EP0199405A3 - Liquid detergents containing surfactant, proteolytic enzyme and boric acid - Google Patents

Liquid detergents containing surfactant, proteolytic enzyme and boric acid Download PDF

Info

Publication number
EP0199405A3
EP0199405A3 EP86200586A EP86200586A EP0199405A3 EP 0199405 A3 EP0199405 A3 EP 0199405A3 EP 86200586 A EP86200586 A EP 86200586A EP 86200586 A EP86200586 A EP 86200586A EP 0199405 A3 EP0199405 A3 EP 0199405A3
Authority
EP
European Patent Office
Prior art keywords
boric acid
proteolytic enzyme
enzyme
containing surfactant
liquid detergents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP86200586A
Other versions
EP0199405B1 (en
EP0199405A2 (en
Inventor
Manuel Garcia Venegas
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to AT86200586T priority Critical patent/ATE77649T1/en
Publication of EP0199405A2 publication Critical patent/EP0199405A2/en
Publication of EP0199405A3 publication Critical patent/EP0199405A3/en
Application granted granted Critical
Publication of EP0199405B1 publication Critical patent/EP0199405B1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38663—Stabilised liquid enzyme compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Enzymes And Modification Thereof (AREA)
  • Peptides Or Proteins (AREA)

Abstract

Liquid detergent compositions containing synthetic surfactant, specific proteolytic enzyme, boric acid or a boron compound capable of forming boric acid in the composition, and calcium ion are disclosed. The compositions exhibit improved enzyme stability because boric acid stabilizes the proteases herein to a greater degree than it does other proteases. Preferred laundry detergent compositions containing anionic surfactant and detergency builder also provide improved cleaning performance, particularly through-the-wash, on enzyme-sensitive stains.
EP86200586A 1985-04-15 1986-04-07 Liquid detergents containing surfactant, proteolytic enzyme and boric acid Expired EP0199405B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT86200586T ATE77649T1 (en) 1985-04-15 1986-04-07 LIQUID DETERGENTS CONTAINING A SURFACE-ACTIVE COMPOUND, A PROTEOLYTIC ENZYME AND BORIC ACID.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US72310385A 1985-04-15 1985-04-15
US723103 1991-06-28

Publications (3)

Publication Number Publication Date
EP0199405A2 EP0199405A2 (en) 1986-10-29
EP0199405A3 true EP0199405A3 (en) 1988-08-31
EP0199405B1 EP0199405B1 (en) 1992-06-24

Family

ID=24904854

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86200586A Expired EP0199405B1 (en) 1985-04-15 1986-04-07 Liquid detergents containing surfactant, proteolytic enzyme and boric acid

Country Status (5)

Country Link
EP (1) EP0199405B1 (en)
JP (1) JPS62596A (en)
AT (1) ATE77649T1 (en)
CA (1) CA1302925C (en)
DE (1) DE3685769T2 (en)

