EP0332026B1 - Tootbrush with slow release of disinfectant and anti-bacterial agents and method of manufacturing the same - Google Patents
Tootbrush with slow release of disinfectant and anti-bacterial agents and method of manufacturing the same Download PDFInfo
- Publication number
- EP0332026B1 EP0332026B1 EP89103503A EP89103503A EP0332026B1 EP 0332026 B1 EP0332026 B1 EP 0332026B1 EP 89103503 A EP89103503 A EP 89103503A EP 89103503 A EP89103503 A EP 89103503A EP 0332026 B1 EP0332026 B1 EP 0332026B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- bristles
- toothbrush
- agent
- anchor
- tuft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000645 desinfectant Substances 0.000 title claims description 17
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000003242 anti bacterial agent Substances 0.000 title description 3
- 239000003814 drug Substances 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 229940079593 drug Drugs 0.000 claims description 16
- 230000001680 brushing effect Effects 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 9
- 238000002483 medication Methods 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000004873 anchoring Methods 0.000 claims 1
- 238000003780 insertion Methods 0.000 claims 1
- 230000037431 insertion Effects 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 claims 1
- 210000000214 mouth Anatomy 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 241000894006 Bacteria Species 0.000 description 6
- 210000003128 head Anatomy 0.000 description 4
- 241000233866 Fungi Species 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910001369 Brass Inorganic materials 0.000 description 2
- 208000010641 Tooth disease Diseases 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 239000000551 dentifrice Substances 0.000 description 2
- 230000002538 fungal effect Effects 0.000 description 2
- 208000024693 gingival disease Diseases 0.000 description 2
- 208000015181 infectious disease Diseases 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- MOFOBJHOKRNACT-UHFFFAOYSA-N nickel silver Chemical compound [Ni].[Ag] MOFOBJHOKRNACT-UHFFFAOYSA-N 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 210000003296 saliva Anatomy 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000009732 tufting Methods 0.000 description 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- WMOOOIUXYRHDEZ-UHFFFAOYSA-N 2,3,4-trichlorobenzaldehyde Chemical compound ClC1=CC=C(C=O)C(Cl)=C1Cl WMOOOIUXYRHDEZ-UHFFFAOYSA-N 0.000 description 1
- TYBHZVUFOINFDV-UHFFFAOYSA-N 2-bromo-6-[(3-bromo-5-chloro-2-hydroxyphenyl)methyl]-4-chlorophenol Chemical compound OC1=C(Br)C=C(Cl)C=C1CC1=CC(Cl)=CC(Br)=C1O TYBHZVUFOINFDV-UHFFFAOYSA-N 0.000 description 1
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 229940027983 antiseptic and disinfectant quaternary ammonium compound Drugs 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 229960001927 cetylpyridinium chloride Drugs 0.000 description 1
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 description 1
- 229960003260 chlorhexidine Drugs 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- -1 e.g. Polymers 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- ACGUYXCXAPNIKK-UHFFFAOYSA-N hexachlorophene Chemical compound OC1=C(Cl)C=C(Cl)C(Cl)=C1CC1=C(O)C(Cl)=CC(Cl)=C1Cl ACGUYXCXAPNIKK-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000036512 infertility Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 239000010956 nickel silver Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B11/00—Brushes with reservoir or other means for applying substances, e.g. paints, pastes, water
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B11/00—Brushes with reservoir or other means for applying substances, e.g. paints, pastes, water
- A46B11/001—Brushes with reservoir or other means for applying substances, e.g. paints, pastes, water with integral reservoirs
- A46B11/0068—Brushes where the reservoir is specifically intended for solid substance that dissolves gradually
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B11/00—Brushes with reservoir or other means for applying substances, e.g. paints, pastes, water
- A46B11/0072—Details
- A46B11/0079—Arrangements for preventing undesired leakage or dispensing
- A46B11/0082—Means for closing, sealing or controlling the flow using capillary action
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B2200/00—Brushes characterized by their functions, uses or applications
- A46B2200/10—For human or animal care
- A46B2200/1066—Toothbrush for cleaning the teeth or dentures
Definitions
- the primary tool for every day cleaning of teeth remains the common toothbrush. Since the toothbrush frequently comes into contact with the oral environment and may be subsequently left in a non-sterile environment until subsequent use, the toothbrush bristles can harbour bacteria and upon re-use of the toothbrush, the bristles can become a source for introducing bacteria into the oral cavity.
