EP0459996A1 - Improved innerseal for a container. - Google Patents

Improved innerseal for a container.

Info

Publication number
EP0459996A1
EP0459996A1 EP90902433A EP90902433A EP0459996A1 EP 0459996 A1 EP0459996 A1 EP 0459996A1 EP 90902433 A EP90902433 A EP 90902433A EP 90902433 A EP90902433 A EP 90902433A EP 0459996 A1 EP0459996 A1 EP 0459996A1
Authority
EP
European Patent Office
Prior art keywords
bonding
container
innerseal
εaid
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP90902433A
Other languages
German (de)
French (fr)
Other versions
EP0459996B1 (en
Inventor
Theresa A Mccarthy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unipac Corp
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Publication of EP0459996A1 publication Critical patent/EP0459996A1/en
Application granted granted Critical
Publication of EP0459996B1 publication Critical patent/EP0459996B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D51/00Closures not otherwise provided for
    • B65D51/18Arrangements of closures with protective outer cap-like covers or of two or more co-operating closures
    • B65D51/20Caps, lids, or covers co-operating with an inner closure arranged to be opened by piercing, cutting, or tearing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D77/00Packages formed by enclosing articles or materials in preformed containers, e.g. boxes, cartons, sacks or bags
    • B65D77/10Container closures formed after filling
    • B65D77/20Container closures formed after filling by applying separate lids or covers, i.e. flexible membrane or foil-like covers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2251/00Details relating to container closures
    • B65D2251/0003Two or more closures
    • B65D2251/0006Upper closure
    • B65D2251/0015Upper closure of the 41-type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2251/00Details relating to container closures
    • B65D2251/0003Two or more closures
    • B65D2251/0068Lower closure
    • B65D2251/0093Membrane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2577/00Packages formed by enclosing articles or materials in preformed containers, e.g. boxes, cartons, sacks, bags
    • B65D2577/10Container closures formed after filling
    • B65D2577/20Container closures formed after filling by applying separate lids or covers
    • B65D2577/2041Pull tabs
    • B65D2577/205Pull tabs integral with the closure

