EP0190280A1 - Gas correlation lidar - Google Patents

Gas correlation lidar

Info

Publication number
EP0190280A1
EP0190280A1 EP85904024A EP85904024A EP0190280A1 EP 0190280 A1 EP0190280 A1 EP 0190280A1 EP 85904024 A EP85904024 A EP 85904024A EP 85904024 A EP85904024 A EP 85904024A EP 0190280 A1 EP0190280 A1 EP 0190280A1
Authority
EP
European Patent Office
Prior art keywords
laser
laser beam
gas
determined
passed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP85904024A
Other languages
German (de)
English (en)
French (fr)
Inventor
Hans Georg Edner
Sune Roland Svanberg
Leif Peter Uneus
Erik Wilhelm Wendt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boliden AB
Original Assignee
Boliden AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boliden AB filed Critical Boliden AB
Publication of EP0190280A1 publication Critical patent/EP0190280A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01SRADIO DIRECTION-FINDING; RADIO NAVIGATION; DETERMINING DISTANCE OR VELOCITY BY USE OF RADIO WAVES; LOCATING OR PRESENCE-DETECTING BY USE OF THE REFLECTION OR RERADIATION OF RADIO WAVES; ANALOGOUS ARRANGEMENTS USING OTHER WAVES
    • G01S17/00Systems using the reflection or reradiation of electromagnetic waves other than radio waves, e.g. lidar systems
    • G01S17/88Lidar systems specially adapted for specific applications
    • G01S17/95Lidar systems specially adapted for specific applications for meteorological use
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/3504Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis
    • G01N21/3518Devices using gas filter correlation techniques; Devices using gas pressure modulation techniques
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/39Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using tunable lasers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A90/00Technologies having an indirect contribution to adaptation to climate change
    • Y02A90/10Information and communication technologies [ICT] supporting adaptation to climate change, e.g. for weather forecasting or climate simulation

