EP0303016A1 - Method of making a gas pressure vessel of austenitic stainless steel by cryogenic forming - Google Patents

Method of making a gas pressure vessel of austenitic stainless steel by cryogenic forming Download PDF

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Publication number
EP0303016A1
EP0303016A1 EP88109402A EP88109402A EP0303016A1 EP 0303016 A1 EP0303016 A1 EP 0303016A1 EP 88109402 A EP88109402 A EP 88109402A EP 88109402 A EP88109402 A EP 88109402A EP 0303016 A1 EP0303016 A1 EP 0303016A1
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Prior art keywords
pressure medium
container
coolant
making
pressure
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Granted
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EP88109402A
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German (de)
French (fr)
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EP0303016B1 (en
Inventor
Werner Konrad Diehl
Martin Dr. Kesten
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Messer Griesheim GmbH
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Messer Griesheim GmbH
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Priority to AT88109402T priority Critical patent/ATE68527T1/en
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/04Hardening by cooling below 0 degrees Celsius
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D26/00Shaping without cutting otherwise than using rigid devices or tools or yieldable or resilient pads, i.e. applying fluid pressure or magnetic forces
    • B21D26/02Shaping without cutting otherwise than using rigid devices or tools or yieldable or resilient pads, i.e. applying fluid pressure or magnetic forces by applying fluid pressure
    • B21D26/033Deforming tubular bodies
    • B21D26/041Means for controlling fluid parameters, e.g. pressure or temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D26/00Shaping without cutting otherwise than using rigid devices or tools or yieldable or resilient pads, i.e. applying fluid pressure or magnetic forces
    • B21D26/02Shaping without cutting otherwise than using rigid devices or tools or yieldable or resilient pads, i.e. applying fluid pressure or magnetic forces by applying fluid pressure
    • B21D26/033Deforming tubular bodies
    • B21D26/049Deforming bodies having a closed end
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D7/00Modifying the physical properties of iron or steel by deformation
    • C21D7/02Modifying the physical properties of iron or steel by deformation by cold working
    • C21D7/10Modifying the physical properties of iron or steel by deformation by cold working of the whole cross-section, e.g. of concrete reinforcing bars
    • C21D7/12Modifying the physical properties of iron or steel by deformation by cold working of the whole cross-section, e.g. of concrete reinforcing bars by expanding tubular bodies