Definitions

  • This invention relates to container innerseals, which are used in conjunction with a conventional threaded-on cap to provide an airtight, hermetically closed seal for containers. More specifically, the invention relates to an improved innerseal for a container which promotes ease of removal in conjunction with improved sealability for containers on which it is applied relative those innerseals which were heretofore known.
  • closures which incorporate an innerseal bonded with an adhesive to an upper container rim.
  • a filled container after being capped is passed through an electromagnetic field generated by induction heating equipment, which heats a foil layer within the innerseal, thereby bringing about the melting of a heat sealable polymeric film coating.
  • One system of this type which has met with significant commercial success bears the trademark "Safe-Gard", and is manufactured by the Minnesota Mining and Manufacturing Company of St. Paul, Minnesota. This system provides a hermetic seal that is suitable for use with ingestible commodities.
  • the seal is particularly effective for products which should be preferably kept free from contamination, oxidation and/or moisture.
  • it is difficult to effectively control the adhesive force by which such innerseals are bonded to the containers, due to the dependency of the sealing force on the amount of inductive power that is applied. Accordingly, it has previously been necessary to maintain strict control over the amount of power that is applied during sealing of such containers, and a wide range of seal tightness may result even if the power range is effectively controlled.
  • the amount of sealing force which could be used was limited by the fact that a proportional amount of force was needed to remove the innerseal from the container by the end user. As a result such seals had to be penetrated or scraped off with a sharp implement such as a knife. This problem was compounded by the inconsistency of sealing forces from container to container and the limitations on sealing force as discussed above.
  • a sealed container of the type which is provided with a safety innerseal includes a container body having an upper rim; and an innerseal including a body portion adapted for fitting over the upper rim, the body portion including membrane structure for preventing passage of fluid through the body portion, structure adapted for bonding the body portion against the upper rim of the container; the bonding structure including a first bonding portion which is bonded to the rim with a first bonding force and a second bonding portion which is adhered to the first bonding portion with a second bonding force, the second bonding force being less than the first bonding force, the first bonding portion having a rupture strength that is less than either of the second bonding force and the first bonding force, and gripping structure attached to an outer periphery of the body portion whereby the sealing structure will delaminate internally during removal from a container.
  • a method for forming a sealed container of the type which includes a safety innerseal includes the steps of providing a container body having an upper rim; placing an innerseal constructed as detailed above over the upper rim; and passing the container and innerseal through a heating station, whereby the innerseal is sealed onto the container body to form a tight, effective closure.
  • FIGURE 1 is a perspective view of a sealed container constructed according to a first preferred embodiment of the invention
  • FIGURE 2 is a fragmentary cross-sectional view through an innerseal portion of the container illustrated in FIGURE 1;
  • FIGURE 3 is a fragmentary cross-sectional view through an innerseal constructed according to a second preferred embodiment of the invention.
  • FIGURE 4 i ⁇ a cross-sectional view of the innerseal arrangement illustrated in FIGURE 1;
  • FIGURE 5 is a cross-sectional view of the container illustrated in FIGURE 1 depicting removal of the innerseal from the container;
  • FIGURE 6 is a graphical representation depicting opening force versus sealing power for the invention and a sealing arrangement which is previously known;
  • FIGURE 7 is a perspective view of a work station for applying and sealing innerseals according to the invention.
  • a container 10 having a neck portion 12 and a rim 14 includes a raised helical thread 16 formed upon neck portion 12 over which an appropriate sealing cap with mating threads may be applied, as is known throughout the art.
  • a sealing arrangement 18 is provided for bonding an orifice defined in container 10 by rim 14.
  • Sealing arrangement 18 includes a removable innerseal 20 having a circular body portion 22 and a flexible tab portion 24, as is shown in Figure 1.
  • Body portion 22 is sized so as to extend over the full extent of the orifice and over rim 14.
  • Tab portion 24 is connected to body portion 22 at an outer peripheral edge thereof, as is shown in Figure 1, and in the preferred embodiment is formed from the same continuously extending layered material as is body portion 22.
