EP0216561B1 - Preheating method of steel strips - Google Patents
Preheating method of steel strips Download PDFInfo
- Publication number
- EP0216561B1 EP0216561B1 EP86306940A EP86306940A EP0216561B1 EP 0216561 B1 EP0216561 B1 EP 0216561B1 EP 86306940 A EP86306940 A EP 86306940A EP 86306940 A EP86306940 A EP 86306940A EP 0216561 B1 EP0216561 B1 EP 0216561B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- steel strip
- preheating
- temperature
- heated
- heating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 110
- 239000010959 steel Substances 0.000 title claims abstract description 110
- 238000000034 method Methods 0.000 title claims abstract description 16
- 238000010438 heat treatment Methods 0.000 claims abstract description 68
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 claims abstract description 18
- 239000002912 waste gas Substances 0.000 claims abstract description 18
- 230000001590 oxidative effect Effects 0.000 claims abstract description 5
- 238000000137 annealing Methods 0.000 claims description 5
- 239000012530 fluid Substances 0.000 claims description 5
- 230000000750 progressive effect Effects 0.000 claims description 4
- 238000004804 winding Methods 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000007789 gas Substances 0.000 abstract description 12
- 238000004519 manufacturing process Methods 0.000 abstract description 10
- 238000009434 installation Methods 0.000 abstract description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 3
- 239000002918 waste heat Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/34—Methods of heating
Definitions
- This invention relates to a preheating method in the continuous heat-treatment of steel strip for progressively heating the steel strip in a plurality of stages to temperatures as near to those in the heating zone as possible.
- a steel strip continuous heat-treating installation for example, a steel strip continuous annealing installation, usually comprises heating, soaking and cooling zones.
- a steel strip is heated to 650°C-850°C in the heating zone.
- radiant tube heating has been employed which, however, makes the installation of the heating zone complicated and large-sized. It is therefore important to preheat the steel strip on the entry side of the heating zone in order to make the installation compact and improve the production efficiency.
- Japanese Laid-open Patent Applications Nos.57-41,330 and 58-73,727 disclose a method of preheating a steel strip in which sensible heat of burned waste heat from a heating zone is recovered in a heating medium by means of a heat-exchanger and the heating medium is introduced into passages formed in rolls about which the steel strip is wound.
- the sensible heat of the burned waste heat at 300-350°C is recovered in the heating medium until the temperature becomes approximately 150°C in order to avoid a problem of dew point of oxygen, and thereafter the steel strip is preheated. In this manner, it is possible to preheat the steel strip to approximately 130-140°C to improve the recovery of waste heat.
- the steel strip preheated to approximately 130-140°C is rapidly heated to 600-850°C by radiation heating mainly by radiant tubes.
- a heating has a limitation of heating speed, a huge installation is needed in order to increase the production.
- the preheating temperature is relatively low, it would be desirable to improve the thermal efficiency.
- Japanese Laid-open Patent Application No.57-76,133 discloses a heating method using rolls heated by induction heating coils without using the burned waste gas.
- This publication discloses an example of heating steel strips to 800°C using heated rolls at 1,000°C. Because of the great temperature difference between the steel strip and the rolls when the steel strip is wound about the rolls, there is a risk of serpentine movement of the steel strip caused by concave thermal crowns on the rolls due to temperature fall at outer peripheries of the rolls about which the steel strip is wound.
- Japanese Laid-open Patent Application No.60,135,530 discloses a preheating method in which sensible heat of burned waste gas from a radiant-tube equipped heating furnace is recovered by using it to heat an atmospheric gas stream in a heat exchanger and the resulting heated gas stream is blown on to steel strip to preheat it.
- the preheating temperature of the steel strip is at the most 100-200°C. It is impossible to obtain higher preheating temperature.
- the temperature of preheated steel strips is within 100-200°C, bad configuration of the rolled steel strips is not straightened by such a low temperature preheating and is maintained even when the steel strips are in an upstream half of a heating zone.
- unevenness of the rolled steel strip is of the order of 1%, therefore, serpentine movements of the steel strips occur while being heated, so that the feeding speed of the steel strips cannot be increased resulting in lower production efficiency.
- the word "unevenness” is intended to mean a deviation of a steel strip from a complete flatness per a unit length.