Definitions

  • the invention relates to a method for producing a pressurized gas container from austenitic steels by cryoforming according to the preamble of claim 1.
  • the strength properties of metastable austenitic steels can be improved by cryoforming by deforming them below their respective martensite transformation temperatures Md or Ms.
  • Md is the temperature above which no martensitic transformation takes place even when deformed
  • Ms is the temperature below which martensite formation begins even without deformation.
  • the preferred coolant used is liquid nitrogen, with which the steels, if desired, can be cooled down to -196 ° C.
  • DE-OS 1 452 533 also discloses the use of this method for producing high-strength pressure vessels.
  • the simultaneous use of liquid nitrogen as the coolant and pressure medium is preferred.
  • the container to be deformed is filled with liquid nitrogen and brought to the high pressure required for the deformation by means of an appropriate cryopump or by injecting a gas.
  • the use of a pressure medium different from the coolant is also mentioned, but appears to be too complex, for example in the form of explosion deformation, or undesirable condensations from the pressure medium are to be expected, possibly freezing the pressure medium with excessive cold removal from the container wall.
  • the invention is therefore based on the object of improving the process for producing pressurized gas containers from austenitic steels by cryogenic shaping in such a way that it does not have the disadvantages mentioned when the coolant is simultaneously used as the pressurizing medium, nor does the difficulties described when using its own pressurizing medium occur.
  • the trichlorofluoromethane CFCl3 used according to the invention which is known as a refrigerant under the designation R11, has properties that enable its use as a separate pressure medium that is independent of the coolant, although this is not actually to be expected due to the temperature range in which it is present as a liquid is.
  • Trichlorofluoromethane solidifies at a temperature which, because of the expedient use of liquid nitrogen as the coolant, is clearly above the temperature at which the cryogenic stretching is carried out.
  • chlorofluorocarbons such as dichlorofluoromethane (CCl2F2, R12) and chlorotrifluoromethane (CClF3, R 13) are also suitable as pressure medium for cryogenic stretching of containers.
  • Cl2F2, R12 dichlorofluoromethane
  • ClF3, R 13 chlorotrifluoromethane
  • the drawing illustrates a device for carrying out the method according to the invention in schematic form.
  • the compressed gas container 1 to be deformed is located in an insulated cooling chamber 2, in which it is cooled to the temperature required for the formation of martensite.
  • Liquid nitrogen which flows through the line 3 and nozzles 4 into the cooling chamber 2, serves as the coolant is sprayed where it evaporates.
  • the temperature reached is indicated by the thermometer 5.
  • CFCl3 as a pressure medium, which is removed from a reservoir 6 and pressed by means of the pump 7 via the line 8 into the interior of the container 1.
  • the pressure is indicated by the manometer 9.
  • the filled pressurized gas container 1 is closed with a releasable, pressure-tight closure 10 and connected to the pump 7 and the line 8 via a filling pipe 11 which extends into the middle of the container.
  • the filling pipe 11 has thermal insulation 12 which prevents the pressure medium from freezing.
  • CFCl3 has a significantly lower thermal conductivity than the container steel, only an edge layer that comes into direct contact with the inner surface of the container can solidify during the deformation process. It is therefore also possible to replace the cooling chamber 2 with a Dewar vessel filled with liquid nitrogen, into which the container 1 is immersed.
  • the process according to the invention can be carried out even under these extreme conditions, provided that care is taken that the container 1 is not immersed in the liquid nitrogen for longer than the time required for the deformation.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

Die Herstellung hochfester Druckgasbehälter (1) aus austenitischen Stählen durch Kryoverformung erfolgt bevorzugt mit flüssigem Stickstoff als Kühlmittel und als Druckmittel. Neben manchen Vorteilen hat diese Methode auch einige Nachteile, u.a. sicherheitstechnischer Art. Die Verwendung eines vom Kühlmittel unterschiedlichen Druckmittels ist jedoch wegen der Gefahr des Auskondensierens von Bestandteilen oder des Einfrierens mit unerwünschter Erwärmung des Druckgasbehälters ebenfalls sehr nachteilig. Zwecks Vermeidung dieser Nachteile wird als vom Kühlmittel unterschiedliches Druckmittel Trichlorfluormethan (CFCl3) verwendet.The manufacture of high-strength pressurized gas containers (1) from austenitic steels by cryoforming is preferably carried out using liquid nitrogen as the coolant and as the pressure medium. In addition to some advantages, this method also has some disadvantages, including Safety-related type. However, the use of a pressure medium different from the coolant is also very disadvantageous because of the risk of components condensing out or of freezing with undesired heating of the pressure gas container. To avoid these disadvantages, trichlorofluoromethane (CFCl3) is used as the pressure medium different from the coolant.

Description

Die Erfindung betrifft ein Verfahren zur Herstellung eines Druckgasbehälters aus austenitischen Stählen durch Kryover­formung nach dem Oberbegriff des Anspruches 1.The invention relates to a method for producing a pressurized gas container from austenitic steels by cryoforming according to the preamble of claim 1.

Die Festigkeitseigenschaften metastabiler austenitischer Stähle können durch Kryoverformung verbessert werden, in­dem sie unterhalb ihrer jeweiligen Martensitumwandlungs­temperatur Md oder Ms verformt werden. Md ist dabei die Temperatur, oberhalb der auch bei Verformung keine mar­tensitische Umwandlung stattfindet, Ms ist dagegen die Temperatur, unterhalb der auch ohne Verformung die Mar­tensitbildung einsetzt. Ein derartiges Verfahren zur Ver­besserung der Festigkeitseigenschaften austenitischer Stähle ist aus der DE-PS 26 54 702 bekannt.The strength properties of metastable austenitic steels can be improved by cryoforming by deforming them below their respective martensite transformation temperatures Md or Ms. Md is the temperature above which no martensitic transformation takes place even when deformed, while Ms is the temperature below which martensite formation begins even without deformation. Such a method for improving the strength properties of austenitic steels is known from DE-PS 26 54 702.

