EP0283314A2

EP0283314A2 - Developer sheet and imaging set and imaging process utilising same

Info

Publication number: EP0283314A2
Application number: EP88302418A
Authority: EP
Inventors: Paul C. Adair; Cheryl Lynn Moore
Original assignee: Mead Corp
Current assignee: Mead Corp
Priority date: 1987-03-18
Filing date: 1988-03-18
Publication date: 1988-09-21
Also published as: KR880011621A; US4772532A; JPS63297089A; CN88101406A; EP0283314A3

Abstract

A developer sheet having reduced tack useful in forming reproductions having a controllable gloss finish or in forming transparencies is provided. The developer sheet has a support with a layer on the surface of the support of a finely divided thermoplastic developer material and a non-reactive, non-scattering pigment. The developer material is capable of reacting with a color precursor to produce a visible image while the pigment reduces tack. Both the developer material and the pigment are capable of forming an essentially transparent film upon the application of heat and/or pressure.

Description

The present invention relates to a developer sheet, to an imaging set comprising an imaging sheet and the developer sheet, and to a process for imaging.
Photosensitive imaging systems employing microencapsulated radiation sensitive compositions are described in our U. S. Patents 4,399,209 and 4,416,966 and in our British Patent Specification 2112536. These imaging systems are characterised in that an imaging sheet including a layer of microcapsules containing a photohardenable or photosoftenable photosensitive composition in the internal phase is image-wise exposed to actinic radiation. In the most typical embodiments, the photosensitive composition is a photopolymerizable composition including a polyethylenically unsaturated compound and a photoinitiator and is encapsulated with a colour precursor. The exposure image-wise hardens the internal phase of the microcapsules. Following exposure, the imaging sheet is subjected to a uniform rupturing force by passing the sheet through the nip between a pair of pressure rollers. U. S. Patent 4,399,209 discloses a transfer system in which the imaging sheet is assembled with a developer sheet prior to being subjected to the rupturing force. Upon passing through the pressure rollers in contact with the developer sheet, the microcapsules image-wise rupture and release the internal phase whereupon the colour precursor migrates to the developer sheet where it reacts with a dry developer and forms a colour image. The imaging system can be designed to reproduce monochromatic or polychromatic full colour images.
Our U. S. Patent 4,554,235 describes an imaging system which is useful in producing high gloss images and is characterised in that the reactive surface of the developer sheet is overcoated with a discontinuous layer of a thermoplastic polymeric pigment. Images are formed as described in U. S. Patents 4,399,209 and 4,416,966. After development, the developer sheet is heated to coalesce the thermoplastic pigment and form a thin uniform layer which imparts gloss to the image.
Our European Patent Application 87307985.9 (published under No. ) describes a developer sheet which may be used to obtain glossy images and which obviates the need for a layer of thermoplastic pigment described in the aforementioned U. S. Patent 4,554,235. This sheet carries a layer of a finely divided thermoplastic developer resin such as a novolak. The developer layer is obtained from a dispersion of the resin in water. After transfer, the colour precursor reacts with the developer and the sheet is heated to melt the developer resin. Thereupon the finely divided particles coalesce into a thin, uniform film. By controlling the heating conditions, the degree of gloss can be controlled to give copies with finishes ranging from matte to high gloss.
While the developer sheets described in the aforementioned application are extremely advantageous, several problems have been encountered in designing sheets for commercial use. One problem is that the developer resins tend to be undesirably tacky. This tackiness results in the developer sheets being difficult to handle. For example, when the developer sheets are stacked, there is a tendency for them to stick to one another. Also, when the developer sheets are fed into the processing equipment, the developer resin may soil paper handling rollers. Also, after the imaged developer sheets are fused, the tendency to stick appears to increase. During any phase in the life of a developer sheet, if the tackiness problem is severe enough, the entire developer layer can be stripped from the developer sheet.
In the carbonless paper art, developer sheets prepared from novolak resins have been modified as described below to improve their performance. In the past, finely divided developer resins have been obtained by grinding a mixture of a developer such as a phenolic resin or a zinc salicylate with another resin and clay to produce a resin grind which is applied to the surface of the developer sheet. For example, U. S. Patent 3,924, 027 discloses a composition including a zinc salicylate, polystyrene, and kaolin.
