EP0251419A1 - Fuel composition and additive concentrates, and their use in inhibiting engine coking - Google Patents
Fuel composition and additive concentrates, and their use in inhibiting engine coking Download PDFInfo
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- EP0251419A1 EP0251419A1 EP87201461A EP87201461A EP0251419A1 EP 0251419 A1 EP0251419 A1 EP 0251419A1 EP 87201461 A EP87201461 A EP 87201461A EP 87201461 A EP87201461 A EP 87201461A EP 0251419 A1 EP0251419 A1 EP 0251419A1
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- composition
- hydrocarbyl
- coking
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- fuel
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/228—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen double bond, e.g. guanidines, hydrazones, semicarbazones, imines; containing at least one carbon-to-nitrogen triple bond, e.g. nitriles
- C10L1/2283—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen double bond, e.g. guanidines, hydrazones, semicarbazones, imines; containing at least one carbon-to-nitrogen triple bond, e.g. nitriles containing one or more carbon to nitrogen double bonds, e.g. guanidine, hydrazone, semi-carbazone, azomethine
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
- C10L1/231—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B3/00—Engines characterised by air compression and subsequent fuel addition
- F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition
Definitions
- Typical olefins include cracked wax olefins, linear alpha olefins, branched chain alpha olefins, polymers and copolymers of lower olefins. These include polymers of ethylene, propylene, isobutylene, 1-hexene, 1-decene and the like.
- Useful copolymers are ethylene-propylene copolymers, ethylene-isobutylene copolymers, propylene-isobutylene copolymers, ethylene-1-decene copolymers and the like.
- the polyalkylene amine is a polyethyleneamine containing 2-6 ethyleneamine units. These are represented by the above formula in which R is the group -CH2CH2- and n has a value of 2-6.
- Such fluids in addition to resulting in great convenience in storage, handling, transportation, blending with fuels, and so forth, also are potent concentrates which serve the function of inhibiting or minimizing the coking characteristics of compression ignition distillate fuels used to operate indirect compression ignition engines.
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
- (a) hydrocarbyl-substituted succinimide or succinamide.
- (b) hydrocarbyl amine having from 3 to 60 carbons and from 1 to 10 nitrogens, and
- (c) N,Nʹ-disalicylidene-1,2-diaminopropane.
Description
- The invention relates to compression ignition fuel compositions and additive mixtures of hydrocarbyl-substituted succinimide or succinamide, hydrocarbyl amine and N,Nʹ-disalicylidene-1,2-diaminopropane in amounts sufficient to resist the coking tendencies of compression ignition fuel compositions when used in the operation of indirect injection diesel engines.
- Throttling diesel nozzles have recently come into widespread use in indirect injection automotive and light-duty diesel truck engines, i.e., compression ignition engines in which the fuel is injected into and ignited in a prechamber or swirl chamber. In this way, the flame front proceeds from the prechamber into the larger compression chamber where the combustion is completed. Engines designed in this matter allow for quieter and smoother operation. The Figure of the Drawing illustrates the geometry of the typical throttling diesel nozzle (often referred to as the "pintle nozzle").
- Unfortunately, the advent of such engines has given rise to a new problem, that of excessive coking on the critical surfaces of the injectors that inject fuel into the prechamber or swirl chamber of the engine. In particular, and with reference to the accompanying Figure, the carbon tends to fill in all of the available corners and surfaces of the obturator 10 and the
form 12 until a smooth profile is achieved. The carbon also tends to block the drilledorifice 14 in theinjector body 16 and fill up to theseat 18. In severe cases, carbon builds up on theform 12 and the obturator 10 to such an extent that it interferes with the spray pattern of the fuel issuing from around the perimeter oforifice 14. Such carbon build up or coking often results in such undesirable consequences as delayed fuel injection, increased rate of fuel injection, increased rate of combustion chamber pressure rise, and increased engine noise, and can also result in an excessive increase in emission from the engine of unburned hydrocarbons. - While low fuel cetane number is believed to be a major contributing factor to the coking problem, it is not the only relevant factor. Thermal and oxidative stability (lacquering tendencies), fuel aromaticity, and such fuel characteristics as viscosity, surface tension and relative density have also been indicated to play a role in the coking problem.
- An important contribution to the art would be a fuel composition which has enhanced resistance to coking tendencies when employed in the operation of indirect injection diesel engines.