Da insbesondere die Ms-Temperaturen sehr niedrig liegen, verwendet man als Kühlmittel bevorzugt flüssigen Stick­stoff, mit dem die Stähle, falls gewüschnt, bis auf -196°C abgekühlt werden können.Since the Ms temperatures in particular are very low, the preferred coolant used is liquid nitrogen, with which the steels, if desired, can be cooled down to -196 ° C.

Aus der DE-OS 1 452 533 ist ferner die Anwendung dieses Verfahrens zur Herstellung hochfester Druckbehälter be­kannt. Bevorzugt wird hierbei die gleichzeitige Verwen­dung von flüssigem Stickstoff als Kühlmittel und Druck­mittel. In diesem Fall wird der zu verformende Behälter mit flüssigem Stickstoff gefüllt und mit Hilfe einer entsprechenden Kryopumpe oder durch Aufdrücken eines Gases auf den für die Verformung erforderlichen hohen Druck gebracht. Die Verwendung eines vom Kühlmittel unterschiedlichen Druckmittels wird ebenfalls genannt, erscheint jedoch zu aufwendig, beispielsweise in Form von Explosionsverformung, oder es sind unerwünschte Kondensationen aus dem Druckmittel zu erwarten, ggf. Ein­frieren des Druckmittels mit übermäßigem Kälteentzug aus der Behälterwand.DE-OS 1 452 533 also discloses the use of this method for producing high-strength pressure vessels. The simultaneous use of liquid nitrogen as the coolant and pressure medium is preferred. In this case, the container to be deformed is filled with liquid nitrogen and brought to the high pressure required for the deformation by means of an appropriate cryopump or by injecting a gas. The use of a pressure medium different from the coolant is also mentioned, but appears to be too complex, for example in the form of explosion deformation, or undesirable condensations from the pressure medium are to be expected, possibly freezing the pressure medium with excessive cold removal from the container wall.

In der Praxis hat sich jedoch bei der gleichzeitigen Verwendung von flüssigem Stickstoff als Kühl- und Druck­mittel eine Reihe von Nachteilen und Schwierigkeiten herausgestellt.In practice, however, a number of disadvantages and difficulties have emerged when using liquid nitrogen as the coolant and pressure medium.

Wenn die Druckübertragung auf die Behälterwand über den flüssigen Stickstoff als Medium erfolgt, erfordert dies die Verwendung aufwendiger, wärmeisolierter Einrichtungen wie Kryopumpen, isolierten Rohrleitungen und Kryobehältern. Bewußt erzeugte oder unvermeidlich entstehende Gaspolster im Behälter oder seinen Zuleitungen erhöhen das Sicher­heitsrisiko bei einem eventuellen Versagen des Behälters während des Kryostreckprozesses. Dazu kommt, daß auch der flüssige Stickstoff bei den relativ hohen erforderlichen Streckdrücken (einige 100 bar) selbst eine merkliche Kompressibilität besitzt, was die bei einem Versagen freigesetzte Energie deutlich erhöht. Deswegen sind für das Kryostrecken aufwendige und die technische Anwendung des Verfahrens behindernde Sicherheitseinrichtungen er­forderlich.If the pressure is transferred to the container wall via the liquid nitrogen as a medium, this requires the use of complex, heat-insulated devices such as cryopumps, insulated pipes and cryogenic containers. Deliberately created or inevitably created gas cushions in the container or its supply lines increase the safety risk in the event of a possible failure of the container during the cryostressing process. In addition, the liquid nitrogen at the relatively high required Stretching pressures (some 100 bar) itself have a noticeable compressibility, which significantly increases the energy released in the event of failure. For this reason, complex safety devices are required for cryogenic stretching and hinder the technical application of the method.

