EP0475934A1 - A method for applying a non-stick embosser roll coating. - Google Patents
A method for applying a non-stick embosser roll coating.Info
- Publication number
- EP0475934A1 EP0475934A1 EP89906223A EP89906223A EP0475934A1 EP 0475934 A1 EP0475934 A1 EP 0475934A1 EP 89906223 A EP89906223 A EP 89906223A EP 89906223 A EP89906223 A EP 89906223A EP 0475934 A1 EP0475934 A1 EP 0475934A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- roll
- weight
- topcoat
- coating
- primer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
- B05D5/083—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2301/00—Inorganic additives or organic salts thereof
- B05D2301/10—Phosphates, phosphoric acid or organic salts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2301/00—Inorganic additives or organic salts thereof
- B05D2301/20—Chromates, chromic acid or organic salts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/54—No clear coat specified
Definitions
- TITLE A Method for Applying A Non-stick Embosser Roll Coating
- This invention provides a method for applying a non-stick embosser roll coating on rolls used for embossing polyolefin film-fibril sheets.
- the coating comprises a primer layer formed from an aqueous suspension of polytetrafluoroethylene with chromic acid and phosphoric acid and at lea ⁇ t one topcoat layer of polytetrafluoroethylene or fluoropolymer blend compositions containing copolymers of perfluorinated polyvinyl ether.
- the film-fibril sheet i ⁇ point bonded.
- Various methods have been disclosed for point bonding polyethylene film-fibril sheets. For example, sheets of flash-spun polyethylene film-fibril strands of the type disclosed in U.S.
- Patent 3,169,899 have been bonded (a) over 3 to 25% of the ⁇ urface area of the sheet by passage through a loaded nip formed by a heated metal roll having 50 to 1000 hard bosses per square inch which extend from the surface of the roll to a height of at least 1.2 times the thickness of the sheet and a hard back-up roll having a Shore Durometer D hardness of at least 70, as disclosed by Miller, United States Patent 4,152,389 and (b) over 1 to 5% of the area of the sheet by passage of the sheet through in a loaded nip formed by a heated, embossed metal roll having bosses and a soft back-up roll of a 60 to 90 Shore Durometer B hardness, as disclosed by Dempsey and Lee, United States Patent 3,478,141.
- any stoppage in production can cause the embossing roll to be covered with molten polymer, which can adhere to the patterned roll ⁇ and can not be completely removed by, for example, bru ⁇ hing.
- non- ⁇ tick coatings are applied to ⁇ uch rolls to eliminate thi ⁇ adhe ⁇ ion, however, the application of n n- ⁇ tick coating ⁇ affect heat tran ⁇ fer through the roll ⁇ , thus the application mu ⁇ t be very precise and uniform.
- Al ⁇ o, embo ⁇ ing patterns with small points cause additional concerns because the small points provide mo ⁇ t of the effective contact area between the embo ⁇ sing roll and the sheet in the nip. Correct coating thickness is crucial in these areas, however, the coating thickness in these small contact area ⁇ i ⁇ difficult to measure accurately.
- Coating compo ⁇ itions of ⁇ ilicones and epoxie ⁇ are disclosed in U.S. Pat. No. 4,252,702. Similar coating compositions but also containing fluorocarbon resins are disclosed in U.S. Patents 4,121,000 and 4,369,279.
- a process for applying a non-stick coating comprising of a primer layer of polytetrafluoroethylene with chromic acid and phosphoric acid and at least one topcoat layer of polytetrafluoroethylene or fluoropolymer blend compo ⁇ ition ⁇ containing copolymer ⁇ of perfluorinated polyvinyl ether for rolls used for embossing polyolefin film-fibril ⁇ heet ⁇ .
- the coating of the present invention provides uniform heat transfer through the roll, optimizes anti-stick properties, allows for increased throughput and extends the roll life over the coatings of the prior art.
- topcoat layer formed of an aqueous mixture of 50 to 100% by weight of total polymer polytetrafluoroethylene and 0 to 50% by weignt. or cotai polymer perfluorinated vinyl ether copolymers of 99.5 to 92% tetrafluoroethylene and 0.5 to 8% poly(propyl vinyl ether) ; (e) baking the roll at least 15 minutes at 371 to 427°C.
- the roll to be coated is heat treated at a metal temperature of about 480°C for at least 4 hours to loosen the old coating and to remove any oils or substances which might be pre ⁇ ent on the surface of the roll, or might be contained inside the roll, either of which could contaminate the final coated ⁇ urface.