- the toothbrush has not been used as a source of medication but, rather, as an applicator for dentrifice. There would be merit in using the toothbrush as such a medication source, preferably as a complement to the dentrifice if a viable and practical low-cost means for doing so could be found.
- U.S. Patent 914,501 is an early approach wherein a reservoir is formed along the sides of the bristles to contain liquid dentrifice.
- This disclosure fails to provide long-lasting means for release of dentrifice or other agents since the liquid dentrifice would be washed from the oral cavity with each use.
- the brushing head has tuft holes containing a disinfectant to be released during brushing.
- Figure 3 of U.K. Patent 1,026,738 discloses recesses 6 disposed annularly around the upper interior perimeter of tuft holes 4 to provide a source of dentrifice when the brush is immersed in water.
- This patent again, fails to teach how a long-lasting source of disinfectant and/or other medications can be maintained over extended periods or be absorbed by the bristles over such long periods, i.e., over a period of extended use, as opposed to prior art teachings which disclose systems which would be effective for only a single use.
- the drawing illustrates, in schematic form, a cross-section of a portion of the head of a toothbrush suitable for the present invention.
- toothbrushes of conventional manufacture are not sterile and, in fact, harbour bacteria which transfers into the oral cavity during repeated brushings.
- the primary instrument for tooth cleaning itself can be source of infection within the mouth.
- toothbrush which is capable of releasing medication effective against tooth and gum disease over extended periods of time, that is, during multiple uses of the toothbrush.
- the solution to these long-recognized needs is the device of the present invention wherein disinfectant, medication or a mixture thereof is contained in a slow-release material. Subsequently, during repeated brushings, the water and saliva present in the oral cavity during brushing seeps into the tuft holes and causes the release of measured amounts of the disinfectant and/or medication. These agents travel up the tuft hole and out of it and into the oral cavity during brushing. Moreover, at the end of brushing, there is sufficient disinfectant remaining on the bristles and toothbrush head and adjacent portions of the handle to sterilize the same so that bacteria will not build up on the brush and contaminate the mouth upon succeeding toothbrushings over an extended period of time, say about 2 to 3 months.
- the drawing shows, in schematic form, a cross-section of a portion of the head of a toothbrush suitable for the present invention.
- the device is generally designated 10 and has a brush head 11.
- Two tuft holes for the bristles, 15 and 16, are depicted in brush head 11.
- the bristles or filament 13 are inserted into the holes 15 and 16, most commonly by an anchor 17, typically composed of aluminum or an alloy such as brass or silver-nickel.
- the toothbrush In operation, the toothbrush is employed in the usual fashion, i.e., dentifrice is applied to the bristles and the brush is inserted into the oral cavity for brushing.
- the water and saliva generated during this process causes measured amounts of disinfectant and/or medication to pass from their capsule enclosures and up along the bristles out of the tuft holes and into the mouth.
- sufficient disinfectant remains on the bristles to render the same sterile, thereby preventing the formation of bacterial colonies and fungal growth which, in the case of prior art toothbrushes, infect the oral cavity when the toothbrush is next used.
- the slow-release material may be of natural or synthetic polymers, e.g., gelatin, polyvinylpyrrolidone and hydroxyethylmethacrylate.
- antimicrobial agents such as chlorhexidine, Triclosan, or bromochlorophene may be employed, as well as other known agents.
- a wide variety of medicaments effective to destroy bacteria and fungus may be employed, both for the purpose of preventing bacterial/fungus growth on the brush and to deliver such ingredients into the oral cavity.
- Hexetidene Phenols in general Trichlorophenyl Formaldehyde Quaternary Ammonium compounds e.g. Benzalkonium Chloride
- Pyridine Derivatives e.g. Cetylpyridinium chloride
- Hexachlorophane e.g., although the toothbrush of the present invention is well-suited for conventional brushing with a dentrifice, it may be used without the latter and thus be employed as a means of delivering suitable medications into the oral cavity.
- the anchor 17 - which is usually metal such as nickel-silver, brass, aluminum, etc.- is coated with the disinfectant and/or antibacterial/fungus agents described above.