Families Citing this family (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4914031A (en) * 1987-04-10 1990-04-03 Amgen, Inc. Subtilisin analogs
US6287841B1 (en) 1988-02-11 2001-09-11 Genencor International, Inc. High alkaline serine protease
PT89702B (en) 1988-02-11 1994-04-29 Gist Brocades Nv PROCESS FOR PREPARING NEW PROTEOLITIC ENZYMES AND DETERGENTS THAT CONTAINS THEM
US5039446A (en) * 1988-07-01 1991-08-13 Genencor International, Inc. Liquid detergent with stabilized enzyme
NZ237570A (en) * 1990-04-13 1993-09-27 Colgate Palmolive Co Enzyme stabilising composition and stabilised enzyme-containing built detergent compositions
KR100226000B1 (en) * 1990-09-28 1999-10-15 데이비드 엠 모이어 Polyhydroxy fatty acid amides in zeolite/layered silicate built detergents
US5178789A (en) * 1991-06-27 1993-01-12 Genencor International, Inc. Liquid detergent with stabilized enzyme
JPH0514182U (en) * 1991-08-08 1993-02-23 津田駒工業株式会社 Weft detection device
AU4024993A (en) * 1992-04-13 1993-11-18 Procter & Gamble Company, The Thixotropic liquid automatic dishwashing composition with enzyme
EP0693549A1 (en) 1994-07-19 1996-01-24 The Procter & Gamble Company Solid bleach activator compositions
ES2115338T3 (en) 1995-07-13 1998-06-16 Procter & Gamble FOAMING COMPOSITION FOR PACKAGING.
EP0753567A1 (en) 1995-07-14 1997-01-15 The Procter & Gamble Company Softening through the wash compositions
EP0778342A1 (en) 1995-12-06 1997-06-11 The Procter & Gamble Company Detergent compositions
CZ355098A3 (en) 1996-05-03 1999-04-14 The Procter & Gamble Company Detergent agents exhibiting enhanced dispersion of dirt and containing polyamine polymers
GB2367065B (en) 2000-09-20 2002-11-20 Reckitt Benckiser Inc Enzyme containing laundry booster compositions
GB0104980D0 (en) * 2001-02-28 2001-04-18 Unilever Plc Liquid cleaning compositions and their use
GB2373254A (en) * 2001-03-16 2002-09-18 Procter & Gamble Detergent product
GB0207430D0 (en) * 2002-03-28 2002-05-08 Unilever Plc Liquid cleaning compositionsand their use
US20110166370A1 (en) 2010-01-12 2011-07-07 Charles Winston Saunders Scattered Branched-Chain Fatty Acids And Biological Production Thereof
EP2569406A4 (en) 2010-05-14 2013-11-13 Sun Products Corp Polymer-containing cleaning compositions and methods of production and use thereof
MX345025B (en) 2010-07-02 2017-01-12 Procter & Gamble Detergent product.
MX2012015187A (en) 2010-07-02 2013-05-09 Procter & Gamble Method for delivering an active agent.
CN102971126B (en) 2010-07-02 2016-03-23 宝洁公司 The method of film is prepared by non-woven webs
CN102971453B (en) 2010-07-02 2015-08-12 宝洁公司 Comprise their method of the long filament of non-flavorants activating agent, nonwoven web and preparation
JP5859526B2 (en) 2010-07-02 2016-02-10 ザ プロクター アンド ギャンブルカンパニー Filaments containing an activator nonwoven web and methods for making the same
US20120172281A1 (en) 2010-07-15 2012-07-05 Jeffrey John Scheibel Detergent compositions comprising microbially produced fatty alcohols and derivatives thereof
JP5715250B2 (en) 2010-07-15 2015-05-07 ザ プロクター アンド ギャンブルカンパニー Rinse-off conditioning composition containing near-end branched alcohol
WO2012138423A1 (en) 2011-02-17 2012-10-11 The Procter & Gamble Company Compositions comprising mixtures of c10-c13 alkylphenyl sulfonates
US20120213726A1 (en) 2011-02-17 2012-08-23 Phillip Richard Green Bio-based linear alkylphenyl sulfonates
EP2725912A4 (en) 2011-06-29 2015-03-04 Solae Llc Baked food compositions comprising soy whey proteins that have been isolated from processing streams
WO2013043803A2 (en) 2011-09-20 2013-03-28 The Procter & Gamble Company Detergent compositions comprising specific blend ratios of isoprenoid-based surfactants
CA2849149A1 (en) 2011-09-20 2013-03-28 The Procter & Gamble Company Detergent compositions comprising sustainable surfactant systems comprising isoprenoid-derived surfactants
WO2013043852A2 (en) 2011-09-20 2013-03-28 The Procter & Gamble Company Easy-rinse detergent compositions comprising isoprenoid-based surfactants
WO2013043855A2 (en) 2011-09-20 2013-03-28 The Procter & Gamble Company High suds detergent compositions comprising isoprenoid-based surfactants
AR088442A1 (en) 2011-09-20 2014-06-11 Procter & Gamble DETERGENT COMPOSITIONS THAT INCLUDE PRIMARY SURFACTANT SYSTEMS THAT INCLUDE SURFACTANTS BASED ON HIGHLY RAMIFIED ISOPRENOIDS AND OTHER SURFACTANTS
WO2013070559A1 (en) 2011-11-11 2013-05-16 The Procter & Gamble Company Surface treatment compositions including shielding salts
EP2800802B1 (en) 2012-01-04 2018-02-28 The Procter and Gamble Company Active containing fibrous structures with multiple regions having differing densities
RU2016140896A (en) 2012-01-04 2018-12-14 Дзе Проктер Энд Гэмбл Компани FIBERAL STRUCTURES CONTAINING PARTICLES AND METHODS FOR THEIR MANUFACTURE
MX342355B (en) 2012-01-04 2016-09-23 Procter & Gamble Active containing fibrous structures with multiple regions.
CA2931976C (en) 2013-12-09 2019-11-12 The Procter & Gamble Company Fibrous structures including an active agent and having a graphic printed thereon
US20150210964A1 (en) 2014-01-24 2015-07-30 The Procter & Gamble Company Consumer Product Compositions
US20170321157A1 (en) * 2016-05-03 2017-11-09 The Procter & Gamble Company Automatic dishwashing detergent composition
US11697905B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles that exhibit consumer acceptable article in-use properties
US11697904B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles that exhibit consumer acceptable article in-use properties
GB2604760B (en) 2017-01-27 2022-11-30 Procter & Gamble Active agent-containing articles that exhibit consumer acceptable article in-use properties
US11697906B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles and product-shipping assemblies for containing the same
WO2020123889A1 (en) 2018-12-14 2020-06-18 The Procter & Gamble Company Foaming fibrous structures comprising particles and methods for making same
US11485934B2 (en) 2019-08-02 2022-11-01 The Procter & Gamble Company Foaming compositions for producing a stable foam and methods for making same
US20210148044A1 (en) 2019-11-15 2021-05-20 The Procter & Gamble Company Graphic-Containing Soluble Articles and Methods for Making Same
CN117043401A (en) 2021-05-28 2023-11-10 宝洁公司 Surfactant-containing natural polymer-based fibrous element and method for producing same
WO2023057367A1 (en) 2021-10-08 2023-04-13 Unilever Ip Holdings B.V. Laundry composition

