EP0409954A4 - Magnetic field transfer device and method - Google Patents
Magnetic field transfer device and methodInfo
- Publication number
- EP0409954A4 EP0409954A4 EP19900902908 EP90902908A EP0409954A4 EP 0409954 A4 EP0409954 A4 EP 0409954A4 EP 19900902908 EP19900902908 EP 19900902908 EP 90902908 A EP90902908 A EP 90902908A EP 0409954 A4 EP0409954 A4 EP 0409954A4
- Authority
- EP
- European Patent Office
- Prior art keywords
- coil
- magnetic field
- coils
- axis
- transfer device
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F6/00—Superconducting magnets; Superconducting coils
- H01F6/005—Methods and means for increasing the stored energy in superconductive coils by increments (flux pumps)
Definitions
- This invention pertains generally to apparatus and methods for producing magnetic fields, and particularly to the manner in which a magnetic field can be transferred between volumes.
- Magnetic field transfer devices may be utilized in inductive energy storage systems and in magnetic refrigeration devices.
- Capacitors often are connected in parallel with magnetic coils for use as a transfer element during inductive transfer between the coils.
- a transfer element generally is required to accomodate about half the initial energy of the first coil in a complementary form during the transfer, in accord with the principle of least action.
- the initial energy is stored in the magnetic field of the coil and the complementary energy is stored in the electric field of the capacitor.
- Capacitors are quite limited in the amount of energy which they are able to store, and therefore may not be suitable for use as a transfer element in many applications.
- a second system described achieves magnetic field transfer by the rotation of a shorted inductance coil magnetically coupled to a coupling coil which is part of a load circuit with at least one other coil. From the initial state of maximum coupling the movable shorted inductance coil is rotated and thus its coupling is reduced. The reduction of the coupling causes a transfer of energy from one coil to the other coil of the load circuit and subjects the rotating coil to an accelerating torque. When the coupling is zero the kinetic energy of the rotating coil is at its maximum; further rotation increases the coupling in the negative direction, decelerating the rotating coil. The transfer is completed and the rotating coil comes to- rest when the coupling is again at maximum but in the opposite direction.
- a magnetic field transfer device in accordance with the present invention includes a pair of inner coils which comprise two equal coplanar inner loops electrically connected together so that any current which moves in one rotational direction around one inner loop moves in the opposite rotational direction around the other inner loop, and an outer coil which is comprised of an outer loop which is outwardly positioned from the inner coils and rotatable in relation to the two inner loops between two positions 180° apart in which the outer loop is coplanar with the inner loops.
- the inner and outer coils may be superconducting.
- the two inner loops conduct current in opposite directions, substantially no current is induced in the inner loops by any external magnetic field in which the inner loops lie, which has equal magnetic fluxes linked with both of the inner loops.
- the outer loop is rotated 180° from its first coplanar position to its second coplanar position, the magnetic field which is located within one inner loop is transferred to the other inner loop and reoriented 180°.
- a second magnetic field transfer device of the invention includes a pair of oppositely wound inner solenoidal coils and an outer solenoidal coil which is outwardly positioned from the two inner coils and rotatable relative to the inner coils.
- Each inner coil preferably includes superconducting windings around an inner coil axis.
- the two inner coil axes are parallel and laterally spaced from each other so that the inner coils are positioned in side-by-side relation.
- Each inner coil may form an inner cylinder which is D-shaped in cross-section and which has an inner cylindrical axis perpendicular to the inner coil axis.
- the coil axis is a straight line at the center of and parallel to the magnetic field of the coil.
- each inner coil includes a straight central wall formed of the windings through which current can flow in a first direction parallel to the inner cylindrical axis, and a curved outer wall through which current can flow in an opposite direction parallel to the inner cylindrical axis.
- the windings in the central wall and outer wall of each inner cylinder are joined together at the ends of each inner cylinder so that the windings forming each inner cylinder are continuous.
- the straight inner walls of the two inner cylinders are adjacent to each other so that a circular outer surface is formed by the two curved outer walls of the inner cylinders.
- the outer solenoidal coil preferably includes superconducting windings around the outer coil axis and forms an outer cylinder with an outer cylindrical axis perpendicular to the outer coil axis.
