EP0445159A1 - Melanges tensio-actifs - Google Patents

Melanges tensio-actifs

Info

Publication number
EP0445159A1
EP0445159A1 EP89912959A EP89912959A EP0445159A1 EP 0445159 A1 EP0445159 A1 EP 0445159A1 EP 89912959 A EP89912959 A EP 89912959A EP 89912959 A EP89912959 A EP 89912959A EP 0445159 A1 EP0445159 A1 EP 0445159A1
Authority
EP
European Patent Office
Prior art keywords
fatty alcohol
alcohol ether
weight
contain
mixtures according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP89912959A
Other languages
German (de)
English (en)
Inventor
Reinhard Müller
Klaus-Dieter Wisotzki
Karl Giede
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0445159A1 publication Critical patent/EP0445159A1/fr
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/37—Mixtures of compounds all of which are anionic
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/06—Ether- or thioether carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/08—Polycarboxylic acids containing no nitrogen or sulfur
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers

Definitions

  • the invention relates to surface-active mixtures with low skin stress.
  • European patent applications 199 131 and 209 910 relate to esters of hydroxycarboxylic acids such as citric acid and tartaric acid. By replacing part of the usual anionic surfactants with such esters, anionic surfactant solutions with improved skin tolerance are obtained.
  • ampholytic and nonionic surfactants are often characterized by improved skin tolerance compared to anionic surfactants.
  • these classes of surfactants cannot be used as a replacement for anionic surfactants for many areas of application, since they do not achieve their properties in crucial points, such as the cleaning action;
  • the foam formation desired for shampoos by the consumer is generally not guaranteed if amphoteric surfactants are used exclusively or predominantly.
  • the invention thus relates to surface-active aqueous mixtures comprising fatty alcohol ether sulfates and at least one further anionic surfactant from the group of fatty alcohol ether tartrates and fatty alcohol ether citrates, characterized in that (a) the
  • Mixtures contain 0.01-3% by weight of alkaline earth metal ions, based on the mixture as a whole, and (b) the fatty alcohol ether sulfates and the other anionic surfactants mentioned are present in a ratio of 70:30 to 1:99.
  • Fatty alcohol ether sulfates are to be understood as meaning the sulfates of the adducts of ethylene oxide (E0) and / or propylene oxide (PO) with saturated and / or unsaturated, linear and / or branched fatty alcohols, which are obtainable by known processes.
  • the fatty alcohols on which the fatty alcohol ether sulfates are based can be pure compounds. However, it is usually preferred to use mixtures of various fatty alcohols obtained from native raw materials such as fats and oils. These fatty alcohols can be mixed with the alkylene oxides for example under pressure and in the presence of catalysts to fatty alcohol alkoxylates.
  • the desired fatty alcohol ether sulfates are finally obtained by reacting the fatty alcohol alkoxylates with, for example, sulfur trioxide and subsequent neutralization with alkali metal, alkaline earth metal or ammonium hydroxides.
  • fatty alcohol ether sulfates whose linear or branched alkyl or alkenyl radicals contain 8-22 carbon atoms. It is also preferred to use fatty alcohol ether sulfates which have an average degree of alkoxylation of 2-15, in particular 3-10. The use of ethoxylated products is particularly preferred. In the context of the invention it is preferred to use fatty alcohol ether sulfates which already contain the amounts of alkaline earth metal ions required according to the invention as counterions.
  • Fatty alcohol ether tartrates to be used according to the invention are monoesters of tartaric acid with alcohols, the addition products of Represent ethylene oxide and / or propylene oxide on fatty alcohols. These fatty alcohols can be saturated and / or unsaturated, linear and / or branched. It is preferred to use fatty alcohols with 8-22 carbon atoms. Likewise preferred are degrees of alkoxylation of 2-15, in particular 3-10. With regard to the importance of the degree of alkoxylation, reference is made to the statements made in the description of the fatty alcohol ether sulfates.
  • the mono-esterified tartaric acid can be used both directly and in the form of its salts, which are obtainable by reacting the non-esterified carboxyl group with appropriate bases.
  • Preferred salts are the alkali metal, alkaline earth metal and ammonium salts. Manufacturing instructions for these compounds can be found in European patent application 209 910.