Definitions

  • idar (dial) technique* " ⁇ is a powerful and widely used remote-sensing method for monitoring of atmospheric gases, e.g. air pollutants.
  • the object of the present invention is to obtain an improved and simplified lidar technique for remote control and sensing for monitoring of atmospheric gases using a combination of lidar and gas filter correlation techniques ⁇ . Basic operational considerations are given below and preliminary remote-sensing experiments on mer ⁇ cury are described.
  • pulsed laser radiation is transmitted into the atmosphere at two alternate wavelengths, one on an absorption line of the species of interest and one off the absorption line but still close in wavelength (reference wavelength).
  • the range-dependent backscattering which is mainly due to Mie scattering from particles, is recorded with an optical telescope equipped by a detector and time- resolving electronics.
  • Atmospheric turbulence which has a correlation time * of less than 10 ms will largely determine dial performance.
  • non-laser (passive) long-path optical absorption monitoring the effects of atmos ⁇ pheric turbulence can be eliminated by fast scanning such as in doas differential £ptical absorption spectroscopy ⁇ , dispersive correlation spectroscopy ⁇ and gas filter correlation spectroscopy4>5.
  • Simultaneous "on/off" monitoring can also be achieved using optical multichannel (array) techniques or systems with beam-splitters.
  • Gas correlation spectroscopy is a particularly simple and powerful technique, where the incoming light is passed either directly to a detector or first passing through a cell containing an optically thick sample of the gas to be studied.
  • the light intensities in a selected wavelength region are balanced out using lock-in or electrical bridge techniques. With the gas present in the atmosphere the light passing through the gas cell is still the same, whereas the additional absorption in the direct beam results in an inbalance in the electronics, which after calibration can be directly expressed as a pp ⁇ rm atmospheric gas burden.
  • the gas correlation concept can readily be applied to the lidar configuration leading to important system simplifications and improvements in signal-to-noise ratio.
  • only one fairly broadband laser is needed and no laser tuning is necessary between pulses.
  • On- and off resonance wavelengths are transmitted and detected simultaneously.
  • the laser is tuned to the 2537 A Hg resonance line.- (A pulsed frequency-doubled dye laser could be used.)
  • the region of Hg absorption (considering isotope shifts, hyperfine structure, Doppler and pressure-broadening) is about 0.05 A.
  • the laser band-width is chosen to be about three times this value. If a short pulse (few ns) is used, no pronounced mode structure will be obtained and a smooth spectral distribu ⁇ tion for the pulse is assumed for simplicity as indicated in the figure.
  • the laser pulse is transmitted into the atmosphere through a Hg cloud at some distance from the lidar system and is finally hitting a topographic target or a retroreflector.
  • the whole spectral distribution is measured, which for the case of no atmospheric mercury is the same as the transmitted spectral distribution.
  • the detected signals in the two arms can be made equal (balanced out as in passive gas correlation) by beam attenuation or gain adjustments. If external Hg is present less signal is detected in this arm whereas the signal in the gas cell arm is unaffected. The inbalance between the two arms indicates the presence of the external gas.
  • spectral and temporal curves at different points in the system are shown illustrating the measurement process. In particular, spectral distributions could be considered for the final target echoes.
  • a deviation from 1 is obtained in the presence of external Hg.
  • the ratio (R) is independent of the laser pulse energy, turbulence effects etc, since the measurements are performed simultaneously on the same pulse, this is true for the signals recorded range resolved at any one delay. For the fast moving platforms this is a great advantage.
  • the percentage deviation from 1 in the divided signal is the same as the one that would have been obtained in a dial measurement where the laser would be used once tuned on the absorption line and once tuned completely off the line. Since a linewidth larger than the absorption linewidth is used the relevant absorption- cross-sections are dependent on the actual laser linewidth, and an optical depth dependence (deviation from the Beer-Lambert law) also persists.
  • a gas correlation lidar system is best calibrated by inserting cells with known ppm-m numbers in the light path between the telescope and the detector arrangement in direct connection with the actual measurements.
  • the spectral distribution within the laser bandwidth will vary from pulse to pulse and this fact will result in a strongly increased noise level, since the two detection arms can no longer be balanced out.
  • it is possible to monitor the relevant spectral fluctuations of the laser by detecting the ratio Q 0 of the intensity of the laser beam for a direct path to a detector and when passing an identical gas correlation cell. No special arrangement is needed for this.
  • the prompt signals due to light scattering in the telescope can be adjusted to a proper level and can be isolated from an atmospheric backscattering background by an initial separation of the transmitted laser beam from the telescope optical axis.
  • the signals are recorded together with the atmospheric returns as indicated in Fig. 1. If a low external gas concentration can be assumed close to the telescope and a laser power yielding a sufficient atmospheric backscatter as in the figure is used, the 0 value can also be obtained from the close-range backscattering. It can easily be shown that
  • a laser simultaneously emitting two close-lying wavelengths could be used together with gas filter techniques as described above.
  • true gas correlation ⁇ with automatic rejection of interfering species should be achievable, e.g. in a NO2 lidar system. Further, the same concept should apply for properly selected wave-length regions of multi-line HF/DF and C0 2 TEA lasers.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Remote Sensing (AREA)
  • Electromagnetism (AREA)
  • Computer Networks & Wireless Communication (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Radar, Positioning & Navigation (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)
  • Spectrometry And Color Measurement (AREA)
EP85904024A 1984-08-10 1985-08-08 Gas correlation lidar Withdrawn EP0190280A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE8404064 1984-08-10
SE8404064A SE450913B (sv) 1984-08-10 1984-08-10 Gaskorrelerad lidar

Publications (1)

Publication Number Publication Date
EP0190280A1 true EP0190280A1 (en) 1986-08-13

Family

ID=20356697

Family Applications (1)

Application Number Title Priority Date Filing Date
EP85904024A Withdrawn EP0190280A1 (en) 1984-08-10 1985-08-08 Gas correlation lidar

Country Status (4)

Country Link
EP (1) EP0190280A1 (sv)
AU (1) AU4722985A (sv)
SE (1) SE450913B (sv)
WO (1) WO1986001295A1 (sv)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2533322A2 (en) 2000-02-09 2012-12-12 NGK Insulators, Ltd. Lithium secondary battery and manufacturing method thereof
US10458904B2 (en) 2015-09-28 2019-10-29 Ball Aerospace & Technologies Corp. Differential absorption lidar
US10921245B2 (en) 2018-06-08 2021-02-16 Ball Aerospace & Technologies Corp. Method and systems for remote emission detection and rate determination