One approach to improving the handling characteristics of developer sheets is to incorporate a stilt material such as starch particles as described in our U. S. Patents 4,399,209 and 4,440,846.
U. S. Patent 4,470,058 teaches a two-coat record sheet for printing by xerographic methods wherein the nonreactive topcoat eliminates the accumulation of contaminants on the fuser roll of copier/duplicators. The record sheet has a base coat comprising phenolformaldehyde novolak resin and a topcoat comprising a nonreactive pigment material. The reference discloses that the preferred nonreactive pigments are such materials as kaolin clay, calcium carbonate and calcined kaolin clay.
Our U. S. Patent 3,617,410 describes a record sheet having improved resistance to smudging wherein the base sheet is coated with a composition comprising a finely powdered, oil-soluble, acid-reactant, polymeric material such as a novolak resin, a substantially nonreactive pigment such as talc, clay or colloidal silica and a binder.
U. S. Patent 4,422,670 describes a developing sheet designed for high speed printing so as to rapidly set the printing ink containing a developing layer consisting of a colour developing agent, calcium carbonate and styrene-butadiene copolymer latex or modified styrene-butadiene copolymer latex of an average particle size of less than 0.08 microns. The latex reduces pigment pick off. The combination is taught to result in an improvement in the water resistance, mark formation ability and printability of the pressure-sensitive recording paper.
We have now found that is possible to provide a developer sheet having reduced tack and which is useful in forming reproductions having a controlled gloss finish or in forming transparencies.
In accordance with a first aspect of the present invention, we provided a developer sheet characterised in having reduced tack and a controlled gloss finish having been prepared by subjecting to heat and/or pressure a support having a layer on the surface of said support of a finely divided thermoplastic developer material and a non-reactive, non-scattering thermoplastic pigment, said developer material being capable of reacting with a colour precursor to produce a visible image, said pigment reducing the tack of said developer layer, and said heat and/or pressure being applied such that said developer material and said pigment form an essentially transparent film upon the application of the said heat and/or pressure.
The invention also provides, in this first aspect thereof, an imaging set comprising an imaging sheet and a developer sheet as above described, the imaging sheet including a support having a layer of photosensitive microcapsules on the surface thereof, said microcapsules containing a photohardenable or photosoftenable composition in the internal phase and having a colour precursor associated therewith.
The term "non-reactive" means that the pigment is not a developer, i.e., it does not react with the colour precursor to produce colouration.
The term "non-scattering" as used herein with respect to the pigment means that the refractive index of the pigment is such that upon melting the developer material, an essentially transparent layer is obtained. In one preferred embodiment, the pigment is a thermoplastic material which melts and coalesces with the developer material upon heating.
In a second alternative aspect thereof, the invention provides an imaging set comprising an imaging sheet and a developer sheet; said imaging sheet having a layer of photosensitive microcapsules on the surface thereof, said microcapsules containing a photohardenable or photosoftenable photosensitive composition in the internal phase and having a colour precursor associated therewith; and being characterised in that said developer sheet includes a support having a layer on the surface of said support of a finely divided thermoplastic developer material and a non-reactive, non-scattering pigment, said developer material being capable of reacting with said colour precursor to produce a visible image, said pigment reducing the tack of said developer layer, and said developer material and said pigment both forming an essentially transparent film upon the application of heat and/or pressure.
In a third alternative aspect of this invention, we provide a process for imaging which comprises image-wise exposing to actinic radiation an imaging sheet including a support having a layer of microcapsules on the surface thereof, said microcapsules including a photohardenable or photosoftenable photosensitive composition as the internal phase and having a colour precursor material associated therewith;