- a method of continuously annealing steel strip in which the strip is preheated and then heated indirectly in a heating zone by means of radiant tubes heated by burned waste gas, characterised in that the preheating is effected progressively in two stages, in the first of which the strip is heated to not more than a maximum predetermined first temperature by direct contact with a gaseous stream which has been heated in a heat exchanger by means of the burned waste gas from the heating zone, and in the second of which the preheated strip from the first preheating stage is further heated to a desired second temperature higher than said maximum first temperature by winding the steel strip over heated rolls through which is circulated a fluid heat medium which has been heated in a heating device to a desired temperature sufficient to cause the strip in the second preheating stage to be raised to said desired higher temperature before entering the heating zone, whereby serpentine movement of the steel strip is substantially reduced.
- a progressive preheating of steel strip in two stages for the purpose of minimising serpentine movement of the steel strip in the continuous annealing of steel strip by indirect heating with radiant tubes in a heating zone, the first preheating being effected by direct heating with a gaseous atmosphere containing sensible heat recovered by heat exchange with burned waste gas from the heating zone, and the second preheating being effected by heated rolls through which a fluid heat medium which has been heated to a desired temperature in a heating device is circulated so as to preheat the steel strip to a higher temperature than that reached in the first preheating stage.
- the temperature of the steel strip is maintained lower than a predetermined temperature, such as by controlling amounts of the gas directed onto the steel strip, in order to prevent formation of thick oxide films on the steel strip.
- the second stage preheating is preferably effected in a non-oxidizing atmosphere.
- a heat medium is heated in a heat medium heating device and supplied and circulated into the rolls, thereby heating the rolls to a desired temperature.
- the temperature of the steel strip is preferably maintained lower than a predetermined temperature by controlling at least one factor among flow rate and temperature of the heat medium and winding angles of the steel strip about the rolls.
- a steel strip 1 is preheated to 100-200°C in a first preheating zone 2 at a first preheating stage and to 250-500°C in a second preheating zone 3 at a second preheating stage.
- burned waste gas is collected from a heating zone 4 including radiant tubes 5 into waste gas collecting ducts 6 and is introduced into a heat-exchanger 7 wherein sensible heat of the waste gas is given to a gas such as the air while the waste gas whose temperature has been lowered is exhausted through a chimney 9 with the aid of a waste gas suction fan 8.
- the temperature of the waste gas is usually of the order of 400°C which is lower than those at which the fan and chimney can thermally resist.
- the heated gas heated in the heat-exchanging (which is referred to hereinafter "hot blast") is circulated by a hot blast circulating fan 10 to be supplied into hot blast chambers 11 arranged in the first preheating zone 2, so that the hot blast is directed onto the steel strip to heat it to 100-200°C.
- nitrogen, nitrogen mixed with hydrogen somewhat, or the like is suitable as the gas directed onto the steel strip in the first preheating zone 2.
- a heat medium 12 in a reservoir 17 is heated in a heat medium heating device 13 and supplied and circulated into rolls 15 with the aid of a circulating pump 14.
- the heated medium 12 flows through the rolls 15 which are heated by the medium, so that the steel strip 1 from the first preheating zone 2 is wound about the rolls so as to pass through the second preheating zone 3 to heat the steel strip 1 to 250-500°C
- the heat medium 12 which has heated the rolls is returned through a return line 16 into the reservoir 17.
- the heat medium may be thermo-oil, metallic sodium, or a molten salt such as a nitrate, for example sodium nitrate or potassium nitrate, or a chloride, for example calcium chloride or sodium chloride.
- a molten nitrate salt is preferable for preventing corrosion of the rolls.
- thermometer or thermometers 18 for the steel strip are provided on an exit side of the first preheating zone 2 to monitor whether the steel strip 1 is heated at temperatures between 100 and 200°C in the first preheating zone. If the temperature of the steel strip is higher than 250°C, thick oxide films are produced on surfaces of the steel strip to lower the quality of the surfaces.
- the amount of the hot blast directed onto the steel strip is controlled by adjusting numbers of revolution of the hot blast circulating fan 10 or provision of dampers in the lines in order to maintain the temperature of the preheated steel strip lower than 250°C.