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Publication number Priority date Publication date Assignee Title
GB2264169B (en) * 1992-02-07 1995-08-02 Alan John Hayes Fluid monitoring
DE4300853C2 (de) * 1993-01-15 2003-09-04 Daimler Chrysler Ag Verfahren zur spektroskopischen Bestimmung des Stickstoffoxidgehalts
DE4324154A1 (de) * 1993-07-19 1995-02-02 Kayser Threde Gmbh Vorrichtung und Verfahren zur räumlich hochauflösenden Analyse mindestens einer Gaskomponente in einem Gasgemisch
US7411196B2 (en) * 2005-08-18 2008-08-12 Itt Manufacturing Enterprises, Inc. Multi-sensors and differential absorption LIDAR data fusion
ATE441101T1 (de) * 2005-12-01 2009-09-15 Pergam Suisse Ag Mobile ferndetektion von fluiden mittels laser
US7884937B2 (en) * 2007-04-19 2011-02-08 Science & Engineering Services, Inc. Airborne tunable mid-IR laser gas-correlation sensor
FR2916849B1 (fr) * 2007-05-29 2010-04-23 Univ Claude Bernard Lyon Procede de teledetection optique de composes dans un milieu
CN102353650A (zh) * 2011-07-06 2012-02-15 南京信息工程大学 基于激光雷达技术的液体爆炸物探测方法与系统
CN103293116B (zh) * 2013-05-03 2015-03-25 中国科学院合肥物质科学研究院 一种微脉冲差分吸收激光雷达水汽时空分布自动连续探测装置
CN103575675A (zh) * 2013-10-30 2014-02-12 中国科学院安徽光学精密机械研究所 机载多角度区域污染分布扫描探测装置
US10557939B2 (en) * 2015-10-19 2020-02-11 Luminar Technologies, Inc. Lidar system with improved signal-to-noise ratio in the presence of solar background noise
CN106442368B (zh) * 2016-07-22 2019-07-30 天津理工大学 基于emd的二氧化硫紫外差分吸收光谱降噪重构方法
CN110470630B (zh) * 2018-05-11 2021-12-28 西安电子科技大学 一种基于差分模式的分布式光纤气体传感器
CN110470605B (zh) * 2018-05-11 2022-02-18 西安电子科技大学 一种基于光纤耦合模式的多节点光声气体检测方法
CN109283550B (zh) * 2018-11-23 2023-05-05 中国科学院合肥物质科学研究院 全固态全天时水汽扫描探测激光雷达系统及探测方法

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US3723007A (en) * 1971-01-22 1973-03-27 Avco Corp Remote quantitative analysis of materials
DE2521934C3 (de) * 1975-05-16 1978-11-02 Erwin Sick Gmbh Optik-Elektronik, 7808 Waldkirch Vorrichtung zur Bestimmung der Konzentrationen von Komponenten eines Abgasgemisches
DE3007236A1 (de) * 1980-02-27 1981-09-10 Messerschmitt-Bölkow-Blohm GmbH, 8000 München Vorrichtung zur ueberwachung eines gebietes auf atmosphaerische parameter
FR2531535B1 (fr) * 1982-08-03 1985-08-30 Onera (Off Nat Aerospatiale) Procede et dispositif de dosage de faible teneur de composants gazeux
DE3334264A1 (de) * 1982-09-25 1984-04-05 Showa Denko K.K., Tokyo Verfahren und messgeraet zum messen der methan-konzentration in einem gasgemisch

Non-Patent Citations (1)

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Title
See references of WO8601295A1 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2533322A2 (en) 2000-02-09 2012-12-12 NGK Insulators, Ltd. Lithium secondary battery and manufacturing method thereof
US10458904B2 (en) 2015-09-28 2019-10-29 Ball Aerospace & Technologies Corp. Differential absorption lidar
US10921245B2 (en) 2018-06-08 2021-02-16 Ball Aerospace & Technologies Corp. Method and systems for remote emission detection and rate determination

Also Published As

Publication number Publication date
AU4722985A (en) 1986-03-07
WO1986001295A1 (en) 1986-02-27
SE8404064D0 (sv) 1984-08-10
SE8404064L (sv) 1986-02-11
SE450913B (sv) 1987-08-10

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RESTELLI P. Camagni and S. Sandroni (Eds). 279-299

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Inventor name: SVANBERG, SUNE, ROLAND

Inventor name: EDNER, HANS, GEORG

Inventor name: WENDT, ERIK, WILHELM

Inventor name: UNEUS, LEIF, PETER