subjecting said imaging sheet to uniform rupturing force such that said microcapsules rupture and release said internal phase in accordance with said image-wise exposure;
In such an imaging set it is not essential that the pigment be thermoplastic provided that it is wet by the thermoplastic material and rendered transparent upon heating.
and contacting said imaging sheet with a developer sheet;
characterised in that said developer sheet has reduced tack and includes a support having a layer on the surface of said support of a finely divided thermoplastic developer material and a non-reactive, non-scattering pigment, in that said developer material is capable of reacting with said colour precursor to produce a visible image, in that said pigment is effective to reduce the tack of said developer layer, in that said developer material and said pigment are adapted both to form an essentially transparent film upon the application of heat and/or pressure, in that said contacting step is conducted at the same time or immediately after subjecting said imaging sheet to said rupturing force; and in that said developer material is fused to form an essentially transparent film.
The applicants have found that the amount of developer material on the surface of the developer sheet can be reduced and replaced by a non-reactive, non-scattering pigment to reduce tack without sacrificing image density. Two factors which influence image density are developer reactivity and the void volume of the developer layer. If the developer material is highly reactive, the amount of developer material present on the developer sheet can be decreased if the void volume of the layer is maintained. It is believed that in the present arrangements, the pigment serves to reduce tack while maintaining sufficient void volume to produce a high density image. Thus, in addition to providing substantial cost savings due to the decreased amount of developer resin required and providing an image having good colour density, the present developer sheets eliminate or substantially reduce tack.
Imaging sets in accordance with the present invention include an imaging sheet carrying a layer of photosensitive microcapsules and a developer sheet. The imaging sheet, as well as the photosensitive compositions, photoinitiators, colour formers, wall formers, encapsulation techniques and development techniques described in U. S. Patent 4,399,209, the disclosure of which is herein incorporated by reference, are useful in the practise of the present invention. Preferred photosensitive compositions are described in European Patent Application 86308967.8 (Publication No. ).
The developer materials used in the present invention are finely divided reactive thermoplastic materials which are capable of reacting with a colour precursor and forming a colour image. Their melting points typically range from about 100 to 200°C, but those skilled in the art will appreciate that materials with higher and lower melting points may also be useful. The particle size is typically in the range of 0.5 to 25 microns.
A typical example of a thermoplastic developer material useful in the practise of the present invention is phenolic resins. Phenolic resins have been conventionally used as developer materials in carbonless, pressure-sensitive recording materials. These resins may be the condensation product of phenols which are preferably para-substituted and formaldehyde. The resins may be further modified to include amounts of salicylic acid or substituted salicylic acids in a manner known in the art. Examples of phenolic resins useful in the practise of the present invention are thermoplastic resins prepared according to the teachings in U. S. Patents 3,455,721; 3,466,184; 3,672,935; 4,025,490; and 4,226,962.
Another class of phenolic resin useful in the practise of the present invention is the products of oxidative coupling of substituted or unsubstituted phenols or biphenols such as the resins described in our European Patent Application No. 86308250.9 (Publication No. EP 0220943) the disclosure of which is to be regarded as incorporated herein by reference.
The phenolic developers useful in the practise of the present invention are usually metallated to improve their developing characteristics. They may be metallated by reaction with a salt such as an oxide or propionate of a metal selected from the group consisting of copper, zinc, aluminium, tin, cobalt and nickel. Most typically, the resins are zincated. The metal content of the resins generally is about 1 to 5% by weight but may range up to 15%.
Preferably phenol-formaldehyde condensation products are used as developer materials. More particularly, alkylphenolic resins and, still more particularly, metallated products of alkylphenolic resins are used. The alkylphenols are usually monosubstituted by an alkyl group which may contain 1 to 12 carbon atoms. Examples of alkylphenols are ortho- or para- substituted ethylphenol, propylphenol, butylphenol, amylphenol, hexylphenol, heptylphenol, octylphenol, nonylphenol, t-butylphenol, t-octylphenol, etc.
