EP0224759A3 - Herstellung von Polymeren durch kationische Polymerisation - Google Patents

Herstellung von Polymeren durch kationische Polymerisation Download PDF

Info

Publication number
EP0224759A3
EP0224759A3 EP86115595A EP86115595A EP0224759A3 EP 0224759 A3 EP0224759 A3 EP 0224759A3 EP 86115595 A EP86115595 A EP 86115595A EP 86115595 A EP86115595 A EP 86115595A EP 0224759 A3 EP0224759 A3 EP 0224759A3
Authority
EP
European Patent Office
Prior art keywords
mol
metal halide
polymers
halide
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP86115595A
Other languages
English (en)
French (fr)
Other versions
EP0224759A2 (de
Inventor
Rüdiger Dr. Musch
Renke Dr. Mottweiler
Dittmar Dr. Nerger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of EP0224759A2 publication Critical patent/EP0224759A2/de
Publication of EP0224759A3 publication Critical patent/EP0224759A3/de
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Die Herstellung von Polymeren mit Halogenendgruppen aus kationisch polymerisierbaren Monomeren mit Hilfe eines Katalysatorsystems aus einem Metallhalogenid und einem organischen Halogenid, wobei pro Mol Monomer 10⁻¹ bis 10⁻⁶ Mol Metallhalogenid anwesend sind und das Met­ allhalogenid im 2-bis 100-fachen molaren Überschuß gegen­ über dem organischen Halogenid eingesetzt wird, in Gegen­ wart eines unter Reaktionsbedingungen inerten Lösungsmittels bei +10°C bis -130°C, führt dann zu Poly­ meren mit enger Molgewichtsverteilung und hohem Funk­ tionalitätsgrad, wenn pro Mol Metallhalogenid 10⁻¹ bis 10⁻⁴ Mol Waser anwesend sind.
EP86115595A 1985-11-23 1986-11-11 Herstellung von Polymeren durch kationische Polymerisation Withdrawn EP0224759A3 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3541408 1985-11-23
DE19853541408 DE3541408A1 (de) 1985-11-23 1985-11-23 Herstellung von polymeren durch kationische polymerisation

Publications (2)

Publication Number Publication Date
EP0224759A2 EP0224759A2 (de) 1987-06-10
EP0224759A3 true EP0224759A3 (de) 1989-06-14

Family

ID=6286614

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86115595A Withdrawn EP0224759A3 (de) 1985-11-23 1986-11-11 Herstellung von Polymeren durch kationische Polymerisation

Country Status (4)

Country Link
EP (1) EP0224759A3 (de)
JP (1) JPS62127301A (de)
CA (1) CA1272547A (de)
DE (1) DE3541408A1 (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3542000A1 (de) * 1985-11-28 1987-06-04 Bayer Ag Verfahren zur herstellung von polymeren mit reaktiven endgruppen
US4968853A (en) * 1987-12-29 1990-11-06 The Lubrizol Corporation Alpha-olefin polymers
FI893125A (fi) * 1988-06-29 1989-12-30 Ceskoslovenska Akademie Ved Ympkopolymerer och foerfarande foer deras framstaellning.
JP2711297B2 (ja) * 1988-08-04 1998-02-10 鐘淵化学工業株式会社 官能性末端を有するイソブチレン系ポリマーの製造法
JPH0255705A (ja) * 1988-08-19 1990-02-26 Kanegafuchi Chem Ind Co Ltd 官能性末端を有するイソブチレン系ポリマーの製造法
GB8912271D0 (en) * 1989-05-27 1989-07-12 Bp Chem Int Ltd Cationic polymerisation of 1-olefins
CA2033328C (en) * 1989-06-06 2002-04-02 Hiroshi Fujisawa Process for preparation of a polymer having reactive terminal group
US5247021A (en) * 1989-06-06 1993-09-21 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Process for preparation of a polymer having reactive terminal group
US5210362A (en) * 1989-06-07 1993-05-11 The Lubrizol Corporation Alpha-olefin polymers
CA2019908A1 (en) * 1989-12-28 1991-06-28 Rudolf Lukas Graft copolymers and the method and initiation system for preparation thereof
US5254649A (en) * 1990-11-28 1993-10-19 Bp Chemicals Limited Cationic polymerization of 1-olefins
US5350819A (en) * 1993-02-19 1994-09-27 Exxon Chemical Patents Inc. Carbocationic catalysts and process for using said catalysts
US5506316A (en) * 1993-02-19 1996-04-09 Exxon Chemical Patents Inc. Carbocationic catalysts and process for using said catalysts
US5403803A (en) * 1993-09-28 1995-04-04 Exxon Chemical Patents Inc. Carbocationic catalyst and process for its use
WO1995031489A1 (en) * 1994-05-13 1995-11-23 Exxon Chemical Patents Inc. Carbocationic catalysts and process for using said catalysts