Der Erfindung liegt daher die Aufgabe zugrunde, das Ver­fahren zur Herstellung von Druckgasbehältern aus auste­nitischen Stählen durch Kryoverformung so zu verbessern, daß es weder die bei gleichzeitiger Verwendung des Kühl­mittels als Druckmittel genannten Nachteile aufweist, noch die bei Verwendung eines eigenen Druckmittels be­schriebenen Schwierigkeiten auftreten.The invention is therefore based on the object of improving the process for producing pressurized gas containers from austenitic steels by cryogenic shaping in such a way that it does not have the disadvantages mentioned when the coolant is simultaneously used as the pressurizing medium, nor does the difficulties described when using its own pressurizing medium occur.

Ausgehend von dem im Oberbegriff des Anspruches 1 be­rücksichtigten Stand der Technik ist diese Aufgabe er­findungsgemäß gelöst mit den im kennzeichnenden Teil des Anspruches 1 angegebenen Merkmalen.Starting from the prior art taken into account in the preamble of claim 1, this object is achieved according to the invention with the features specified in the characterizing part of claim 1.

Eine vorteilhafte Weiterbildung der Erfindung ist im Unteranspruch angegeben.An advantageous development of the invention is specified in the subclaim.

Das gemäß der Erfindung verwendete Trichlorfluormethan CFCl₃, welches als Kältemittel unter der Bezeichnung R11 bekannt ist, besitzt Eigenschaften, die seinen Ein­satz als separates, vom Kühlmittel unabhängiges Druck­mittel ermöglichen, obwohl dies aufgrund des Temperatur­bereiches, in dem es als Flüssigkeit vorliegt, eigentlich nicht zu erwarten ist.The trichlorofluoromethane CFCl₃ used according to the invention, which is known as a refrigerant under the designation R11, has properties that enable its use as a separate pressure medium that is independent of the coolant, although this is not actually to be expected due to the temperature range in which it is present as a liquid is.

Trichlorfluormethan erstarrt bei einer Temperatur, die wegen der zweckmäßigen Verwendung von flüssigem Stick­stoff als Kühlmittel deutlich über der Temperatur liegt, bei der das Kryostrecken durchgeführt wird.Trichlorofluoromethane solidifies at a temperature which, because of the expedient use of liquid nitrogen as the coolant, is clearly above the temperature at which the cryogenic stretching is carried out.

Bei Raumtemperatur ist es flüssig, so daß es mit einer normalen hydraulischen Pumpe in den zu verformenden Behälter gepreßt werden kann. Daß es diesen Aggregat­zustand während des Kryostreckvorganges beibehalten kann, obwohl der zu verformende Behälter von außen mit flüssigem Stickstoff gekühlt wird, verdankt es seiner, im Vergleich zum Stahl, geringen Wärmeleitfähigkeit und großen spezifischen Wärme. λ Stahl (-196 °C) ∼ 6 [W/mK];λ CFCL₃(-120 °C)<O.2 [W/mK]
cp Stahl (-196 °C)=0.15 [J/gk];cp CFCl₃(-120 °C)=0.79[J/gK]
It is liquid at room temperature so that it can be pressed into the container to be deformed using a normal hydraulic pump. The fact that it can maintain this state of matter during the cryostressing process, even though the container to be deformed is cooled from the outside with liquid nitrogen, is due to its low thermal conductivity and high specific heat compared to steel. λ steel (-196 ° C) ∼ 6 [W / mK]; λ CFCL₃ (-120 ° C) <O.2 [W / mK]
cp steel (-196 ° C) = 0.15 [J / gk]; cp CFCl₃ (-120 ° C ) = 0.79 [J / gK]

Durch diese Eigenschaften wird ein schneller Temperatur­ausgleich zwischen der von außen gekühlten Behälterwand und dem Druckmedium im Behälter verhindert.These properties prevent rapid temperature compensation between the externally cooled container wall and the pressure medium in the container.

