spun from an environmentally acceptable mixture comprising carbon dioxide and water.
- There is provided by this invention a process for flash spinning plexifilamentary film-fibril strands of a fiber-forming polymer that is substantially plasticizable in carbon dioxide or water and has a melting point less than 300°C, comprising the steps of:
- (a) forming a spin mixture of water, carbon dioxide and the polymer at a temperature of at least 130°C and a pressure that is greater than the autogenous pressure of the mixture; and
- (b) thereafter flash spinning the mixture into a region of substantially lower temperature and pressure,
wherein the carbon dioxide is present in the range of from 30 to 90 percent based on the total weight of the spin mixture, and
provided that the polymer constituent of the spin mixture does not consist of ethylene vinyl alcohol copolymer together with from 0 to 6.5% of a polyolefin, the percentage being based on the total weight of the spin mixture. - Preferably, the polymer is a polyolefin selected from the group consisting of polyethylene, polypropylene, ethylene vinyl alcohol copolymers and combinations thereof. An especially desirable combination is polyethylene with ethylene vinyl alcohol to which is grafted about 10% by weight of a high density polyethylene.
- As used herein, the terms "substantially plasticizable" mean that the polymers are softened and become less viscous by imbibbing the carbon dioxide and/or water.
- The term "plexifilamentary film-fibril strand" or simply "plexifilamentary strand", as used herein, means a strand which is characterized as a three-dimensional integral network of a multitude of thin, ribbon-like, film-fibril elements of random length and of less than about 4 microns average thickness, generally coextensively aligned with the longitudinal axis of the strand. The film-fibril elements intermittently unite and separate at irregular intervals in various places throughout the length, width and thickness of the strand to form the three-dimensional network. Such strands are described in further detail by Blades and White, United States Patent 3,081,519 and by Anderson and Romano, United States Patent 3,227,794.
- Polymers particularly useful in the practice of this invention are polyethylene, polypropylene, grafted and ungrafted copolymers of ethylene and vinyl alcohol (hereinafter sometimes referred to as "EVOH"), graft copolymers of acrylic acid, polyurethane, and combinations thereof. The copolymers of ethylene and vinyl alcohol have a copolymerized ethylene content of about at least 20 mole%. The ethylene vinyl alcohol copolymer may include as an optional comonomer other olefins such as propylene, butene-1, pentene-1, or 4-methylpentene-1 in such an amount as to not change the inherent properties of the copolymer, generally in an amount of up to about 5 mole%, based on the total copolymer. The melting points of these ethylene vinyl alcohol polymers are generally between about 160 and 190°C. Ethylene vinyl alcohol polymers are normally prepared by copolymerization of ethylene with vinyl acetate followed by saponification of the acetate groups to the hydroxyl groups. At least about 90% of the acetate groups should by saponified, this being necessary to achieve sufficient mixing of the polymer. This process is well known in the art.
- A particularly advantageous EVOH polymer can be prepared by grafting long chains of polyethylene or polypropylene (i.e., blocks), onto the random ethylene vinyl alcohol copolymer. The grafting process is accomplished by properly mixing EVOH and a pendant anhydride containing polyolefins in the molten state under shear through either a batch or continuous mixing device (e.g., haake mixer or extruder). The grafted polymers appear to be more compatible with additional polyolefins used in most of the flash spinning experiments. A polyolefin graft level of 5-50% by weight is most useful.
- The process requires forming a spin mixture of the polymer, water and carbon dioxide. The water is present in the range from 5 to 50 percent based on the total weight of the spin mixture. The carbon dioxide is present in the range from 30 to 90 percent based on the total weight of the spin mixture. The polymer is present in the range from 1.5 to 25 percent based on the total weight of the spin mixture.
- As noted above, the spin mixture may also comprise ethylene vinyl alcohol copolymer and an additional polymer present in the range from 0 to 25 percent based on the total weight of the spin mixture. Conveniently, polyethylene and polypropylene are the preferred additional polymers.
