EP0321821A3 - Liquid radiation-curable resin used as a secondary coating for optical conductors - Google Patents

Liquid radiation-curable resin used as a secondary coating for optical conductors Download PDF

Info

Publication number
EP0321821A3
EP0321821A3 EP19880120733 EP88120733A EP0321821A3 EP 0321821 A3 EP0321821 A3 EP 0321821A3 EP 19880120733 EP19880120733 EP 19880120733 EP 88120733 A EP88120733 A EP 88120733A EP 0321821 A3 EP0321821 A3 EP 0321821A3
Authority
EP
European Patent Office
Prior art keywords
meth
acrylate
coatings
molecular weight
hydroxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP19880120733
Other languages
German (de)
French (fr)
Other versions
EP0321821A2 (en
Inventor
Siegfried Dr. Birkle
Hans-Dieter Dr. Feucht
Rainer Dr. Kamps
Eva-Maria Rissel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Original Assignee
Siemens AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens AG filed Critical Siemens AG
Publication of EP0321821A2 publication Critical patent/EP0321821A2/en
Publication of EP0321821A3 publication Critical patent/EP0321821A3/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
    • C08G59/1461—Unsaturated monoacids
    • C08G59/1466—Acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/58—Epoxy resins
    • C08G18/581—Reaction products of epoxy resins with less than equivalent amounts of compounds containing active hydrogen added before or during the reaction with the isocyanate component
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8108—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group
    • C08G18/8116—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group esters of acrylic or alkylacrylic acid having only one isocyanate or isothiocyanate group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • C08G59/1444—Monoalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1477—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/40—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Emergency Medicine (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Paints Or Removers (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)

Abstract

Zur Herstellung von Sekundärcoatings für Lichtwellenleiter werden Harze benötigt, die flüssig sind und aufgrund einer hohen Strahlenempfindlichkeit und einer Viskosität, die allenfalls den Zusatz relativ geringer Mengen an Verdün­ nungsmitteln erfordert, Sekundärcoatings ergeben, welche ein Einfriergebiet ≧ +60°C besitzen und mit den Primär­ coatings, insbesondere auf der Basis von Urethanacrylaten, verträglich sind. For the production of secondary coatings for optical fibers you need resins that are liquid and due to a high radiation sensitivity and a viscosity that at most the addition of relatively small amounts of diluent means required secondary coatings, which have a freezing area ≧ + 60 ° C and with the primary coatings, especially based on urethane acrylates, are tolerated.

Dies wird durch ein Harz erreicht, das ein Reaktionspro­ dukt von (Meth)acrylsäure oder Glycerindi(meth)acrylat bzw. Pentaerythrittri(meth)acrylat mit einem 2:1-Addukt aus einem Diepoxid und einem α,ω-Diol mit einem mittleren Molekulargewicht zwischen 600 und 3000 oder ein Reaktions­ produkt von (Meth)acrylsäure bzw. -säurechlorid oder Iso­ cyanatoalkyl-(meth)acrylat mit einem Umsetzungsprodukt aus dem 2:1-Addukt und einem niedermolekularen einwertigen Alkohol (C₁ bis C₁₀), einem niedermolekularen zweiwertigen Alkohol (C₂ bis C₄) oder Wasser ist, wobei das Diepoxid ein aromatischer Diglycidylether und das α,ω-Diol ein α,ω-hydroxyterminiertes Polyoxyalkylen, ein α,ω-hydroxy­ terminierter Polyester, ein α,ω-hydroxyterminiertes Poly­ butadien oder ein α,ω-hydroxyterminiertes organofunktio­ nelles Polysiloxan ist. This is achieved by a resin that is a reaction pro product of (meth) acrylic acid or glycerol di (meth) acrylate or pentaerythritol tri (meth) acrylate with a 2: 1 adduct from a diepoxide and an α, ω-diol with a medium one Molecular weight between 600 and 3000 or a reaction product of (meth) acrylic acid or acid chloride or iso cyanatoalkyl (meth) acrylate with a reaction product the 2: 1 adduct and a low molecular weight monovalent Alcohol (C₁ to C₁₀), a low molecular weight dihydric Alcohol (C₂ to C₄) or water, the diepoxide an aromatic diglycidyl ether and the α, ω-diol α, ω-hydroxy terminated polyoxyalkylene, an α, ω-hydroxy terminated polyester, an α, ω-hydroxy terminated poly butadiene or an α, ω-hydroxy-terminated organofunction is polysiloxane.