- the outer coil is rotatable about the two inner coils around a rotational axis which is substantially perpendicular to the inner and outer coil axes.
- the outer cylinder includes two substantially semi-cylindrical walls. Current can flow through the first semi-cylindrical walls in a first direction parallel to the outer cylindrical axis, and through the second semi-cylindrical wall in an opposite direction parallel to the outer cylindrical axis.
- the windings in the two semi-cylindrical walls are joined together at the ends of the outer cylinder so that the windings forming the outer cylinder are continuous.
- the magnetic field of the outer coil augments the magnetic field of one of the inner coils and diminishes the other.
- one magnetic field is doubled in strength, while the other is diminished to zero.
- the outer coil then is rotated 180° around the inner coils, the augmented magnetic field is transferred from the one inner coil to the other inner coil and reoriented 180°.
- a third magnetic field transfer device of the invention is similar to the second device, except that the inner coils each form an inner cylinder with a circular instead of D-shaped cross-section.
- the magnetic field transfer devices are capable of transferring magnetic fields between volumes which are very close to each other. With these devices, the magnetic field transfer can be accomplished with negligible energy losses, and with reversibility. Generally, the back electromotive force (EMF) within the coils during operation is substantially zero, so that the work required to turn the outer coil is negligible.
- the volumes which contain the magnetic fields may take substantially any shape, and the coils may be arranged to accomodate a magnetic field of any direction.
- Fig. 1 shows a first magnetic field transfer device in accord with the invention.
- Fig. 2 shows the manner in which the two inner loops and the single outer loop of the first magnetic field transfer device are combined.
- Fig. 3 shows the first magnetic field transfer device after the outer loop has been rotated 180° from the position shown in Fig. 2, such that the augmented magnetic field has been transferred from the left inner loop to the right inner loop and is reoriented 180°.
- Fig. 4 shows a schematic cross-sectional perspective view of a second magnetic field transfer device of the invention, wherein the cross-section is taken through the center of the device along the coil axes of the inner and outer coils.
- Fig. 5 is an illustrative view showing a plane current sheet and a hollow tube superimposed on each other to illustrate the functioned principles of the inner coils of the device of Fig. 4.
- Fig. 6 shows a schematic cross-sectional view of an exemplary structure for the two inner coils of the second magnetic field transfer device.
- Fig. 7 shows a cross-sectional view of a preferred implementation of the second magnetic field transfer device.
- Fig. 13 shows a graph of the magnetic field strengths in the left and right inner coils of the second magnetic field transfer device as a function of the angle ⁇ .
- Fig. 14 shows a perspective view of a third magnetic field transfer device of the invention.
- Fig. 15 shows a cross-sectional view of the third magnetic field transfer device taken along the section line 15-15 of Fig. 14.
- Fig. 16 is a perspective view of a fourth magnetic field transfer device of the invention.
- Figs. 1-3 show a first magnetic field transfer device 10 which is fairly simple in structure and yet may be used to transfer a magnetic field from one volume to another volume. Although the fields within the loops of this device are not nearly uniform, this simple embodiment is useful in illustrating the principles of the invention.
- the first device 10 includes two rectangular coplanar inner loops 11 and 12 which are dimensioned identically, and an outer loop 13 which is dimensionally large enough to encircle the two inner loops 11 and 12.
- Each inner loop 11 or 12 acts as an inner solenoidal coil of one (e.g., superconducting) winding (or a compact group of windings) around an inner coil axis 14 or 15.
- the two axes 14 and 15 of the loops 11 and 12 are parallel and laterally spaced from each other so that the loops 11 and 12 are positioned in side-by-side relation.
- the inner loops 11 and 12 are electrically connected together so that any current which moves around one of the inner loops 11 or 12 moves in an opposite rotational direction around the other inner loop 11 or 12.
- the two inner loops 11 and 12 are wound oppositely about their axes 14 and 15. 0/09095
- the outer loop 13 acts as an outer solenoidal coil of one superconducting winding (or a compact group of windings) around the outer coil axis 16.
- a change in current within the loops 11 and 12 will occur if there are different magnetic fluxes through the loops 11 and 12. Normally this will not occur.
