EP0178172B1 - Process for recovering hydrogen and hydrocarbons from the effluent stream of a hydrogen-producing hydrocarbon conversion process - Google Patents
Process for recovering hydrogen and hydrocarbons from the effluent stream of a hydrogen-producing hydrocarbon conversion process Download PDFInfo
- Publication number
- EP0178172B1 EP0178172B1 EP85307249A EP85307249A EP0178172B1 EP 0178172 B1 EP0178172 B1 EP 0178172B1 EP 85307249 A EP85307249 A EP 85307249A EP 85307249 A EP85307249 A EP 85307249A EP 0178172 B1 EP0178172 B1 EP 0178172B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- stream
- process stream
- hydrocarbons
- hydrogen
- zone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/229—Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/048—Composition of the impurity the impurity being an organic compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S62/00—Refrigeration
- Y10S62/931—Recovery of hydrogen
- Y10S62/932—From natural gas
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
Description
- The subject process relates to a product recovery process for use with a hydrogen-producing hydrocarbon conversion process. Specifically, the subject product recovery process relates to product recovery from a catalytic process referred to as dehydrocyclodimerization wherein two or more molecules of a light aliphatic hydrocarbon, such as propane, are joined together to form a product aromatic hydrocarbon. Non-aromatic hydrocarbons are also produced, especially when substantial amounts of olefins are present in the feed. The invention specifically relates to a separatory method which may be used to recover hydrogen, unconverted reactants, product aromatic hydrocarbons and light hydrocarbon products from a vapor phase reaction zone effluent stream. This separatory method allows for recycling unconverted feed hydrocarbons to the reaction zone.
- There are a large number of references which describe the conversion of light aliphatic hydrocarbons to aromatic hydrocarbons. For instance, U.S. Patent 2,992,283 issued to J. Eng describes the conversion of propylene to a variety of higher molecular weight hydrocarbons using a treated crystalline aluminosilicate as the catalyst. U.S. Patent 4,347,394 issued to C. M. Detz et al describes the conversion of Cs-plus hydrocarbons to aromatics using a non-acidic zeolite supporting a platinum compound. U.S. Patent 4,329,532 issued to P. J. Conn et al describes the conversion of C4-minus olefins or mixtures of olefins and paraffins to aromatic hydrocarbons. The catalyst comprises a crystalline silicate having a specified composition, crystallite size range,and X-ray diffraction pattern. U.S. Patent 4,444,988 issued to L. M. Capsuto et al describes a process flow for the recovery of the products of a similar process consuming a C2-CS olefinic feedstock.
- U.S. Patent 4,180,689 issued to E. E. Davies et al describes the conversion of C3-C8 aliphatic hydrocarbons to aromatic hydrocarbons in a process which employs a catalyst comprising gallium supported on an aluminosilicate. U.S. Patent 3,761,389 issued to L. D. Rollmann et al describes an improved process for converting C2 to 400°F hydrocarbons to aromatics over a ZSM-5 type catalyst. The improvement resides in the use of two reaction stages in series, with the first being at more severe operating conditions. U.S. Patent 3,843,740 issued to T. O. Mitchell et al also describes a process for aromatizing aliphatic feedstocks using two different catalysts in the reactor. This reference is also pertinent for the process diagram illustrating the recovery of the product aromatics by fractionation.
- The separation of product hydrocarbons from a reaction zone effluent stream which also contains light hydrocarbons and possibly hydrogen is important to the successful operation of several hydrocarbon conversion processes. For instance, U.S. Patents 3,537,978 issued to W. B. Borst, Jr. and 3,574,089 issued to J. T. Forbes describe the recovery of naphtha, hydrogen-rich recycle gas, and light hydrocarbon streams from the effluent of a catalytic reforming zone. U.S. Patent 3,101,261 issued to C. W. Skarstrom illustrates a process to recover hdyrogen light ends and naphtha from the effluent of a reforming reaction zone. These references are pertinent for their showing of the use of such separatory techniques as partial condensation, stripping columns, and absorption.
- U.S. Patents 4,381,417 issues to B. V. Vora et al, and 4,381,418 issued to S. A. Gewartowski et al. describe product recovery systems for dehydrogenation processes in which expansion of a gas stream provides fluids used as coolant media. Referring to the latter reference, the reactor effluent is cooled, dried, further cooled, and then passed into a vapor-
liquid separation zone 28. The vapors from this zone are depressurized inturbine 32 to yield a cold mixed phase stream collected inseparation zone 34. Liquid from this zone is flashed into the separation zone 51. - U.S. Patent 3,838,553 issued to K. S. Koherty is pertinent for its description of the use of low temperatures and elevated pressures to affect the separation of vapors and for the integration of a low temperature separation zone with a different type of separation zone. In Figure 2 of this reference, the still high pressure effluent of the low temperature separation zone flows into a pressure swing adsorption zone.