Another class of thermoplastic developer material is a resin-like condensation product of a polyvalent metal salt, and a phenol, a phenol- formaldehyde condensation product, or a phenol-salicylic acid-formaldehyde condensation product. One example of this developer material is available from Schenectady Chemical Co. under the designation HRJ 4250 and HRJ 4252. These products are reported to be a metallated condensation product of an ortho- or para-substituted alkylphenol, a substituted salicylic acid, and formaldehyde.
It is critical that the developer materials be present on the surface of the developer sheet as finely divided particles (preferably about 1 to 5 microns in size).
Finely divided thermoplastic developer material useful in the practice of the present invention may be obtained by several processes. A developer material can be prepared in a conventional manner and a melt of the material can be atomized. Alternatively, a melt of the developer material can be injected into a rapidly agitated aqueous medium whereupon the melt is solidified as droplets which are recovered. The developer material can also be dissolved in a solvent/non-solvent system and the solvent removed. Other materials such as Schenectady HRJ 4250 and HRJ 4252 are obtained in a dispersed form. Other methods of forming aqueous emulsions of developer resins are described in U.S. Patent 4,612,254.
The pigments used in the present invention to reduce tack are non-scattering pigments. The refractive index of the pigment should be approximately the same as that of the developer material.
Examples of non-melting pigments are coating clays (such as Kaolin), silica, alumina, and talc.
While non-melting pigments can be used, the preferred pigments are non-reactive thermoplastic pigments, and preferably have a melting point similar to the melting point of the developer material and are capable of being fused with the developer material to form an essentially transparent film upon the application of heat or pressure. Typical examples of useful thermoplastic pigments include thermoplastic polymer pigments, latices and wax particles.
The pigment preferably has a particle size in the range of about 0.5 to 25 microns, and more preferably, about 1 to 10 microns and a melting point less than about 200°C.
The amount of the pigment mixed with the developer material is a function of the nature of the pigment, its particle size and the developer reactivity. Typically the pigment is employed in an amount of about 0.1 to 1.0 parts by weight per 1 part by weight developer material.
Typical examples of useful pigments are pigments obtained upon drying such as Dow XD 899301 latex, Dow 722 latex, Dow 788 latex, products of Dow Chemical Co., UCAR 4630x latex, UCAR 4510 latex, styrene-acrylic latices of Union Carbide Corp., polyvinyl acetate emulsion 202A, a product of Union Oil Company of California, polystyrene latices 5611 and 5612, products of Union Oil Co. of California, Polysar 1183, Polysar 9010-P and Polysar 1164, polystyrene latices of Polysar Latex Co., acrylic latex 200, a product of Union Oil Co. of California, polyvinylidene chloride latices 542 and MS-153, products of Union Oil Co. of California, Casco wax, a wax emulsion from Borden Co., and Paraco, a wax emulsion from Hercules Chemical Co.
To prepare the developer sheet, the developer material can be mixed with the pigment and coated on a support in a conventional manner. In most cases, aqueous emulsions or dispersions of the developer material and the pigment will simply be mixed. Coating methods such as doctor blade coating, wire wound bar coating, roll coating etc. may be used. For transparencies, transparent substrates such as a polyester film which is commercially available as Mylar from E.I. Du Pont de Nemours & Co., Inc. may be used. Otherwise, paper may be used. The developer material and pigment are applied to the support in combined amounts of about 3 to 15 g/ sq.m.
In most cases, heat or a combination of heat and pressure is used to film out the developer material and the pigment. For example, after colour development in a photosensitive system, the developer material and pigment are filmed out by heating the developer sheet to a temperature above the melting point of the resin by contact with a heated roller or a pair of heated rollers or by the passage of the developer sheet over a heater platen. Alternatively, the developer sheet can be placed in a hot oven.
Preferably the developer sheet is heated after transferring the colour precursor to the surface of the developer sheet as opposed to simultaneously therewith. This enables the colour precursor to fully react with the developer material while its surface area is high and while the void volume of the developer layer is high and consequently better image density is obtained.