- thermometer or thermometers 19 for the steel strip are provided on an exit side of the second preheating zone 3 to monitor whether the temperature of the steel strip on the exit side of the second preheating zone 3 is maintained within 250-500°C while one or more of the flow rate and temperature of the heat medium 12 flowing into the rolls 15 and winding angles of the steel strip about the rolls are controlled.
- Figs. 2-8 illustrate results of investigation of thermal efficiency, serpentine movement of steel strips, surface conditions and installation investment concerning the invention.
- Fig. 2 and 3 illustrate thermal efficiencies in cases of the present invention, reference example A using only radiant tubes and reference example B using hot blast and radiant tubes.
- the thermal efficiency is greatly improved by effecting the second stage preheating with rolls mainly by the heat transmission between directly contacting metals.
- Fig. 3 is a graph illustrating the fall in production efficiency due to serpentine movements of steel strips occurring before the heating zone when unevennesses of the steel strips are 0.5-1.0% before the heat treatment. This graph clearly shows the superiority of the present invention.
- Fig. 4 illustrates the fall in production efficiency due to serpentine movements of steel strips similar to those in Fig. 3, in comparison with the reference example B. It is clear that the serpentine movements can be prevented by rapidly raising the temperature of the steel strips to the order of 500°C by preheating with rolls.
- an abscissa indicates temperature difference between the heat medium and steel strips on the exit side of the second preheating zone and an ordinate indicates serpentine movement of steel strips per one heating roll.
- the temperature difference is more than 300°C, the serpentine movements increase to an extent that the practical use is prohibitive. It is understood from this fact that the progressive heating with less temperature difference is suitable.
- Fig. 6 illustrates the relation between thickness of oxide films and the temperature of steel strips on the exit side of the first preheating zone heating with hot blast. It is clearly evident that when the temperature of the steel strips is more than 250°C, the thickness of the oxide films increases. Even if the steel strips were reduced after preheating, the bad surface conditions of the steel strips could not be amended as shown in Fig. 7.
- Fig. 7 illustrates observation of surfaces of steel strips which were subjected to the treatment for forming phosphate or chromium oxide films thereon after the continuous heat treatment and degreasing. An ordinate indicates the surface conditions of the strips.
- Fig. 8 illustrates the surface condition of steel strips in case of the second preheating zone with the air or non-oxidizing atmosphere.
- the quantity of heat and flow rate of the respective gases when the temperature of the steel strips on the exit side of the heating zone became 750°C are as follows under the same conditions as those above described.
- Sensible heat of the heat-up gas was given through a heat-exchanger to the air to be used in the first preheating zone, so that the temperature of the heat-up gas dropped from 600°C to 350°C.
- the amount of the air circulating through the first preheating zone was 80,000 Nm/h.
- the quantity of heat of 2x106 Kcal/h was obtained by heat-exchanging.
- the air temperature was 250°C on an entry side of the heat-exchanger and 330°C on an exit side thereof.
- Table 1 shows the temperatures of steel strips on the exit side of the first preheating zone.
- This invention allows steel strips to be preheated to higher temperatures for the purpose of preventing serpentine movements of the steel strips, thereby improving the production efficiency and compacting the installation.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Strip Materials And Filament Materials (AREA)
- Coating With Molten Metal (AREA)
- Manufacturing Of Steel Electrode Plates (AREA)
- Heat Treatments In General, Especially Conveying And Cooling (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Coating By Spraying Or Casting (AREA)
Abstract
Description
- This invention relates to a preheating method in the continuous heat-treatment of steel strip for progressively heating the steel strip in a plurality of stages to temperatures as near to those in the heating zone as possible.
- A steel strip continuous heat-treating installation, for example, a steel strip continuous annealing installation, usually comprises heating, soaking and cooling zones. A steel strip is heated to 650°C-850°C in the heating zone. As it is necessary to maintain a reducing atmosphere in the heating zone, radiant tube heating has been employed which, however, makes the installation of the heating zone complicated and large-sized. It is therefore important to preheat the steel strip on the entry side of the heating zone in order to make the installation compact and improve the production efficiency.
- Concerning the preheating on the entry side of the heating zone, Japanese Laid-open Patent Applications Nos.57-41,330 and 58-73,727 disclose a method of preheating a steel strip in which sensible heat of burned waste heat from a heating zone is recovered in a heating medium by means of a heat-exchanger and the heating medium is introduced into passages formed in rolls about which the steel strip is wound.