  • a sealing or bonding layer which includes a first bonding portion and a second bonding portion.
  • the first bonding portion adheres to rim 14 with a first bonding force, and to the second bonding portion with a second bonding force which is less than the first bonding force.
  • the first bonding portion has a rupture strength that is less than either of the first or second bonding forces.
  • the sealing layer is adhered to the remainder of the body portion with a third bonding force that is greater than the second bonding force.
  • FIG. 2 is a fragmentary cross-sectional view of the layers which together form innerseal 20.
  • a first bonding portion such as a sealing layer 26 of heat sealable material is provided on a lower surface of innerseal 20 for bonding to the upper rim 14 of container 10.
  • sealing layer 26 is formed of a multilayer polymeric film such as polyethylene or polyester and has a thickness of between 0.5-4 mils (0.0127-0.102 mm). Most preferably, the thickness of sealing layer 26 is approximately 1 mil (0.0254 mm).
  • Sealing layer 26 may alternatively be formed of polypropylene, ethylene vinyl acetate copolymer (EVA) or a similar heat sealable material having relatively low tensile and shear strengths.
  • EVA ethylene vinyl acetate copolymer
  • Layer 28 may for example be formed of Adcote 503A which is available from Morton Norwich Products, Inc. of Chicago, Illinois.
  • the layer 28 of adhesive causes sealing layer 26 to adhere to a layer 30 of fluid impervious material.
  • Layer 30 is in the preferred embodiment formed of a metallic foil. Most preferably, layer 30 is formed of aluminum foil having a thickne ⁇ of between 1 and 2 mils (0.0254-0.051 mm).
  • Reinforcement layer 34 is in the preferred embodiment formed of polyester and has a thicknes ⁇ of between 0.5-20 mils (0.0127-0.508 mm). Preferably, reinforcement layer 34 is between 2-4 mils (0.051-0.101 mm).
  • reinforcement layer 34 may be formed of paper, polyethylene, a polymeric foamed sheet material or an equivalent material having a relatively high strength again ⁇ t tearing.
  • An example of a paper which ha ⁇ been found ⁇ uitable for reinforcement layer 34 is 80 lb. bleached Kraft paper from Sorg Paper Co. of Middleton, Ohio. The weight of this paper i ⁇ 80 lbs.
  • reinforcement layer 34 could be formed from the class of materials known as non-woven fabrics such as Tyvek , which is manufactured by DuPont Corporation.
  • the various layers in innerseal 20 de ⁇ cribed above with reference to Figure 2 extend throughout both the body portion 22 and the tab portion 24 of inner ⁇ eal 20. Two ⁇ pecific con ⁇ truction ⁇ of an inner ⁇ eal con ⁇ tructed according to the embodiment of Figure 2 and which have proven ⁇ atisfactory in practice will now be detailed:
  • sealing layer 26 is formed of a film of 50 OL-2 Mylar brand film, which consists of an upper layer having a thicknes ⁇ of 0.4 mils (0.01 mm) and a lower layer having a thicknes ⁇ of 0.1 mils (0.002 mm) which is bonded to the upper layer. Both the upper and lower layer ⁇ are co po ⁇ ed of polye ⁇ ter, and the lower layer is formulated to have a lower melting point than the upper layer for sealability.
  • Adhesive layer 28 in this construction is formed of Adcote 503A adhesive, and layer 30 is formed of an aluminum foil having a thickness of approximately 1 mil (0.025 mm).
  • Reinforcement layer 34 is formed of a polye ⁇ ter film having a thickness of approximately 2 mils (0.05 mm), and is bonded to layer 30 with an adhesive layer 32 formed of Adcote 503A adhesive, which is spread to a coating weight of 0.925-1.4 grains per 24 ⁇ quare inche ⁇ (77.4-117.2 mg/200 cm 2 .
  • Adcote 503A adhesive Adcote 503A adhesive
  • Example 2 In thi ⁇ con ⁇ truction, ⁇ ealing layer 26 is formed of Mylar 5O-OL2 film which has a total thickness of approximately 0.5 mils (0.0127 mm) and is constructed in the manner de ⁇ cribed above with reference to Example 1.
  • Layer 30 i ⁇ formed of aluminum foil having a thickness of approximately 1 mil ( 0.025 mm) and is bonded to layer 26 with a layer 28 formed of Adcote 503A adhesive.
  • Reinforcement layer 34 is formed of a polyethylene foam having a thicknes ⁇ of approximately 5 mil ⁇ (0.127 mm), which is bonded to layer 30 with an adhesive layer 32 of Adcote 503A adhesive, which is spread to a coating weight of 0.925-1.4 grains per 24 square inches (77.4-117.2 mg/200 cm 2 ).
  • FIG. 3 depict ⁇ in fragmentary cro ⁇ - ⁇ ection a ⁇ econd embodiment 48 of an inner ⁇ eal constructed according to the invention.
  • Innerseal 48 includes a first bonding portion embodied as sealing layer 26, a fluid impervious layer 30, an adhesive layer 32 and a reinforcement layer 34 each of which correspond to those layers described above in reference to the embodiment of Figure 2.
  • innerseal 48 incorporates a primer layer 50 and a second bonding portion embodied as an adhesive layer 52 which together cause foil layer 30 to adhere to sealing layer 26.