- the magnetic fields (each B ⁇ ) through the loops 11 and 12 are directed oppositely through the inner loops 11 and 12.
- Fig. 2 shows the magnetic field B in the left inner loop 11 directed downwardly into the page, and the magnetic field B in the right inner loop 12 directed upwardly from the page.
- Each of these two oppositely directed magnetic fields cause the flux linked with the individual inner loops 11 and 12 to be ⁇ _.
- the flux linked with the two inner loops 11 and 12 is:
- An external field can be produced by a current I in the outer loop alone as shown in Fig. 2. Again, the field strength is B, and since the area which the outer loop 13 forms is about twice as large as a single inner loop 11 or 12, the flux linked with the outer loop 13 is substantially 2 ⁇ . As shown in Fig. 2, if the two inner loops 11 and 12 and the outer loop 13 are superimposed on each other, the magnetic field in the outer loop 13 doubles the magnetic field strength in the left inner loop 11 and diminishes the magnetic field strength in the right inner loop 12 to substantially zero.
- the superposition or addition of the external field created by the outer loop 13 over the two inner loops 11 and 12 does not change the current I in those inner loops 11 and 12.
- the flux linked with the inner double loop (two inner loops 11 and 12 together) and with the outer loop 13, remains unchanged at 2 ⁇ _.
- the field in the left inner loop 11 is then zero and the field in the right inner loop 12 is 2 B , a field which projects out of the page in Fig. 3.
- the augmented magnetic field is transferred from the left inner loop 11 to the right inner loop 12 when the outer loop 13 is rotated 180°. Additionally, the augmented magnetic field is reoriented 180°. Initially, as shown in Fig.
- the augmented magnetic field projects directly into the page within the left inner loop 11, while the magnetic field in the right inner loop 12 is cancelled.
- the augmented magnetic field is transferred from the left inner loop 11 to the right inner loop 12 as the outer loop 13 rotates 180°, and a converse transfer occurs upon another 180° rotation.
- Rotation around any other axis of symmetry has the same effect, for example, about the axis y-y of Fig. 3.
- the diagonals would also be possible axis of rotation.
- the magnetic field transfer device 10 is a simple device which is particularly effective in demonstrating the principle by which the present invention moves a magnetic field from one volume or location to another and back, with very little work being required. The process is reversible, and any energy loss is small since the back EMF and local eddy currents within the loops are kept to a minimum. Additionally, the first device 10 demonstrates that the volumes in which the process is carried on can be very close to each other. The particular direction of the field, and the shape of the volumes are not critical.
- a second magnetic field transfer device 20 is shown schematically in Fig. 4.
- the second device 20 is a preferred embodiment which can be adapted for use with magnetic refrigeration apparatuses to transfer reversibly a magnetic field from one volume to another.
- the second magnetic field transfer device includes an outer solenoidal coil 21 of circular cross-section which substantially encloses two oppositely wound inner solenoidal coils 22 and 23 which each have D-shaped cross-sections.
- the outer solenoidal coil 21 is a dipole coil formed with preferably superconducting windings 24 (individual turns not shown for clarity of illustration) generally around an outer coil axis 26 between radii r Q and r.
- the outer coil 21 is wrapped to form an outer cylinder with an outer cylindrical axis 28 which runs perpendicular to the outer coil axis 26.
- the windings 24 are wound to run substantially in two opposite directions parallel to the outer cylindrical axis 28 to form two substantially semicylindrical walls 29 as shown in Fig. 4.
- the windings 24 in the outer coil 21 are wound so that in the left semicylindrical wall 29 the current flows in a first direction parallel to the outer cylindrical axis 28, while in the right semi-cylindrical wall 29 the current flows in an opposite direction also parallel to the outer cylindrical axis 28.
- the windings 24 of the two semicylindrical walls 29 are joined together at the ends of the outer cylinder so that the windings forming the outer coil 21 are continuous. If current flows through the outer coil 21 parallel to the outer cylindrical axis 28 in both directions with a current distribution proportional to j cos ⁇ (where ⁇ is the angle from the origin as shown in Fig. 4), then the outer coil 21 produces a uniform and vertical magnetic field
- Each inner coil 22 or 23 is formed with superconducting windings 25 around the inner coil axis at 31 or 32 between radii r. and r.