- In accordance with one of its aspects, this invention provides distillate fuel for indirect injection compression ignition engines containing a combination of (a) hydrocarbyl-substituted succinimide or succinamide, (b) hydrocarbylamine having from 3 to 60 carbons and from 1 to 10 nitrogens and (c) N,Nʹ-disalicylidene-1, 2-diaminopropane, said combination being present in an amount sufficient to suppress and preferably to minimize coking, especially throttling nozzle coking, in the prechambers or swirl chambers of indirect injection compression ignition engines operated on such fuel.
- Included in the invention is additive fluid concentrate for use in distillate fuels and which contains a combination as defined above.
- Since the invention also embodies the operation of an indirect injection compression ignition engine in a manner which results in reduced coking, a still further embodiment of the present invention is a method of inhibiting coking, especially throttling nozzle coking, in the prechambers or swirl chambers of an indirect injection compression ignition engine, which comprises supplying said engine with a distillate fuel containing a combination as defined above, said combination being present in an amount sufficient to suppress and preferably to minimize such coking in an engine operated on such fuel.
- A feature of this invention is that the combination of additives utilized in its practice is capable of suppressing coking tendencies of fuels used to operate indirect injection compression ignition engines. Such behavior was exhibited in a series of standard engine dynamometer tests conducted as described in the Example hereinafter.
- The hydrocarbyl-substituted succinimides, component (a) of the fuels of this invention, are well known. They are readily made by first reacting an olefinically unsaturated hydrocarbon of the desired molecular weight with maleic anhydride to form a hydrocarbyl-substituted succinic anhydride. Reaction temperatures of 100-250°C are used. With higher boiling olefinically-unsaturated hydrocarbons, good results are obtained at 200-250°C. This reaction can be promoted by the addition of chlorine. Typical olefins include cracked wax olefins, linear alpha olefins, branched chain alpha olefins, polymers and copolymers of lower olefins. These include polymers of ethylene, propylene, isobutylene, 1-hexene, 1-decene and the like. Useful copolymers are ethylene-propylene copolymers, ethylene-isobutylene copolymers, propylene-isobutylene copolymers, ethylene-1-decene copolymers and the like.
- Hydrocarbyl substituents have also been made from olefin terpolymers. Very useful products have been made from ethylene-C3-12 alpha olefin - C5-12 nonconjugated diene terpolymers; such as ethylene-propylene-1,4-hexadiene terpolymer; ethylene-propylene-1,5-cyclooctadiene terpolymer; ethylene-propylene-1,5-cyclooctadiene terpolymer; ethylene-propylene-norbornene terpolymers and the like.
- Of the foregoing, by far the most useful hydrocarbyl substituents are derived from butene polymers, especially polymers of isobutylene.
- The molecular weight of the hydrocarbyl substituent can vary over a wide range. It is desirable that the hydrocarbyl group have a molecular weight of at least 500. Although there is no critical upper limit, a preferred range is 500-500,000 number average molecular weight. The more preferred average molecular weight is 700-5,000 and most preferably 900-3,000.
- Hydrocarbyl-substituted succinimides and succinamides are made by reaction of the desired hydrocarbyl-substituted succinic anhydride with an amine having at least one reactive hydrogen atom bonded to an amine nitrogen atom. Examples of these are methyl amine, dimethyl amine, n-butyl amine, di-(n-dodecyl) amine, N-(aminoethyl) piperidine, piperazine, N-(3-aminopropyl) piperazine, and the like.
- Preferably, the amine has at least one reactive primary amine group capable of reacting to form the preferred succinimides. Examples of such primary amines are n-octyl amine, N,N-dimethyl-1,3-propane diamine, N-(3-aminopropyl) piperazine, 1,6-hexane diamine, and the like.
- Hydroxyalkyl amines can also be used to make the succinimide-succinamide components of the invention which contain some ester groups. These amines include ethanol amine, diethanol amine, 2-hydroxypropyl amine, N-hydroxyethyl ethylenediamine and the like. Such hydroxyalkyl amines can be made by reacting a lower alkylene oxide, such as ethylene oxide, propylene oxide or butylene oxide with ammonia or a primary or secondary amine such as ethylene diamine, dethylene triamine, triethylene tetramine, tetraethylenepentamine and the like.
