EP0417126A1 - Device for connecting a container to a dispensing head. - Google Patents

Device for connecting a container to a dispensing head.

Info

Publication number
EP0417126A1
EP0417126A1 EP89905453A EP89905453A EP0417126A1 EP 0417126 A1 EP0417126 A1 EP 0417126A1 EP 89905453 A EP89905453 A EP 89905453A EP 89905453 A EP89905453 A EP 89905453A EP 0417126 A1 EP0417126 A1 EP 0417126A1
Authority
EP
European Patent Office
Prior art keywords
concentrate
gas
connector
container
bottle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP89905453A
Other languages
German (de)
French (fr)
Other versions
EP0417126B1 (en
Inventor
Alistair Scott
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Isoworth Ltd
Original Assignee
Isoworth Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB8811604A external-priority patent/GB2218696B/en
Application filed by Isoworth Ltd filed Critical Isoworth Ltd
Publication of EP0417126A1 publication Critical patent/EP0417126A1/en
Application granted granted Critical
Publication of EP0417126B1 publication Critical patent/EP0417126B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67DDISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
    • B67D1/00Apparatus or devices for dispensing beverages on draught
    • B67D1/08Details
    • B67D1/0829Keg connection means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67DDISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
    • B67D1/00Apparatus or devices for dispensing beverages on draught
    • B67D1/0042Details of specific parts of the dispensers
    • B67D1/0078Ingredient cartridges
    • B67D1/0079Ingredient cartridges having their own dispensing means