  • Fatty alcohol ether citrates to be used according to the invention are mono- and / or diesters of citric acid with alcohols, which are addition products of ethylene oxide and / or propylene oxide with fatty alcohols. These fatty alcohols can be saturated and / or unsaturated, linear and / or branched. It is preferred to use fatty alcohols with 8-22 carbon atoms. Likewise preferred are degrees of alkoxylation of 2-15, in particular 3-10. With regard to the importance of the degree of alkoxylation, reference is also made to the explanations in the description of the fatty alcohol ether sulfates.
  • the mono- and / or diverestered citric acid can be used both directly and in the form of its salts, which are obtainable by reacting the non-esterified carboxyl group or groups with appropriate bases.
  • Preferred salts are the alkali metal, alkaline earth metal and ammonium salts. Manufacturing instructions for these compounds can be found in European patent application 199 131.
  • the ethoxylated compounds are preferred both with regard to the fatty alcohol ether tartrates and with regard to the fatty alcohol ether citrates.
  • a very particularly preferred fatty alcohol ether tartrate is sodium lauryl (7 E0) tartrate.
  • such mixtures which contain 0.05-1% by weight, in particular 0.05-0.5% by weight, of alkaline earth metal ions.
  • the magnesium ion is of particular importance.
  • the surface-active mixtures contain a total of 2-50% by weight of anionic surfactants. A content of 5-30% by weight is preferred.
  • the surface-active mixtures according to the invention can additionally contain 0.5-20% by weight, in particular 1-10% by weight, of ampholytic and / or zwitterionic surfactants.
  • Ampholytic surfactants are surface-active compounds which, in addition to a C 8 -C 18 -alkyl or -acyl group, contain at least one free amino group and at least one -COOH or -S0 3 H group in the molecule and for formation inner salts are capable.
  • ampholytic surfactants are N-alkylglycine, N-alkylpropionic acid, N-alkylaminobutyric acid, N-alkyliminodipropionic acid, N-hydroxyethyl-N-alkylamidopropylglycine, N-alkyltaurine, N-alkyl sarcosine, 2-alkylaminopropionic acid and alkylaminoacetic acid each with about 8 to 18 C. Atoms in the alkyl group.
  • Zwitterionic surfactants are surface-active compounds that contain at least one quaternary ammonium group and at least one -COO (-) - or -SO 3 (-) - group in the molecule.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example the cocoalkyl-dimethylammonium glycinate, N-acyl-aminopropyl-N, N-dimethylammonium glycinate, for example the cocoacylaminopropyl-dimethylammonium glycinate, and 2-alkyl-3-carboxylmethyl-3-hydroxyethyl-imidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethyl-hydroxyethylcarboxymethylglycinate.
  • the skin-protecting properties of the agents according to the invention come into their own when they are formulated in such a way that they have a pH close to the neutral point. Agents with pH values in the range from 5.5 to 7.5, in particular from 6.5 to 7.5, are therefore preferred.
  • the agents according to the invention can be used in a large number of consumer products such as hair care products, hair shampoos, body care lotions, shower baths and products for infant care.
  • these products contain the usual ingredients such as emulsifiers, oil components, fats and waxes, solubilizers, thickeners, superfatting agents, biogenic agents, film formers, fragrances, dyes, pearlescent agents, foam stabilizers, preservatives and pH regulators.
  • emulsifiers the usual substances in cosmetic preparations such.
  • Usual oil components are substances such as paraffin oil, vegetable oils, fatty acid esters, squalane and 2-octyldodecanol, while the fats and waxes used are, for example, walnut, beeswax, montan wax, paraffin and cetylstearyl alcohol.
  • Low monohydric or polyhydric alcohols such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol, 1,3-butylene glycol and diethylene glycol are usually used as solubilizers.
  • Substances such as polyethoxylated lanolin derivatives, lecithin derivatives and fatty acid alkanolamides can be used as superfatting agents, the latter also simultaneously serving as foam stabilizers.
  • Suitable thickeners are, for example, polysaccharides, in particular xanthan gum, guar gum, agar agar, alginates and tyloses, and also carboxymethyl cellulose and hydroxyethyl cellulose, further higher molecular weight polyethylene glycol mono- and diesters of fatty acids, polyacrylates, polyvinyl alcohol and polyvinyl pyrrolidone and finally electrolytes such as table salt and ammonium chloride, if desired in combination with alkyl ether sulfates.
  • polysaccharides in particular xanthan gum, guar gum, agar agar, alginates and tyloses, and also carboxymethyl cellulose and hydroxyethyl cellulose, further higher molecular weight polyethylene glycol mono- and diesters of fatty acids, polyacrylates, polyvinyl alcohol and polyvinyl pyrrolidone and finally electrolytes such as table salt and ammonium chloride, if desired in combination with