- A more preferred class of primary amines used to make the succinimide, succinamide or mixtures thereof are the polyalkylene amines. These are polyamines and mixtures of polyamines which have the general formula
H₂N R - NH nH
wherein R is a divalent aliphatic hydrocarbon group having 2-4 carbon atoms and n is an integer from 1-10 including mixtures of such polyalkylene amines. - In a highly preferred embodiment, the polyalkylene amine is a polyethyleneamine containing 2-6 ethyleneamine units. These are represented by the above formula in which R is the group -CH₂CH₂- and n has a value of 2-6.
- The amine used to make the succinimide, succinamide or mixture thereof need not be all amine. A mono or poly-hydroxyalcohol may be included in the reaction. Such alcohols can be reacted concurrently with the amine or the two alcohol and amine may be reacted sequentially. Useful alcohols are methanol, ethanol, n-dodecanol, 2-ethyl hexanol, ethylene glycol, propylene glycol, diethylene glycol, 2-ethoxy ethanol, trimethylol propane, pentaerythritol, dipentaerythritol and the like.
- Useful amine-alcohol products are described in U.S. 3,184,474; U.S. 3,576,743; U.S. 3,632,511; U.S. 3,804,763; U.S. 3,836,471; U.S. 3,936,480; U.S. 3,948,800; U.S. 3,950,341; U.S. 3,957,854; U.S. 3,957,855; U.S. 3,991,098; U.S. 4,071,548 and U.S. 4,173,540.
- The reaction between the hydrocarbyl-substituted succinic anhydride and the amine can be carried out by mixing the components and heating the mixture to a temperature high enough to cause a reaction to occur but not so high as to cause decomposition of the reactants or products or the anhydride may be heated to reaction temperature and the amine added over an extended period. A useful temperature is 100-250°C. Best results are obtained by conducting the reaction at a temperature high enough to distill out water formed in the reaction.
- A preferred succinimide-succinamide component is available as an article of commerce from the Edwin Cooper Company under the designation HITEC® E-644. This product comprises a mixture of active ingredients and solvent. Thus, when HITEC® E-644 is used as component (b) in formulating the fuels of this invention, the product as received should be used at a concentration of at least about 40 PTB (pounds per thousand barrels) - 0.11436 grams per liter - to insure that the finished blend contains an adequate quantity of the foregoing succinimide-succinamide ingredient although smaller amounts may be successfully employed.
- It is not believed that there is anything critical as regards the maximum amount of component (a) used in the fuel. Thus, the maximum amount of this component will probably be governed in any given situation by matters of choice and economics.
- While a variety of hydrocarbyl amines may be used in the fuel compositions of this invention, a primary aliphatic amine, the aliphatic group of which is tertiary, e.g., an amine of the formula:
R-NH₂
wherein R is one or a mixture of tertiary aliphatic groups containing 8 to 18 or more (preferably 12-16) carbon atoms is preferred. Most preferably, these tertiary aliphatic groups are tertiary alkyl groups. It is also preferred that hydrocarbyl amine component (c) include in addition to the above-depicted amine one or more hydrocarbyl amines differing therefrom. - U.S. Pat. No. 3,909,215 gives a description of the various hydrocarbyl amines having from 3 to 60 carbons and from 1 to 10 nitrogens which may be employed in the fuels of this invention. A few additional examples of desirable amines include 2,6-di-tert-butyl-α-dimethylamino-p-cresol, N-cyclohexyl-N,N-dimethylamine, and N-alkyl,N,N-dimethylamines in which the alkyl group is one or a combination of alkyl groups preferably having 8 to 18 or more carbon atoms.
- A particularly preferred hydrocarbyl amine is available commercially from the Rohm and Haas Company under the designation Primene 81R. The Primene 81R is believed to be a mixture of primary aliphatic amines in which the aliphatic groups are predominantly C₁₂ and C₁₄ tertiary alkyl groups.
- The fuels of this invention should contain at least 1.5 to 40 PTB (0.00429 to 0.1143 grams/liter) of component (b), the hydrocarbyl amine.
- The metal deactivator N,Nʹ-disalicylidene-1,2-diaminopropane (c) is also included in the combination. This compound (80 weight percent active compound in 20 weight percent toluene solvent) is available as an article of commerce from Ethyl Corporation under the designation "Ethyl" MDA.
- The fuels of this invention should contain at least 0.2 to 5 PTB (0.00572 to 0.012 grams per liter) of component (c), the metal deactivator, preferably N.Nʹ-disalicylidene-1,2-diaminopropane.