- a water-swellable coating or a coating capable of releasing the above agent(s) in concentrations sufficient to achieve the disinfecting and medicinal purposes described when wet, is applied to the metal.
- the metal anchors are usually derived from a continuous spool of the metal(s) mentioned above and are passed to the tufting machine and cut to size in situ.
- the coating material may be, for example, a polyvinyl or similar polymer capable of forming a film, e.g., cast from alcohol.
- the coating can be applied to the spool of metal at the source of manufacture or just prior to the tufting process via a coating bath or spray. To retain sufficient material, a groove may be formed on one or both sides of the metal anchor to hold the coating material.
- a variation of the above is to form the metal anchor in two or more strips (not shown) and to apply the coating as a "sandwich" between two of the strips.
- the anchor can be made of high strength plastic which then can be coated with the agent(s) described above.
Landscapes
- Brushes (AREA)
Description
- Health care costs are increasing dramatically in the United States and other countries. A significant component of these escalating costs is tooth and gum disease.
- Advances in dentrifice compositions and modalities for treatment of peridontal disease have greatly assisted in the prevention and treatment of these conditions.
- However, the primary tool for every day cleaning of teeth remains the common toothbrush. Since the toothbrush frequently comes into contact with the oral environment and may be subsequently left in a non-sterile environment until subsequent use, the toothbrush bristles can harbour bacteria and upon re-use of the toothbrush, the bristles can become a source for introducing bacteria into the oral cavity.
- Additionally, the toothbrush has not been used as a source of medication but, rather, as an applicator for dentrifice. There would be merit in using the toothbrush as such a medication source, preferably as a complement to the dentrifice if a viable and practical low-cost means for doing so could be found.
- Although the technical problem of designing a toothbrush capable of delivering dentrifice and other agents has long been recognized, no satisfactory workable system has been developed to meet this long-felt need.
- The prior art illustrates that this is so. For example, U.S. Patent 914,501 is an early approach wherein a reservoir is formed along the sides of the bristles to contain liquid dentrifice. This disclosure fails to provide long-lasting means for release of dentrifice or other agents since the liquid dentrifice would be washed from the oral cavity with each use.
- Another attempt to solve the problem is disclosed in U.S. Patent 1,238,883 wherein the "bristles" of the brush are vulcanized rubber and incorporated polishing and cleaning substances.
- In U.S. Patent 1,214,556 a cotton insert containing dentifrice is placed in the brush. This is believed to be impractical as it would require consumers to undertake the cumbersome task of replacing inserts after every use. A similar insert device is described in U.S. Patent 4,588,089 wherein an envelope containing toothpaste is inserted in a toothbrush and released by a spike. This technique is also employed in U.S. Patent 3,316,580 which suggests the use of an envelope disposed between the bristles. Such devices requiring inserts are complicated to use.
- Similar reservations would apply to U.S. Patent 4,453,679 in which the handle of the toothbrush has a separate attachment for releasing various agents. Indeed, the handle-dispensing approach is the subject of a number of earlier efforts to solve the problem such as U.S. Patents 1,896,982; 2,077,758 and 2,303,667, plus U.K. Patent 259,268.
- Another approach believed to be unsuccessful is to coat or to spray the bristles with various agents. Representatives of this group are U.S. Patents 1,982,660; 3,302,230; 3,691,585 and Canadian Patent 549,168.
- It is evident from examination of the above patents that none of the devices solves the twin problems of maintaining bristles of the toothbrush sterile in a practical manner and providing a viable slow release mechanism for anti-bacterial agents or other medications.
- A different approach is shown in British Patent 259,268 wherein a disinfectant is disposed to communicate with the tuft holes of the bristles. However, even in Figures 7-9 of the patent, the reservoir is not located within the tuft holes themselves, nor is there any suggestion of the use of medications other than disinfectants. Importantly, this patent fails to teach how the material to be transferred to the bristles is, in fact, so communicated there to and absorbed by them. In view of the fact that virtually all toothbrushes on the market today employ hydrophobic plastic bristles, it is not understood how the device of this patent would operate to transfer disinfectant or other medications up through the bristles of such modern toothbrushes.
- In DE-C 451 728 the brushing head has tuft holes containing a disinfectant to be released during brushing.