  • Biogenic active ingredients are to be understood as plant extracts, protein breakdown products and vitamin complexes.
  • Common film formers are, for example, polyvinylpyrrolidone, vinylpyrrolidone-vinyl acetate copolymers, polymers of the acrylic acid series, quaternary cellulose derivatives and similar compounds.
  • the substances listed in the annex to the Cosmetics Ordinance are suitable as preservatives.
  • Pearlescent agents are in particular glycol distearic acid esters such as ethylene glycol distearate, but also fatty acid monoglycol esters.
  • the dyes which can be used are the substances which are suitable and approved for cosmetic purposes, as compiled, for example, in the publication "Cosmetic Dyes” by the Dye Commission of the German Research Foundation, published by Verlag Chemie, Weinheim, 1984. These dyes are usually used in concentrations of 0.001 to 0.1% by weight, based on the mixture as a whole.
  • further components of the agents according to the invention are fragrances and substances which serve to adjust the pH of the agents.
  • the mixtures according to the invention are preferably used in products which are used for washing, dyeing, waving or rinsing hair.
  • the mixtures are particularly suitable for shampoos for washing hair.
  • the swelling of the pig epidermis served as a measure of the skin compatibility of the surfactant mixtures.
  • the required epidermis was obtained immediately after young pigs were slaughtered and stored frozen.
  • the Q value of the water-treated skin is therefore by definition 0%; negative values indicate anti-swelling properties.
  • the properties of mixtures of a surfactant mixture T it Eucarol (R) TA 1 were examined.
  • the surfactant mixture T was produced as follows:
  • a mixture of 96 kg of an adduct of 10 mol ethylene oxide with a coconut fatty alcohol C 12 -C 18 (54 weight percent C 12 , 22 weight percent C 14 , 10 weight percent C16, 12 weight percent C 18 ), 113 kg of an adduct of 2 mol ethylene oxide with one Coconut fatty alcohol C 12 -C 14 (73 weight percent C 12 , 27 weight percent C 14 ) and 24.5 kg of an adduct of 2 moles of ethylene oxide with an oleyl-cetyl alcohol (65 weight percent C 18 , 30 weight percent C 16 , 5 weight percent C 14 , Iodine number 50) was reacted with 74.4 kg of chlorosulfonic acid at a temperature of 10 to 20 ° C.
  • the alkyl ether sulfate obtained had an anionic surfactant content of 0.592 mol / kg (determined by two-phase titration according to DGF unit method H-III-10).
  • the surfactant mixture T thus obtained had an anionic surfactant content of approximately 0.59 mol / kg, corresponding to approximately 28 percent by weight (calculated with an average molecular weight of the anionic surfactants of 475).
  • the foam behavior of the surfactant mixtures was determined using a motorized blow-foam apparatus in accordance with DIN 53902.
  • 340 ml of surfactant solution (2% by weight of active substance in tap water from Düsseldorf-Holthausen at 18 ° dH) were prepared.
  • the foam was generated at room temperature with a perforated plate (holes of 1 mm in diameter, 10 impacts at a frequency of 50 impacts / min, 13 cm stroke); it is very fine-pored and thus largely corresponds to a foam that forms on the head when shampooing.
  • the measurements were carried out as a duplicate determination without grease contamination of the surfactant solution.
  • CTFA name Cocoamidopropyl Betaine (approx. 30% active substance, approx. 5% NaCl, (HENKEL) 4 Mixture of coconut fatty acid diethanolamide (approx. 70%) and
  • This mixture was diluted with water and also used in the form of a solution with 2% by weight of active substance.
  • the measured amounts of foam of the surfactant solutions according to the invention are given in the following table in percent based on the amount of foam of the comparison substance.
  • T surfactant mixture Eucarol TA
  • CTFA name Coco-betaine (approx. 30% active substance, approx. 6% NaCl) (HENKEL)
  • the foaming behavior of these ternary surfactant mixtures was determined in the same way as for the binary mixtures.
  • the aqueous mixtures contained 1.6% by weight of active substance of the binary mixture of surfactant T / Eucarol TA in the ratio given below and 0.4% by weight of active substance of the third surfactant component A.
  • the measured amounts of foam of the surfactant solutions according to the invention are given in the following table in percent based on the amount of foam of the comparison substance.
  • the table also shows the value for a mixture which contains 2% by weight of active substance of the binary mixture of surfactant mixture T and Eucarol TA.