As previously indicated, imaging sheets useful in the practise of the present invention can be prepared by following the teachings in U.S. Patent 4,399,209.
Positive-working photosensitive compositions useful in the practise of the present invention usually include a photoinitiator in combination with a monomer, a dimer, or an oligomer which is polymerizable to a higher molecular weight compound, or a polymer which is crosslinked upon exposure. For a negative working material, a compound which is depolymerizable or otherwise photolyzable upon exposure may be used.
Ethylenically unsaturated organic compounds are useful photosensitive materials. These compounds contain at least one terminal ethylene group per molecule.
Typically, liquid ethylenically unsaturated compounds having two or more terminal ethylene groups per molecule are preferred.Examples of this preferred subgroup are ethylenically unsaturated acid esters of polyhydric alcohols such as ethylene glycol dimethacrylate, triethylene glycol dimethacrylate, trimethylolpropane triacrylate (TMPTA) and trimethyol propane trimethacrylate. Another example of a useful radiation sensitive composition is an acrylate prepolymer derived from the partial reaction of pentaerythritol with acrylic acid, methacrylic acid, or acrylic or methacrylic acid esters. Another group of substances useful as photosensitive compositions include isocyanate modified acrylic, methacrylic and itaconic acid esters of polyhydric alcohols.
Negative working imaging systems can be obtained by encapsulating photosoftenable compositions in the microcapsules. An example of a photosoftenable material that may be useful in the practise of the invention is polyaldehydes as described in U.S. Patents 4,108,839; 3,984,253; and 3,915,704; polycarbonates as described in Frecht et al., J. Imaging Science, 30 (2). p. 59 (1986); 3-oximino-2-butanone methacrylate which undergoes main chain scission upon U.V. exposure, poly 4ʹ-alkyl acylophenones, and certain resins having a quinone diazide residue. See Reichmanis, E.; Am. Chem. Soc. Div. Org. Coat. Plast. Chem. Prepr. 1980. 43, 243-251 and Lukac, I.; Chmela S., Int. Conf. on Modif. Polym. 5th Bratislave, Czech. July 3-6, 1979, I.U.P.A.C. Oxford, England 1979, 1, 176-182.
In most cases, the photosensitive composition includes a photoinitiator. It is possible to use either homolytic photoinitiators which are converted to an active species by radiation and generate a radical by abstracting a hydrogen from a hydrogen donor, or photoinitiators which complex with a sensitizer to produce a free radical generating species, or photoinitiators which otherwise generate radicals in the presence of a sensitizer. If the system relies upon ionic polymerization, the photoinitiator may be the anion or cation generating type, depending on the nature of the polymerization.
Examples of photoinitiators useful in the present invention include diaryl ketone derivatives, and benzoin alkyl ethers. The photoinitiator is selected based on the sensitivity of the system that is desired. Where ultraviolet sensitivity is desired, suitable photoinitiators include alkoxy phenyl ketones, O-acylated oximinoketones, polycyclic quinones, benzophenones and substituted benzophenones, xanthones, thioxanthones, halogenated compounds such as chlorosulphonyl and chloromethyl polynuclear aromatic compounds, chlorosulphonyl and chloromethyl heterocyclic compounds, chlorosulphonyl and chloromethyl benzophenones and fluorenones, and haloalkanes. In many cases, it is advantageous to use a combination of imaging photoinitiators.
For visible light sensitivity, see our European Patent Application No. 86308967.8 (Publication No. ).
The amount of photoinitiator used in the photosensitive composition depends on the particular photosensitive material selected. It must be present in an amount sufficient to initiate the photochemistry within a short exposure time. The photoinitiator may be used to sequester oxygen which is present in the microcapsules and inhibits photopolymerization by conducting a non-imaging, oxygen sequestering pre-exposure or co-exposure. When the photoinitiator is also relied upon for sequestering oxygen, it must be used in amounts sufficient to fulfill both this function and its imaging function.
It is possible to use various compounds as chromogenic materials in the practise of the present invention. If the chromogenic material is encapsulated with the photosensitive composition, it should not interfere with the sensitivity of the system. One example of a chromogenic material useful in the practise of the invention is colourless electron donating compounds. Representative examples of such colour precursors include substantially colourless compounds having in their partial skeleton a lactone, a lactam, a sultone, a spiropyran, an ester or an amido structure such as triarylmethane compounds, bisphenylmethane compounds, xanthene compounds, fluorans, thiazine compounds, spiropyran compounds and the like. Crystal Violet Lactone and Copikem X, IV and XI (products of Hilton-Davis Co.) are often used alone or in combination as colour precursors in practise of the present invention.