  • Adhe ⁇ ive layer 52 may for example be formed of Kraton ⁇ _D 1107 adhesive, which is preferably ⁇ pread to a coating weight of approximately 1-2 grain ⁇ per each 24 ⁇ quare inche ⁇ (83.7-167.4 mg/200 cm 2 ) .
  • Primer layer 50 i ⁇ provided to cau ⁇ e adhe ⁇ ive layer 52 to adhere to fluid imperviou ⁇ layer 30 more ⁇ trongly than it adhere ⁇ to ⁇ ealing layer 26.
  • inner ⁇ eal 48 i ⁇ con ⁇ trained to delaminate along the interface between adhe ⁇ ive layer 52 and ⁇ ealing layer 26 when it is removed from a container 10.
  • Primer layer 50 is preferably formed of a chlorinated polyolefin ⁇ uch as CP 343-1 primer, which i ⁇ manufactured by the Ea ⁇ tman Chemical Corporation of King ⁇ port, Tenne ⁇ ee.
  • Example 3 Two examples of inner ⁇ eal 48 which have been constructed and have proven to perform satisfactorily in practice will now be detailed:
  • sealing layer 26 is formed of polyethylene film having a thicknes ⁇ of approximately 1 mil (0.025 mm).
  • Adhe ⁇ ive layer 52 i ⁇ formed of Kraton __ 1107 adhe ⁇ ive and is spread to a coating weight of approximately 1 grain (83.7 mg/200 cm 2 ) .
  • Primer layer 50 is formed of Eastman CP 343-1 primer.
  • Layer 30 is formed of aluminum foil having a thickne ⁇ of approximately 1 mil (0.025 mm), and i ⁇ joined to layer 34 by mean ⁇ of an adhesive layer 32 of Adcote 503A adhesive, which is spread to a coating weight of 0.925-1.4 grains per 24 in 2 (77.4-117.2 mg/200 cm 2 ) .
  • Reinforcement layer 34 is formed of a polyester film having a thickness of approximately 2 mils (0/05 mm) .
  • sealing layer 26 i ⁇ formed of a polyethylene film having a thickne ⁇ of approximately 1 mil (0.025 mm), which i ⁇ adhered to a layer 30 of aluminum foil having a thickne ⁇ of approximately 1 mil (0.025 mm) by a primer layer 50 formed of Ea ⁇ tman CP 343-1 primer and an adhe ⁇ ive layer 52 formed of Kraton _D 1107, which i ⁇ spread to a coating weight of approximately 1 grain (83.7 mg/200 cm 2 ).
  • Reinforcement layer 34 i ⁇ formed of a sheet of 80 lb./ream (130 g/m 2 ) Kraft paper having a thickne ⁇ of approximately 6 mil ⁇ (0.152 mm), which i ⁇ bonded to layer 30 by an adhe ⁇ ive coating of Adcote 503A, which i ⁇ ⁇ pread to the coating weight de ⁇ cribed in Example 1.
  • This delaminated area is depicted in Figure 5 a ⁇ a ⁇ tripped surface 38.
  • a portion 36 of seal material remains adhered to the rim 14. Because the rupture strength of sealing layer 26 is les ⁇ than either of the abovementioned bonding forces, as tab portion 24 is pulled further upwardly, the sealing layer 26 is caused to rupture and then to tear progressively around the inner edge of rim 14, until the body portion 22 is completely removed from container 10. The delaminated layer 36 of seal material will remain adhered to rim 14 and will not interfere with removal of material from container 10.
  • delamination is caused to occur within sealing layer 26 when tab portion 24 is grasped and pulled upwardly.
  • delamination ha ⁇ been found to occur ⁇ ub ⁇ tantially along the interface between the two component layer ⁇ of polye ⁇ ter within the film, with the exception that a certain amount of ⁇ plitting occurs into the lower layer during delamination.
  • delamination might initially occur on the interface portion, deviate ⁇ lightly into the lower layer of polye ⁇ ter, then return to the interface layer.
  • FIG. 6 provide ⁇ a graphical repre ⁇ entation of the advantage ⁇ of the invention over a prior art arrangement.
  • curve 54 depict ⁇ the force required to open a prior art innerseal having a single amorphous polyester adhesive layer, ⁇ uch as Vitel ® PE 100, ver ⁇ u ⁇ a power ⁇ etting in an inductive heating station which is used to melt the adhesive layer onto a container.
  • Vitel __ PE 100 is commercially available from
  • the cap was tightened with a ⁇ pring torque tester available from Owens Illinois Glas ⁇ Co. of Toledo, Ohio to 20 inch-pound ⁇ (230.5 gram-meters).
  • the innerseal was bonded to the bottle with a Lepel high frequency induction unit, Model No. T-2.5-1KC-AP-BW, made by Lepel High Frequency Laboratories, Inc. of New York City, New York.
  • the power setting of the induction unit was varied, and is expres ⁇ ed in Figure 6 a ⁇ a percentage, to determine the effect on opening (removal) force.
  • the bottle, cap, and inner ⁇ eal were allowed to cool and the cap wa ⁇ removed.
  • a 6 inch (152 mm) length of No. 898 filament tape available from Minnesota Mining and Manufacturing Company of St.
  • Thi ⁇ may be done directly, or by placing the inner ⁇ eal 20, 48 within a threaded cap member and threading the cap member onto thread ⁇ 16 of neck portion 14 ⁇ o that the innerseal 20, 48 is forced again ⁇ t rim 14, in a manner that i ⁇ known in the art.
  • the layer 30 of metallic foil is heated up, which in turn causes layer 26 to adhere to rim 14, effectively sealing innerseal 20 onto the neck portion 12 of container 10.
  • the amount of heat applied to innerseal 20 must be sufficient to cause layer 26 to melt and adhere to rim 14 with more adhe ⁇ ive force than exi ⁇ ts between layer 26 and PSA layer 52, for the reasons discu ⁇ ed above, and to en ⁇ ure proper ⁇ ealing of the container 10.