- Figure 3 of U.K. Patent 1,026,738 discloses recesses 6 disposed annularly around the upper interior perimeter of tuft holes 4 to provide a source of dentrifice when the brush is immersed in water. This patent, again, fails to teach how a long-lasting source of disinfectant and/or other medications can be maintained over extended periods or be absorbed by the bristles over such long periods, i.e., over a period of extended use, as opposed to prior art teachings which disclose systems which would be effective for only a single use.
- It is an object of this invention to provide a toothbrush so designed that it will incorporate means for maintaining the brush sterile over long periods.
- It is another object of this invention to provide a toothbrush which is capable over long periods of time of releasing anti-bacterial agents and other medications.
- It is yet another object of the invention to provide disinfectants and/or other materials in slow-release form incorporated in the toothbrush structure so that the materials are released through the bristles over extended time periods to keep the toothbrush sterile and clean and, if medications are used, to assist in the application thereof to the teeth during brushing.
- These and further objects of the invention will be observed from the following detailed description, the drawings and the claims.
- The drawing illustrates, in schematic form, a cross-section of a portion of the head of a toothbrush suitable for the present invention.
- As indicated, it is known that toothbrushes of conventional manufacture are not sterile and, in fact, harbour bacteria which transfers into the oral cavity during repeated brushings. Thus, the primary instrument for tooth cleaning itself can be source of infection within the mouth.
- It would be desirable, in addition to eliminating the foregoing infection problem, to provide a toothbrush which is capable of releasing medication effective against tooth and gum disease over extended periods of time, that is, during multiple uses of the toothbrush.
- Certain of the prior patents discussed above recognize the problem of toothbrush sterility and the desirability of using the toothbrush to deliver medication.
- The solution to these long-recognized needs is the device of the present invention wherein disinfectant, medication or a mixture thereof is contained in a slow-release material. Subsequently, during repeated brushings, the water and saliva present in the oral cavity during brushing seeps into the tuft holes and causes the release of measured amounts of the disinfectant and/or medication. These agents travel up the tuft hole and out of it and into the oral cavity during brushing. Moreover, at the end of brushing, there is sufficient disinfectant remaining on the bristles and toothbrush head and adjacent portions of the handle to sterilize the same so that bacteria will not build up on the brush and contaminate the mouth upon succeeding toothbrushings over an extended period of time, say about 2 to 3 months.
- To illustrate one embodiment of the invention, the drawing shows, in schematic form, a cross-section of a portion of the head of a toothbrush suitable for the present invention. Thus, the device is generally designated 10 and has a brush head 11. Two tuft holes for the bristles, 15 and 16, are depicted in brush head 11.
- As shown the bristles or
filament 13 are inserted into theholes anchor 17, typically composed of aluminum or an alloy such as brass or silver-nickel. - In operation, the toothbrush is employed in the usual fashion, i.e., dentifrice is applied to the bristles and the brush is inserted into the oral cavity for brushing. The water and saliva generated during this process causes measured amounts of disinfectant and/or medication to pass from their capsule enclosures and up along the bristles out of the tuft holes and into the mouth. At the end of brushing, sufficient disinfectant remains on the bristles to render the same sterile, thereby preventing the formation of bacterial colonies and fungal growth which, in the case of prior art toothbrushes, infect the oral cavity when the toothbrush is next used.
- The slow-release material may be of natural or synthetic polymers, e.g., gelatin, polyvinylpyrrolidone and hydroxyethylmethacrylate.
- As disinfectants to kill bacteria and fungal colonies on the bristles and brush, antimicrobial agents such as chlorhexidine, Triclosan, or bromochlorophene may be employed, as well as other known agents. A wide variety of medicaments effective to destroy bacteria and fungus may be employed, both for the purpose of preventing bacterial/fungus growth on the brush and to deliver such ingredients into the oral cavity.
- As for disinfectants/antibacterials, others that could be included are:
Hexetidene
Phenols in general
Trichlorophenyl
Formaldehyde
Quaternary Ammonium compounds
(e.g. Benzalkonium Chloride)
Pyridine Derivatives
(e.g. Cetylpyridinium chloride)
Hexachlorophane
Indeed, although the toothbrush of the present invention is well-suited for conventional brushing with a dentrifice, it may be used without the latter and thus be employed as a means of delivering suitable medications into the oral cavity. - According to the invention the anchor 17 - which is usually metal such as nickel-silver, brass, aluminum, etc.- is coated with the disinfectant and/or antibacterial/fungus agents described above.