- The spinning mixture may optionally contain a surfactant. The presence of such a surfactant appears to assist in emulsifying the polymer, or in otherwise aiding in forming a mixture. Examples of suitable nonionic surfactants are disclosed in U. S. Patent No. 4,082,887, the contents of which is herein incorporated by reference. Among the suitable, commercially available, nonionic surfactants are the "Spans", which are mixtures of the esters of the monolaurate, monooleate and monostearate type and the "Tweens", which are the polyoxyethylene derivatives of these esters. The "Spans" and the "Tweens" are products of ICI Americas, Wilmington, DE.
- The required temperatures for preparing the spin mixture and for flash-spinning the mixture are usually about the same and usually are in the range of 130 to 275°C. The mixing and the flash-spinning are performed at a pressure that is higher than the autogenous pressure of the mixture. The pressure during the spin mixture preparation is generally in the range from 1,200 to 6,000 psi.
- Conventional flash-spinning additives can be incorporated into the spin mixtures by known techniques. These additives can function as ultraviolet-light stabilizers, antioxidants, fillers, dyes, surfactants and the like.
- Two autoclaves were used in the following non-limiting examples. One autoclave, designated a "300cc" autoclave (Autoclave Engineers, Inc., Erie, PA) was equipped with a turbine-blade agitator, temperature and pressure measuring devices, heating means, a means of pumping in carbon dioxide under pressure and inlets for loading the ingredients. An exit line from the bottom of the autoclave was connected through a quick-acting valve to a spin orifice 0.079 cm in diameter. The spin orifice had a length to diameter ratio of 1 with a tapered conical entrance at an angle of 120 degrees. The second autoclave, designated a "1 gallon" autoclave (again made by Autoclave Engineers, Inc.), was equipped in an analogous manner to that of the "300cc" autoclave.
- The surface area of the plexifilamentary film-fibril strand product is a measure of the degree and fineness of fibrillation of the flash-spun product. Surface area is measured by the BET nitrogen absorption method of S. Brunauer, P.H. Emmett and E. Teller, Journal of American Chemical Society, Vol. 60, pp. 309-319 (1938) and is reported as m²/g.
- Tenacity and elongation of the flash-spun strand are determined with an Instron tensile-testing machine. The strands are conditioned and tested at 70°F (21.1°C) and 65% relative humidity. The strands are then twisted to 10 turns per inch and mounted in the jaws of the Instron Tester. A 1-inch gauge length and an elongation rate of 60% per minute are used. The tenacity at break is recorded in grams per denier (gpd).
- The denier of the strand is determined from the weight of a 15 cm sample length of strand.
- In the non-limiting examples which follow, all parts and percentages are by weight unless otherwise indicated. The conditions of all Examples are summarized in Table I.
- The "1 gallon" autoclave was loaded with 600 g ASPUN® 6801 and 700 g water, then the vessel was closed. The exit manifold of the autoclave was fitted with a spin orifice of 0.035" with a tapered conical entrance at an angle of 120 degrees. A vacuum educator was used to pump the vessel to 20 in. mercury pressure for 15 seconds to remove most of the air but not to significantly remove water. The vessel was then pressurized with carbon dioxide until 1500 g of carbon dioxide had been added, the amount measured with a "Micro-motion" mass flow instrument. Agitation was begun and set to 1000 rpm. Heating of the vessel was begun and continued until the goal temperature of 170°C was reached. Pressure was adjusted by bleeding small amounts of vapor until the pressure stabilized at 4,500 psi. The mixture was held at 170°C for 1 minute, the agitator slowed to about 250 rpm and the exit valve promptly opened to permit the mixture to flow to the spin orifice, which had been heated to 210°C. The result was the formation of a finely fibrillated continuous yarn.
- The procedure of Example 1 was used except that the autoclave was loaded with 300 g ASPUN® 6801, 125 g Selar® OH 4416 ethylene/vinyl alcohol copolymer of melt index 16 (E.I. du Pont de Nemours and Co., Wilmington, Delaware), 840 g water, and was charged with 1700 g carbon dioxide. Spinning gave a finely fibrillated continuous yarn very much like that of Example 1 except the yarn is more hydrophilic and has some elastic recovery properties.