Definitions

  • This invention relates to carbonation apparatus and to connectors and is particularly concerned with a connector for connecting a bottle of concentrated flavouring to a device, which may form part of a carbonating apparatus, for dispensing the concentrate from the bottle for mixing with carbonated water.
  • a carbonation apparatus having a concentrate dispenser which includes a metering chamber into which concentrate is drawn from a supply bottle by the action of a venturi to which carbon dioxide gas is supplied under pressure when the concentrate is to be dispensed. Gas from the venturi is passed into the concentrate bottle so that any concentrate which becomes entrained in the gas is returned to the concentrate bottle.
  • the connector for attaching the bottle to the concentrate dispenser accordingly includes a passage for receiving a dip tube through which concentrate is supplied to the metering chamber, a passage through which the gas from the venturi may enter the bottle and a passage providing a vent to atmosphere from the interior of the bottle so that the pressurised gas may escape from the bottle.
  • a number of resilient latches are provided on the connector for securing the connector to the dispenser.
  • the present invention aims in one aspect to provide a connector of improved construction.
  • the connector should provide a stable connection i.e. the bottle of concentrate should be held relatively immovably in position.
  • the connector should be such that it can be moulded at low cost from synthetic plastics material.
  • the connector of the above US patent comprises a cylindrical body which is attached (essentially permanently) to the bottle containing concentrate and which has provided therein a structure which defines the above-mentioned passages and includes -a baffle arrangement which prevents the carbon dioxide gas entering the bottle from directly passing to the vent to atmosphere, which would involve the risk that drops of concentrate might be discharged through the vent.
  • Several latches are integral with the cylindrical body.
  • a dip tube and seal are provided which, although not intended to be disposable, are in the absence of a bottle not connected to the dispenser and thus there is risk of loss of these parts.
  • the latches are preferably positioned outwardly of the cylindrical body of the connector but lower than the upper extremity thereof. This not only reduces the height of the connector compared to the arrangement shown in US Patent 4,726,494, in which the latches project above the connector, but also, at least in a preferred form, provides the latches in such a way that they cannot be damaged in transit.
  • the invention provides latch means in the form of a ring surrounding a body portion of the connector, the ring preferably being detachable for removing an empty bottle from the carbonation apparatus.
  • a ring may provide a particularly stable connection.
  • Another aspect of the invention is especially concerned with reducing the cost of the connector by providing a simplified baffle arrangement so that the connector is more easily mouldable.
  • the aforementioned dip tube is substantially permanently - attached to the apparatus.
  • Another aspect of the invention is concerned with facilitating the attachment of a concentrate supply device to a container, such as a bottle, of concentrate.
  • a dip tube is substantially permanently attached to the concentrate dispensing device as just mentioned.
  • One possibility would be to mount the dispensing device and dip tube in such a way that there is sufficient space below the lower extremity of the dip tube for positioning the concentrate container beneath the dip tube and then raising it up to the level required for connecting to the concentrate dispensing device.
  • the carbonation apparatus being unduly bulky.
  • the invention provides, in a further aspect, a concentrate dispensing device which is movable relative to the carbonation apparatus, preferably being detachable therefrom, to facilitate connection of a new bottle of concentrate to the housing.
  • a particularly advantageo ⁇ s embodiment involves the provision on the apparatus of a gas supply socket which is directed horizontally outwardly of the apparatus and is for receiving a cooperating horizontally directed gas receiving nipple of the concentrate supply device, an upwardly directed concentrate receiving socket positioned below the gas supply socket for cooperation with a corresponding downwardly directed concentrate supply nipple of the concentrate supply device, the gas supply nipple being vertically movable for permitting engagement and disengagment of the concentrate supply nipple and concentrate receiving socket whilst the gas supply socket and gas receiving nipple remain engaged.
  • This arrangement permits easy connection and disconnection of the concentrate supply device from the carbonation appartus for replacement of an exhausted concentrate container.
  • Fig. 1 is a diagrammatic representation of a carbonation apparatus in which the invention may be embodied
  • Fig. 2 is a section through part of the apparatus of Fig. 1 showing a connector according to a preferred embodiment of the invention in a position in which it is securing the concentrate bottle to a concentrate dispenser;
  • Fig. 3 is a section showing the parts of Fig. 2 separated from each other;
  • Fig. 4 is a perspective view showing some of the parts illustrated in Fig. 3, also with the parts -separated from each other;
  • Fig. 5 is a partial section showing the concentrate bottle being separated from the dispenser after exhaustion of the supply of concentrate
  • Fig. 6 illustrates part of the connector showing the relationship between the connector and the sealing member
  • Fig. 7 shows the connector in combination with a seal cover and a cap, before use of the bottle
  • Fig. 8 is a perspective view of part of a carbonation apparatus according to a preferred embodiment of the invention.
  • Fig. 9 is a section through part of the apparatus shown in Fig. 8; and Fig. 10 is a section similar to Fig. 9 but showing the parts in a different position.
  • a carbonation apparatus for home use comprises a carbonation chamber 100 preferably of a capacity for forming a single drink at a time, for example about 6 to 16 fluid ounces.
  • a supply of carbon dioxide is contained in a cylinder 102 which is connected to a valve arrangement 104 through which carbon dioxide may be supplied to the chamber 100 for carbonating water therein.
  • the carbonation arrangement is preferably as described in our US Patent No. 4,719,056 and equivalents in other countries.
  • a bottle 104 containing concentrated flavouring is connected, by a connector 106, to a concentrate dispenser 108. Carbon dioxide gas under pressure may be supplied thereto via the valve arrangement 104 and a conduit 110 for actuating the dispenser.
  • a discharge valve 114 at the bottom of the carbonating chamber 100 is manually operable for discharging carbonated water into a drinking vessel, " such as a glass 116 resting on a support 118.