- the roll i ⁇ mechanically rotated in the oven to insure any internal heating oils or liquids are allowed to either flow from the roll or be uniformly spread within the roll, where they will evaporate and decompose during the heating.
- the ⁇ urface i ⁇ then grit bla ⁇ ted to remove the old coating and provide a clean surface for the coating.
- the roll is grit blasted using vertical, horizontal and diagonal sweeping motions.
- the grit blasting material mu ⁇ t be gentle enough to remove the coating without damaging the patterned surface of the embossing roll.
- the grit and particulates from the coating are removed using compressed air before the primer coat i ⁇ applied to the roll.
- Two different layer ⁇ are applied to the roll to yield the non-stick coating of the present invention; (1) at least one primer layer and (2) at lea ⁇ t one topcoat layer. There i ⁇ a bake cycle after the application of the primer and the topcoat layer.
- the primer layer i ⁇ an aqueous mixture " f 10 to 98 weight! polytetrafluoroethylene, 1 to 45 weight% chromic acid, and 1 to 45 weight% phosphoric acid based on the combined weight of polymer and acid, as disclosed in U.S. Patent No. 2,562,118.
- the teachings of U.S. 2,562,118 are herein incorporated by reference.
- the separate liquids of the primer layer, the polymer of tetrafluoroethylene and the mixed acid constituent, are thoroughly mixed together at room temperature by rolling the containers. Shaking creates bubbles which are undesirable. During this rolling procedure the roll to be coated is heated to 29°C surface metal temperature and held for 10 minutes.
- a specific volume of primer can be applied to the roll.
- the primer solution is strained to remove any large particles before application.
- Conventional compressed air spray equipment i ⁇ used to spray the primer layer on the rolls at approximately 40-60 psig.
- the volume may be checked after the first pas ⁇ to determine if the correct quantity i ⁇ being applied to the roll.
- the volume must be checked after the second pass.
- the volume of primer should be that which indicates a final primer dry film layer thicknes ⁇ of 5 to 18 micrometers. If any other volume remains, the primer should be cleaned off with water and the roll should be lightly grit blasted before re-application of the primer. Correct primer application is essential to the application proces ⁇ . Traditional primer application will be very blotchy due to the minimal amount of material actually applied to the roll.
- the roll witn *cne appne ⁇ primer layer is placed in an oven and allowed to bake at 218 to 260°C metal temperature for at least 15 minutes. Uniformity of bake i ⁇ also important, with a maximum of 5°C difference from one end of the roll to the other.
- Thermocouples can be placed on the metal roll at the ends to ensure that the end ⁇ reach the required baking temperature. After baking, the roll is allowed to cool below 49°C before applying topcoat.
- the topcoat layer i ⁇ a fluoropolymer blend coating composition containing copolymers of perfluorinated polyvinyl ether. Fluoropolymer blend compositions containing copolymers of perfluorinated polyvinyl ether are described in U.S. Patent No. 4,252,859. U.S. 4,252,859 is incorporated herein by reference.
- the topcoat layer comprise ⁇ at lea ⁇ t one layer on the primer layer.
- the topcoat layer i ⁇ formed of an aqueou ⁇ mixture of 50 to 100% by weight of total polymer polytetrafluoroethylene and 0 to 50% by weight of total polymer perfluorinated vinyl ether copolymer ⁇ of 99.5 to 92% tetrafluoroethylene and 0.5 to 8% poly(propyl vinyl ether) baked on the embos ⁇ er roll at least 30 minutes at 371 to 427°C.
- the topcoat is brought to room temperature and is stirred gently by rolling the container. If foaming occurs, the rolling has been too severe and the material should not be used until the foam ha ⁇ di ⁇ appeared.
- the topcoat is applied at a greater thickne ⁇ than the primer, and the volume approach i ⁇ again u ⁇ ed to control the thickne ⁇ s of the of the topcoat.
- the volume of topcoat coating is measured and ⁇ trained through 200 by 200 micron opening ⁇ .
- a light ⁇ pray is set on the compres ⁇ ed air paint gun, using 40 to 45 p ⁇ ig ⁇ pray pressure.