- More particularly, a water-swellable coating, or a coating capable of releasing the above agent(s) in concentrations sufficient to achieve the disinfecting and medicinal purposes described when wet, is applied to the metal. For example, the metal anchors are usually derived from a continuous spool of the metal(s) mentioned above and are passed to the tufting machine and cut to size in situ. The coating material may be, for example, a polyvinyl or similar polymer capable of forming a film, e.g., cast from alcohol. The coating can be applied to the spool of metal at the source of manufacture or just prior to the tufting process via a coating bath or spray. To retain sufficient material, a groove may be formed on one or both sides of the metal anchor to hold the coating material.
- A variation of the above is to form the metal anchor in two or more strips (not shown) and to apply the coating as a "sandwich" between two of the strips.
- Further, the anchor can be made of high strength plastic which then can be coated with the agent(s) described above.
Claims (2)
- A toothbrush comprising a brush head having a plurality of tuft holes (15, 16) for the reception and retention of respective multiplicities of bristles (13) in the tuft holes, each multiplicity of bristles being attached in a corresponding tuft hole by a corresponding anchor (17), and at least one of said tuft holes containing therein an agent releasing material which contains and slowly releases the agent during repeated brushings, the release of the agent being activated by contact of the agent releasing material with liquid during brushing, said agent being selected from the group consisting of disinfectants and medications, characterized in that said agent releasing material is applied as a coating on the surface of the anchor in said at least one tuft hole prior to insertion of the anchor inside said at least one tuft hole.
- A method of manufacturing a toothbrush comprising the step of forming a brush head with a plurality of tuft holes (15, 16), characterized by the further steps of coating the surface of an anchor (17) with an agent selected from the group consisting of disinfectants, medications and mixtures thereof and anchoring a plurality of bristles (13) in one of said plurality of tuft holes by inserting said coated anchor therein.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US16565088A | 1988-03-08 | 1988-03-08 | |
US165650 | 1988-03-08 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0332026A1 EP0332026A1 (en) | 1989-09-13 |
EP0332026B1 true EP0332026B1 (en) | 1993-07-14 |
Family
ID=22599844
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89103503A Expired - Lifetime EP0332026B1 (en) | 1988-03-08 | 1989-02-28 | Tootbrush with slow release of disinfectant and anti-bacterial agents and method of manufacturing the same |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0332026B1 (en) |
JP (1) | JPH027903A (en) |
AU (1) | AU616483B2 (en) |
BR (1) | BR8901058A (en) |
CA (1) | CA1321290C (en) |
DE (1) | DE68907502T2 (en) |
DK (1) | DK169886B1 (en) |
MX (1) | MX169824B (en) |
PH (1) | PH27587A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8240937B2 (en) | 2002-09-05 | 2012-08-14 | Colgate-Palmolive Company | Oral care implement with bead retention |
US8282298B2 (en) | 2008-06-26 | 2012-10-09 | Colgate-Palmolive Company | Oral care implement |
US8449211B2 (en) | 2002-09-05 | 2013-05-28 | Colgate-Palmolive Company | Oral care toothbrush |
US8459892B2 (en) | 2008-06-25 | 2013-06-11 | Colgate-Palmolive Company | Oral care implement |
US8734042B2 (en) | 2010-03-31 | 2014-05-27 | Colgate-Palmolive Company | Oral care implement with rapid flavor release |