  • a conduit 120 supplies concentrate from the dispenser 108 to the discharge valve 114 for mixing with the carbonated water.
  • the entire apparatus is contained in a suitable housing indicated very diagrammatically at 122 and is designed to be as compact as possible.
  • the concentrate dispenser 108 comprises a housing 122 containing a metering chamber 124 which includes a main portion 124a and an auxiliary portion 124b in communication with each other.
  • a wall 126 defines a compartment 128 which is within the chamber 124 and is in communication with the bottom of the concentrate bottle 104 via a dip tube 130 which passes through the connector 106.
  • a passage 132 is connected to the conduit 110 for receiving gas therefrom and, when the dispenser 108 is operated, this gas passes through a small aperture
  • Concentrate supply conduit 120 is connected to a pipe 142 forming part of a hollow cylindrical member 144 which is detachably connected to a nipple 146 integral with the housing 122.
  • An 0-ring 148 on the outside of the nipple 146 forms a friction fit with the internal surface of member 144.
  • a vertically movable valve 150 (shown in the open position)" includes a seal 152 and, in the absence of the member 144, is urged downwardly by a spring 154 into a closed position in which the seal 152 engages a seat 156.
  • a concentrate discharge opening 162 is provided at the bottom of portion 124b of chamber 124 and, when chamber 124 is empty, is closed by a ball 164.
  • the ball 164 floats upwardly on the concentrate so that the chamber 124 communicates with the nipple 142 via the opening 162, the valve 156 being at this time open.
  • the position of the valve 156 prevents residual concentrate in the chamber 124 from dripping from the dispenser 108 when the dispenser 108 is disconnected from member 144, for example to facilitate attachment of a fresh bottle 104.
  • the floatable ball valve 164 closes immediately the chamber 124 has been emptied, during a drink forming operation, and thus ensures that the conduit 120 remains full of concentrate ready for the next drink forming operation. This facilitates ensuring that the appropriate amount of concentrate is dispensed into each carbonated drink.
  • the connector 106 comprises a cylindrical body 170, a baffle structure 172 at one end of the cylindrical body 170, a skirt 174 at the other end of the cylindrical body 170 and a latching ring 176, all of which are formed as a single unitary moulding of synthetic plastics material.
  • the connector 106 is secured to the bottle 104 by means of a rib 178 formed inside the cylindrical body 170 and a rib 180 formed inside the skirt 174.
  • the neck of the bottle is provided with an annular convex portion 182. near the upper end for engagement by the rib 178 and a flange 184 for engagement by the rib 180.
  • the ribs 178 and 180 are so shaped that the connector can be forced on to the neck of the bottle when attaching the connector to the bottle but cannot easily be removed.
  • Spokes 186 connect the skirt 174 to the cylindrical body 170.
  • the baffle structure 172 comprises inner and outer rings 188,190 and a plurality of baffled plates 192 arranged in radial planes and interconnecting the rings 188 and 190.
  • An inwardly directed flange 194 at the upper end of body 170 supports the outer ring 190 which, in turn, supports the baffles 192 which, again in turn, support the inner ring 188.
  • the axial extent of the baffle plates 192 is equal to that of the outer ring 190.
  • a circular recess 196 is defined by the upper extremity of the inner ring 188 and the inner extremities of the baffle plates 192.
  • the latching ring 176 is connected to the cylindrical body 170 via a tear-off ring 198 and the spokes 186.
  • the ring 198 is provided with a tab 200 which may be gripped between finger and thumb when the ring 198 is to be torn off.
  • a number of inwardly directed projections 202 having downwardly inclined upper surfaces 204 and radial lower surfaces 206 are formed inside the latching ring 176.
  • the dispenser 108 is provided with a downwardly directed cylindrical boss 208 having an axial slot 210 and an outwardly directed projection 212 near its lower end.
  • the projection 212 forms a complete annulus apart from the discontinuity at slot 210.
  • the lower surface 214 of projection 212 is inclined and the upper surface 216 is radial.
  • the cylindrical body 170 of the connector is inserted into the hollow boss 208 which thereby enters the space between cylindrical body 170 and latching ring 176.
  • the afore-described shape of the projections 202 and 214 ensures that projection 202 may slide over projection 214, the boss 208 and ring 176 being sufficiently resilient to accommodate this, until the connector 106 becomes locked to the boss 208 by the interengagement of surfaces 206 and 216.
  • the bottle can thereafter only be removed (other than with exceptional difficulty) by tearing off the strip 198 so that the latching ring 176 becomes separated from the remainder of the connector 106.
  • the detached ring 176 may be easily distorted in shape to enable it to be removed without difficulty from the boss 208.
  • the compartment 128 of dispenser 108 communicates with dip tube 130 via an aperture 220.
  • Four downwardly directed prongs 222 integral with the housing 122 are distributed around the aperture 220 at spaced apart positions and have hooks 224 at their lower ends.
  • a cylindrical collar 226 loosely surrounds the prongs 222 and is provided with four inwardly directed projections 228 which limit the downward movement of the collar 226 relative to the prongs 222, as shown in
  • the collar 226 is secured inside the upper end of the dip tube 130 by ribs 230 and, at its upper end, is provided with an outwardly directed flange 232 the upper surface of which has an annular ridge 234.
  • a solid elastomeric seal 240 is carried by the dispenser 108 underneath the housing 122 and has a central opening 242 in which the prongs 222 are received and an eccentrically positioned nipple 244 having an opening 246 therethrough which tightly receives the lower end of pipe 138 to form a seal therewith. Edge 248 of seal 240 is enlarged.
  • the bottles 104 of concentrate are supplied with a cover which closes the upper end of the connector 106 until the bottle is to be connected to the dispenser 108 for use.
  • a cover which closes the upper end of the connector 106 until the bottle is to be connected to the dispenser 108 for use.
  • Such cover may, for example, comprise an aluminium foil closure adhered to the upper surface of flange 194 and/or the upper surface of ring 190.
  • the flange 232 of sleeve 230 will locate in the recess defined by the upper surface of ring 188 and the inner edges of baffles 192 and will be supported by the upper surface of ring 188.
  • the ridge 234 on flange 232 will be pushed into the elastomeric member 240 in order to form an air-tight seal between the dip tube 130 and the body 122.
  • the enlarged edge portion 248 of the member 240 forms an airtight seal with the portion of the upper surface of flange 194 engaged thereby.