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1441610A (fr) * 1964-05-01 1966-06-10 Exxon Research Engineering Co Procédé de polymérisation de monooléfines à l'aide d'un système catalysant nouveau
US3342883A (en) * 1964-10-07 1967-09-19 Chevron Res Copolymers of isobutylene and omega-monohalo-1-alkenes
US3932553A (en) * 1974-07-26 1976-01-13 Exxon Research And Engineering Company Oligomerization of propylene
US3963772A (en) * 1973-02-09 1976-06-15 E. I. Du Pont De Nemours And Company Alternating alkylene/acrylic telomers
US4113790A (en) * 1974-08-02 1978-09-12 Snam Progetti, S.P.A. Process for the preparation of linear alpha-olefin oligomers, subsequent hydrogenation thereof and saturated products thus obtained
US4276394A (en) * 1979-09-10 1981-06-30 The University Of Akron Novel telechelic polymers, block copolymers and processes for the preparation thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1441610A (fr) * 1964-05-01 1966-06-10 Exxon Research Engineering Co Procédé de polymérisation de monooléfines à l'aide d'un système catalysant nouveau
US3342883A (en) * 1964-10-07 1967-09-19 Chevron Res Copolymers of isobutylene and omega-monohalo-1-alkenes
US3963772A (en) * 1973-02-09 1976-06-15 E. I. Du Pont De Nemours And Company Alternating alkylene/acrylic telomers
US3932553A (en) * 1974-07-26 1976-01-13 Exxon Research And Engineering Company Oligomerization of propylene
US4113790A (en) * 1974-08-02 1978-09-12 Snam Progetti, S.P.A. Process for the preparation of linear alpha-olefin oligomers, subsequent hydrogenation thereof and saturated products thus obtained
US4276394A (en) * 1979-09-10 1981-06-30 The University Of Akron Novel telechelic polymers, block copolymers and processes for the preparation thereof

Also Published As

Publication number Publication date
EP0224759A2 (de) 1987-06-10
CA1272547A (en) 1990-08-07
JPS62127301A (ja) 1987-06-09
DE3541408A1 (de) 1987-05-27

Similar Documents

Publication Publication Date Title
EP0224759A3 (de) Herstellung von Polymeren durch kationische Polymerisation
ATE41667T1 (de) Herstellung von aromatischen polymeren.
IE870982L (en) Molecular weight modifier for use with lanthanide and¹actinide catalysts
EP1197500A4 (de) Olefinpolymere und herstellungsverfahren davon
KR860700257A (ko) 아크릴 별모양 중합체
NO903797D0 (no) Metall-koordinasjonskomplekser, polymerisasjonskatalysatorer som inneholder slike komplekser og anvendels av katalysatoren.
BR9504690A (pt) Iniciadores de polimerização e/ou de reticulação por via catiônica e sob ativação fotoquímico e/ou térmica e/ou por feixes de elétrons de monômeros e/ou de polimeros de grupamentos organofuncionais composições processo para tornar artigos não aderentes e artigos revestidos
ATE133690T1 (de) Metallocen-katalysatorsysteme für die polymersation von olefinen, mit einer silizium- hydrocarbyl-brücke.
IE44097L (en) Quaternary ammonium polymer mixtures
ES482592A1 (es) Procedimiento para la produccion de microparticulas polime- ricas de adiccion reticuladas.
IT1016841B (it) Procedimento per la produzione di un polimero a terminazione ossidri lica
EP0175122A3 (de) Verfahren zur Herstellung von Polymeren mit reaktiven Endgruppen
FR2274632A1 (fr) Procede de preparation d'un catalyseur de polymerisation, catalyseur obtenu et ses applications
DE3779400D1 (de) Katalysatorbestandteile und katalysatoren fuer die polymerisation von alpha-olefinen zu stereoregularen polymeren mit beschraenkter molekulargewichtsverteilung.
GB2269180A (en) Process for the synthesis of oligomeric vinylamides and vinylamines
Schubert et al. Group transfer polymerization of methyl acrylate in tetrahydrofuran with tetrabutylammonium fluoride trihydrate and tetrabutylammonium cyanide as catalysts
EP0257567A3 (en) Resin-fortified emulsion polymers and methods of preparing the same
AU3912895A (en) Fuctional copolymers of low molar mass, processes for their preparation, and their use
EP0101136A3 (de) Katalysator zur Polymerisation von Olefinen, Katalysatorkomponente davon und Verfahren zur Herstellung dieser Katalysatorkomponente
ATE84803T1 (de) Herstellung von aromatischen keton-sulfoncopolymeren.
Okamura et al. Cationic polymerization of trioxane in solid state catalyzed by stannic chloride
GB1231822A (de)
JP2004514768A (ja) 高分子量パーフルオロシクロブタンポリマーおよびその製造方法
JPH0225370B2 (de)
SU465921A1 (ru) Способ получени линейных полиолефинов

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19861111

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): DE FR GB IT

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): DE FR GB IT

17Q First examination report despatched

Effective date: 19901116

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN

18W Application withdrawn

Withdrawal date: 19910315

R18W Application withdrawn (corrected)

Effective date: 19910315

RIN1 Information on inventor provided before grant (corrected)

Inventor name: MOTTWEILER, RENKE, DR.

Inventor name: MUSCH, RUEDIGER, DR.

Inventor name: NERGER, DITTMAR, DR.