Neben Trichlorfluormethan sind prinzipiell auch noch andere Fluorchlorkohlenwasserstoffe wie Dichlorfluor­methan (CCl₂F₂, R12) und Chlortrifluormethan (CClF₃, R 13) als Druckmedium zum Kryotrecken von Behältern geeignet. Allerdings haben diese den Nachteil, daß sie bei Raumtemperatur und normalem Umgebungsdruck nicht mehr als Flüssigkeit vorliegen, sondern unter erhöhtem Druck gehalten werden müssen.In addition to trichlorofluoromethane, other chlorofluorocarbons such as dichlorofluoromethane (CCl₂F₂, R12) and chlorotrifluoromethane (CClF₃, R 13) are also suitable as pressure medium for cryogenic stretching of containers. However, these have the disadvantage that they are no longer present as a liquid at room temperature and normal ambient pressure, but must be kept under increased pressure.

Die Zeichnung veranschaulicht als Ausführungsbeispiel eine Einrichtung zur Durchführung des erfindungsgemäßen Verfahrens in schematischer Form.As an exemplary embodiment, the drawing illustrates a device for carrying out the method according to the invention in schematic form.

Der zu verformende Druckgasbehälter 1 befindet sich in einer isolierten Kühlkammer 2, in welcher er auf die für die Martensitbildung erforderliche Temperatur abgekühlt wird. Als Kühlmittel dient flüssiger Stickstoff, der durch die Leitung 3 und Düsen 4 in die Kühlkammer 2 eingesprüht wird, wo er verdampft. Die erreichte Tempe­ratur wird durch das Thermometer 5 angezeigt. Erfindungs­gemäß wird der erforderliche Verformungsdruck mit CFCl₃ als Druckmittel aufgebracht, welches einem Reservoir 6 entnommen und mittels der Pumpe 7 über die Leitung 8 in das Innere des Behälters 1 gedrückt wird. Der Druck wird durch das Manometer 9 angezeigt.The compressed gas container 1 to be deformed is located in an insulated cooling chamber 2, in which it is cooled to the temperature required for the formation of martensite. Liquid nitrogen, which flows through the line 3 and nozzles 4 into the cooling chamber 2, serves as the coolant is sprayed where it evaporates. The temperature reached is indicated by the thermometer 5. According to the required deformation pressure is applied with CFCl₃ as a pressure medium, which is removed from a reservoir 6 and pressed by means of the pump 7 via the line 8 into the interior of the container 1. The pressure is indicated by the manometer 9.

Der gefüllte Druckgasbehälter 1 ist mit einem lösbaren, druckdichten Verschluß 10 verschlossen und über eine bis in die Behältermitte ragendes Füllrohr 11 mit der Pumpe 7 und der Leitung 8 verbunden. Am Eintritt in den Druckgasbehälter 1 besitzt das Füllrohr 11 eine ther­mische Isolierung 12, die ein Einfrieren des Druckmittels verhindert. Die für die Durchführung des erfindungsge­mäßen Verfahrens erforderlichen Sicherheitsvorkehrungen gehen über das bei routinemäßig durchgeführten Wasser­druckprüfungen von Behältern übliche Maß nicht hinaus.The filled pressurized gas container 1 is closed with a releasable, pressure-tight closure 10 and connected to the pump 7 and the line 8 via a filling pipe 11 which extends into the middle of the container. At the entry into the compressed gas container 1, the filling pipe 11 has thermal insulation 12 which prevents the pressure medium from freezing. The safety precautions required to carry out the method according to the invention do not go beyond what is customary for routinely carried out water pressure tests on containers.

Da CFCl₃ eine deutlich geringere Wärmeleitfähigkeit als der Behälterstahl besitzt, kann während des Verformungs­prozesses nur eine mit der Behälterinnenoberfläche un­mittelbar in Berührung kommende Randschicht erstarren. Es ist daher auch möglich, die Kühlkammer 2 durch ein mit flüssigem Stickstoff gefülltes Dewargefäß zu er­setzen, in welches der Behälter 1 eintaucht. Das erfin­dungsgemäße Verfahren kann selbst unter diesen extremen Bedingungen durchgeführt werden, sofern man darauf achtet, daß der Behälter 1 nicht länger als während der für die Verformung erforderlichen Zeit in den flüssigen Stick­stoff eintaucht.Since CFCl₃ has a significantly lower thermal conductivity than the container steel, only an edge layer that comes into direct contact with the inner surface of the container can solidify during the deformation process. It is therefore also possible to replace the cooling chamber 2 with a Dewar vessel filled with liquid nitrogen, into which the container 1 is immersed. The process according to the invention can be carried out even under these extreme conditions, provided that care is taken that the container 1 is not immersed in the liquid nitrogen for longer than the time required for the deformation.

