EP0200543A2 - Vanne pour la commande d'écoulement de gaz d'une bonbonne cylindrique de gaz à haute pression - Google Patents
Vanne pour la commande d'écoulement de gaz d'une bonbonne cylindrique de gaz à haute pression Download PDFInfo
- Publication number
- EP0200543A2 EP0200543A2 EP86303279A EP86303279A EP0200543A2 EP 0200543 A2 EP0200543 A2 EP 0200543A2 EP 86303279 A EP86303279 A EP 86303279A EP 86303279 A EP86303279 A EP 86303279A EP 0200543 A2 EP0200543 A2 EP 0200543A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- valve
- cylinder
- pressure
- gas
- fluid passage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/04—Arrangement or mounting of valves
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
- F17C2205/0323—Valves
- F17C2205/0329—Valves manually actuated
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
- F17C2205/035—Flow reducers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
- F17C2205/0382—Constructional details of valves, regulators
Definitions
- the present invention is directed to an improved cylinder valve for mounting on a high pressure gas cylinder for controlling the flow of gas from the cylinder. More particularly, the invention relates to an improved cylinder valve which can significantly contribute to the safe handling of hazardous gases such as those used extensively in the semiconductor industry.
- a known cylinder valve for controlling the flow of gas from a high pressure gas cylinder is a manually operated cylinder valve.
- the gas cylinders When the high pressure gas cylinders contain hazardous gases such as those used in the semiconductor industry, the gas cylinders are placed in a gas cabinet which is ventilated for safety in the event of leaks.
- One problem associated with the use of the known manually operated cylinder valve in such an application is that it requires the operator to reach inside the gas cabinet to actuate the valves. The ingress and egress from the gas cabinet is time consuming and possibly dangerous to the operator in the event of gas leaks.
- One proposed solution to this problem involves the provision of a remotely controlled device within the gas cabinet to rotate the knob on the manually operated cylinder valves in the same manner as the operator would rotate the valves by hand.
- an object of the present invention is to provide an improved cylinder valve which avoids the aforementioned problems associated with the known manually operated cylinder valve. More specifically, an object of the invention is to provide an improved cylinder valve which enables the operator to actuate the cylinder valve from outside the gas cabinet, without having to reach inside the cabinet, which cylinder valve safely closes itself upon failure of a valve control signal as in a power failure, for example.
- a further object of the present invention is to provide an improved cylinder valve for mounting on a high pressure gas cylinder for controlling the flow of gas from the cylinder which significantly contributes to the safety of handling of hazardous gases such as those used extensively in the semiconductor industry by permitting the remote control of the cylinder valve to be subordinated to other parameters such as sensed earthquakes to effect an automatic closure of the cylinder valve to prevent gas leaks and possible injury.
- An additional object of the present invention is to provide an improved cylinder valve which can be mounted on a high pressure gas cylinder as a substitute for an existing hand operated valve, the cylinder valve of the invention having a physical configuration to fit within the existing safety cap of the gas cylinder and incorporating a safety pressure device according to the Compressed Gas Association specification (CGAS 1.1) and which cylinder valve has an outlet fitting meeting the configuration requirements of the CGA specifications.
- CGAS 1.1 Compressed Gas Association specification
- the cylinder valve of the invention which is adapted to be mounted on a high pressure gas cylinder as a substitute for a hand operated valve for controlling the flow of gas from the cylinder.
- the cylinder valve comprises means for mounting the cylinder valve on the high pressure gas cylinder, fluid passage means for conveying gas through the cylinder valve from an inlet for communicating with the high pressure gas cylinder to an outlet, first valve means for opening and closing the fluid passage means to control the flow of gas through the fluid passage means, and fluid pressure operated actuator means for operating the first valve means in response to the application of an external control pressure to the actuator means.
- an external source of a control fluid pressure permits the remote control of the cylinder valve so that the operator does not have to reach inside a gas cabinet to actuate the cylinder valve.