- The "300 cc" autoclave was used and operated in the same manner as the "1 gallon" autoclave. Through an addition port, the autoclave was loaded with 30 g Alathon®/7050 high density linear polyethylene, melt index 17:5, (Occidential Chemical Corporation, Houston, Texas) and 56 g water. Most of the air was removed from the autoclave by brief evacuation to 20 in. mercury. The autoclave was then pressurized with 146 g carbon dioxide, the agitator set to 2000 rpm and heating begun up to a goal temperature of 170°C. When the goal temperature was reached, the pressure was adjusted by venting small amounts of the mixture to give 4,500 psi. The mixture was then agitated an additional 15 minutes. The exit valve was opened and the mixture spun through the spin orifice. The result was a pulp consisting of finely fibrillated fibers of high quality, ranging from 1/16 to 2 inches in length. The fibers are useful for formation of sheet structures made by known paper making processes.
- The procedure of Example 3 was followed, except the autoclave was charged with 30 g ASPUN® 6801 resin, 15 g Selar® OH 4416 resin, and 56 g water, and was pressurized with carbon dioxide to a pressure of 3700 psi at spinning. The result was a continuous, finely fibrillated continuous plexifilamentary yarn.
- The procedure of Example 1 was followed, except the autoclave was loaded with 500 g ASPUN® 6801 resin, 100 g SELAR® OH 4416 resin, 700 g water and 1300 g carbon dioxide; then the autoclave was heated at 170°C to a goal pressure of 5,500 psi. The agitator was changed to a multiple high shear paddle/turbine design. High quality continuous finely fibrillated yarn was produced that gave a twisted break tenacity of 1.45 g/denier at 38% elongation.
- Example 5 was re-run under the same conditions but the spinning temperature was increased to 180°C. The yarn was essentially equivalent to Example 17 and measured 1.72 g/denier tenacity at 38.7% elongation. Surface area was measured by the nitrogen absorption technique to be 4.44 m²/g.
- The procedure of Example 1 was followed except that the autoclave was loaded with 300 g Alathon® 7050, 100 g of "E64179-124-1" (a ethylene vinyl alcohol copolymer to which has been grafted about 10% by weight high density polyethylene), 1200 g carbon dioxide and 500 g distilled water. A slotted spinning nozzle designed to produce a flat rather than cylidrical web shape was used. The goal temperature was 175°C. Otherwise, the procedure was the same as Example 1. The result was the formation of a finely fibrillated continuous yarn that had a twisted tenacity of 4 g/denier, an elongation of 46% and a surface area of 13 m²/g as measured by the BET method.
- "E64179-124-1" is not a commercially available product. It is prepared by taking SELAR® OH 4416 and modifying it through in situ grafting with high density polyethylene resin that has itself been modified. The high density polyethylene resin was modified in a twin screw extruder through the controlled addition of a peroxide initiator and maleic anhydride. The modified resin is referred to as "HDPE-G-MAN" (high density polyethylene grafted by maleic anhydride addition). The SELAR® OH 4416 was modified through in situ grafting with the "HDPE-G-MAN" at about 10% by weight in a twin screw extruder at 220°C. The anhydride/hydroxyl reaction provides the grafting site to chemically link up the HDPE and the EVOH.
- The procedure of Example 7 was followed except that 380 g Alathon®/7050 and 20 g of "64179-124-1" was used. The result was essentially the same as Example 7 except that the resulting yarn was much less hydrophilic and hand sheets made from the yarn exhibited bonding characteristics more like that expected of pure polyethylene yarn.
- The procedure of Example 8 was used except that into the autoclave were loaded 300 g of Shell PP WRS5-675 (polypropylene polymer commercially available from Shell Chemical Company, Short Hills, New Jersey), 100 g of "64179-124-5" (a ethylene vinyl alcohol copolymer as described in Example 7 except that to which has been grafted about 20% polypropylene by weight), and 1555 g carbon dioxide. The goal temperature was 200°C. A finely fibrillated 20 inch wide swath was produced that was slightly more coarse that seen when polyethylene was the polymer.
- The procedure of Example 8 was used except that 300 g of "HTX-6133" (a melt spinnable polyurethane polymer (a butylene/poly (alkylene ether) phthalate)), 120 g Alathon®/7050 high density polyethylene and 1715 g carbon dioxide were loaded into the autoclave. The goal temperature was 180°C. A very finely fibrillated yarn was produced with a unique "silky" feel and elastomeric properties.