- the roll is sprayed with at lea ⁇ t one layer ⁇ o that a final total dry film topcoat thickness of 18 to 61 micrometer ⁇ is reached. After a layer is applied, the volume of liquid remaining is again checked to confirm that the correct volume of coating has been applied to the roll. If more remains, additional layers of coating can be applied if uniformity of coating on the roll i ⁇ adequate. If too ⁇ mall an amount remain ⁇ to apply an additional layer, the roll mu ⁇ t be grit blasted and the entire coating procedure repeated.
- the roll ⁇ hould be placed in the oven for final curing.
- the roll is baked in the oven for 15 minutes at 399°C metal temperature.
- Minimum bake mu ⁇ t be at least 30 minutes at 371°C; maximum bake must not exceed 427°C and should not exceed 371°C for more than 3 hours.
- the temperature at both ends of the roll should be within 5°C.
- An embosser roll coated in accordance with this invention had a coating comprising: a) a primer layer of dry film thickne ⁇ between 5 to 18 micrometers formed of an aqueous suspension of 42.4 weight% polytetrafluoroethylene, 4.2 weight% chromic acid 3.6 weight! phosphoric acid and approximately 50 weight% water, baked on the embosser roll at 232°C for 15 minutes; b) a topcoat layer of dry film thickne ⁇ between 18 to 61 micrometers formed of an aqueous mixture of 94.4 weight% of total polymer polytetrafluoro-ethylene and 15.6 weight% perfluorinated vinyl ether copolymers of
- the aqueous suspen ⁇ ion was approximately 50 weight% water, 1 weight% pigment, 46 weight% polymer and
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Abstract
Un procédé permet d'appliquer un revêtement sur un rouleau de gaufrage de feuilles en pellicules et en fibrilles de polyoléfine. Le revêtement comprend une couche de fond formée d'une suspension aqueuse de polytétrafluoroéthylène avec de l'acide chromique et de l'acide phosphorique et une couche supérieure en polytétrafluoroéthylène ou en copolymères perfluorés de polyvinyléther de tétrafluoroéthylène et de poly(propylvinyléther).A method allows a coating to be applied to an embossing roll of sheets of polyolefin films and fibrils. The coating comprises a base layer formed of an aqueous suspension of polytetrafluoroethylene with chromic acid and phosphoric acid and an upper layer of polytetrafluoroethylene or perfluorinated copolymers of polyvinyl ether of tetrafluoroethylene and poly (propylvinyl ether).
Description
Claims
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US1989/001992 WO1990013366A1 (en) | 1989-05-12 | 1989-05-12 | A method for applying a non-stick embosser roll coating |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0475934A1 true EP0475934A1 (en) | 1992-03-25 |
EP0475934A4 EP0475934A4 (en) | 1993-01-27 |
EP0475934B1 EP0475934B1 (en) | 1995-04-05 |
Family
ID=22214999
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89906223A Expired - Lifetime EP0475934B1 (en) | 1989-05-12 | 1989-05-12 | A method for applying a non-stick embosser roll coating |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0475934B1 (en) |
JP (1) | JPH04505120A (en) |
WO (1) | WO1990013366A1 (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2562118A (en) * | 1950-02-09 | 1951-07-24 | Du Pont | Polytetrafluoroethylene coating compositions |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4196256A (en) * | 1978-08-28 | 1980-04-01 | Xerox Corporation | Long life fuser roll |
US4430406A (en) * | 1981-10-22 | 1984-02-07 | Eastman Kodak Company | Fuser member |
KR880005492A (en) * | 1986-10-30 | 1988-06-29 | 쓰찌다 요시오 | Manufacturing method of heat fixing roller |
US4755400A (en) * | 1987-03-19 | 1988-07-05 | International Business Machines Corporation | Hot roll fuser and method of making a fuser roll |
-
1989
- 1989-05-12 JP JP50600989A patent/JPH04505120A/en active Pending
- 1989-05-12 WO PCT/US1989/001992 patent/WO1990013366A1/en active IP Right Grant
- 1989-05-12 EP EP89906223A patent/EP0475934B1/en not_active Expired - Lifetime
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2562118A (en) * | 1950-02-09 | 1951-07-24 | Du Pont | Polytetrafluoroethylene coating compositions |
Non-Patent Citations (1)
Title |
---|
See also references of WO9013366A1 * |
Also Published As
Publication number | Publication date |
---|---|
EP0475934B1 (en) | 1995-04-05 |
EP0475934A4 (en) | 1993-01-27 |
JPH04505120A (en) | 1992-09-10 |
WO1990013366A1 (en) | 1990-11-15 |
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