- the safety of the operator is further enhanced by an additional feature of the invention wherein means are provided in the cylinder valve for causing the first valve means to close the fluid passage means upon loss of the external control pressure to the actuator means. That is, in the event of a power failure during an earthquake or other catastrophe, the operator's safety is ensured to the extent possible by closure of the fluid passage means in the cylinder valve.
- the cylinder valve is physically configured to fit within an existing safety cap for the high pressure gas cylinder on which the cylinder valve is mounted.
- a pressure safety device according to the CGA specification (CGA S1.1) is provided in the cylinder valve in fluid communication with the fluid passage means. The pressure safety device operates to release gas pressure in the valve above a safe operating temperature and/or pressure.
- the cylinder valve further comprises second valve means located downstream of the first valve means in the vicinity of the outlet for opening and closing the fluid passage means to control the flow of gas through the fluid passage means.
- Means are provided for yieldably biasing the second valve means toward.a position to close the fluid passage means.
- means are provided for moving the second valve means to a position to open the fluid passage means in response to attachment of a connector to the outlet. Because of this a hazardous gas cannot be accidentally discharged from the cylinder valve outlet when its accompanying gas conduit has not been attached-to the outlet of the cylinder valve.
- the fluid pressure operated actuator means of the cylinder valve is a pneumatically operated actuator for opening the first valve means in response to the application of an external control pressure to the actuator.
- the means for causing the first valve means to close the fluid passage means upon loss of external control pressure yieldably biases the first valve means toward a position to close the fluid passage means so that upon loss of the external control pressure to the actuator the first valve means closes the fluid passage means.
- the pneumatically operated actuator and the means for yieldably biasing the first valve means constitute or operate jointly as a pressure regulator means in the disclosed embodiment for operating the first valve means so as to regulate the gas pressure in the fluid passage means downstream of the first valve means in response to the application of the external control pressure to the actuator while effecting the fail safe mode, that is, closing the fluid passage means, upon loss of the external control pressure to the actuator.
- the pneumatically operated actuator comprises a piston-cylinder unit to which the external control fluid pressure is applied.
- Means are provided for transmitting movement of a piston of the piston-cylinder unit to the first valve means for opening the first valve means.
- the means for transmitting movement of the piston to the first valve means includes a movable diaphragm defining a portion of the fluid passage means downstream of the first valve means, means outside of the fluid passage means for transmitting the movement of the piston to the diaphragm, and means inside of the fluid passage means for transmitting movement of the diaphragm to the first valve means for opening the first valve means.
- the diaphragm moves so as to balance the opposing forces thereon from, on the one hand, the piston-cylinder unit as a result of the control pressure thereto, and; on the other hand, the gas pressure on the diaphragm downstream of the first valve means which corresponds to the outlet gas pressure.
- the valve opening at the first valve means is controlled to create downstream a pressure determined by the force applied by the actuator.
- the outlet pressure is related to the value of the control pressure to the actuator.
- a one-way restrictor means is provided in the fluid passage means downstream of the first valve means, particularly between the second valve means and the outlet, for restricting the flow of gas flowing in the fluid passage means in the direction of the outlet.
- the restrictor means does not interfere with the reverse flow during the filling operation.
- an adapter can be applied to the pneumatic actuator to provide an override manual actuation as may be needed at the filling plant.
- the materials of the cylinder valve which contact the gas from the high pressure gas cylinder are resistant to hazardous gases including ammonia, silane, dichlorosilane, hydrogen chloride, arsine and phosphine and back-up seal means are provided in the cylinder valve to protect against diaphragm failure.
- the cylinder valve 1 of the invention is designed to mount directly on a high pressure gas cylinder 2, as a substitute for an existing hand wheel valve, and to fit within an existing protection or safety cap 3 as shown in Figure 8.
- the space within a typical safety cap is defined by a cylindrical envelope with a diameter of three inches and a height of 4.25 inches.