- In this disclosed method, the sensible heat of the burned waste heat at 300-350°C is recovered in the heating medium until the temperature becomes approximately 150°C in order to avoid a problem of dew point of oxygen, and thereafter the steel strip is preheated. In this manner, it is possible to preheat the steel strip to approximately 130-140°C to improve the recovery of waste heat.
- In this case, however, the steel strip preheated to approximately 130-140°C is rapidly heated to 600-850°C by radiation heating mainly by radiant tubes. As such a heating has a limitation of heating speed, a huge installation is needed in order to increase the production. Moreover, as the preheating temperature is relatively low, it would be desirable to improve the thermal efficiency.
- On the other hand, Japanese Laid-open Patent Application No.57-76,133 discloses a heating method using rolls heated by induction heating coils without using the burned waste gas. This publication discloses an example of heating steel strips to 800°C using heated rolls at 1,000°C. Because of the great temperature difference between the steel strip and the rolls when the steel strip is wound about the rolls, there is a risk of serpentine movement of the steel strip caused by concave thermal crowns on the rolls due to temperature fall at outer peripheries of the rolls about which the steel strip is wound.
- Even if the rolls are inherently provided with convex crowns in profile in order to stabilize the crown of the heating rolls, it is very difficult to maintain stable crowns because of variation in temperature of the steel strip passing about the rolls according to thickness of the steel strip in case of large temperature difference between the steel strip and heating rolls.
- Moreover, it has been known that there is provided on the entry side of a heating zone a preheating furnace into which burned waste gas is directly introduced or there is provided on the entry side of a heating zone a non-oxidizing furnace for preheating steel strips (direct firing system). With the former, however, the burned waste gas directly contacts steel strips, so that there is a tendency for surfaces of strips to become worse due to oxidization of the surfaces and foreign substances (oxides, carbides and the like) in the waste gas attached on the surfaces. In the latter, the initial cost is increased.
- Furthermore, Japanese Laid-open Patent Application No.60,135,530 discloses a preheating method in which sensible heat of burned waste gas from a radiant-tube equipped heating furnace is recovered by using it to heat an atmospheric gas stream in a heat exchanger and the resulting heated gas stream is blown on to steel strip to preheat it. In this method, however, the preheating temperature of the steel strip is at the most 100-200°C. It is impossible to obtain higher preheating temperature. When the temperature of preheated steel strips is within 100-200°C, bad configuration of the rolled steel strips is not straightened by such a low temperature preheating and is maintained even when the steel strips are in an upstream half of a heating zone. In that case unevenness of the rolled steel strip is of the order of 1%, therefore, serpentine movements of the steel strips occur while being heated, so that the feeding speed of the steel strips cannot be increased resulting in lower production efficiency. The word "unevenness" is intended to mean a deviation of a steel strip from a complete flatness per a unit length.
- It is an object of the present invention to provide a method of preheating steel strip, which makes it possible to achieve high temperature preheating by progressive preheating without causing serpentine movement of the steel strip, so that the heating zone can be made compact and the production efficiency improved.
- Thus in accordance with one aspect of the invention, there is provided a method of continuously annealing steel strip in which the strip is preheated and then heated indirectly in a heating zone by means of radiant tubes heated by burned waste gas, characterised in that the preheating is effected progressively in two stages, in the first of which the strip is heated to not more than a maximum predetermined first temperature by direct contact with a gaseous stream which has been heated in a heat exchanger by means of the burned waste gas from the heating zone, and in the second of which the preheated strip from the first preheating stage is further heated to a desired second temperature higher than said maximum first temperature by winding the steel strip over heated rolls through which is circulated a fluid heat medium which has been heated in a heating device to a desired temperature sufficient to cause the strip in the second preheating stage to be raised to said desired higher temperature before entering the heating zone, whereby serpentine movement of the steel strip is substantially reduced.