- HTX-6133 is a very soft HYTREL® resin comprised of 77 wt.% soft segment and 23 wt.% hard segment. It is specifically described in the Examples (Preparation of Elastomer A) in U.S. Patent 4,731,407 (Benim et al.), the entire contents of which are incorporated by reference herein.
- The procedure of Example 3 was used except that the autoclave was loaded with 15.5 g of Selar® 4416 ethylene vinyl alcohol copolymer of melt index 16 (commercially available from E.I. du Pont de Nemours and Company, Wilmington, Delaware), 15.5 g of Polybond® 1011 acrylic acid graft copolymer with polypropylene of melt index 20 (commercially available from British Petroleum Chemicals, Hackettstown, New Jersey), 49 g distilled water and 120 g carbon dioxide. The mixture was stirred at 200°C and 5000 psi pressure for 15 minutes prior to spinning through a 0.0031 inch spin orifice. A well fibrillated, continuous plexifilamentary yarn was produced.
TABLE 1 Example# %EVOH %Additional Polyolefin %Surfactant %H2O %CO2 T°C Spinning P(psi) 1 0 21.4 LDPE 0 25.0 53.6 170 4500 2 4.2 10.1 LDPE 0 28.3 57.3 170 4500 3 0 12.9 HDPE 0 23.2 62.9 170 4500 4 0 12.9 LDPE 0 23.2 62.9 170 3700 5 3.8 19.2 LDPE 0 26.9 50.0 170 5500 6 3.8 19.2 LDPE 0 26.9 50.0 180 5500 7 4.8 14.3 HDPE 0 23.8 57.1 175 4500 8 1.0 18.1 HDPE 0 23.8 57.1 175 4500 9 4.1 12.2 PP 0 20.4 63.3 200 4500 10 11.4* 4.6 HDPE 0 19.0 65.1 180 4500 11 7.8 7.8 PP/AA 0 24.5 60.0 200 5000 HDPE= high density polyethylene
LDPE= low density polyethylene
PP= polypropylene
AA= acrylic acid
* Polymer used was polyurethane and not EVOH - Although particular embodiments of the present invention have been described in the foregoing description, it will be understood by those skilled in the art that the invention is capable of numerous modifications. Reference should be made to the appended claims, rather than to the foregoing specification, as indicating the scope of the invention.
- 1 psi = 6.895 kPa
1 gallon = 3.79 litres
1 denier = 1.11 d tex
1 inch = 2.54 cm
Claims (12)
- A process for flash spinning plexifilamentary film-fibril strands of a polymer that is substantially plasticizable in carbon dioxide or water and has a melting point less than 300°C, comprising the steps of:(a) forming a spin mixture of water, carbon dioxide and the polymer at a temperature of at least 130°C and a pressure that is greater than the autogenous pressure of the mixture; and(b) thereafter flash spinning the mixture into a region of substantially lower temperature and pressure,
wherein the carbon dioxide is present in the range of from 30 to 90 percent based on the total weight of the spin mixture, and
provided that the polymer constituent of the spin mixture does not consist of ethylene vinyl alcohol copolymer together with from 0 to 6.5% of a polyolefin, the percentage being based on the total weight of the spin mixture. - A process according to claim 1 wherein the water is present in the range from 5 to 50 percent based on the total weight of the spin mixture.
- A process according to claim 1 or 2 wherein the polymer is present in the range from 1.5 to 25 percent based on the total weight of the spin mixture.
- A process according to claim 1, 2 or 3 wherein the polymer is selected from polyolefins, polyurethanes, graft copolymers of acrylic acid or a combination thereof.
- A process according to claim 4 wherein the polyolefin is selected from polypropylene; polyethylene; or ethylene vinyl alcohol copolymers together with from more than 6.5% to 25% of polypropylene or polyethylene, the percentage being based on the total weight of the spin mixture.
- A process according to claim 5 wherein the ethylene vinyl alcohol copolymer has been grafted to between 5-50% by weight high density polyethylene.
- A process according to claim 6 wherein the ethylene vinyl alcohol copolymer has been grafted to about 10% by weight high density polyethylene.
- A process according to any preceding claim wherein the spin mixture is formed at a temperature in the range of 130 to 275°C and a pressure in the range from 8 to 40 MPa (1,200 to 6,000 psi).