- the cylinder valve of the invention is physically configured to fit within this safety cap. It is connected to the high pressure gas cylinder 2 by means of a threaded sleeve 4 depending from the lower portion of the cylinder valve as shown in Figures 2 through 4, 6 and 8.
- the cylinder valve 1 is connected to the high pressure gas cylinder 2 by a 3/4 National Gas Taper (NGT) thread formed on the threaded sleeve 4.
- NKT National Gas Taper
- a fluid passage 5 is provided in the cylinder valve for conveying gas through the cylinder valve from an inlet 6 at the threaded sleeve 4 for communicating with the high pressure gas cylinder 2 to an outlet 7 of the cylinder valve.
- the outlet 7 is defined by an outlet fitting 8 which is screwed into the cylinder valve body 9 and locked in place by two retaining pins 10.
- the oulet fitting is sealed by a Teflon gasket 11, backed by a static O-ring seal 12.
- the outlet fitting is formed with an outlet thread 13 for attachment of a connector 14 to the outlet 7 of the cylinder valve 1 in the manner illustrated in Figure 9 of the drawings.
- the outlet fitting 8 meets the configuration requirements for a Compressed Gas Association (CGA) connection.
- the outlet thread 13 can be one of the following according.to CGA requirement:
- the cylinder valve 1 further includes a pressure safety device 15 according to the CGA specification (CGA Sl.l). More specifically, as shown in Figure 6 the pressure safety device 15 is in fluid communication with the fluid passage 5 adjacent the inlet 6 by means of a fluid passage 16. The pressure safety device is attached to the valve body 9 by a 1/4 NPT thread 17 as shown in Figure 6. Two types of safety devices are used, namely a burst disk 18 backed by a fusible alloy 19 and a cap 20 with a fusible alloy 21.
- the safety device can be a burst disk (Inconel) with gasket (silver) and sealing cap (brass chromeplated) backed by a fusible alloy, rated 3360 psi at 165°F., or a stainless cap with alloy fusible at 165°F, in the case of ammonia service, for example.
- a first valve 22 is provided in the cylinder valve 1 for opening and closing the fluid passage 5 to control the flow of gas through the fluid passage.
- the first valve 22 is biased by a spring 23 against an annular Teflon seal 24 about an opening 25 of a cap 26 to normally close the passage 5.
- the cap 26 is threadedly connected to the valve body 9 with a Teflon seal 27 interposed.
- a retainer 28 is positioned within the cap 26 to retain the seal 24 in position adjacent 25.
- a screen 29 is provided in the fluid passage 5 immediately upstream of the first valve 22 to protect the valve seat assembly against particulate contamination.
- a second screen 30 is provided in the passage 5 adjacent to the inlet 6.
- the valve 22 is provided with an elongated nose 31 on its upper end as shown in Figure 4 which projects into an enlarged area 32 of the fluid passage 5 so that the valve 22 may be actuated by a pneumatically operated actuator generally designated by the reference numeral 33.
- Plates 34, 35 and 36 are positioned within the enlarged area 32 of the fluid passage 5 between the elongated nose 31 of the valve 22 and a movable metal diaphragm 37 defining the upper wall of the enlarged area 32 of the passage 5.
- the plates are biased upwardly in the enlarged area 32 against the metal diaphragm 37 by means of a spring 38 and also by the end of the elongated nose 31 of the valve 22 which engages the lower plate 34.
- the upper plate 36 is formed with an annular raised portion 39 for engaging the metal diaphragm 37 and cooperating with the lower surface of a button 40 arranged on the opposite side of the diaphragm for transmitting downward force from the pneumatically operated actuator 33 to the elongated nose 31 of valve 22 for opening the valve as discussed below.
- the metal diaphragm 37 is supported on the cylinder valve body 9 about the enlarged area 32 by means of an annular cap 41 which presses the diaphragm against the upper edges of a shoulder 44 of the valve body surrounding the enlarged area.