Abstract

An easily removable innerseal for a container and method of application relates to an improved arrangement having a body portion (22) adapted for fitting over the upper rim of a container and a flexible element (24) attached to the body portion for a user to grip. The body portion is provided with a lower bonding layer, which includes a first bonding portion (26) and a second bonding portion (28) adhered to the first portion, and a layer (30) to prevent fluid from passing therethrough. The bonding force between the first and second bonding portions is designed to be weaker than the bonding force between the bonding layer and the container. In addition, the rupture strength of the first bonding portion is less than either of the bonding forces. As a result, the force required to remove the innerseal from the container is not dependent upon the amount of heat applied during sealing, because delamination will occur between the two bonding portions in an area over the container rim (14), leaving a residue of the first adhesive portion attached to the rim. By gripping the flexible element and pulling it upwardly, a user can remove the innerseal from the container without having to puncture or scrape the innerseal with a sharp object, which is frequently required to remove innerseals of the type commonly in use today. The method of application includes the steps of applying the body portion of the innerseal around the rim portion of a container and passing the container through an induction type heating station.

Description

IMPROVED INNERSEAL FOR A CONTAINER AND METHOD OF APPLYING
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to container innerseals, which are used in conjunction with a conventional threaded-on cap to provide an airtight, hermetically closed seal for containers. More specifically, the invention relates to an improved innerseal for a container which promotes ease of removal in conjunction with improved sealability for containers on which it is applied relative those innerseals which were heretofore known.
2. Description of the Prior Art
In view of the need in contemporary society for airtight, hermetically closed seals on containers for food, medicine and the like, closures have been developed which incorporate an innerseal bonded with an adhesive to an upper container rim. To effect such a seal, a filled container after being capped is passed through an electromagnetic field generated by induction heating equipment, which heats a foil layer within the innerseal, thereby bringing about the melting of a heat sealable polymeric film coating. One system of this type which has met with significant commercial success bears the trademark "Safe-Gard", and is manufactured by the Minnesota Mining and Manufacturing Company of St. Paul, Minnesota. This system provides a hermetic seal that is suitable for use with ingestible commodities. The seal is particularly effective for products which should be preferably kept free from contamination, oxidation and/or moisture. However, it is difficult to effectively control the adhesive force by which such innerseals are bonded to the containers, due to the dependency of the sealing force on the amount of inductive power that is applied. Accordingly, it has previously been necessary to maintain strict control over the amount of power that is applied during sealing of such containers, and a wide range of seal tightness may result even if the power range is effectively controlled. Moreover, the amount of sealing force which could be used was limited by the fact that a proportional amount of force was needed to remove the innerseal from the container by the end user. As a result such seals had to be penetrated or scraped off with a sharp implement such as a knife. This problem was compounded by the inconsistency of sealing forces from container to container and the limitations on sealing force as discussed above.
Although innerseals which have integral tab portions for gripping purposes have been developed, as is disclosed in U.S. Patent No. 4,754,890 to Ullman et al., the basic problem of grippability in conjunction with a limited and unpredictable range of sealing forces has not been effectively solved to date. It is within this context that the present invention assumes significance.
It is clear that there has existed a long and unfilled need in the prior art for container innerseals which are easily removable by an end user without scraping or puncturing, and that have a consistent removal force which allows a strong seal to be provided between the innerseal and container regardless of the sealing force, and that obviates the need for strict control during the sealing process. SUMMARY OF THE INVENTION
According to the invention, a sealed container of the type which is provided with a safety innerseal includes a container body having an upper rim; and an innerseal including a body portion adapted for fitting over the upper rim, the body portion including membrane structure for preventing passage of fluid through the body portion, structure adapted for bonding the body portion against the upper rim of the container; the bonding structure including a first bonding portion which is bonded to the rim with a first bonding force and a second bonding portion which is adhered to the first bonding portion with a second bonding force, the second bonding force being less than the first bonding force, the first bonding portion having a rupture strength that is less than either of the second bonding force and the first bonding force, and gripping structure attached to an outer periphery of the body portion whereby the sealing structure will delaminate internally during removal from a container.
According to a second aspect of the invention, a method for forming a sealed container of the type which includes a safety innerseal includes the steps of providing a container body having an upper rim; placing an innerseal constructed as detailed above over the upper rim; and passing the container and innerseal through a heating station, whereby the innerseal is sealed onto the container body to form a tight, effective closure.
These and various other advantages and features of novelty which characterize the invention are pointed .out with particularity in the claims annexed hereto and forming a part hereof. However, for a better understanding of the invention, its advantages, and the objects obtained by its use, reference should be made to the drawings which form a further part hereof, and to the accompanying descriptive matter, in which there is illustrated and described a preferred embodiment of the invention.
BRIEF DESCRIPTION OF THE DRAWINGS FIGURE 1 is a perspective view of a sealed container constructed according to a first preferred embodiment of the invention; FIGURE 2 is a fragmentary cross-sectional view through an innerseal portion of the container illustrated in FIGURE 1;
FIGURE 3 is a fragmentary cross-sectional view through an innerseal constructed according to a second preferred embodiment of the invention.
FIGURE 4 iε a cross-sectional view of the innerseal arrangement illustrated in FIGURE 1;
FIGURE 5 is a cross-sectional view of the container illustrated in FIGURE 1 depicting removal of the innerseal from the container;
FIGURE 6 is a graphical representation depicting opening force versus sealing power for the invention and a sealing arrangement which is previously known; and
FIGURE 7 is a perspective view of a work station for applying and sealing innerseals according to the invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMEN (S) Referring to the drawings, wherein corresponding structure is identified by like reference numerals throughout the views, and particularly referring to Figure 1, a container 10 having a neck portion 12 and a rim 14 includes a raised helical thread 16 formed upon neck portion 12 over which an appropriate sealing cap with mating threads may be applied, as is known throughout the art.