- the two inner coil axes 31 and 32 are parallel and laterally spaced from each other so that the inner coils 22 and 23 are positioned in side-by-side relationship.
- Each inner coil 22 or 23 is wound to form an inner cylinder with an inner cylindrical axis 34 or 35 perpendicular to the inner coil axis 31 or
- Each inner cylinder includes a straight central wall
- the magnetic fields formed by each of the two inner coils 22 and 23 alone are Ba and B.b, respectively, and the field formed by the outer coil 21 is B .
- the outer cylindrical axis 28 forms a rotational axis for the outer coil 21.
- FIG. 5 A plane current sheet 45 of thickness 2d, with current density j_ is shown in the upper left of Fig. 5.
- a hollow tube of inner radius r. with electrical current flowing in a direction upwardly (out of the page) will produce zero magnetic field inside the hollow tube 46.
- the plane current sheet 45 and the hollow tube 46 are superimposed on each other to form two D-shape volumes 47 with equal and opposite uniform fields.
- the hollow tube 46 carries the return current of a section of the plane sheet 45, and the thickness of the hollow tube 46 is adjusted accordingly.
- the plane sheet 45 cannot extend upwardly and downwardly to infinity.
- the plane sheet 45 is cut off preferably at the outer radius of the hollow tube 46, so that the entire arrangement can fit into the outer coil 21.
- the field distorting effect of cutting the plane sheet 45 can be alleviated by thickening the edges as shown schematically at 48 in Fig. 6. As shown in Fig.
- the planar sheet 45 actually becomes the two straight central walls 37 and 38.
- a theoretically exact winding cross-section can be determined.
- the width of the edges 48 will be determined by a compromise between the level of tolerance of deviations from field uniformity and the desired simplicity of coil construction.
- Fig. 7 illustrates a full-sized winding cross-section of the second magnetic field transfer device 20.
- Such a device 20 will have a stored energy 3 (14.32 MJ/m ) of 20 kJ.
- the outer coil 21 semicylindrical walls 29 are each tapered as they approach the outer coil axis 26. This allows the current to be distributed throughout the outer coil 21 in proportion to cos ⁇ , as stated earlier.
- the angle ⁇ is an angle formed between any point on the semicylindrical walls 29 and a midpoint 50 of the semicylindrical wall 29, with respect to the outer cylindrical axis 28.
- the torque on the outer coil 21 during rotation will be about zero.
- the energy of a coil system consisting of two hypothetical coils I and II is
- each coil 21, 22, and 23 there are static forces operating on the structure of each coil 21, 22, and 23.
- the winding structure forming the straight central walls 37 and 38 and the curved outer walls 42 and 43 must be strong enough to contain these forces. Any unbalanced forces between the coils 21, 22 and 23 will be transmitted by conventional rotation bearings which support the rotating outer coil 21.
- Figures 8-12 show schematically the magnetic fields in the left inner coil 22 (the field designated generally by the numeral 54) and in the right inner coil 23 (designated generally by the numeral 55), and the static forces which operate upon the straight central walls 37 and 38, curved outer walls 42 and 43, and the semi-cylindrical walls 29 of the outer coil 21.
- Figure 13 shows the field strength in Teslas (T) for the magnetic field 54 (B ) in the left inner coil 22 and the magnetic field 55 (B.) in the right inner coil 23 for the structure of Fig. 7 with the foregoing exemplary dimensions.
- the magnetic field 55 in the right inner coil 23 is equal to
- the flux return structure iron
- the fields thereby created should be less than 1 Tesla and therefore will produce bearing forces of not more than about 10 kN.
- the second magnetic field transfer device 20 transfers a magnetic field from the inside of one inner coil to the inside of the other inner coil in a reversible process with substantially no back EMF and no torque during rotation of the outer coil 21.
- a transfer of the magnetic field from the left inner coil 22 to the right inner coil 23 is demonstrated in Figs. 8-12.
- the coils 21, 22 and 23 are connected to a source of electric current which flows through the coils as shown.
- the superconducting coil may be put into a persistent mode (that is, the beginning and end of the winding are superconductively connected to each other) .
- the required current is such that the minimum field in the coil 22 or 23 is zero.