- a Teflon seal 42 in an annular recess 43 about the shoulder 44 is compressed between the valve body 9 and the cap 41 to prevent escape of gases from the fluid passage 5 around the diaphragm.
- the cap 41 is urged downwardly in position against the diaphragm and shoulder 44 by means of cas 45 and 46, the lower end 47 of an actuator assembly 48 which is threadedly attached to the upper end of the recess .3 of the valve body and by a spring 49 positioned between the upper surface of the cap 46 and the lower end of a biston 50 of the actuator assembly as illustrated in Figure 4.
- a pin 51 is positioned adjacent a plug 90 threadedly atached in an opening 52 of the piston 50.
- the lower end o.the pin is connected to the button 40 so that downwardly directed forces produced in the pneumatically operated actuatc- assembly 48 are transmitted to the metal diaphragm 37 and plates 34, 35 and 36 beneath the diaphragm to the valve 22 or opening the valve.
- a retainer 53 is positioned about the pin 51 and held in position by com- plamentarily shaped openings formed in the caps 45 and 46.
- 0-rings 54, 55 and 56 provide back-up seals between the several members of the pneumatically operated actuator 33 as shown in Figure 4 to prevent leakage in the event of failure of the metal diaphragm 37.
- the piston 50 of the actuator assembly 48 is actually a dual piston configuration as seen from Figure 7 comprising a first piston 91 and second piston 92.
- the control pressure is applied to each piston which is located in its own chamber, 93 and 94, respectively.
- the pressure is applied to one side of each piston, while the other side is at atmospheric pressure.
- a spacer 95 separates the two chambers.
- the upper piston 91 has a sealed extension 96 protruding through the spacer.
- O-rings 97 seal the actuator assembly in the manner illustrated in Figure 7. Teflon rings 98 back-up the O-rings adjacent the pistons.
- the dual piston 50 is normally maintained in an upper position by the spring 38. It moves downwardly within the stepped cylinder 57 of the actuator assembly to open the valve 22 in response to the introduction of pressurized air from an external, remote source of-pressurized air 58 shown schematically in Figure 4.
- a fitting 59 is incorporated in the cylinder valve to receive the control pressure through a 1/8 OD nylon tubing, for example.
- a valve 60 located in the line from the source 58 permits the remote actuation of the pneumatically operated actuator 33 so that the operator does not have to reach within a gas cabinet enclosing the high pressure cylinder.
- the fitting 59 can be removed from the upper end of the actuator assembly 48 and a custom adapter, not shown, may be applied to the actuator assembly to provide an override manual actuation depressing the dual piston and opening the valve 22 as may be needed at the filling plant.
- a second valve 61 is located in the fluid passage 5 in the vicinity of the outlet 7 of the cylinder valve 1 for opening and closing the fluid passage to provide an additional control of the flow of gas through the fluid passage.
- a spring 62 biases the valve 61 against a Teflon seal 63 to close the passage 5 at an opening through the seal which forms a portion of the fluid passage 5.
- the seal 63 is supported between a cap 64 threadedly attached to the valve body 9 and a retainer 65 positioned within the cap.
- the connection between the cap 64 and the valve body 9 is sealed by a Teflon seal 66.
- a screen 67 is positioned immediately up stream of the spring 62 and valve 61 to protect the valve seat assembly from particulate contamination.
- the second valve 61 is provided with an elongated nose 68 which extends outwardly through an opening 63 in the cap 64 to enable the valve to be opened by a mechanism 70 upon attachment of a connector 14 to the outlet.
- the mechanism 70 is positioned within a stepped bore 71 of the outlet fitting 8 and includes a sliding valve 72, plates 73 and 74 and a spring 75 acting between the valve body 9 and the plates 73 and 74 to bias the plates and sliding valve against respective shoulders 76 and 77 of the stepped bore 71 so that the valve 61 makes sealing contact with the seal 63.
- the mechanism 70 opens the valve 61 as the sliding valve 72 is moved to the left.