  • baffle plates 192 which engage the under surface of member 240 at the right hand side thereof as seen in the drawings (i.e. in the region of nipple 244), also form a seal with the member 240.
  • gas from the pipe 138 passes through the nipple 244 and one or more of the spaces between baffles 192 at the right hand side of the structure as seen in Fig. 2 and into the bottle 104.
  • Fig. 2 gas from the pipe 138 passes through the nipple 244 and one or more of the spaces between baffles 192 at the right hand side of the structure as seen in Fig. 2 and into the bottle 104.
  • FIG. 6 showing the relationship between the seal 240 and the baffle structure, the spaces between the majority of the baffles 192 vent- the interior of the bottle 104 to atmosphere via the interior of boss 208 and the slot 210 therein. Further, Fig. 6 also shows that gas from the pipe 246 is delivered into the spaces between one or more of the baffles regardless of the rotational position of the connector relative to the pipe 138.
  • the radial baffles 192 ensure that the gas entering the connector 106 from pipe 138 cannot circulate circumferentially and is thus forced to enter the upper portion of the bottle 104 before it can be exhausted to atmosphere for example along the route shown by arrow B in Fig. 2. This ensures that concentrate entrained in the gas entering the connector 106 from the pipe 138 returns to the body of concentrate in the bottle without being ejected from the apparatus.
  • dimension a between surface 206 of projection 202 and the upper surfaces of ring 190 and flange 194 should be properly related to the dimensions of the dispenser.
  • dimension a As shown in Fig. 3, dimension a
  • dimension al should be slightly less than dimension a.
  • Dimension b which is the distance between the upper surfaces of rings 188 and 190 (i.e. the depth of the recess which receives flange 232) is preferably 1.8 mm approximately.
  • the dimension c which is the distance between the upper surface of ring 190 and the upper surface of flange 194 is preferably 0.5mm and is related to the size of the enlargement 248 of member 240.
  • a cover 290 is shown bonded to the top surface of the connector, the bonding preferably being with the surface 190.
  • a cup-shaped cap 292 of resilient synthetic plastics material is also provided and this has a snap-on projection 294 which engages with a cooperating projection 296 on the connector.
  • the cap 302 protects the cover 300, which may be of relatively delicate material such as aluminium foil, from damage in transit and the ability to easily provide such a cap is an advantage of the preferred embodiment of the invention.
  • connector 106 as illustrated in the drawings and described in detail meets all of the requirements set out above.
  • the arrangement of the latch 176 at a position spaced outwardly of but below the upper extremity of the cylindrical body 170 provides for compactness and the structure is connectable and disconnectable, in the manner described, with great ease.
  • the required reliability is provided and low cost is achieved since the structure shown can be easily moulded as a single unit from synthetic plastics material.
  • the provision of the latches 204 on a ring ensures great stability when the concentrate bottle is connected to the carbonation apparatus and this ring cannot accidentally be broken off during to dropping the bottle before use. A simple snap-on connection to the apparatus is achieved.
  • the need to detach ring 176 by tearing off strip 198 in order to remove the used bottle ensures that the bottle cannot be reused and thus substantially eliminates the risk that the carbonating apparatus could be rendered inoperable by using an unsuitable concentrate, for example a concentrate which was too viscous.
  • the housing 122 of the machine which housing is shown only diagrammatically in Fig. 1, includes a main portion 300 containing the carbonation chamber (not shown) and defining a cavity 302 for receiving a glass or other drinking vessel and in the upper portion of which the discharge valve arrangement 114 is located.
  • a comparment 304 is provided on the left-hand side of the housing 122 as seen in Fig. 8 for containing three bottles of concentrate, each containing concentrate of respectively different flavour, labelled 104a, 104b and 104c.
  • the compartment 304 is defined by a base 306, a back wall 308, side walls 310, a removable cover 312 and a low front wall 314. For clarity, the walls 310, cover 312 and front wall 314 are illustrated only in broken lines.
  • the compartment 304 also contains three dispensers 108a, 108b and 108c and each is connected to a respective one of the bottles of concentrate by connector 106a, 106b and 106c respectively, which connectors are secured to the bottles.
  • the carbon dioxide supply cylinder may be provided at the other side of the housing 122.
  • the dispensers 108a, b and c are all detachable from the carbonation apparatus so that the connection between the connector 106 and dispenser 108 may be easily made, and the dip tube 130 inserted into the bottle, whilst the dispenser 108 is detached, thus avoiding the need for providing sufficient space in the compartment 304 for this to take place with the dispenser 108 in situ.
  • Fig. 8 shows dispenser 108a detached from the apparatus and removed from the compartment 304 so that a fresh bottle of concentrate 104a may be fitted.
  • the dispenser 108a is reattached by firstly inserting nipple 133a into hollow cylindrical gas connector housing 316a, as shown in Fig. 9, so that 0-ring 135 forms a substantially gas tight seal. In this way, passage 132 is connected to gas conduit 110.
  • Housing 316a is carried by a slide member 318a which is slidably mounted in a slot 320a in a wall 322 of housing 122 so that the slide 318a may be vertically moved.
  • slide 318a is moved downwardly as shown by the arrow 324 until the position shown in Fig.
  • the apparatus may be operated in the manner previously described in which the required amount of concentrate for a single drink is drawn into the metering chamber 124 by the Venturi effect of gas exiting from the aperture 134 and, upon operation of the valve 114, is supplied from the chamber 124 to the drinking vessel via the conduit 120.
  • the corresponding dispenser 108a When the concentrate in one of the bottles has been exhausted, the corresponding dispenser 108a may be raised from the position shown in Fig. 10 to that shown in Fig. 9, thereby disconnecting the nipple 146 from housing 144, and thereafter the dispenser may be moved horizontally to the left as shown in Figs. 8, 9 and 10 to disconnect the nipple 133 from the housing 216.
  • the exhausted bottle 106 may then be removed by removing tear-off strip 198 from connector 106, the ring 176 then removed from boss 210, and a fresh bottle of concentrate connected to dispenser 108.
  • dispenser 108 has been shown as containing a Venturi pump, other means may be provided for causing the concentrate to move from the bottle to the dispensing chamber. It is particularly preferred, however, that a gas driven pump, preferably a Venturi pump, should be used.