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Birds (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

Des mélanges tensio-actifs aqueux contiennent des sulfates éthériques d'alcools gras et au moins un autre agent tensio-actif anionique du groupe des tartrates éthériques et des citrates éthériques des alcools gras, contenant entre 0,01 et 3 % en poids d'ions de métaux alcalino-terreux, par rapport à l'ensemble du mélange. Le rapport entre les quantités des sulfates éthériques d'alcools gras et des autres agents tensio-actifs anioniques mentionnés est compris entre 70:30 et 1:99. Ces mélanges se caractérisent par le fait qu'ils sont bien supportés par la peau, tout en ayant une bonne capacité de nettoyage et un bon pouvoir moussant.
EP89912959A 1988-11-25 1989-11-16 Melanges tensio-actifs Pending EP0445159A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3839769 1988-11-25
DE3839769A DE3839769A1 (de) 1988-11-25 1988-11-25 Oberflaechenaktive mischungen

Publications (1)

Publication Number Publication Date
EP0445159A1 true EP0445159A1 (fr) 1991-09-11

Family

ID=6367850

Family Applications (2)

Application Number Title Priority Date Filing Date
EP89912959A Pending EP0445159A1 (fr) 1988-11-25 1989-11-16 Melanges tensio-actifs
EP89121215A Expired - Lifetime EP0371339B1 (fr) 1988-11-25 1989-11-16 Mélanges surfactifs

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP89121215A Expired - Lifetime EP0371339B1 (fr) 1988-11-25 1989-11-16 Mélanges surfactifs

Country Status (6)

Country Link
EP (2) EP0445159A1 (fr)
AT (1) ATE86095T1 (fr)
CA (1) CA2003517A1 (fr)
DE (2) DE3839769A1 (fr)
ES (1) ES2053920T3 (fr)
WO (1) WO1990006105A2 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4122200A1 (de) * 1991-07-04 1993-01-07 Henkel Kgaa Waessrige zubereitungen oberflaechenaktiver substanzen
DE4301994C1 (de) * 1993-01-26 1994-08-25 Wella Ag Haar- und Körperreinigungsmittel
ITMI981579A1 (it) * 1998-07-10 2000-01-10 Condea Augusta Spa Composizione detergente ad azione ammorbidente e protettiva delle fibre naturali
DE19945577B4 (de) * 1999-09-23 2004-08-12 Cognis Deutschland Gmbh & Co. Kg Kosmetische und/oder pharmazeutische Zubereitungen und deren Verwendung
DE19945578B4 (de) * 1999-09-23 2004-08-19 Cognis Deutschland Gmbh & Co. Kg Kosmetische und/oder pharmazeutische Zubereitungen und deren Verwendung
DE10055303A1 (de) * 2000-11-08 2002-05-23 Cognis Deutschland Gmbh Verwendung von Gemischen
DE102004035633A1 (de) * 2004-07-22 2006-02-09 Cognis Ip Management Gmbh Konditionierende tensidische Zubereitung

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1201411B (it) * 1985-03-26 1989-02-02 Rol Raffineria Olii Lubrifican Tesnioattivi derivati dall'acido citrico
IT1187714B (it) * 1985-07-26 1987-12-23 Rol Raffineria Olii Lubrifican Tenisoattivi derivati da idrossiacidi bicarbossilici
US4759875A (en) * 1986-01-14 1988-07-26 S. C. Johnson & Son, Inc. Oxo-derived mild surfactant blends

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9006105A2 *

Also Published As

Publication number Publication date
DE3839769A1 (de) 1990-05-31
EP0371339B1 (fr) 1993-03-03
WO1990006105A3 (fr) 1990-07-12
ES2053920T3 (es) 1994-08-01
EP0371339A2 (fr) 1990-06-06
DE58903666D1 (de) 1993-04-08
WO1990006105A2 (fr) 1990-06-14
EP0371339A3 (en) 1990-08-01
CA2003517A1 (fr) 1990-05-25
ATE86095T1 (de) 1993-03-15

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