A sealing arrangement 18 is provided for bonding an orifice defined in container 10 by rim 14. Sealing arrangement 18 includes a removable innerseal 20 having a circular body portion 22 and a flexible tab portion 24, as is shown in Figure 1. Body portion 22 is sized so as to extend over the full extent of the orifice and over rim 14. Tab portion 24 is connected to body portion 22 at an outer peripheral edge thereof, as is shown in Figure 1, and in the preferred embodiment is formed from the same continuously extending layered material as is body portion 22.
Common to all of the below described embodiments is a sealing or bonding layer which includes a first bonding portion and a second bonding portion. The first bonding portion adheres to rim 14 with a first bonding force, and to the second bonding portion with a second bonding force which is less than the first bonding force. The first bonding portion has a rupture strength that is less than either of the first or second bonding forces. The sealing layer is adhered to the remainder of the body portion with a third bonding force that is greater than the second bonding force.
Figure 2 is a fragmentary cross-sectional view of the layers which together form innerseal 20. A first bonding portion such as a sealing layer 26 of heat sealable material is provided on a lower surface of innerseal 20 for bonding to the upper rim 14 of container 10. In the preferred embodiment, sealing layer 26 is formed of a multilayer polymeric film such as polyethylene or polyester and has a thickness of between 0.5-4 mils (0.0127-0.102 mm). Most preferably, the thickness of sealing layer 26 is approximately 1 mil (0.0254 mm). Sealing layer 26 may alternatively be formed of polypropylene, ethylene vinyl acetate copolymer (EVA) or a similar heat sealable material having relatively low tensile and shear strengths. Laminated to a top surface of sealing layer 26 iε a second bonding portion such aε a layer 28 of pressure sensitive adhesive (PSA) . Layer 28 may for example be formed of Adcote 503A which is available from Morton Norwich Products, Inc. of Chicago, Illinois.
The layer 28 of adhesive causes sealing layer 26 to adhere to a layer 30 of fluid impervious material. Layer 30 is in the preferred embodiment formed of a metallic foil. Most preferably, layer 30 is formed of aluminum foil having a thickneεε of between 1 and 2 mils (0.0254-0.051 mm).
A reinforcement layer 34 iε laminated to layer 30 via a layer 32 of laminated adhesive, which for example may be formed of Adcote 503A. Reinforcement layer 34 is in the preferred embodiment formed of polyester and has a thicknesε of between 0.5-20 mils (0.0127-0.508 mm). Preferably, reinforcement layer 34 is between 2-4 mils (0.051-0.101 mm). Alternatively, reinforcement layer 34 may be formed of paper, polyethylene, a polymeric foamed sheet material or an equivalent material having a relatively high strength againεt tearing. An example of a paper which haε been found εuitable for reinforcement layer 34 is 80 lb. bleached Kraft paper from Sorg Paper Co. of Middleton, Ohio. The weight of this paper iε 80 lbs. per ream, which is equivalent to 130 grams/m2. As a second alternative, reinforcement layer 34 could be formed from the class of materials known as non-woven fabrics such as Tyvek , which is manufactured by DuPont Corporation. In the preferred embodiment, the various layers in innerseal 20 deεcribed above with reference to Figure 2 extend throughout both the body portion 22 and the tab portion 24 of innerεeal 20. Two εpecific conεtructionε of an innerεeal conεtructed according to the embodiment of Figure 2 and which have proven εatisfactory in practice will now be detailed:
Example 1:
In thiε conεtruction, which is εuitable for use with containers 10 that are formed of polyester or polyvinyl chloride, sealing layer 26 is formed of a film of 50 OL-2 Mylar brand film, which consists of an upper layer having a thicknesε of 0.4 mils (0.01 mm) and a lower layer having a thicknesε of 0.1 mils (0.002 mm) which is bonded to the upper layer. Both the upper and lower layerε are co poεed of polyeεter, and the lower layer is formulated to have a lower melting point than the upper layer for sealability. Adhesive layer 28 in this construction is formed of Adcote 503A adhesive, and layer 30 is formed of an aluminum foil having a thickness of approximately 1 mil (0.025 mm). Reinforcement layer 34 is formed of a polyeεter film having a thickness of approximately 2 mils (0.05 mm), and is bonded to layer 30 with an adhesive layer 32 formed of Adcote 503A adhesive, which is spread to a coating weight of 0.925-1.4 grains per 24 εquare incheε (77.4-117.2 mg/200 cm2. In this construction, it has been found that delamination occurε within εealing layer 26 when the innerεeal iε being removed from a container 10. Example 2: In thiε conεtruction, εealing layer 26 is formed of Mylar 5O-OL2 film which has a total thickness of approximately 0.5 mils (0.0127 mm) and is constructed in the manner deεcribed above with reference to Example 1. Layer 30 iε formed of aluminum foil having a thickness of approximately 1 mil ( 0.025 mm) and is bonded to layer 26 with a layer 28 formed of Adcote 503A adhesive. Reinforcement layer 34 is formed of a polyethylene foam having a thicknesε of approximately 5 milε (0.127 mm), which is bonded to layer 30 with an adhesive layer 32 of Adcote 503A adhesive, which is spread to a coating weight of 0.925-1.4 grains per 24 square inches (77.4-117.2 mg/200 cm2).. In this conεtruction, delamination during opening of the innerεeal haε alεo been found to occur within the sealing layer 26.
Figure 3 depictε in fragmentary croεε-εection a εecond embodiment 48 of an innerεeal constructed according to the invention. Innerseal 48 includes a first bonding portion embodied as sealing layer 26, a fluid impervious layer 30, an adhesive layer 32 and a reinforcement layer 34 each of which correspond to those layers described above in reference to the embodiment of Figure 2. However, innerseal 48 incorporates a primer layer 50 and a second bonding portion embodied as an adhesive layer 52 which together cause foil layer 30 to adhere to sealing layer 26. Adheεive layer 52 may for example be formed of Kraton <_D 1107 adhesive, which is preferably εpread to a coating weight of approximately 1-2 grainε per each 24 εquare incheε (83.7-167.4 mg/200 cm2) . Primer layer 50 iε provided to cauεe adheεive layer 52 to adhere to fluid imperviouε layer 30 more εtrongly than it adhereε to εealing layer 26. In thiε way, innerεeal 48 iε conεtrained to delaminate along the interface between adheεive layer 52 and εealing layer 26 when it is removed from a container 10. Primer layer 50 is preferably formed of a chlorinated polyolefin εuch as CP 343-1 primer, which iε manufactured by the Eaεtman Chemical Corporation of Kingεport, Tenneεεee.
Two examples of innerεeal 48 which have been constructed and have proven to perform satisfactorily in practice will now be detailed: Example 3:
In this construction, sealing layer 26 is formed of polyethylene film having a thicknesε of approximately 1 mil (0.025 mm). Adheεive layer 52 iε formed of Kraton __ 1107 adheεive and is spread to a coating weight of approximately 1 grain (83.7 mg/200 cm2) . Primer layer 50 is formed of Eastman CP 343-1 primer. Layer 30 is formed of aluminum foil having a thickneεε of approximately 1 mil (0.025 mm), and iε joined to layer 34 by meanε of an adhesive layer 32 of Adcote 503A adhesive, which is spread to a coating weight of 0.925-1.4 grains per 24 in2 (77.4-117.2 mg/200 cm2) . Reinforcement layer 34 is formed of a polyester film having a thickness of approximately 2 mils (0/05 mm) . Example 4:
In this construction, sealing layer 26 iε formed of a polyethylene film having a thickneεε of approximately 1 mil (0.025 mm), which iε adhered to a layer 30 of aluminum foil having a thickneεε of approximately 1 mil (0.025 mm) by a primer layer 50 formed of Eaεtman CP 343-1 primer and an adheεive layer 52 formed of Kraton _D 1107, which iε spread to a coating weight of approximately 1 grain (83.7 mg/200 cm2). Reinforcement layer 34 iε formed of a sheet of 80 lb./ream (130 g/m2) Kraft paper having a thickneεε of approximately 6 milε (0.152 mm), which iε bonded to layer 30 by an adheεive coating of Adcote 503A, which iε εpread to the coating weight deεcribed in Example 1.
Turning now to Figureε 4 and 5, the removal of an innerεeal 20, 48 from container 10 will be deεcribed. Innerεeal 20 iε εealed onto the rim portion 14 of container 10 in a manner which will be deεcribed below. To remove innerεeal 20, 48 from itε poεition around rim 14 as is shown in Figure 4, the tab portion 24 is grasped and pulled upwardly. Because the adhesive layer is bonded to the sealing layer with a bonding force which is lesε than the bonding force between the εealing layer and the container rim, this movement initially results in delamination of adhesive layer 52 from sealing layer 26, in the portion of innerseal 20 which extends over rim 14. This delaminated area is depicted in Figure 5 aε a εtripped surface 38. At this time, a portion 36 of seal material remains adhered to the rim 14. Because the rupture strength of sealing layer 26 is lesε than either of the abovementioned bonding forces, as tab portion 24 is pulled further upwardly, the sealing layer 26 is caused to rupture and then to tear progressively around the inner edge of rim 14, until the body portion 22 is completely removed from container 10. The delaminated layer 36 of seal material will remain adhered to rim 14 and will not interfere with removal of material from container 10.
In the case of an innerseal 20, delamination is caused to occur within sealing layer 26 when tab portion 24 is grasped and pulled upwardly. Where 50 OL-2 Mylar brand film is uεed to form εealing layer 26, delamination haε been found to occur εubεtantially along the interface between the two component layerε of polyeεter within the film, with the exception that a certain amount of εplitting occurs into the lower layer during delamination. For example, delamination might initially occur on the interface portion, deviate εlightly into the lower layer of polyeεter, then return to the interface layer. The delaminated area which is cauεed to adhere to rim portion 14 iε depicted in Figure 5 aε εtripped εurface 38. Aε iε the caεe with innerεeal 48, a portion 36 of εeal material remainε adhered to the rim 14. Aε top portion 24 iε pulled further upwardly, the sealing layer 26 is caused to rupture and then to tear progressively around the inner edge of rim 14, until the body portion 22 is completely removed from container 10.
Because delamination occurs within the innerseal 20, 48 rather than directly between sealing layer 26 and rim 14, it is not necesεary to maintain aε strict a control over the amount of heat applied to sealing layer 26 during the sealing process, as was the case in innerseal designε previouεly known. Figure 6 provideε a graphical repreεentation of the advantageε of the invention over a prior art arrangement. In Figure 6, curve 54 depictε the force required to open a prior art innerseal having a single amorphous polyester adhesive layer, εuch as Vitel® PE 100, verεuε a power εetting in an inductive heating station which is used to melt the adhesive layer onto a container. Vitel __ PE 100 is commercially available from
Goodyear Tire and Rubber Company of Akron, Ohio. Curve
56 depicts the force required to open an innerseal constructed according to Example 1 in the description of innerseal 20. In the test for opening force which was used to produce the data shown in Figure 6, a 4 ounce (118.3 ml) 43,410 finish continuouε thread polyeεter bottle waε uεed in conjunction with a 43,410 finiεh polypropylene cap. The bottle iε available from Setco, Inc. of Anaheim, California, and the cap iε available from Tubed Productε, Inc. of Easthampton, Maine. Each teεted innerεeal waε positioned within the cap with the tab folded back between the cap and the innerseal, and with the heat sealable side of the innerseal facing the open end of the cap. The cap was tightened with a εpring torque tester available from Owens Illinois Glasε Co. of Toledo, Ohio to 20 inch-poundε (230.5 gram-meters). The innerseal was bonded to the bottle with a Lepel high frequency induction unit, Model No. T-2.5-1KC-AP-BW, made by Lepel High Frequency Laboratories, Inc. of New York City, New York. The power setting of the induction unit was varied, and is expresεed in Figure 6 aε a percentage, to determine the effect on opening (removal) force. After bonding, the bottle, cap, and innerεeal were allowed to cool and the cap waε removed. A 6 inch (152 mm) length of No. 898 filament tape available from Minnesota Mining and Manufacturing Company of St. Paul, Minneεota, waε folded in half with the adhesive surfaces in contact with each other and each adhesive surface was adhered to opposing surfaces of the tab of the innerseal. The bottle was then clamped in the lower jaw of an Instron Model 1123 Tensile Tester so that the bottle iε vertical. The filament tape was clamped in the upper jaw of the Inεtron teεter. Aε the jawε of the Inεtron εeparate, the innerεeal εeparates from the bottle and the level of force achieved at separation was recorded.
By comparing the two curves 54, 56, it may clearly be seen that a much wider range of power settings may be used in the present invention to keep opening force within a desired range than was posεible for the prior art innerεeal. Accordingly, it iε poεεible to maintain a much higher level of quality control over the opening force of containerε εealed with innerseals according to the invention. Referring now to Figure 7, the preferred procesε for applying an innerεeal 20, 48 to a container will now be deεcribed. Aε iε εhown in Figure 7, an innerεeal 20, 48 iε firεt placed over the opening in container 10 εo that itε peripheral edgeε extend over rim portion 14. Thiε may be done directly, or by placing the innerεeal 20, 48 within a threaded cap member and threading the cap member onto threadε 16 of neck portion 14 εo that the innerseal 20, 48 is forced againεt rim 14, in a manner that iε known in the art. Thiε proceεε iε depicted εchematically in Figure 7 at an application station 40. After application of innerseal 20, 48 to a container 10, the asεembly iε tranεported via a conveyor 46 or the like to a heat sealing station 42, which includes an induction heater 44. As the asεembly conεiεting of bottle 10 and innerseal 20 paεεes through induction heater 44, the layer 30 of metallic foil is heated up, which in turn causes layer 26 to adhere to rim 14, effectively sealing innerseal 20 onto the neck portion 12 of container 10. The amount of heat applied to innerseal 20 must be sufficient to cause layer 26 to melt and adhere to rim 14 with more adheεive force than exiεts between layer 26 and PSA layer 52, for the reasons discuεεed above, and to enεure proper εealing of the container 10.
It is to be understood, however, that even though numerous characteristics and advantages of the present invention have been set forth in the foregoing description, together with details of the structure and function of the invention, the discloεure iε illuεtrative only, and changes may be made in detail, eεpecially in matterε of shape, εize and arrangement of parts within the principleε of the invention to the full extent indicated by the broad general meaning of the termε in which the appended claimε are expreεεed.