Abstract

A connector for a bottle of concentrate for a carbonating apparatus has a cylindrical body the upper end of which carries a structure defining a number of radially extending baffle and a central opening through which a dip tube may be inserted into the bottle. A latching ring for connecting the connector to the carbonation apparatus is carried by the body at a position outwardly thereof and lower than the baffle structure. The latching ring is constructed to snap on to a corresponding boss on the carbonation apparatus. The bottle is detached from the carbonation apparatus, after exhaustion of the contents, by removal of a tear-off strip which connects the latching ring to the body of the connector. To facilitate connection of a fresh bottle of concentrate to the apparatus, the apparatus includes a housing which is detachable from the remainder of the apparatus and which carries the dip tube and other elements co-operable with the connector for attaching the bottle.

Description

DEVICE FOR CONNECTING A CONTAINER TO A DISPENSING HEAD
This invention relates to carbonation apparatus and to connectors and is particularly concerned with a connector for connecting a bottle of concentrated flavouring to a device, which may form part of a carbonating apparatus, for dispensing the concentrate from the bottle for mixing with carbonated water.
Our US Patent No. 4,726,494 and equivalents thereof in other countries discloses a carbonation apparatus having a concentrate dispenser which includes a metering chamber into which concentrate is drawn from a supply bottle by the action of a venturi to which carbon dioxide gas is supplied under pressure when the concentrate is to be dispensed. Gas from the venturi is passed into the concentrate bottle so that any concentrate which becomes entrained in the gas is returned to the concentrate bottle. The connector for attaching the bottle to the concentrate dispenser accordingly includes a passage for receiving a dip tube through which concentrate is supplied to the metering chamber, a passage through which the gas from the venturi may enter the bottle and a passage providing a vent to atmosphere from the interior of the bottle so that the pressurised gas may escape from the bottle. A number of resilient latches are provided on the connector for securing the connector to the dispenser.
Although the arrangement described in the above US patent functions excellently, the present invention aims in one aspect to provide a connector of improved construction.
Important requirements for the connector are:
a. It must provide a reliable mechanical connection which is such that it does not become disconnected in use and that an adequate seal is provided between the connector and the dispenser so that concentrate is not spilled during use of the apparatus.
b. It must be easy to connect to the dispenser, particularly so that the invention may be ideal for use in the home where young children may be expected to be able to replace the bottle of concentrate after exhaustion of the supply therein. c. For the same reason, the connector should be easily disconnectable.
d. Since home carbonation apparatus should be as compact as possible, the connector must also be compact and minimise the space required.
e. The connector should provide a stable connection i.e. the bottle of concentrate should be held relatively immovably in position.
f. The cost of manufacture should be minimised, for which purpose the connector should be such that it can be moulded at low cost from synthetic plastics material.
g. Ideally, after an empty concentrate bottle has been removed from the apparatus, it should not be reconnectable to the apparatus for reuse. This is to avoid the possibility of the bottle being refilled with unsuitable concentrate which might" adversely affect the operation of the apparatus and for reasons of hygiene. The connector of the above US patent comprises a cylindrical body which is attached (essentially permanently) to the bottle containing concentrate and which has provided therein a structure which defines the above-mentioned passages and includes -a baffle arrangement which prevents the carbon dioxide gas entering the bottle from directly passing to the vent to atmosphere, which would involve the risk that drops of concentrate might be discharged through the vent. Several latches are integral with the cylindrical body. These are attached to the outside of the body and project upwardly beyond the upper extremity of the cylindrical body for engagement in a cooperating groove provided in the dispenser. A dip tube and seal are provided which, although not intended to be disposable, are in the absence of a bottle not connected to the dispenser and thus there is risk of loss of these parts.
One aspect of the invention is especially concerned with providing a more compact and stable arrangement and a preferred feature of the invention for achieving this resides in a novel latch arrangement. In accordance with this feature, the latches are preferably positioned outwardly of the cylindrical body of the connector but lower than the upper extremity thereof. This not only reduces the height of the connector compared to the arrangement shown in US Patent 4,726,494, in which the latches project above the connector, but also, at least in a preferred form, provides the latches in such a way that they cannot be damaged in transit.
In yet a further aspect, the invention provides latch means in the form of a ring surrounding a body portion of the connector, the ring preferably being detachable for removing an empty bottle from the carbonation apparatus. Such a ring may provide a particularly stable connection.
Another aspect of the invention is especially concerned with reducing the cost of the connector by providing a simplified baffle arrangement so that the connector is more easily mouldable.
In accordance with a further aspect, the aforementioned dip tube is substantially permanently - attached to the apparatus.
Another aspect of the invention is concerned with facilitating the attachment of a concentrate supply device to a container, such as a bottle, of concentrate. In practice, difficulties may arise particularly were a dip tube is substantially permanently attached to the concentrate dispensing device as just mentioned. One possibility would be to mount the dispensing device and dip tube in such a way that there is sufficient space below the lower extremity of the dip tube for positioning the concentrate container beneath the dip tube and then raising it up to the level required for connecting to the concentrate dispensing device. However, such an arrangement would result in the carbonation apparatus being unduly bulky. In order to solve this problem, the invention provides, in a further aspect, a concentrate dispensing device which is movable relative to the carbonation apparatus, preferably being detachable therefrom, to facilitate connection of a new bottle of concentrate to the housing. A particularly advantageoμs embodiment involves the provision on the apparatus of a gas supply socket which is directed horizontally outwardly of the apparatus and is for receiving a cooperating horizontally directed gas receiving nipple of the concentrate supply device, an upwardly directed concentrate receiving socket positioned below the gas supply socket for cooperation with a corresponding downwardly directed concentrate supply nipple of the concentrate supply device, the gas supply nipple being vertically movable for permitting engagement and disengagment of the concentrate supply nipple and concentrate receiving socket whilst the gas supply socket and gas receiving nipple remain engaged. This arrangement permits easy connection and disconnection of the concentrate supply device from the carbonation appartus for replacement of an exhausted concentrate container.
The invention is described further by way of example with reference to the accompanying drawings in which:
Fig. 1 is a diagrammatic representation of a carbonation apparatus in which the invention may be embodied;
Fig. 2 is a section through part of the apparatus of Fig. 1 showing a connector according to a preferred embodiment of the invention in a position in which it is securing the concentrate bottle to a concentrate dispenser; Fig. 3 is a section showing the parts of Fig. 2 separated from each other;
Fig. 4 is a perspective view showing some of the parts illustrated in Fig. 3, also with the parts -separated from each other;
Fig. 5 is a partial section showing the concentrate bottle being separated from the dispenser after exhaustion of the supply of concentrate;
Fig. 6 illustrates part of the connector showing the relationship between the connector and the sealing member;
Fig. 7 shows the connector in combination with a seal cover and a cap, before use of the bottle;
Fig. 8 is a perspective view of part of a carbonation apparatus according to a preferred embodiment of the invention;
Fig. 9 is a section through part of the apparatus shown in Fig. 8; and Fig. 10 is a section similar to Fig. 9 but showing the parts in a different position.