- A process according to claim 5 wherein the spin mixture comprises ethylene vinyl alcohol copolymer and additional polyolefin present in the range from more than 6.5 to 25 percent based on the total weight of the spin mixture.
- A process according to claim 9 wherein the additional polyolefin comprises polyethylene or polypropylene.
- A process according to any preceding claim wherein the spin mixture further comprises a surfactant present in the range from 0 to 2 percent based on the total weight of the spin mixture.
- A process according to claim 9 wherein the ethylene vinyl alcohol copolymer comprises at least 20 mole % of ethylene units.
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US602344 | 1990-10-20 | ||
US60234490A | 1990-10-23 | 1990-10-23 | |
EP90312694 | 1990-11-21 | ||
EP90312694A EP0431801B1 (en) | 1989-11-22 | 1990-11-21 | A process for flash spinning polyolefins |
US688017 | 1991-04-19 | ||
US07/688,017 US5192468A (en) | 1989-11-22 | 1991-04-19 | Process for flash spinning fiber-forming polymers |
Publications (2)
Publication Number | Publication Date |
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EP0482882A1 EP0482882A1 (en) | 1992-04-29 |
EP0482882B1 true EP0482882B1 (en) | 1995-12-27 |
Family
ID=27233628
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Application Number | Title | Priority Date | Filing Date |
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EP19910309740 Expired - Lifetime EP0482882B1 (en) | 1990-10-23 | 1991-10-22 | A process for flash spinning fiber-forming polymers |
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EP (1) | EP0482882B1 (en) |
DE (1) | DE69115844T2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10322460B4 (en) * | 2003-05-16 | 2007-02-08 | Corovin Gmbh | Method and apparatus for producing a spunbonded web of filaments of broken fibers, filaments of broken fibers and nonwoven web |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0527019B1 (en) * | 1991-08-03 | 1999-04-21 | Asahi Kasei Kogyo Kabushiki Kaisha | Halogen group solvent and solution using said solvent and process for producing three-dimensional fiber |
US5527865A (en) * | 1995-03-24 | 1996-06-18 | The University Of North Carolina At Chapel Hill | Multi-phase polymerization process |
US5816700A (en) * | 1995-10-26 | 1998-10-06 | E. I. Du Pont De Nemours And Company | Process and apparatus for mechanically mixing polymers and lower viscosity fluids |
US6179458B1 (en) | 1996-11-01 | 2001-01-30 | E. I. Du Pont De Nemours And Company | Forming a solution of fluids having low miscibility and large-scale differences in viscosity |
US20050029695A1 (en) | 2002-09-25 | 2005-02-10 | Weinberg Mark Gary | Surface-modified plexifilamentary structures, and compositions therefor |
US11261543B2 (en) * | 2015-06-11 | 2022-03-01 | Dupont Safety & Construction, Inc. | Flash spinning process |
CN114293322B (en) * | 2021-12-31 | 2022-12-13 | 湖北拓盈新材料有限公司 | Preparation method of high-moisture-permeability low-water-permeability composite non-woven fabric |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3081519A (en) * | 1962-01-31 | 1963-03-19 | Fibrillated strand | |
US3987139A (en) * | 1972-03-20 | 1976-10-19 | Crown Zellerbach Corporation | Process of forming synthetic fibers |
GB1450892A (en) * | 1972-09-26 | 1976-09-29 | Ici Ltd | Production of fibrils |
CA2029550C (en) * | 1989-11-22 | 2001-07-31 | Don Mayo Coates | Process for flash spinning polyolefins |
US5009820A (en) * | 1990-03-05 | 1991-04-23 | E. I. Du Pont De Nemours And Company | Process of making acicular para-aramide particles |
-
1991
- 1991-10-22 EP EP19910309740 patent/EP0482882B1/en not_active Expired - Lifetime
- 1991-10-22 DE DE1991615844 patent/DE69115844T2/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10322460B4 (en) * | 2003-05-16 | 2007-02-08 | Corovin Gmbh | Method and apparatus for producing a spunbonded web of filaments of broken fibers, filaments of broken fibers and nonwoven web |
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DE69115844T2 (en) | 1996-08-01 |
DE69115844D1 (en) | 1996-02-08 |
EP0482882A1 (en) | 1992-04-29 |
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