LWL-Coatings FO coatings

EP19880120733 1987-12-23 1988-12-12 Liquid radiation-curable resin used as a secondary coating for optical conductors Withdrawn EP0321821A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3743993 1987-12-23
DE3743993 1987-12-23

Publications (2)

Publication Number Publication Date
EP0321821A2 EP0321821A2 (en) 1989-06-28
EP0321821A3 true EP0321821A3 (en) 1991-01-16

Family

ID=6343528

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19880120733 Withdrawn EP0321821A3 (en) 1987-12-23 1988-12-12 Liquid radiation-curable resin used as a secondary coating for optical conductors

Country Status (2)

Country Link
US (2) US5057587A (en)
EP (1) EP0321821A3 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0321821A3 (en) * 1987-12-23 1991-01-16 Siemens Aktiengesellschaft Liquid radiation-curable resin used as a secondary coating for optical conductors
EP0562373A3 (en) * 1992-03-23 1994-05-25 Siemens Ag Immobilisation of biochemical substances
EP0562368A3 (en) * 1992-03-23 1994-09-28 Siemens Ag Epoxy functional polyethers
DE59307719D1 (en) * 1992-03-23 1998-01-08 Siemens Ag Biosensor
US6042943A (en) * 1998-03-23 2000-03-28 Alvin C. Levy & Associates, Inc. Optical fiber containing a radiation curable primary coating composition
US5985952A (en) * 1998-03-23 1999-11-16 Alvin C. Levy & Associates, Inc. Radiation curable primary coating composition for an optical fiber
US6362249B2 (en) * 1998-09-04 2002-03-26 Dsm Desotech Inc. Radiation-curable coating compositions, coated optical fiber, radiation-curable matrix forming material and ribbon assembly
US20040054036A1 (en) * 2000-10-26 2004-03-18 Hatton Kevin Brian High functional polymers
EP1238995A1 (en) * 2001-03-06 2002-09-11 Vantico AG High functional polymers

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1549956A (en) * 1967-03-02 1968-12-13
FR2076127A1 (en) * 1970-01-15 1971-10-15 Continental Can Co
US4099837A (en) * 1976-05-26 1978-07-11 Bell Telephone Laboratories, Incorporated Coating of fiber lightguides with UV cured polymerization products

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH443342A (en) * 1962-05-07 1967-09-15 Ciba Geigy Process for the production of new hydroxyl-containing polyether esters
US4221892A (en) * 1978-11-30 1980-09-09 The Dow Chemical Company Photocurable partially esterified polyepoxides
DE2926415A1 (en) * 1979-06-29 1981-01-08 Siemens Ag METHOD FOR PRODUCING A TOW-RESISTANT LIGHT-WAVE GUIDE
US4383091A (en) * 1980-09-19 1983-05-10 The Dow Chemical Company Urethane modified polymers having hydroxyl groups
NL8400727A (en) * 1984-03-07 1985-10-01 Philips Nv OPTICAL GLASS FIBER PROVIDED WITH A PLASTIC COATING AND METHOD FOR THE MANUFACTURE THEREOF.
JPS61227947A (en) * 1985-03-29 1986-10-11 Nitto Electric Ind Co Ltd Coating material for optical glass fiber
EP0204497B1 (en) * 1985-05-28 1994-07-13 Nippon Paint Co., Ltd. Polymerisation process employing compounds having polymerisable acylurethane structures
FI82866C (en) * 1985-06-24 1991-04-25 Siemens Ag Process for making structured heat-resistant layers and their use
DE3606950A1 (en) * 1986-03-04 1987-10-01 Basf Ag ELASTOMER-MODIFIED, curable vinyl resins
EP0321821A3 (en) * 1987-12-23 1991-01-16 Siemens Aktiengesellschaft Liquid radiation-curable resin used as a secondary coating for optical conductors