- In accordance with another aspect of the invention, there is provided the use of a progressive preheating of steel strip in two stages for the purpose of minimising serpentine movement of the steel strip in the continuous annealing of steel strip by indirect heating with radiant tubes in a heating zone, the first preheating being effected by direct heating with a gaseous atmosphere containing sensible heat recovered by heat exchange with burned waste gas from the heating zone, and the second preheating being effected by heated rolls through which a fluid heat medium which has been heated to a desired temperature in a heating device is circulated so as to preheat the steel strip to a higher temperature than that reached in the first preheating stage.
- In a preferred embodiment, in the case of using an oxygen-containing gas such as air in the first stage preheating, the temperature of the steel strip is maintained lower than a predetermined temperature, such as by controlling amounts of the gas directed onto the steel strip, in order to prevent formation of thick oxide films on the steel strip. The second stage preheating is preferably effected in a non-oxidizing atmosphere.
- In the second preheating stage, a heat medium is heated in a heat medium heating device and supplied and circulated into the rolls, thereby heating the rolls to a desired temperature. The temperature of the steel strip is preferably maintained lower than a predetermined temperature by controlling at least one factor among flow rate and temperature of the heat medium and winding angles of the steel strip about the rolls.
- For a better understanding of the invention and to show how the same may be carried into effect, reference will now be made, by way of example, to the accompanying drawings in which:
- Fig. 1 is a schematic view illustrating a heating apparatus for effecting the method according to the invention;
- Fig. 2 is a graph illustrating a comparison between the thermal efficiency of the invention and conventional methods;
- Fig. 3 is a graph illustrating a comparison between fall in production efficiency of the invention and conventional methods;
- Fig. 4 is a graph illustrating the relation between the fall in production efficiency due to serpentine movement of the invention compared with conventional methods;
- Fig. 5 is a graph illustrating serpentine movement in connection with temperature difference between heat medium and steel strip;
- Fig. 6 is a graph illustrating the relation between thickness of oxide films and steel strip temperature;
- Fig. 7 is a graph illustrating the relation between surface conditions and steel strip temperature;
- Fig. 8 is a graph illustrating the relation between surface conditions and atmosphere in preheating zones; and
- Fig. 9 is a graph illustrating the relation between steel strip temperature and investment and repayment indexes.
- Referring to Fig. 1, in accordance with the invention, a steel strip 1 is preheated to 100-200°C in a
first preheating zone 2 at a first preheating stage and to 250-500°C in asecond preheating zone 3 at a second preheating stage. - First, burned waste gas is collected from a heating zone 4 including
radiant tubes 5 into wastegas collecting ducts 6 and is introduced into a heat-exchanger 7 wherein sensible heat of the waste gas is given to a gas such as the air while the waste gas whose temperature has been lowered is exhausted through a chimney 9 with the aid of a wastegas suction fan 8. The temperature of the waste gas is usually of the order of 400°C which is lower than those at which the fan and chimney can thermally resist. - The heated gas heated in the heat-exchanging (which is referred to hereinafter "hot blast") is circulated by a hot
blast circulating fan 10 to be supplied into hot blast chambers 11 arranged in thefirst preheating zone 2, so that the hot blast is directed onto the steel strip to heat it to 100-200°C. - Other than the air, nitrogen, nitrogen mixed with hydrogen somewhat, or the like is suitable as the gas directed onto the steel strip in the
first preheating zone 2. - On the other hand, a
heat medium 12 in a reservoir 17 is heated in a heatmedium heating device 13 and supplied and circulated intorolls 15 with the aid of a circulatingpump 14. Theheated medium 12 flows through therolls 15 which are heated by the medium, so that the steel strip 1 from thefirst preheating zone 2 is wound about the rolls so as to pass through thesecond preheating zone 3 to heat the steel strip 1 to 250-500°C Theheat medium 12 which has heated the rolls is returned through areturn line 16 into the reservoir 17. - The heat medium may be thermo-oil, metallic sodium, or a molten salt such as a nitrate, for example sodium nitrate or potassium nitrate, or a chloride, for example calcium chloride or sodium chloride. A molten nitrate salt is preferable for preventing corrosion of the rolls.