- The coking-inhibiting components (a), (b) and (c) of the invention can be added to the fuels by any means known in the art for incorporating small quantities of additives into distillate fuels. Components (a), (b) and (c) can be added separately or they can be combined and added together. It is convenient to utilize additive fluid mixtures which consist of hydrocarbyl-substituted succinimide-succinamide agents, hydrocarbylamine and N,Nʹ-disalicylidene-1,2-diaminopropane. These additive fluid mixtures are added to distillate fuels. In other words, part of the present invention are coking inhibiting fluids which comprise hydrocarbyl-substituted succinimide-succinamide, hydrocarbyl amine having from 3 to 60 carbons and 1 to 10 nitrogens, and metal deactivator, preferably N,Nʹ-disalicylidene-1,2-diaminopropane.
- In these fluid compositions, the amount of components (a), (b) and (c) can vary widely. In general, the fluid compositions contain 10 to 97.9% by weight of the hydrocarbyl-substituted succinimide-succinamide component, 20 to 75% by weight of the hydrocarbyl amine and 0.1 to 15% by weight metal deactivator. Typically, from 0.01% by weight up to 1.0% by weight of the combination will be sufficient to provide good coking-inhibiting properties to the distillate fuel. A preferred distillate fuel composition contains from 0.1 to 0.5% by weight of the combination containing from 50% to 97.9% by weight of the hydrocarbyl succinimide-succinamide component and from 2.0% to 45% by weight of the hydrocarbyl amine and from 0.1 to 5.0% by weight of the metal deactivator, preferably N,Nʹ-disalicylidene-1,2-diaminopropane.
- Such fluids in addition to resulting in great convenience in storage, handling, transportation, blending with fuels, and so forth, also are potent concentrates which serve the function of inhibiting or minimizing the coking characteristics of compression ignition distillate fuels used to operate indirect compression ignition engines.
- The additive fluids, as well as the distillate fuel compositions of the present invention may also contain other additives such as, corrosion inhibitors, antioxidants, metal deactivators, detergents, cold flow improvers, inert solvents or diluents, and the like.
- The practice and advantages of this invention will become still further apparent from the following illustrative Example.
- In order to determine the effect of the fuel compositions of the present invention on the coking tendency of diesel injectors in indirect injection compression ignition engines, use was made of a commercial diesel engine operated on a coking test cycle developed by Institute Francais Petrole and as practiced by Peugeot S. A. The amount of coking together with a quantitative indication of the adverse consequences of such coking was determined by means of (i) injector air flow performance, (ii) emission of unburned hydrocarbons, (iii) engine noise, and (iv) injector deposit ratings. The engine employed in the tests was a 1982 Peugeot 2.3 liter, 4-cylinder, turbo-charged XD2S diesel engine connected to a Midwest dynamometer through an engine clutch. This engine is equipped with Bosch injectors positioned within prechambers, and is deemed representative of the indirect injection compression ignition engines widely used in automobiles and light-duty trucks.
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- A test blend was prepared from the base fuel. The Test Fuel contained a combination of (i) 41 PTB (0.117 grams per liter) of HITEC E-644, a product of Edwin Cooper, Inc., believed to be a hydrocarbyl succinimide-succinamide made by reacting two moles of a polyisobutenyl succinic anhydride (PIBSA) with one mole of a polyethylene amine mixture having an average composition corresponding to tetraethylene pentamine, (ii) 14 PTB (0.04 grams per liter) of a hydrocarbyl amine available commercially from Rohm and Haas Company under the designation Primene 81R, and (iii) 1.7 PTB (0.00486 grams per liter) of "Ethyl" Metal Deactivator, a product of Ethyl Corporation, the active ingredient of which is N,Nʹ-disalicylidene-1,2-diaminopropane. The manufacturer gives the following typical properties for its HITEC E-644 product:
- The Primene 81R is believed to be a mixture of primary aliphatic amines in which the aliphatic groups are predominatly C₁₂ and C₁₄ tertiary alkyl groups.
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- Shell Rotella T, an SAE 30, SF/CD oil was used as the crankcase lubricant.
- Before starting each test, new Bosch DNOSD - 1510 nozzles were installed using new copper gaskets and flame rings. The fuel line was flushed with the new test fuel composition to be tested and the fuel filter bowl and fuel return reservoir were emptied to avoid additive carry-over from test-to-test.