- Selectively permeable membranes are described in U.S. Patents 4,180,388 issued to T. E. Graham et al, and 4,264,338 issued to H. R. Null. These references are also pertinent for their showing of various arrangements of two or more membrane separation units in various series flow with recycle and interstage compression.
- The invention is a unique method of separating unconverted reactants from the product hydrogen and Cs-plus hydrocarbons contained in the vapor phase effluent stream of a hydrogen-producing hydrocarbon conversion process - for example, a dehydrocyclodimerization process. The process is characterized by a flow scheme which features an initial compression of a vapor stream followed by integrated absorption, selective membrane separation and autorefrigeration zones. This allows obtaining the benefits of these different separation techiques without extensive utilities and capital costs for gas compression. A broad embodiment of the invention may be characterized as a process for the recovery of hydrogen and hydrocarbons from a vapor phase stream derived from a reactor effluent of a hydrocarbon conversion process which comprises the steps of compressing a vapor phase first process stream which comprises hydrogen and C,-C3 hydrocarbons; passing the first process steam into a membrane separation zone in which the first process stream is contacted with at least one selective membrane through which hydrogen selectively permeates and thereby producing a hydrogen-rich product stream which is removed from the process and a vapor phase second process stream which comprises Cl-C3 hydrocarbons; forming a vapor phase third process stream comprising methane and a liquid phase fourth process stream which comprises ethane and propane by partially condensing the second process stream by indirect heat exchange against a cooling medium followed by vapor-liquid separation; flashing the fourth process stream to a subtantially lower pressure and thereby forming a vapor phase sixth process stream, which comprises methane and a liquid phase fifth process stream, which comprises ethane and propane; employing the fifth process stream, to cool the second process stream; and removing the sixth process stream from the process.
- The drawing is a simplified schematic diagram of a process which converts a propane-containing mixture fed through
lines 1 and 5 into benzene removed in line 42 and C7-ptus aromatics removed inline 45. The effluent stream of the reactor 7 is partially condensed and separated into vapor and condensate phases. The vapor phase is processed through theabsorber 15 to yield vapor which flows into selectivemembrane separation zones - Processes for the conversion of light aliphatic hydrocarbons to aromatic or nonaromatic Cs-plus hydrocarbons have been the subject of significant development efforts as evidenced by the previously cited references. The basic utility of the process is the conversion of the low cost highly available C3 and C4 hydrocarbons into the more valuable aromatic hydrocarbons and hydrogen or to convert the feed hydrocarbons to higher molecular weight products. This may be desired simply to upgrade the value of the hydrocarbons. It may also be desired to correct an overabund- ance of the C3 and C4 hydrocarbons or to fulfil a need for the aromatic hydrocarbons. The aromatic hydrocarbons are highly useful in the production of a wide range of petrochemicals, with benzene being one of the most widely used basic feed hydrocarbon chemicals. The product aromatic hydrocarbons are also useful as blending components in high octane number motor fuels.
- The feed compounds to the subject process are light aliphatic hydrocarbons having from 2 to 4 carbon atoms per molecule. The feed stream may comprise a single compound or a mixture of two or more of the compounds. The preferred feed compounds are propane, propylene, the butanes, and the butylenes. The preference for an olefinic or a saturate feed is dependent on the price of the available feeds and the value of the corresponding products. The feed stream to the process may also contain some C2 and C5 hydrocarbons. It is preferred that the concentration of C5 hydrocarbons in the feed stream to the process is held to the minimum practical level. The normally preferred products of the process are CG- plus aromatic hydrocarbons. However, with an olefinic feed substantial amounts of aliphatic C6- plus compounds are produced. Dehydrocyclodimerization processes are not 100% selective and some nonaromatic Cs-plus hydrocarbons are produced even from saturate feeds. The very great majority of the C6-plus product hydrocarbons will nevertheless be benzene, toluene, and the various xylene isomers with a high purity saturate feed. A small amount of Cg-plus aromatics is also produced. Sizeable olefin concentrations in the feed significantly decrease the production of aromatics.