With reference to Fig. 1, a carbonation apparatus for home use comprises a carbonation chamber 100 preferably of a capacity for forming a single drink at a time, for example about 6 to 16 fluid ounces. A supply of carbon dioxide is contained in a cylinder 102 which is connected to a valve arrangement 104 through which carbon dioxide may be supplied to the chamber 100 for carbonating water therein. The carbonation arrangement is preferably as described in our US Patent No. 4,719,056 and equivalents in other countries. A bottle 104 containing concentrated flavouring is connected, by a connector 106, to a concentrate dispenser 108. Carbon dioxide gas under pressure may be supplied thereto via the valve arrangement 104 and a conduit 110 for actuating the dispenser. A discharge valve 114 at the bottom of the carbonating chamber 100 is manually operable for discharging carbonated water into a drinking vessel," such as a glass 116 resting on a support 118. A conduit 120 supplies concentrate from the dispenser 108 to the discharge valve 114 for mixing with the carbonated water. The entire apparatus is contained in a suitable housing indicated very diagrammatically at 122 and is designed to be as compact as possible.
With reference to Figs. 2 to 4, the concentrate dispenser 108 comprises a housing 122 containing a metering chamber 124 which includes a main portion 124a and an auxiliary portion 124b in communication with each other. A wall 126 defines a compartment 128 which is within the chamber 124 and is in communication with the bottom of the concentrate bottle 104 via a dip tube 130 which passes through the connector 106.
A passage 132 is connected to the conduit 110 for receiving gas therefrom and, when the dispenser 108 is operated, this gas passes through a small aperture
134, a space 136, a downwardly directed pipe 138 having an enlarged upper end 140 and through the connector 106 into the bottle 104. The gas passes through the aperture 134 at high speed so that the venturi effect reduce pressure in space 136 and therefor in chamber 124 with which space 136 is in communication. The reduced pressure draws concentrate into the chamber 124 via the dip tube 130 and compartment 128. The upper edge of wall 126 defines the maximum level of concentrate in the chamber 124 after termination of the gas supply since any concentrate above this level will be returned to the bottle 104 through the dip tube 130. Further, if the chamber 124 overfills while the gas supply is still continuing, excess concentrate will be returned to the concentrate bottle with the stream of gas through pipe 138. Thus, it may be found, from time to time, that there is some circulation of concentrate between the bottle and chamber 124 and then back into the bottle while the gas supply continues but, nevertheless, after termination of the gas supply, the correct metered amount of concentrate will be left in the chamber 124.
Concentrate supply conduit 120 is connected to a pipe 142 forming part of a hollow cylindrical member 144 which is detachably connected to a nipple 146 integral with the housing 122. An 0-ring 148 on the outside of the nipple 146 forms a friction fit with the internal surface of member 144. A vertically movable valve 150 (shown in the open position)" includes a seal 152 and, in the absence of the member 144, is urged downwardly by a spring 154 into a closed position in which the seal 152 engages a seat 156. Upwardly directed prongs 158 provided inside the member 144 engage a lower portion 160 of the valve 150 so as to raise, and thereby open, the valve when member 144 is connected to nipple 146. A concentrate discharge opening 162 is provided at the bottom of portion 124b of chamber 124 and, when chamber 124 is empty, is closed by a ball 164. When the chamber 124 contains concentrate, the ball 164 floats upwardly on the concentrate so that the chamber 124 communicates with the nipple 142 via the opening 162, the valve 156 being at this time open. The position of the valve 156 prevents residual concentrate in the chamber 124 from dripping from the dispenser 108 when the dispenser 108 is disconnected from member 144, for example to facilitate attachment of a fresh bottle 104. The floatable ball valve 164 closes immediately the chamber 124 has been emptied, during a drink forming operation, and thus ensures that the conduit 120 remains full of concentrate ready for the next drink forming operation. This facilitates ensuring that the appropriate amount of concentrate is dispensed into each carbonated drink.
The connector 106 comprises a cylindrical body 170, a baffle structure 172 at one end of the cylindrical body 170, a skirt 174 at the other end of the cylindrical body 170 and a latching ring 176, all of which are formed as a single unitary moulding of synthetic plastics material. The connector 106 is secured to the bottle 104 by means of a rib 178 formed inside the cylindrical body 170 and a rib 180 formed inside the skirt 174. The neck of the bottle is provided with an annular convex portion 182. near the upper end for engagement by the rib 178 and a flange 184 for engagement by the rib 180. The ribs 178 and 180 are so shaped that the connector can be forced on to the neck of the bottle when attaching the connector to the bottle but cannot easily be removed. Spokes 186 connect the skirt 174 to the cylindrical body 170.
The baffle structure 172 comprises inner and outer rings 188,190 and a plurality of baffled plates 192 arranged in radial planes and interconnecting the rings 188 and 190. An inwardly directed flange 194 at the upper end of body 170 supports the outer ring 190 which, in turn, supports the baffles 192 which, again in turn, support the inner ring 188. The axial extent of the baffle plates 192 is equal to that of the outer ring 190. The lower extremities of the rings 188 and
190 are in the same radial plane but the ring 188 is shorter (in the axial direction) than the ring 190 so that a circular recess 196 is defined by the upper extremity of the inner ring 188 and the inner extremities of the baffle plates 192.
The latching ring 176 is connected to the cylindrical body 170 via a tear-off ring 198 and the spokes 186. The ring 198 is provided with a tab 200 which may be gripped between finger and thumb when the ring 198 is to be torn off. A number of inwardly directed projections 202 having downwardly inclined upper surfaces 204 and radial lower surfaces 206 are formed inside the latching ring 176.
The dispenser 108 is provided with a downwardly directed cylindrical boss 208 having an axial slot 210 and an outwardly directed projection 212 near its lower end. The projection 212 forms a complete annulus apart from the discontinuity at slot 210. The lower surface 214 of projection 212 is inclined and the upper surface 216 is radial.
In order to attach a fresh bottle of concentrate to the dispenser 108, the cylindrical body 170 of the connector is inserted into the hollow boss 208 which thereby enters the space between cylindrical body 170 and latching ring 176. The afore-described shape of the projections 202 and 214 ensures that projection 202 may slide over projection 214, the boss 208 and ring 176 being sufficiently resilient to accommodate this, until the connector 106 becomes locked to the boss 208 by the interengagement of surfaces 206 and 216. The bottle can thereafter only be removed (other than with exceptional difficulty) by tearing off the strip 198 so that the latching ring 176 becomes separated from the remainder of the connector 106. After the connector has been removed from the boss 208, the detached ring 176 may be easily distorted in shape to enable it to be removed without difficulty from the boss 208.
The compartment 128 of dispenser 108 communicates with dip tube 130 via an aperture 220. Four downwardly directed prongs 222 integral with the housing 122 are distributed around the aperture 220 at spaced apart positions and have hooks 224 at their lower ends. A cylindrical collar 226 loosely surrounds the prongs 222 and is provided with four inwardly directed projections 228 which limit the downward movement of the collar 226 relative to the prongs 222, as shown in
Fig. 5, in the absence of the connector 106. The collar 226 is secured inside the upper end of the dip tube 130 by ribs 230 and, at its upper end, is provided with an outwardly directed flange 232 the upper surface of which has an annular ridge 234.
A solid elastomeric seal 240 is carried by the dispenser 108 underneath the housing 122 and has a central opening 242 in which the prongs 222 are received and an eccentrically positioned nipple 244 having an opening 246 therethrough which tightly receives the lower end of pipe 138 to form a seal therewith. Edge 248 of seal 240 is enlarged.