Claims (2)

1. Verfahren zur Herstellung eines Druckgasbehälters (1) aus austenitischen Stählen durch Kryoverformung, bei dem der Druckgasbehälter durch ein tiefkaltes Kühl­mittel unter die jeweilige Martensitumwandlungstempe­ratur (Md; Ms) abgekühlt und durch Einleiten eines Druckmittels in das Behälterinnere zur gewünschten Größe aufgeweitet wird,
dadurch gekennzeichnet,
daß als Druckmittel Trichlorfluormethan (CFCl₃) ver­wendet wird.
1. A process for producing a pressurized gas container (1) from austenitic steels by cryoforming, in which the pressurized gas container is cooled below the respective martensite transformation temperature (Md; Ms) by a cryogenic coolant and expanded to the desired size by introducing a pressure medium into the interior of the container,
characterized,
that trichlorofluoromethane (CFCl₃) is used as pressure medium.
2. Verfahren nach Anspruch 1,
dadurch gekennzeichnet,
daß die Abkühlung durch Stickstoff erfolgt.
2. The method according to claim 1,
characterized,
that the cooling is done by nitrogen.
EP88109402A 1987-08-13 1988-06-14 Method of making a gas pressure vessel of austenitic stainless steel by cryogenic forming Expired - Lifetime EP0303016B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT88109402T ATE68527T1 (en) 1987-08-13 1988-06-14 PROCESS FOR THE MANUFACTURE OF A COMPRESSED GAS TANK FROM AUSTENITIC STEELS BY CRYEOFORMING.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19873726960 DE3726960A1 (en) 1987-08-13 1987-08-13 METHOD FOR PRODUCING A COMPRESSED GAS CONTAINER FROM AUSTENITIC STEELS BY CRYFORMING
DE3726960 1987-08-13

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Publication Number Publication Date
EP0303016A1 true EP0303016A1 (en) 1989-02-15
EP0303016B1 EP0303016B1 (en) 1991-10-16

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US (1) US4846900A (en)
EP (1) EP0303016B1 (en)
JP (1) JPS6465230A (en)
AT (1) ATE68527T1 (en)
DE (1) DE3726960A1 (en)

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EP0840054A2 (en) * 1996-11-04 1998-05-06 Messer Griesheim Gmbh Composite container for gases
WO2012175499A3 (en) * 2011-06-22 2013-02-21 Mt Aerospace Ag Pressure vessel for receiving and storing cryogenic fluids, in particular cryogenic liquids, methods for producing said pressure vessel, and use of said pressure vessel

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DE102011105426B4 (en) 2011-06-22 2013-03-28 Mt Aerospace Ag Pressure vessel for receiving and storing cryogenic fluids, in particular cryogenic fluids, and method for its production and its use
DE102017204240A1 (en) * 2017-03-14 2018-09-20 Robert Bosch Gmbh Fuel tank for a fuel cell system and method of manufacturing a fuel tank
CN109500195B (en) * 2018-11-19 2019-11-29 大连理工大学 A kind of special tubes and pipes of aluminium alloy part ultralow temperature pressure medium manufacturing process
CN113106207B (en) * 2021-04-20 2022-09-02 吉安锐迈管道配件有限公司 Quenching cooling device and process for ultralow-temperature 9Ni steel heat treatment

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EP0840054A3 (en) * 1996-11-04 1998-11-04 Messer Griesheim Gmbh Composite container for gases
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Also Published As

Publication number Publication date
EP0303016B1 (en) 1991-10-16
US4846900A (en) 1989-07-11
DE3726960A1 (en) 1989-02-23
ATE68527T1 (en) 1991-11-15
JPS6465230A (en) 1989-03-10

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