- the magnetic field 54 in the left inner coil 22 begins to weaken, and also rotates at half the angular velocity of the outer coil 21.
- the magnetic field 54 in the left inner coil 22 will have rotated ⁇ 2 degrees as shown in Fig. 9.
- the two fields 54 and 55 are equal and at 45° angles to the plane of the straight central walls 37 and 38.
- the angle ⁇ 180°, the left magnetic field 54 diminishes to 0, and the right magnetic field 55 increases to full strength.
- a third magnetic field transfer device 70 of the invention is shown in Figs. 14 and 15.
- the device 70 is similar to the second magnetic field transfer device 20 except that its two inner coils 71 and 72 each have a circular cross-section instead of a D-shaped cross-section. Additionally, since the inner coils 71 and 72 each have a circular cross-section instead of a D-shaped cross-section. Additionally, since the inner coils 71 and
- the outer coil 73 which also is circular in cross-section, does not follow the contour of the two inner coils 71 and 72. Instead, the outer coil 73 is spaced outwardly from the inner coils 71 and 72 at varying distances with respect to the two inner coils 71 and 72.
- the superconducting windings 86 and 87 are wound around the inner coil axis 75 or 76 to form inner cylinders 71 and 72 which have cylindrical axes 78 and
- the outer coil 73 is comprised of superconducing windings 85 around the outer coil axis 81 to form an outer cylinder 73 with an outer cylindrical axis 82 about which the outer cylinder 73 rotates.
- an augmented magnetic field 84 is formed in the left inner coil 71, while the field in the right inner coil 72 is cancelled.
- the outer coil 73 is rotated 180°, the augmented magnetic field is transferred to the right inner coil 72 and reoriented 180°.
- the device 70 therefore operates in a manner similar to the second device 20.
- a fourth magnetic field transfer device, somewhat similar in construction to the device 70 is shown generally at 90 in Fig. 16.
- the device 90 has an outer coil 91, which may be formed identically to the outer coil
- the inner coils 92 and 93 may be formed in an identical manner as the outer coil 91, having equal radius, and lying longitudinally adjacent are another within the outer cylinder.
- the inner coils are connected together to conduct current in the same manner as the two inner coils 11 and 12 of the device 10 of Fig. 1.
- Rotation of the outer coil 91 around its cylindrical axis 95 by 180° transfers flux from the volume within one of the coils 92 and 93 to the other, in a manner analogous to rotation of the outer coil 13 about the axis ' y-y as shown in Fig. 3 which transfers flux between the two inner coils
- the magnetic field transfer devices 10, 20, 70 and 90 allow a magnetic field to be transferred between two volumes which are very close to each other, through a process which is reversible and substantially lossless. This process is accomplished with a minimum amount of work since the torque opposing the rotation of the outer coil can be made very small.
- the inner coils 12 of the first device 10 are rectangular in shape
- the inner coils 22 and 23 of the second device 20 are cylinders with D-shaped cross-section
- the inner coils 71 and 72 of the third device 70 and inner coils 92 and 93 of the device 90 are cylinders of circular cross-section
- the particular shape of the volumes between which the magnetic field is transferred is not crucial.
- the inner coils and outer coils may be configured to transfer a field which runs in almost any direction.
- the rotational axes 18, 28 and 82 of the outer coils 13, 21, and 73 are positioned between the inner coils and substantially parallel thereto, these rotational axes could be placed in some other position such that they are perpendicular to the inner coil axes 14, 15, 31, 32, 75 and 76. It is understood that the invention is not confined to the particular embodiments herein illustrated and described but embraces such modified forms thereof as come within the scope of the following claims.