The bottles 104 of concentrate are supplied with a cover which closes the upper end of the connector 106 until the bottle is to be connected to the dispenser 108 for use. Such cover may, for example, comprise an aluminium foil closure adhered to the upper surface of flange 194 and/or the upper surface of ring 190. When the bottle is to be attached to the dispenser, the cover is first removed, and the dip tube 130 is then inserted into the bottle through the ring 188. Initially, the dip tube 130 and collar 230 will be in the position shown in Fig. 5 but, as the body 170 is inserted fully into the boss 208, the flange 232 of sleeve 230 will locate in the recess defined by the upper surface of ring 188 and the inner edges of baffles 192 and will be supported by the upper surface of ring 188. As the connector 106 is pushed fully home and the latching ring 176 engages the projection 214, the ridge 234 on flange 232 will be pushed into the elastomeric member 240 in order to form an air-tight seal between the dip tube 130 and the body 122. Also, the enlarged edge portion 248 of the member 240 forms an airtight seal with the portion of the upper surface of flange 194 engaged thereby. Further, the upper extremities of those baffle plates 192 which engage the under surface of member 240 at the right hand side thereof as seen in the drawings (i.e. in the region of nipple 244), also form a seal with the member 240. Thus, as indicated by arrow A in Fig. 2, gas from the pipe 138 passes through the nipple 244 and one or more of the spaces between baffles 192 at the right hand side of the structure as seen in Fig. 2 and into the bottle 104. As further seen in Fig. 2, and as will be appreciated from consideration of Fig. 6 showing the relationship between the seal 240 and the baffle structure, the spaces between the majority of the baffles 192 vent- the interior of the bottle 104 to atmosphere via the interior of boss 208 and the slot 210 therein. Further, Fig. 6 also shows that gas from the pipe 246 is delivered into the spaces between one or more of the baffles regardless of the rotational position of the connector relative to the pipe 138. By virtue of the cooperation between the seal 240 and the baffles 192, the radial baffles 192 ensure that the gas entering the connector 106 from pipe 138 cannot circulate circumferentially and is thus forced to enter the upper portion of the bottle 104 before it can be exhausted to atmosphere for example along the route shown by arrow B in Fig. 2. This ensures that concentrate entrained in the gas entering the connector 106 from the pipe 138 returns to the body of concentrate in the bottle without being ejected from the apparatus.
In order to ensure that the required seals are created when the connector 106 is attached to the dispenser 108, the dimension a between surface 206 of projection 202 and the upper surfaces of ring 190 and flange 194 should be properly related to the dimensions of the dispenser. Thus, as shown in Fig. 3, dimension a
might be 11- mm and dimension al should be slightly less than dimension a. Dimension b, which is the distance between the upper surfaces of rings 188 and 190 (i.e. the depth of the recess which receives flange 232) is preferably 1.8 mm approximately. The dimension c, which is the distance between the upper surface of ring 190 and the upper surface of flange 194 is preferably 0.5mm and is related to the size of the enlargement 248 of member 240.
When the full concentrate bottle is supplied, it is necessary to provide a cover preventing the liquid being spilled. Thus, in Fig. 7, a cover 290 is shown bonded to the top surface of the connector, the bonding preferably being with the surface 190. Further, a cup-shaped cap 292 of resilient synthetic plastics material is also provided and this has a snap-on projection 294 which engages with a cooperating projection 296 on the connector. The cap 302 protects the cover 300, which may be of relatively delicate material such as aluminium foil, from damage in transit and the ability to easily provide such a cap is an advantage of the preferred embodiment of the invention.
The preferred embodiment of connector 106 as illustrated in the drawings and described in detail meets all of the requirements set out above. Particularly, the arrangement of the latch 176 at a position spaced outwardly of but below the upper extremity of the cylindrical body 170 provides for compactness and the structure is connectable and disconnectable, in the manner described, with great ease. The required reliability is provided and low cost is achieved since the structure shown can be easily moulded as a single unit from synthetic plastics material. The provision of the latches 204 on a ring ensures great stability when the concentrate bottle is connected to the carbonation apparatus and this ring cannot accidentally be broken off during to dropping the bottle before use. A simple snap-on connection to the apparatus is achieved. The need to detach ring 176 by tearing off strip 198 in order to remove the used bottle ensures that the bottle cannot be reused and thus substantially eliminates the risk that the carbonating apparatus could be rendered inoperable by using an unsuitable concentrate, for example a concentrate which was too viscous.
With reference to Fig. 8, the housing 122 of the machine, which housing is shown only diagrammatically in Fig. 1, includes a main portion 300 containing the carbonation chamber (not shown) and defining a cavity 302 for receiving a glass or other drinking vessel and in the upper portion of which the discharge valve arrangement 114 is located. A comparment 304 is provided on the left-hand side of the housing 122 as seen in Fig. 8 for containing three bottles of concentrate, each containing concentrate of respectively different flavour, labelled 104a, 104b and 104c. The compartment 304 is defined by a base 306, a back wall 308, side walls 310, a removable cover 312 and a low front wall 314. For clarity, the walls 310, cover 312 and front wall 314 are illustrated only in broken lines.
The compartment 304 also contains three dispensers 108a, 108b and 108c and each is connected to a respective one of the bottles of concentrate by connector 106a, 106b and 106c respectively, which connectors are secured to the bottles. The bottles
104a, b, c, connectors 106a, b, c and dispensers 108a, b, c are all as described with reference to Figs. 1 to
7, these parts being designated by the same reference numbers with the addition of a, b and c to indicate the different items in Fig. 8. A further compartment
(not shown) for the carbon dioxide supply cylinder may be provided at the other side of the housing 122.
It will be recalled from earlier description that the dip tube 130 remains attached to the dispenser 108a during attachment and detachment of concentrate bottles. In order that the compartment 304 may be made as compact as possible, the dispensers 108a, b and c are all detachable from the carbonation apparatus so that the connection between the connector 106 and dispenser 108 may be easily made, and the dip tube 130 inserted into the bottle, whilst the dispenser 108 is detached, thus avoiding the need for providing sufficient space in the compartment 304 for this to take place with the dispenser 108 in situ. Thus, Fig. 8 shows dispenser 108a detached from the apparatus and removed from the compartment 304 so that a fresh bottle of concentrate 104a may be fitted. After fitting the fresh bottle 104a, the dispenser 108a is reattached by firstly inserting nipple 133a into hollow cylindrical gas connector housing 316a, as shown in Fig. 9, so that 0-ring 135 forms a substantially gas tight seal. In this way, passage 132 is connected to gas conduit 110. Housing 316a is carried by a slide member 318a which is slidably mounted in a slot 320a in a wall 322 of housing 122 so that the slide 318a may be vertically moved. After nipple 133a has been inserted into housing 316a, with the slide 318a in the upper position, slide 318a is moved downwardly as shown by the arrow 324 until the position shown in Fig. 10 is reached in which the nipple 146a is fully inserted into the member 144 so that the valve member 150 is moved to the open position by engagement with the elements 158. In the position shown in Fig. 10, the apparatus may be operated in the manner previously described in which the required amount of concentrate for a single drink is drawn into the metering chamber 124 by the Venturi effect of gas exiting from the aperture 134 and, upon operation of the valve 114, is supplied from the chamber 124 to the drinking vessel via the conduit 120.
When the concentrate in one of the bottles has been exhausted, the corresponding dispenser 108a may be raised from the position shown in Fig. 10 to that shown in Fig. 9, thereby disconnecting the nipple 146 from housing 144, and thereafter the dispenser may be moved horizontally to the left as shown in Figs. 8, 9 and 10 to disconnect the nipple 133 from the housing 216. The exhausted bottle 106 may then be removed by removing tear-off strip 198 from connector 106, the ring 176 then removed from boss 210, and a fresh bottle of concentrate connected to dispenser 108.
Various modifications are possible within the scope of the invention. For example, although the dispenser 108 has been shown as containing a Venturi pump, other means may be provided for causing the concentrate to move from the bottle to the dispensing chamber. It is particularly preferred, however, that a gas driven pump, preferably a Venturi pump, should be used.