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2126242A (en) * 1982-08-30 1984-03-21 Colgate Palmolive Co Stabilized enzyme-containing detergent compositions
US4507219A (en) * 1983-08-12 1985-03-26 The Proctor & Gamble Company Stable liquid detergent compositions
EP0162033A2 (en) * 1984-05-14 1985-11-21 The Procter & Gamble Company Liquid detergents containing boric acid to stabilize enzymes
EP0130756B1 (en) * 1983-06-24 1991-02-06 Genencor International, Inc. Procaryotic carbonyl hydrolases, methods, dna, vectors and transformed hosts for producing them, and detergent compositions containing them

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2126242A (en) * 1982-08-30 1984-03-21 Colgate Palmolive Co Stabilized enzyme-containing detergent compositions
EP0130756B1 (en) * 1983-06-24 1991-02-06 Genencor International, Inc. Procaryotic carbonyl hydrolases, methods, dna, vectors and transformed hosts for producing them, and detergent compositions containing them
US4507219A (en) * 1983-08-12 1985-03-26 The Proctor & Gamble Company Stable liquid detergent compositions
EP0162033A2 (en) * 1984-05-14 1985-11-21 The Procter & Gamble Company Liquid detergents containing boric acid to stabilize enzymes

Also Published As

Publication number Publication date
EP0199405B1 (en) 1992-06-24
ATE77649T1 (en) 1992-07-15
EP0199405A2 (en) 1986-10-29
JPS62596A (en) 1987-01-06
CA1302925C (en) 1992-06-09
DE3685769D1 (en) 1992-07-30
DE3685769T2 (en) 1993-01-21

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