- A thermometer or
thermometers 18 for the steel strip are provided on an exit side of thefirst preheating zone 2 to monitor whether the steel strip 1 is heated at temperatures between 100 and 200°C in the first preheating zone. If the temperature of the steel strip is higher than 250°C, thick oxide films are produced on surfaces of the steel strip to lower the quality of the surfaces. The amount of the hot blast directed onto the steel strip is controlled by adjusting numbers of revolution of the hotblast circulating fan 10 or provision of dampers in the lines in order to maintain the temperature of the preheated steel strip lower than 250°C. - Moreover, a thermometer or
thermometers 19 for the steel strip are provided on an exit side of thesecond preheating zone 3 to monitor whether the temperature of the steel strip on the exit side of thesecond preheating zone 3 is maintained within 250-500°C while one or more of the flow rate and temperature of theheat medium 12 flowing into therolls 15 and winding angles of the steel strip about the rolls are controlled. - Figs. 2-8 illustrate results of investigation of thermal efficiency, serpentine movement of steel strips, surface conditions and installation investment concerning the invention.
- Experiments were carried out under the following conditions.
Steel strips : general cold rolled steel strips
Thickness of steel strips : 0.5-1.6 mm
Width of steel strips : 700-1,600 mm
Speed of steel strips passing through preheating zones : 100-300 m/min
Unevenness of steel strips on entry side of preheating zones : 0.5-1.5%
Tensile force in steel strips : 0.5-1.5 kg/mm²
Steel strip temperature at entry side of the first preheating zone (heating by hot blast) : 40-60°C
Steel strip temperature at exit side of the first preheating zone : 100-200°C
Steel strip temperature at exit side of the second preheating zone (heating with rolls) : 250-500°C
Heat medium : chloride
Temperature of heat medium : 200-600°C - Fig. 2 and 3 illustrate thermal efficiencies in cases of the present invention, reference example A using only radiant tubes and reference example B using hot blast and radiant tubes.
- As can be seen from Fig. 2, the thermal efficiency is greatly improved by effecting the second stage preheating with rolls mainly by the heat transmission between directly contacting metals.
- Fig. 3 is a graph illustrating the fall in production efficiency due to serpentine movements of steel strips occurring before the heating zone when unevennesses of the steel strips are 0.5-1.0% before the heat treatment. This graph clearly shows the superiority of the present invention.
- Fig. 4 illustrates the fall in production efficiency due to serpentine movements of steel strips similar to those in Fig. 3, in comparison with the reference example B. It is clear that the serpentine movements can be prevented by rapidly raising the temperature of the steel strips to the order of 500°C by preheating with rolls.
- In Fig. 5, an abscissa indicates temperature difference between the heat medium and steel strips on the exit side of the second preheating zone and an ordinate indicates serpentine movement of steel strips per one heating roll. When the temperature difference is more than 300°C, the serpentine movements increase to an extent that the practical use is prohibitive. It is understood from this fact that the progressive heating with less temperature difference is suitable.
- The reason why the large temperature difference increases the serpentine movements of the steel strips is as follows. When the temperature difference is large, center portions of the heating rolls are cooled more than edge portions of the rolls to increase concave crowns occurring on the heating rolls, so that the steel strips become unstable at the center portions of the rolls and tend to move to the edge portions owing to the usual tendency of the steel strips to move toward locations where tensile forces in the steel strips increase.
- Fig. 6 illustrates the relation between thickness of oxide films and the temperature of steel strips on the exit side of the first preheating zone heating with hot blast. It is clearly evident that when the temperature of the steel strips is more than 250°C, the thickness of the oxide films increases. Even if the steel strips were reduced after preheating, the bad surface conditions of the steel strips could not be amended as shown in Fig. 7.
- Fig. 7 illustrates observation of surfaces of steel strips which were subjected to the treatment for forming phosphate or chromium oxide films thereon after the continuous heat treatment and degreasing. An ordinate indicates the surface conditions of the strips.
- Fig. 8 illustrates the surface condition of steel strips in case of the second preheating zone with the air or non-oxidizing atmosphere.
- When the steel strips in the second preheating zone with the air were heated to 250-500°C, the oxide films became extremely thick. Even after reducing the steel strips in the heating zone, uneven oxide films remained on the surfaces under the bad surface treated condition.
- As seen from Fig. 9, when the temperature of the steel strips on the exit side of the first preheating zone were higher than 200°C, both investment index and repayment year index became higher. In other words, installations such as hot blast circulating fans, motors, heat-exchangers and the like are enlarged to increase both the investment and repayment year.