Claims

CLAIMS :
1. A connector for connecting a container of concentrate to a concentrate dispenser of a carbonation apparatus, comprising: a body connected or adapted to be connected to the upper end of a bottle; and latching means carried by said body and disposed below said upper end thereof and spaced outwardly of said body.
2. The connector according to claim 1, wherein said latching means is provided with inwardly directed projections.
3. A connector according to claim 2, wherein said latching means comprises a latching ring on which said projections are formed.
4. A connector according to claim 3, wherein said latching ring is connected to said body through a tear-off strip.
5. A connector according to any of claims 1 to 4, including structure carried by said body adjacent the upper end thereof and defining a central opening through which a dip tube may be inserted into said container.
6. Apparatus according to claim 5, wherein said structure comprises an inner ring defining said opening for said dip tube, an outer ring connected to said body and baffle means interconnecting said inner and outer rings and defining passageways through which gas may pass into and out of the container.
7. A connector according to claim 6, wherein said baffle means comprises baffle plates in axially extending radial planes.
8. A connector according to claim 7, wherein said structure is such that gas may pass therethrough by movement axially thereof without deflection whilst within said structure.
9. A concentrate supply device for connection to a connector according to any of claims 1 to 8 for supplying concentrate from a said container thereof to a carbonation apparatus, comprising a housing, and opening in the bottom of said housing for permitting concentrate to enter said housing from said container thereof, outwardly directed catch means attached to said housing and positioned outwardly of said opening and spaced below said housing so that, when said connector is connected thereto, said catch means may be located between said body and said latching means of said connector for cooperation with said latching means, and means for discharging concentrate from said housing to said carbonation appparatus.
10. A device according to claim 9, including a metering chamber for metering the amount of concentrate dispensed.
11. A device according to claim 10, including gas operated means for transferring concentrate from said container to said metering chamber.
12. A device according to claim 11, wherein said gas operated means comprises a venturi adapted to receive gas under pressure from said carbonation apparatus and arranged to draw concentrate from said container into said housing.
13. A device according to claim 12, including passage means for supplying gas from said venturi to said connector.
14. A device for supplying concentrate from a container thereof to carbonation apparatus for forming flavoured carbonated drinks, comprising gas receiving means for receiving gas under pressure for operating said device, and concentrate discharge means for discharging concentrate from said device, said gas receiving means comprising a first nipple which is arranged in use to extend generally horizontally for connection to a generally horizontally directed gas supply socket of said apparatus, and said concentrate discharge means comprising a second nipple which is arranged in use to be disposed below said first nipple and to extend generally vertically downwards for connection to an upwardly opening concentrate receiving socket of said apparatus.
15. A device according to claim 14, including a metering chamber for metering the amount of concentrate dispensed.
16. A device according to claim 14 or 15, including a venturi in communication with said first nipple for creating reduced pressure in said device for drawing concentrate from said container to said device.
17. A device according to claim 16, including a gas discharge passage for supplying gas from said venturi into a container of concentrate connected to said connecting means.
18. A device according to claim 17, wherein said venturi and said gas discharge passage are arranged so that excess concentrate supplied to said device may be returned to said container with said gas from said venturi.
19. A device according to any of claims 14 to 18, including a dip tube for insertion into the container of concentrate for the transfer of concentrate from the container to the device.
20. A device according to any of claims 14 to 19 wherein said nipples are rigidly mounted on said device.
21. Carbonation apparatus for use with a device according to any of claims 14 to 20, including a- carbonation chamber for containing water to be carbonated, carbon dioxide supply means for supplying carbon dioxide to said chamber for carbonating said water, discharge means for discharging said carbonated water, a gas supply socket directed substantially horizontally and outwardly of said apparatus and mounted for substantially vertical movement, and a substantially vertically upwardly directed concentrate receiving socket positioned below said gas supply socket, said sockets being for receiving said respective nipples of said concentrate supply device so that gas under pressure may be supplied thereto through said gas supply socket and concentrate may be received therefrom through said concentrate receiving socket for mixing with said carbonated water.
EP89905453A 1988-05-17 1989-05-05 Device for connecting a container to a dispensing head Expired - Lifetime EP0417126B1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB8811604A GB2218696B (en) 1988-05-17 1988-05-17 Concentrate bottle connector
GB8811604 1988-05-17
GB8816477A GB2218688B (en) 1988-05-17 1988-07-11 Carbonation apparatus
GB8816477 1988-07-11
PCT/GB1989/000487 WO1989011444A2 (en) 1988-05-17 1989-05-05 Device for connecting a container to a dispensing head

Publications (2)

Publication Number Publication Date
EP0417126A1 true EP0417126A1 (en) 1991-03-20
EP0417126B1 EP0417126B1 (en) 1995-01-11

Family

ID=26293895

Family Applications (1)

Application Number Title Priority Date Filing Date
EP89905453A Expired - Lifetime EP0417126B1 (en) 1988-05-17 1989-05-05 Device for connecting a container to a dispensing head

Country Status (12)

Country Link
EP (1) EP0417126B1 (en)
JP (1) JPH03504226A (en)
CN (1) CN1038996A (en)
AT (1) ATE116948T1 (en)
AU (1) AU3550389A (en)
BR (1) BR8907435A (en)
DE (1) DE68920579T2 (en)
DK (1) DK272890A (en)
ES (1) ES2014111A6 (en)
IL (1) IL90205A0 (en)
MX (1) MX171039B (en)
WO (1) WO1989011444A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2343108C1 (en) * 2004-09-13 2009-01-10 Микро Матик А/С Distributive line of system for drink distribution
EP1764148A1 (en) * 2005-09-14 2007-03-21 Jäger, Urs Device for making mixed beverages, and pressurized container therefore
NL2017109B1 (en) 2016-07-05 2018-01-12 Heineken Supply Chain Bv Beverage dispensing assembly and beverage container
NL2017940B1 (en) * 2016-12-06 2018-06-19 Apiqe Holdings Llc Water dispensers for dispensing carbonized water
NL2018956B1 (en) 2017-05-19 2018-11-28 Heineken Supply Chain Bv Beverage dispensing assembly and beverage container
NL2018955B1 (en) 2017-05-19 2018-11-28 Heineken Supply Chain Bv Beverage dispensing assembly and beverage container

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0080261A3 (en) * 1981-10-09 1984-07-25 Cadbury Schweppes Limited Liquid dispensing package and valve
FR2534557A3 (en) * 1982-10-15 1984-04-20 Astra Plastique Stopping device for pressurised containers
GB2186265B (en) * 1986-02-10 1989-11-01 Isoworth Ltd Beverage dispensing apparatus

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO8911444A3 *

Also Published As

Publication number Publication date
JPH03504226A (en) 1991-09-19
CN1038996A (en) 1990-01-24
ATE116948T1 (en) 1995-01-15
DK272890D0 (en) 1990-11-15
IL90205A0 (en) 1989-12-15
MX171039B (en) 1993-09-27
DE68920579D1 (en) 1995-02-23
DK272890A (en) 1990-11-15
WO1989011444A2 (en) 1989-11-30
WO1989011444A3 (en) 1989-12-28
DE68920579T2 (en) 1995-09-14
BR8907435A (en) 1991-04-02
ES2014111A6 (en) 1990-06-16
EP0417126B1 (en) 1995-01-11
AU3550389A (en) 1989-12-12

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