Images can also be formed by encapsulating a chelating agent, as a chromogenic material, which reacts with a metal salt, as a developer, to generate a colour image upon being released from the microcapsules. Some typical examples of useful image-forming pairs of this type are nickel nitrate and N,Nʹ bis(2-octanoyloxethyl)dithiooxamide, and alum [Fe(III)] and yellow prussiate.
The internal phase may also include an oil. Inclusion of the oil will often improve half tone gradation. Examples of carrier oils are alkylated biphenyls (e.g., monoisopropylbiphenyl), polychlorinated biphenyls, castor oil, mineral oil, deodourized kerosene, naphthenic mineral oils, dibutyl phthalate, dibutyl fumerate, brominated paraffin and mixtures thereof. Alkylated biphenyls are generally less toxic and preferred.
The photosensitive microcapsules useful in the practise of the present invention are easily formed using conventional techniques such as coacervation, liquid-liquid phase separation, interfacial polymerization and the like. Various melting, dispersing and cooling methods may also be used.
The photosensitive compositions are usually oleophilic and can be encapsulated in hydrophilic wall-forming materials such as gelatin-type materials (see U.S. Pat. Nos. 2,730,456 and 2,800,457 to Green et al.) including gum arabic, polyvinyl alcohol, carboxymethylcellulose; resorcinol-formaldehyde wall formers (see U.S. Pat. No. 3755,190 to Hart et al.); isocyanate wall-formers (see U.S. Pat. No. 3,914,511 to Vassiliades); isocyanate-polyol wall-formers (see U.S. Pat. No. 3,796,669 to Kirintani et al.); urea formaldehyde wall-formers, particularly urea-resorcinol-formaldehyde in which oleophilicity is enhanced by the addition of resorcinol (see U.S. Pat. Nos. 4,001,140; 4,087,376 and 4,089,802 to Foris et al.); and melamine-formaldehyde resin and hydroxylpropyl cellulose (see U. S. Patent No. 4,025,455 to Shackle).
Embodiments of developer sheet in accordance with the present invention are particularly useful in full colour imaging systems such as those described in our British Patent Specification 2,113,860 the disclosure of which is to be regarded as incorporated herein by reference. The microcapsules used in full colour imaging individually contain cyan, magenta and yellow colour precursors and photosensitive compositions having distinctly different sensitivities. A uniform mixture of the microcapsules is distributed over the surface of the support. Images are formed by separating the red, green and blue components of the image to be reproduced and, if necessary, translating these components into different wavelengths of actinic radiation to which the photosensitive compositions are distinctly sensitive. The photosensitive material is image-wise exposed to the translated radiation and thereafter it is subjected to a uniform rupturing force, such as pressure, which causes the microcapsules in the underexposed and unexposed areas to rupture and release the colour precursors. The colour precursors then react with the developer material to produce a full colour image.
The spectral sensitivity of photosensitive microcapsules is principally a function of the photoinitiator used in the encapsulated photosensitive composition. In order to design photosensitive microcapsules useful in full colour imaging having distinctly different spectral sensitivities, photoinitiators must be designed or selected which have mutually exclusive sensitivities in at least three distinct wavelength regions. That is, the photoinitiator used in a microcapsule containing a cyan color precursor must be substantially more sensitive in a wavelength region in which the photoinitiators used in the microcapsules associated with the magenta and yellow color precursors are subtantially less sensitive and ideally insensitive. Likewise, the photoinitiator used in the microcapsules containing the cyan color precursor must be subtantially less sensitive and ideally insensitive in a wavelength region in which the photoinitiators used in the microcapsules containing the magenta and yellor color precursors are preferentially sensitive. The sale considerations govern the selection of the initiators associated with the microcapsules containing the yellow and magenta color precursors. Of course, in a visible light sensitive system, initiators are selected which are selectively sensitive to red, green and blue light.
In addition to being useful in photosensitive systems of the type described above, the developer sheet of the present invention is also useful in conventional pressure-sensitive carbonless systems.
The present invention is illustrated in more detail by the following non-limiting examples:

Example 1

A coating mixture was prepared with the following composition: HRJ-4250 Developer Emulsion
(50% solids) a product of
Schenectady Chemical Co. 500g

Deionized water 210g
Borden Cascowax EW-403H 71g
This mixture of developer emulsion and wax emulsion was machine coated on 80 lb. Black and White glossy (a product of The Mead Corp.) with a #18 Meyer rod. A control coating was made with only the HRJ-4250 and water.
Monochrome cyan, magenta, and yellow capsule sheets prepared as described in our British Patent Specification No. 2,180,358, were exposed and developed against the test and control developer sheets. After heating at 150°C for one minute, a slight density gain was noted for the wax system, presumably due to a higher attained gloss. The fused wax sheet felt much less tacky than the developer-only developer sheet.

Example 2

The pH of Lytron 2705 latex (Morton Thiokol) was adjusted from 8.8 to 5.7 with 10% H₂SO₄ and diluted to 35% solids, HRJ-4250 at pH 5.7 was also adjusted to 35%. The two emulsions were mixed in the following ratios and then coated on PV Alcohol-subbed 3 mil Mylar ^R with a #24 Meyer bar and allowed to dry:
Standard cyan and magenta monochrome capsule sheets were developed against these sheets, the sheets were heated at 150°C for 60 seconds, and transmission densities measured as above.
Thus, even at a replacement of 50% of the developer spheres with Lytron, no appreciable density loss was noted. At this level, however, a slight haziness was evident in the transparency.

Claims

1. A developer sheet characterised in having reduced tack and a controlled gloss finish having been prepared by subjecting to heat and/or pressure a support having a layer on the surface of said support of a finely divided thermoplastic developer material and a non-reactive, non-scattering thermoplastic pigment, said developer material being capable of reacting with a colour precursor to produce a visible image, said pigment reducing the tack of said developer layer, and said heat and/or pressure being applied such that said developer material and said pigment form an essentially transparent film upon the application of the said heat and/or pressure.

2. A developer sheet according to Claim 1, further characterised in that said developer material is a phenolic resin, and preferably a phenol-formaldehyde resin.

3. A developer sheet according to any preceding claim, further characterised in that said pigment comprises wax particles, a thermoplastic latex or a thermoplastic polymer.

4. A developer sheet according to any preceding claim, further characterised in that said pigment and/or said developer material has a particle size generally in the range of 0.5 to 25 microns.

5. A developer sheet according to any preceding claim, further characterised in that said pigment and/or said developer material has a melting point of 200°C or less.

6. A developer sheet according to any preceding claim, further characterised in that said pigment is present in an amount of 0.1 to 1 parts by weight per 1 part by weight developer material.

7. An imaging set comprising an imaging sheet and a developer sheet; said imaging sheet including a support having a layer of photosensitive microcapsules on the surface thereof, said microcapsules containing a photohardenable or photosoftenable photosensitive composition in the internal phase and having a colour precursor associated therewith; and being characterised in that said developer sheet comprises a developer sheet according to any preceding claim.

8. A process for imaging which comprises image-wise exposing to actinic radiation an imaging sheet including a support having a layer of microcapsules on the surface thereof, said microcapsules including a photohardenable or photosoftenable photosensitive composition as the internal phase and having a colour precursor material associated therewith;
subjecting said imaging sheet to a uniform rupturing force such that said microcapsules rupture and release said internal phase in accordance with said image-wise exposure;
and contacting said imaging sheet with a developer sheet;
characterised in that said developer sheet has reduced tack and includes a support having a layer on the surface of said support of a finely divided thermoplastic developer material and a non-reactive, non-scattering pigment, in that said developer material is capable of reacting with said colour precursor to produce a visible image, in that said pigment is effective to reduce the tack of said developer layer, in that said developer material and said pigment are adapted both to form an essentially transparent film upon the application of heat and/or pressure, in that said contacting step is conducted at the same time or immediately after subjecting said imaging sheet to said rupturing force; and in that said developer material is fused to form an essentially transparent film.

9. A process according to Claim 8, further characterised in that said developer sheet comprises a developer sheet according to any of Claims 2 to 6.

10. An imaging set comprising an imaging sheet and a developer sheet; said imaging sheet having a layer of photosensitive microcapsules on the surface thereof, said microcapsules containing a photohardenable or photosoftenable photosensitive composition in the internal phase and having a colour precursor associated therewith; and being characterised in that said developer sheet includes a support having a layer on the surface of said support of a finely divided thermoplastic developer material and a non-reactive, non-scattering pigment, said developer material being capable of reacting with said colour precursor to produce a visible image, said pigment reducing the tack of said developer layer, and said developer material and said pigment both forming an essentially transparent film upon the application of heat and/or pressure.