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Magnetic Resonance Imaging Apparatus (AREA)
- Particle Accelerators (AREA)
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT90902908T ATE93988T1 (en) | 1989-02-06 | 1990-02-01 | MAGNETIC FIELD TRANSMISSION ARRANGEMENT AND METHOD. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/307,365 US4901047A (en) | 1989-02-06 | 1989-02-06 | Magnetic field transfer device and method |
US307365 | 1994-09-16 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0409954A1 EP0409954A1 (en) | 1991-01-30 |
EP0409954A4 true EP0409954A4 (en) | 1991-07-24 |
EP0409954B1 EP0409954B1 (en) | 1993-09-01 |
Family
ID=23189434
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90902908A Expired - Lifetime EP0409954B1 (en) | 1989-02-06 | 1990-02-01 | Magnetic field transfer device and method |
Country Status (6)
Country | Link |
---|---|
US (1) | US4901047A (en) |
EP (1) | EP0409954B1 (en) |
JP (1) | JP2732944B2 (en) |
CA (1) | CA2009342C (en) |
DE (1) | DE69003046T2 (en) |
WO (1) | WO1990009095A2 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5182914A (en) * | 1990-03-14 | 1993-02-02 | Astronautics Corporation Of America | Rotary dipole active magnetic regenerative refrigerator |
US5473301A (en) * | 1994-09-12 | 1995-12-05 | Westinghouse Electric Corporation | Energy storage inductor apparatus |
JPH10321430A (en) * | 1997-05-23 | 1998-12-04 | Mitsubishi Electric Corp | Superconductive electromagnet device |
US5920151A (en) * | 1997-05-30 | 1999-07-06 | Candescent Technologies Corporation | Structure and fabrication of electron-emitting device having focus coating contacted through underlying access conductor |
AU2002360563A1 (en) | 2001-12-12 | 2003-06-23 | Astronautics Corporation Of America | Rotating magnet magnetic refrigerator |
US7038565B1 (en) | 2003-06-09 | 2006-05-02 | Astronautics Corporation Of America | Rotating dipole permanent magnet assembly |
US6946941B2 (en) * | 2003-08-29 | 2005-09-20 | Astronautics Corporation Of America | Permanent magnet assembly |
WO2005074608A2 (en) * | 2004-02-03 | 2005-08-18 | Astronautics Corporation Of America | Permanent magnet assembly |
US9995511B2 (en) | 2013-12-17 | 2018-06-12 | Astronautics Corporation Of America | Magnetic refrigeration system with improved flow efficiency |
JP7170337B2 (en) * | 2020-10-22 | 2022-11-14 | 大学共同利用機関法人自然科学研究機構 | Variable magnetic field generation system and static magnetic refrigeration system using the same |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1280440B (en) * | 1963-12-24 | 1968-10-17 | Siemens Ag | Device for generating magnetic pulses of high power |
GB1113854A (en) * | 1965-06-23 | 1968-05-15 | Gen Electric Co Ltd | Improvements in or relating to superconducting magnets |
FR1517759A (en) * | 1966-09-07 | 1968-03-22 | Commissariat Energie Atomique | Method for transferring energy to a conductive medium and apparatus for carrying out this method |
US3602854A (en) * | 1968-11-04 | 1971-08-31 | Hitachi Ltd | Flux pump |
US4190817A (en) * | 1977-02-09 | 1980-02-26 | Mario Rabinowitz | Persistent current superconducting method and apparatus |
-
1989
- 1989-02-06 US US07/307,365 patent/US4901047A/en not_active Expired - Lifetime
-
1990
- 1990-02-01 DE DE90902908T patent/DE69003046T2/en not_active Expired - Fee Related
- 1990-02-01 EP EP90902908A patent/EP0409954B1/en not_active Expired - Lifetime
- 1990-02-01 WO PCT/US1990/000645 patent/WO1990009095A2/en active IP Right Grant
- 1990-02-01 JP JP2503137A patent/JP2732944B2/en not_active Expired - Fee Related
- 1990-02-05 CA CA002009342A patent/CA2009342C/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See references of WO9009095A3 * |
Also Published As
Publication number | Publication date |
---|---|
DE69003046D1 (en) | 1993-10-07 |
EP0409954A1 (en) | 1991-01-30 |
WO1990009095A2 (en) | 1990-08-23 |
JPH03505027A (en) | 1991-10-31 |
EP0409954B1 (en) | 1993-09-01 |
US4901047A (en) | 1990-02-13 |
JP2732944B2 (en) | 1998-03-30 |
CA2009342A1 (en) | 1990-08-06 |
CA2009342C (en) | 1998-04-07 |
DE69003046T2 (en) | 1993-12-16 |
WO1990009095A3 (en) | 1990-11-01 |
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