- At the start of each test, the engine was operated at 1000 rpm, light load for 15 minutes. After this warm-up, the engine was subjected to the following automatic cycle:
-
- Hydrocarbon exhaust emissions were measured at the start of each test (after the first 20-minute cycle), at the 6-hour test interval and at the end of the test. These measurements were made at 750, 1000, and 1400 rpm idle. Noise level readings were made at a location three feet from the engine exhaust side. The measurements were made at the start and at the end of the test while operating at three idle speeds, viz., 750, 1000 and 1400 rpm.
- After the test operation, the injectors were carefully removed from the engine so as not to disturb the deposits formed thereon. Measurements were made of air flow through each nozzle at different pintle lifts, and pintle deposits were rated using the CRC deposit rating system.
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- The results presented in the Table show that there were less coking deposits (higher air flow rate and fewer deposits), less engine noise and less hydrocarbon emissions with the fuel of the invention, as compared to the Base Fuel.
Claims (11)
H₂N R - NHH
wherein R is a divalent aliphatic hydrocarbon group having 2-4 carbon atoms and n is an integer from 1-10, including mixtures of said polyakyleneamines.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT87201461T ATE43626T1 (en) | 1983-12-30 | 1984-12-28 | FUEL COMPOSITION AND ADDITIVE CONCENTRATES AND THEIR USE FOR ENGINE SLUDGE INHIBITION. |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US567089 | 1983-12-30 | ||
US06/567,089 US4482356A (en) | 1983-12-30 | 1983-12-30 | Diesel fuel containing alkenyl succinimide |
US567071 | 1983-12-30 | ||
US06/567,090 US4482357A (en) | 1983-12-30 | 1983-12-30 | Fuel Compositions |
US06/567,071 US4482355A (en) | 1983-12-30 | 1983-12-30 | Diesel fuel compositions |
US567090 | 1983-12-30 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP84309143.0 Division | 1984-12-28 |
Publications (2)
Publication Number | Publication Date |
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EP0251419A1 true EP0251419A1 (en) | 1988-01-07 |
EP0251419B1 EP0251419B1 (en) | 1989-05-31 |
Family
ID=27416008
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP84309143A Expired EP0147240B1 (en) | 1983-12-30 | 1984-12-28 | Fuel compositions and additive concentrates, and their use in inhibiting engine coking |
EP87201460A Expired EP0247706B1 (en) | 1983-12-30 | 1984-12-28 | Fuel composition and additive concentrates, and their use in inhibiting engine coking |
EP87201461A Expired EP0251419B1 (en) | 1983-12-30 | 1984-12-28 | Fuel composition and additive concentrates, and their use in inhibiting engine coking |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
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EP84309143A Expired EP0147240B1 (en) | 1983-12-30 | 1984-12-28 | Fuel compositions and additive concentrates, and their use in inhibiting engine coking |
EP87201460A Expired EP0247706B1 (en) | 1983-12-30 | 1984-12-28 | Fuel composition and additive concentrates, and their use in inhibiting engine coking |
Country Status (2)
Country | Link |
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EP (3) | EP0147240B1 (en) |
CA (3) | CA1270642A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0482253A1 (en) * | 1990-10-23 | 1992-04-29 | Ethyl Petroleum Additives Limited | Environmentally friendly fuel compositions and additives therefor |
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US5575823A (en) * | 1989-12-22 | 1996-11-19 | Ethyl Petroleum Additives Limited | Diesel fuel compositions |
US5944858A (en) * | 1990-09-20 | 1999-08-31 | Ethyl Petroleum Additives, Ltd. | Hydrocarbonaceous fuel compositions and additives therefor |
EP0482253A1 (en) * | 1990-10-23 | 1992-04-29 | Ethyl Petroleum Additives Limited | Environmentally friendly fuel compositions and additives therefor |
Also Published As
Publication number | Publication date |
---|---|
EP0147240A2 (en) | 1985-07-03 |
EP0247706A3 (en) | 1988-01-13 |
EP0247706A2 (en) | 1987-12-02 |
CA1270642A (en) | 1990-06-26 |
EP0251419B1 (en) | 1989-05-31 |
CA1284883C (en) | 1991-06-18 |
CA1284583C (en) | 1991-06-04 |
EP0147240A3 (en) | 1986-04-02 |
EP0247706B1 (en) | 1989-06-14 |
EP0147240B1 (en) | 1989-04-05 |
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