-
- Sensible heat of the heat-up gas was given through a heat-exchanger to the air to be used in the first preheating zone, so that the temperature of the heat-up gas dropped from 600°C to 350°C.
- On the other hand, the amount of the air circulating through the first preheating zone was 80,000 Nm/h. The quantity of heat of 2x10⁶ Kcal/h was obtained by heat-exchanging. In this case, the air temperature was 250°C on an entry side of the heat-exchanger and 330°C on an exit side thereof.
-
-
- Under above conditions, when steel strips of 0.8 mm thickness were heated at passing speed of 200 m/min, the steel strips at 200°C on the entry side were heated to 350°C on the exit side.
- This invention allows steel strips to be preheated to higher temperatures for the purpose of preventing serpentine movements of the steel strips, thereby improving the production efficiency and compacting the installation.
Claims (6)
- A method of continuously annealing steel strip in which the strip is preheated and then heated indirectly in a heating zone by means of radiant tubes heated by burned waste gas, characterised in that the preheating is effected progressively in two stages, in the first of which the strip is heated to not more than a maximum predetermined first temperature by direct contact with a gaseous stream which has been heated in a heat exchanger by means of the burned waste gas from the heating zone, and in the second of which the preheated strip from the first preheating stage is further heated to a desired second temperature higher than said maximum first temperature by winding the steel strip over heated rolls through which is circulated a fluid heat medium which has been heated in a heating device to a desired temperature sufficient to cause the strip in the second preheating stage to be raised to said desired higher temperature before entering the heating zone, whereby serpentine movement of the steel strip is substantially reduced.
- A method according to Claim 1, wherein the gaseous stream used in the first preheating stage is an oxygen-containing stream and the maximum predetermined first temperature is controlled so as to prevent formation of a thick oxide film on the steel strip.
- A method according to Claim 1 or 2, wherein the second preheating stage is effected in a non-oxidizing atmosphere.
- A method according to Claim 1, 2 or 3, wherein said maximum predetermined first temperature is 250°C and said desired higher second temperature is in the range from 250 to 500°C.
- A method according to Claim 1, 2, 3 or 4, wherein the fluid heat medium used in the second preheating stage is a molten nitrate.
- Use of a progressive preheating of steel strip in two stages for the purpose of minimising serpentine movement of the steel strip in the continuous annealing of steel strip by indirect heating with radiant tubes in a heating zone, the first preheating being effected by direct heating with a gaseous atmosphere containing sensible heat recovered by heat exchange with burned waste gas from the heating zone, and the second preheating being effected by heated rolls through which a fluid heat medium which has been heated to a desired temperature in a heating device is circulated so as to preheat the steel strip to a higher temperature than that reached in the first preheating stage.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT86306940T ATE92969T1 (en) | 1985-09-10 | 1986-09-09 | PROCESS FOR PREHEATING STEEL STRIP. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP198625/85 | 1985-09-10 | ||
| JP60198625A JPS6260825A (en) | 1985-09-10 | 1985-09-10 | Preheating method in continuous heat treatment of steel strip |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0216561A2 EP0216561A2 (en) | 1987-04-01 |
| EP0216561A3 EP0216561A3 (en) | 1988-08-03 |
| EP0216561B1 true EP0216561B1 (en) | 1993-08-11 |
Family
ID=16394308