- An annular Teflon seal 78 is provided in the outer free end of the sliding valve 72 to make sealing contact with the nipple of the connector before opening the fluid passage 5 by means of the second valve 61 to the downstream side of the first valve 22.
- the mechanism 70 closes the fluid passage by means of the second valve 61 before breaking the seal from the connector.
- a one-way restrictor79 is located in the fluid passage 5 between the second valve 61 and the outlet 7 for restricting the flow of gas flowing in the fluid passage - in a direction toward the outlet 7.
- the restrictor is in the form of a metal button 80 having a relatively small centrally located bore therein with a diameter of 0.0135 inch, for example.
- the button 80 is normally biased against a shoulder 82 of the sliding valve 72 with a Teflon seal 83 interposed by means of a spring 84 acting between the button 80 and a washer-screen 85 which protects the restriction
- the washer-screen 85 and spring 84 are retained in position within the sliding valve 72 by a ring 86 which cooperates with a shoulder 87 of the sliding valve.
- the outer diameters of the button 80 and Teflon seal 83 are 0.010 inch less than the diameter of the adjacent annular portion of the step bore 71 of the sliding valve so that during a filling operation gas pressure will move the button and seal away from the shoulder 82 and permit the incoming gas to pass unrestricted into the gas cylinder.
- the restrictor 79 is effective in the out flow direction only and does not interfere with the reverse flow during the filling operation.
- the materials of construction of the cylinder valve which contact the gas are resistant to hazardous gases such as ammonia, silane, dichlorosilane, hydrogen chloride, arsine and phosphine.
- the valve body, outlet fitting and parts in contact with the process gas are preferably formed of 316 stainless steel.
- the metallic components of of the closures including the valves and springs and also the diaphragm 37 are also formed of 316 stainless steel.
- the seals of the closures are preferably fluoropolymer and the O-rings are preferably formed of Viton or Kalrez.
- the outlet fitting seals are preferably Teflon, Viton or Kalrez.
- the pneumatically operated actuator is preferably formed of brass which has been electroless nickel plated and wherein the centrally located 0-ring is Silicone and the back-up rings are Teflon as noted previously.
- the valve is mounted directly on a high pressure gas cylinder containing a hazardous gas at a pressure of up to 3,000 psi by means of the threaded sleeve 4 on the lower end of the valve.
- a connector 14 is attached to the outlet fitting 8 in the manner illustrated in Figure 9 for distributing gas by way of a conduit 88 connected to the nipple 89 of the connector 14 once the valve 1 is actuated. Attachment of the connector 14 opens the second valve 61 through the movement of the sliding valve 72, plates 73 and 74 and valve 61 against the bias of the springs 62 and 75.
- the valve 1 can then be operated to release gas from the gas cylinder 2 to the conduit 88 by actuating the valve 60 in the fluid pressure line extending from the external source of pressurized air 58 to the fitting 59 of the valve 1.
- the control air pressure applied to the pneumatically operated actuator 33 is typically in the range of 0 to 100 psi but may go up to 150 psi.
- the cylinder valve can be used to control the flow of gas from a cylinder containing a gas under a pressure up to 3,000 psi.
- control pressure of 80 psi for example, will create an outlet pressure of approximately 500 psi at the outlet 7 of the cylinder valve. At this pressure the restrictor 79 will limit the gas flow from the cylinder valve outlet to 30 liters per minute. A change in the control pressure of 10 psi will result in a change in the outlet pressure of approximately 100 psi.
- the pneumatically operated actuator 33 in combination with the spring 23 operate the first valve 22 to regulate the gas pressure downstream of the first valve as a result of the balance of the forces from the control pressure on one side of the metal diaphragm 37 and the gas pressure in the fluid passage 5 downstream of the valve 22 acting on the other side of the diaphragm. If the pressure in the gas cylinder is lower than 500 psi, the outlet pressure will be equal to that in the cylinder. This would be the case for ammonia and dichlorosilane, for example.