Claims

WHAT IS CLAIMED IS:
1. An improved eaεy opening innerεeal for uεe with a container of the type having an opening defined by an upper rim, comprising: a body portion having an upper surface and adapted for fitting over an upper rim of a container, said body portion including membrane means for preventing passage of fluid through said body portion; and means adapted for bonding said body portion against the upper rim of the container; said bonding means having a first bonding portion for bonding against the container rim with a first bonding force and a second bonding portion which iε adhered to said first bonding portion with a second bonding force which is leεε than said first bonding force, said first bonding portion having a rupture strength that is leεε than either of said εecond bonding force and εaid first bonding force; and gripping means attached to an outer periphery of εaid body means for a user to grip while removing εaid innerεeal from a container, whereby a firεt part of εaid firεt bonding portion will delaminate from εaid second bonding portion over the container rim and remain adhered to the rim when said gripping meanε iε pulled, while a second part of said first bonding portion will remain adhered to εaid second bonding portion, thereby exposing the opening.
2. An innerseal according to claim 1, wherein said membrane means comprises a fluid impermeable membrane.
3. An innerseal according to claim 2, wherein εaid membrane comprises a layer of aluminum foil.
4. An innerseal according to claim 2, wherein said membrane further compriseε an adheεive layer bonded to said second bonding portion; and said first bonding portion compriεes a first bonding strata and said second bonding portion comprises a second bonding strata.
5. An innerseal according to claim 4, wherein said first bonding strata has a lower melting temperature than said second bonding strata.
6. An innerseal according to claim 4, wherein said first bonding strata is comprised of a material selected from the group consisting essentially of polyester, polypropylene, polyethylene and EVA and laminates or blends thereof.
7. An innerseal according to claim 2, wherein εaid first bonding portion compriεeε a layer of heat εealable film, and εaid second bonding portion compriεeε a layer of presεure εenεitive adhesive.
8. An innerseal according to claim 7, wherein said layer of heat εealable material compriεeε a material εelected from the group conεisting esεentially of polyeεter, polypropylene, polyethylene and EVA and laminates or blendε thereof.
9. An innerεeal according to claim 1, wherein said gripping meanε and εaid body portion are formed of a continuouεly extending common layered material.
10. A εealed container of the type which is provided with a εafety innerεeal, comprising: a container body having an upper rim; and an innerεeal compriεing a body portion for fitting over εaid upper rim, εaid body portion having an upper εurface and including membrane meanε for preventing paεεage of fluid through said body portion, meanε adapted for bonding εaid body portion againεt εaid upper rim, εaid bonding meanε having a firεt bonding portion for bonding againεt εaid container rim with a firεt bonding force and a second bonding portion which is adhered to said firεt bonding portion with a second bonding force which is lesε than εaid firεt bonding force, εaid firεt bonding portion having a rupture strength that is lesε than either of εaid εecond bonding force and εaid firεt bonding force; and gripping means attached to an outer periphery of said body means for a user to grip while removing said innerseal from a conainer, whereby a first part of εaid first bonding portion will delaminate from said second bonding portion over the container rim and remain adhered to the rim when said gripping means is pulled, while a second part of said first bonding portion will remain adhered to said second sealing portion, thereby exposing the opening.
11. An innerseal according to claim 10, wherein said membrane means comprises a fluid impermeable membrane.
12. An innerseal according to claim 11, wherein εaid membrane compriseε a layer of aluminum foil.
13. An innerεeal according to claim 11, wherein said membrane further compriseε an adheεive layer bonded to said second bonding portion; and said first bonding portion compriseε a first bonding strata and said second bonding portion compriεeε a second bonding strata.
14. An innerseal according to claim 13, wherein said first bonding εtrata haε a lower melting temperature than εaid εecond bonding εtrata.
15. An innerseal according to claim 13, wherein said first bonding strata is comprised of a material selected from the group consisting esεentially of polyester, polypropylene, polyethylene and EVA and laminates or blends thereof.
16. An innerseal according to claim 11, wherein said first bonding portion comprises a layer of heat sealable film, and said second bonding portion comprises a layer of pressure sensitive adhesive.
17. An innerseal according to claim 16, wherein said layer of heat sealable material is comprises of a material selected from the group consiεting eεεentially of polyester, polypropylene, polyethylene and EVA and laminates or blends thereof.
18. An innerseal according to claim 10, wherein said gripping means and said body portion are formed of a continuously extending common layered material.
19. A method for forming a sealed container of the type which includes a safety innerseal, comprising:
(a) providing a container body having an upper rim;
(b) placing an innerseal comprising: a body portion sized for fitting over the upper rim, and having an upper surface, a bonding meanε having a firεt bonding portion and a second bonding portion which is adhered to the first bonding portion with a εecond bonding force, the firεt bonding portion having a rupture strength which is less than the second bonding force; a layer for preventing passage of fluid therethrough; and gripping means connected to an outer periphery of the body portion for graεping by a uεer over the upper rim of the container; and (c) paεεing the container and innerseal through a heating station, whereby the innerseal is sealed onto the container body with a first bonding force which iε greater than εaid second bonding force.
20. A method according to claim 19, wherein said innerseal includes a layer of metallic foil, and wherein step (c) utilizes an inductive type device for heating the metallic foil, whereby the innerseal is sealed onto the upper rim of the container body.
EP90902433A 1989-02-27 1990-01-17 Improved innerseal for a container Expired - Lifetime EP0459996B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US31439489A 1989-02-27 1989-02-27
US314394 1989-02-27
PCT/US1990/000335 WO1990009935A1 (en) 1989-02-27 1990-01-17 Improved innerseal for a container and method of applying

Publications (2)

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EP0459996A1 true EP0459996A1 (en) 1991-12-11
EP0459996B1 EP0459996B1 (en) 1994-12-28

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JP (1) JP2873252B2 (en)
KR (1) KR100196812B1 (en)
AT (1) ATE116251T1 (en)
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BR (1) BR9007166A (en)
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DE (1) DE69015621T2 (en)
DK (1) DK0459996T3 (en)
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MX (1) MX172110B (en)
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US9540148B2 (en) * 2010-02-26 2017-01-10 Monfitello Inc. Lightweight single-dose container
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NZ232233A (en) 1993-04-28
ES2065523T3 (en) 1995-02-16
AU639438B2 (en) 1993-07-29
DE69015621D1 (en) 1995-02-09
ZA89737B (en) 1989-10-25
ZA90737B (en) 1990-12-28
DE69015621T2 (en) 1995-06-22
CA2046864A1 (en) 1990-08-28
AU4959590A (en) 1990-09-26
KR100196812B1 (en) 1999-06-15
DK0459996T3 (en) 1995-05-29
JP2873252B2 (en) 1999-03-24
BR9007166A (en) 1991-11-12
MX172110B (en) 1993-12-03
ATE116251T1 (en) 1995-01-15
EP0459996B1 (en) 1994-12-28
WO1990009935A1 (en) 1990-09-07
NO308731B1 (en) 2000-10-23
KR920700154A (en) 1992-02-19
NO913370D0 (en) 1991-08-27
NO913370L (en) 1991-10-22
JPH04505598A (en) 1992-10-01

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