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP86306940A Expired - Lifetime EP0216561B1 (en) | 1985-09-10 | 1986-09-09 | Preheating method of steel strips |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0216561B1 (en) |
| JP (1) | JPS6260825A (en) |
| KR (1) | KR910009967B1 (en) |
| AT (1) | ATE92969T1 (en) |
| AU (1) | AU573988B2 (en) |
| CA (1) | CA1286575C (en) |
| DE (1) | DE3688868T2 (en) |
| ES (1) | ES2002294A6 (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2820148B1 (en) * | 2001-01-31 | 2003-10-31 | Stein Heurtey | IMPROVEMENTS IN METHODS FOR HEATING STEEL STRIPS IN VERTICAL OVENS |
| JP5043587B2 (en) * | 2007-10-12 | 2012-10-10 | 中外炉工業株式会社 | Metal strip continuous heat treatment equipment |
| AT507669B1 (en) * | 2009-07-03 | 2010-07-15 | Ebner Ind Ofenbau | METHOD FOR HEATING LIGHT METAL BLOCKS |
| CN103103323A (en) * | 2013-01-21 | 2013-05-15 | 江苏沙钢集团有限公司 | Method for producing cold-billet silicon steel without adopting heat-preservation pit |
| KR101631034B1 (en) * | 2015-09-07 | 2016-06-16 | 주식회사 포스코 | Descaling apparatus and descaling method using thereof |
| AT520134B1 (en) * | 2017-07-13 | 2020-03-15 | Andritz Tech & Asset Man Gmbh | METHOD FOR REDUCING NITROGEN OXIDES IN TAPE TREATMENT OVENS |
| CN109321741A (en) * | 2017-07-31 | 2019-02-12 | 湖北华鑫科技股份有限公司 | The automatic annealing machine of precision steel strip |
| CN111879116A (en) * | 2020-07-30 | 2020-11-03 | 泰兴市天一冶金科技发展有限公司 | Billet steel smelting gas walking beam furnace sectional heating mechanism |
| CN114807583A (en) * | 2022-03-21 | 2022-07-29 | 光丰(肇庆)钢业有限公司 | Production process of steel belt |
| CN117737393A (en) * | 2022-09-15 | 2024-03-22 | 宝山钢铁股份有限公司 | Jet radiant tube preheating system |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60135530A (en) * | 1983-12-22 | 1985-07-18 | Kawasaki Steel Corp | Continuous annealing method of steel strip |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4069008A (en) * | 1976-03-19 | 1978-01-17 | Allegheny Ludlum Industries, Inc. | Method and apparatus for heating a workpiece |
| AU509460B2 (en) * | 1976-12-23 | 1980-05-15 | Armco Steel Corporation | Treating steel strip prior to metal coating |
| DE3142860A1 (en) * | 1981-10-29 | 1983-05-11 | Italimpianti (Deutschland) Industrieanlagen GmbH, 4000 Düsseldorf | "METHOD AND DEVICE FOR PREHEATING" |
| AU576272B2 (en) * | 1984-11-13 | 1988-08-18 | Kyorin Pharmaceutical Co. Ltd. | Quinolone carboxylic acid derivates |
-
1985
- 1985-09-10 JP JP60198625A patent/JPS6260825A/en active Granted
-
1986
- 1986-09-09 CA CA000517747A patent/CA1286575C/en not_active Expired - Lifetime
- 1986-09-09 DE DE86306940T patent/DE3688868T2/en not_active Expired - Fee Related
- 1986-09-09 KR KR1019860007539A patent/KR910009967B1/en not_active Expired
- 1986-09-09 ES ES8601728A patent/ES2002294A6/en not_active Expired
- 1986-09-09 EP EP86306940A patent/EP0216561B1/en not_active Expired - Lifetime
- 1986-09-09 AT AT86306940T patent/ATE92969T1/en not_active IP Right Cessation
- 1986-09-10 AU AU62555/86A patent/AU573988B2/en not_active Ceased
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60135530A (en) * | 1983-12-22 | 1985-07-18 | Kawasaki Steel Corp | Continuous annealing method of steel strip |
Non-Patent Citations (1)
| Title |
|---|
| CHEMICAL ABSTRACTS, vol. 103, 09 December 1985, Columbus, OH (US); p. 219, no. 199435u; JP-A-60 135530 (Kawasaki Steel Corp.; Mitsubishi Heavy Industries, Ltd) 18-07-1985 * |
Also Published As
| Publication number | Publication date |
|---|---|
| KR910009967B1 (en) | 1991-12-07 |
| ES2002294A6 (en) | 1988-08-01 |
| EP0216561A3 (en) | 1988-08-03 |
| JPS6344805B2 (en) | 1988-09-07 |
| KR870003212A (en) | 1987-04-16 |
| ATE92969T1 (en) | 1993-08-15 |
| CA1286575C (en) | 1991-07-23 |
| JPS6260825A (en) | 1987-03-17 |
| DE3688868D1 (en) | 1993-09-16 |
| DE3688868T2 (en) | 1993-11-25 |
| EP0216561A2 (en) | 1987-04-01 |
| AU573988B2 (en) | 1988-06-23 |
| AU6255586A (en) | 1987-03-12 |
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