USD732831S1 (en) | 2009-02-05 | 2015-06-30 | Colgate-Palmolive Company | Toothbrush |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01101917A (en) * | 1987-10-15 | 1989-04-19 | Sangi Co Ltd | Toothbrush |
FR2643261A1 (en) * | 1989-02-22 | 1990-08-24 | Tonelli Jean Charles | Improvement to dentifrices |
DE19646519A1 (en) * | 1996-11-12 | 1998-05-14 | Pedex & Co Gmbh | Dental care device and method for manufacturing cleaning elements for dental care devices |
DE19818553C1 (en) * | 1998-04-24 | 1999-08-05 | Rueb F A Holding Gmbh | Making plastic toothbrush combating microorganism growth amongst its bristles |
US7331731B2 (en) | 2002-09-05 | 2008-02-19 | Colgate-Palmolive Company | Oral care toothbrush |
ITPD20130126A1 (en) * | 2013-05-10 | 2014-11-11 | Spazzolificio Piave Spa | HEAD OF TEETH BRUSH |
WO2016051287A1 (en) * | 2014-09-29 | 2016-04-07 | Koninklijke Philips N.V. | Oral care device having a pump-free fluid delivery system |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE451728C (en) * | 1927-11-03 | Cornelius Gordijn Jr | Brush with a brush body provided with cavities for receiving an antiseptic | |
JPS437396Y1 (en) * | 1965-10-12 | 1968-04-02 | ||
JPS4318259Y1 (en) * | 1966-06-15 | 1968-07-29 | ||
US3378870A (en) * | 1967-03-22 | 1968-04-23 | Matsunaga Kenji | Toothbrush |
PH23397A (en) * | 1985-12-11 | 1989-07-26 | Unilever Nv | Oral hygiene product |
-
1989
- 1989-02-28 DE DE89103503T patent/DE68907502T2/en not_active Expired - Fee Related
- 1989-02-28 EP EP89103503A patent/EP0332026B1/en not_active Expired - Lifetime
- 1989-03-01 AU AU30876/89A patent/AU616483B2/en not_active Ceased
- 1989-03-06 MX MX015159A patent/MX169824B/en unknown
- 1989-03-07 DK DK110989A patent/DK169886B1/en active
- 1989-03-07 BR BR898901058A patent/BR8901058A/en not_active IP Right Cessation
- 1989-03-07 PH PH38298A patent/PH27587A/en unknown
- 1989-03-07 CA CA000592981A patent/CA1321290C/en not_active Expired - Fee Related
- 1989-03-08 JP JP1055999A patent/JPH027903A/en active Pending
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8240937B2 (en) | 2002-09-05 | 2012-08-14 | Colgate-Palmolive Company | Oral care implement with bead retention |
US8449211B2 (en) | 2002-09-05 | 2013-05-28 | Colgate-Palmolive Company | Oral care toothbrush |
US8764332B2 (en) | 2002-09-05 | 2014-07-01 | Colgate-Palmolive Company | Oral care toothbrush |
US9265337B2 (en) | 2002-09-05 | 2016-02-23 | Colgate-Palmolive Company | Oral care toothbrush |
US8459892B2 (en) | 2008-06-25 | 2013-06-11 | Colgate-Palmolive Company | Oral care implement |
US9131767B2 (en) | 2008-06-25 | 2015-09-15 | Colgate-Palmolive Company | Oral care implement |
US8282298B2 (en) | 2008-06-26 | 2012-10-09 | Colgate-Palmolive Company | Oral care implement |
US8628264B2 (en) | 2008-06-26 | 2014-01-14 | Colgate-Palmolive Company | Oral care implement |
US9149110B2 (en) | 2008-06-26 | 2015-10-06 | Colgate-Palmolive Company | Oral care implement |
USD732831S1 (en) | 2009-02-05 | 2015-06-30 | Colgate-Palmolive Company | Toothbrush |
USD782825S1 (en) | 2009-02-05 | 2017-04-04 | Colgate-Palmolive Company | Toothbrush |
US8734042B2 (en) | 2010-03-31 | 2014-05-27 | Colgate-Palmolive Company | Oral care implement with rapid flavor release |
Also Published As
Publication number | Publication date |
---|---|
DE68907502D1 (en) | 1993-08-19 |
DK169886B1 (en) | 1995-03-27 |
DE68907502T2 (en) | 1994-02-17 |
PH27587A (en) | 1993-08-18 |
AU3087689A (en) | 1989-09-14 |
DK110989A (en) | 1989-09-09 |
JPH027903A (en) | 1990-01-11 |
EP0332026A1 (en) | 1989-09-13 |
BR8901058A (en) | 1989-10-24 |
MX169824B (en) | 1993-07-27 |
CA1321290C (en) | 1993-08-17 |
DK110989D0 (en) | 1989-03-07 |
AU616483B2 (en) | 1991-10-31 |
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