- a custom tool may be applied to the actuator to override manually the pressure regulating function and create at the outlet a pressure equal to that in the cylinder, 600 psi for HCL, 2,000 psi for silane mix, arsine mix and phosphine mix, for example.
- a fail-safe mode where the valve 22 closes the fluid passage ? under the action of the spring 23 thereby enhancing the safety of the hazardous gas distribution system of the invention.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
- Control Of Fluid Pressure (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US72941485A | 1985-05-01 | 1985-05-01 | |
US729414 | 1985-05-01 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0200543A2 true EP0200543A2 (fr) | 1986-11-05 |
EP0200543A3 EP0200543A3 (fr) | 1987-07-29 |
Family
ID=24930924
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP86303279A Ceased EP0200543A3 (fr) | 1985-05-01 | 1986-04-30 | Vanne pour la commande d'écoulement de gaz d'une bonbonne cylindrique de gaz à haute pression |
Country Status (1)
Country | Link |
---|---|
EP (1) | EP0200543A3 (fr) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0298272A2 (fr) * | 1987-07-09 | 1989-01-11 | Messer Griesheim Gmbh | Régulateur de température pour gaz |
GB2211586A (en) * | 1988-01-12 | 1989-07-05 | Neriki Kk | Gas cylinder valve |
FR2779247A1 (fr) * | 1998-05-29 | 1999-12-03 | Air Liquide | Detendeur a pilotage pneumatique de la pression d'utilisation |
US10247732B2 (en) | 2010-06-01 | 2019-04-02 | Indiana University Research And Technology Corporation | Materials and methods for diagnosing and predicting the course of prostate cancer |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3192782A (en) * | 1961-11-02 | 1965-07-06 | Robertshaw Controls Co | Flexible seal |
DE2155452A1 (de) * | 1971-11-08 | 1973-05-17 | Yamato Sangyo Co Ltd | Regelventil |
FR2163837A5 (fr) * | 1971-12-03 | 1973-07-27 | Procedes Sem | |
FR2176727A1 (en) * | 1972-03-22 | 1973-11-02 | Solvay | Discharge valve - for liquefied gas cylinder permitting liq and/or gas discharge |
-
1986
- 1986-04-30 EP EP86303279A patent/EP0200543A3/fr not_active Ceased
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3192782A (en) * | 1961-11-02 | 1965-07-06 | Robertshaw Controls Co | Flexible seal |
DE2155452A1 (de) * | 1971-11-08 | 1973-05-17 | Yamato Sangyo Co Ltd | Regelventil |
FR2163837A5 (fr) * | 1971-12-03 | 1973-07-27 | Procedes Sem | |
FR2176727A1 (en) * | 1972-03-22 | 1973-11-02 | Solvay | Discharge valve - for liquefied gas cylinder permitting liq and/or gas discharge |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0298272A2 (fr) * | 1987-07-09 | 1989-01-11 | Messer Griesheim Gmbh | Régulateur de température pour gaz |
DE3722692A1 (de) * | 1987-07-09 | 1989-01-19 | Messer Griesheim Gmbh | Druckregler fuer gase |
EP0298272A3 (en) * | 1987-07-09 | 1990-07-18 | Messer Griesheim Gmbh | Gas pressure regulator |
GB2211586A (en) * | 1988-01-12 | 1989-07-05 | Neriki Kk | Gas cylinder valve |
GB2211586B (en) * | 1988-01-12 | 1992-03-11 | Neriki Kk | Gas-cylinder valve |
FR2779247A1 (fr) * | 1998-05-29 | 1999-12-03 | Air Liquide | Detendeur a pilotage pneumatique de la pression d'utilisation |
US10247732B2 (en) | 2010-06-01 | 2019-04-02 | Indiana University Research And Technology Corporation | Materials and methods for diagnosing and predicting the course of prostate cancer |
Also Published As
Publication number | Publication date |
---|---|
EP0200543A3 (fr) | 1987-07-29 |
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Inventor name: OLLIVIER, LOUIS A. |