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1549956A (en) * 1967-03-02 1968-12-13
FR2076127A1 (en) * 1970-01-15 1971-10-15 Continental Can Co
US4099837A (en) * 1976-05-26 1978-07-11 Bell Telephone Laboratories, Incorporated Coating of fiber lightguides with UV cured polymerization products

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, Vol. 106, No. 20, 18 Mai 1987, Columbus, Ohio, USA, Ref. No. 61227947, Zusammenfassung; & JP,A,61 227 947 (NITTO ELECTRIC INDUSTRIAL CO) (11-10-1986). *

Also Published As

Publication number Publication date
US5109089A (en) 1992-04-28
US5057587A (en) 1991-10-15
EP0321821A2 (en) 1989-06-28

Similar Documents

Publication Publication Date Title
DE2757733C2 (en) Process for the preparation of water-dilutable, base-neutralized acidic resins and their use
EP0168713B1 (en) (meth)acrylic acid ester modified organopolysiloxanes, their preparation and use as abhesive coating compositions
DE3810140C1 (en)
EP0321821A3 (en) Liquid radiation-curable resin used as a secondary coating for optical conductors
DE69300270T2 (en) Radiation curable compositions and method of use.
AT404733B (en) METHOD FOR PRODUCING RADIATION-CURABLE WATER-THINNABLE URETHANE RESINS AND THE USE THEREOF
PT84285B (en) PROCESS FOR THE PREPARATION OF QUICKLY CURED EPOXY RESINS
KR870008978A (en) Application method of composite coating and liquid crosslinking composition
ATE51630T1 (en) PROCESS FOR THE MANUFACTURE OF AN EXTERNAL CROSSLINKING, EPOXY GROUP-FREE AMINOPOLY(METH)-ACRYLATE RESIN, THE RESIN AVAILABLE WITH IT, ITS USE, KTL BATH CONTAINING IT AND ITS USE FOR COATING OBJECTS.
DE2000668A1 (en) Polythioetheroxyalkylene epoxies
EP0976716A1 (en) Process for the preparation of esters of (meth)acrylic acid
DE3101343C1 (en) Process for making epoxy resins flexible
DE2115918C3 (en) Process for the production of epoxy polyadducts
EP0321820A3 (en) Liquid radiation-curable resin used as a secondary coating for optical conductors
DE2549656A1 (en) NEW HARDENING AGENTS FOR EPOXY RESINS
EP0921168B1 (en) Radiation curable products based on epoxy(meth)acrylates
DE1469904A1 (en) Process for producing hardened resins with extensive elasticity
MX168332B (en) CONTROLLED CONVERSION EPOXY RESINS AND A METHOD FOR THEIR PREPARATION
DE2344843A1 (en) ARTIFICIAL RESIN MIXTURES WITH HIGH REACTIVITY UNDER THE EFFECT OF IONIZING RAYS
GB1001670A (en) Stoving finishes
US2189572A (en) Process for fractionating resinous products
DE3115198A1 (en) CURABLE COATING AGENTS AND METHOD FOR THE PRODUCTION OF SCRATCH-RESISTANT COATINGS ON PLASTICS
DE3134494A1 (en) "LIQUIDS OF HIGH VISCOSITY AND METHOD FOR THE PRODUCTION THEREOF"
DE2262157C2 (en) Low-viscosity, halogen-containing self-extinguishing epoxy resins, process for their preparation and their use
ES2018655B3 (en) COPOLYMERS BY POLYESTER GRAFT, COMPOSITIONS FOR FLEXIBLE COATING THAT CONTAIN THE SAME AND BRANCHES OF POLYESTER BRANCHES TO PREPARE THEM.

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): DE FR GB IT

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): DE FR GB IT

17P Request for examination filed

Effective date: 19901205

RHK1 Main classification (correction)

Ipc: C08G 59/16

17Q First examination report despatched

Effective date: 19920902

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 19930316