- The subject invention is directed to the recovery of the product hydrocarbons from the effluent stream of the reaction zone. Therefore, the configuration of the reaction zone and the composition of the catalyst employed within the reaction zone are not basic elements of the invention or limiting characteristics of the invention. Nevertheless, in order to provide a background to the subject invention, it is felt useful to describe the preferred reactor system. This system comprises a moving bed radial flow multistage reactor such as is described in U.S. Patents 3,652,231; 3,692,496; 3,706,536; 3,785,963; 3,825,116; 3,839,196; 3,839,197; 3,854,887; 3,856,662; 3,918,930; 3,981,824; 4,094,814; 4,110,081; and 4,403,909. These patents also describe catalyst regeneration systems and various aspects of moving catalyst bed operations and equipment. This reaction system has been widely employed commercially for the reforming of naphtha fractions. Its use has also been described for the dehydrogenation of light paraffins.
- This reactor system normally employs a spherical catalyst having a diameter between about 1/64 and inch (about 0.04 to about 0.32 cm). The catalyst preferably comprises a support material and a metallic component deposited on the support material as through impregnation or coprecipitation. The previously cited references point out that the current trend is the use of a zeolitic support material, with the catalyst referred to in the art as a ZSM-5 type zeolite being often specified as a preferred material. When properly formulated, it appears this zeolitic material by itself has significant activity for the dehydrocyclodimerization reaction. However, it is still preferred to employ a metallic component within the catalyst system to increase the activity of the catalyst. The preferred metallic component is gallium as described in the previously cited U.S. Patent 4,180,689. A dehydrocyclodimerization reaction zone is preferably operated at a temperature between about 9200-1050°F (493°-566°C) and a pressure under 100 psig (689 kPag). Hydrogen-producing reactions are. - normally favored by lower pressures, and pressures under about 70 psig (483 kPag) at the outlet of the reaction zone are highly preferred. Other conditions may be preferred for other reactions.
- The drawing illustrates the preferred embodiment of the invention. Those skilled in the art will recognize that this process flow diagram has been simplified by the elimination of many necessary pieces of process equipment including some heat exchangers, process control systems, pumps, fractionation column overhead and reboiler systems. It may also be readily discerned that the process flow presented in the drawing may be modified in many aspects without departing from the basic overall concept of the invention. For example, the heat exchange shown in the drawing has been held to a minimum for purposes of simplicity. Those skilled in the art will recognize that the choice of heat exchange methods employed to obtain the necessary heating and cooling at various points within the process is subject to a large amount of variation as to how it is performed. In a process as complex as this, there exists many possibilities for indirect heat exchange between different process streams. Depending on the specific location and circumstances of the installation of the subject process, it may also be desired to employ heat exchange against steam, hot oil, or process streams from other processing units not shown on the drawing.
- Referring now to the drawing, the liquid phase feed stream comprises an admixture of propane and butane can enter the process either through
lines 1 or 5 or can be split between these two entry points. In the case where line 1 is used, at least a portion of the feed is passed into debutanizer column 2 through line 1. The C4-minus hydrocarbons which enter the debutanizer 2 with the feed are concentrated into a net overhead stream carried byline 3, which is combined with a recycle stream fromline 35 to form the stream flowing through line 4. This stream can be admixed with a second portion of the feed stream carried byline 5 to form a charge stream which is passed into the reactor 7 via line 6. Alternatively, all of the feed can enter throughline 5 and be combined with recycle C4-minus material at the intersection oflines 5 and 4. The hydrocarbons which enter the reactor 7 are therein contacted with a dehydrocyclodimerization catalyst at conditions effective to convert a significant amount of the entering paraffins to aromatic hydrocarbons, a process which also produces significant quantities of hydrogen and some ligher hydrocarbons such as methane and ethane. Preferably, the reactor 7 contains several separate stages in which the feed materials are contacted with moving beds of catalyst. Interstage heaters not shown in the drawing would be provided to supply the necessary heat for the endothermic dehydrocyclodimerization reaction. If a highly olefinic charge stream was being processed, this would result in an exothermic reaction and interstage coolers would be provided instead. Fresh or regenerated catalyst is passed into the top of the reactor throughline 46 and the used or spent catalyst is withdrawn through line 47 for passage to regeneration facilities. - The effluent of the reactor 7 withdrawn via line 8 is a vapor phase stream comprising an admixture of reaction products and unconverted feed hydrocarbons. This vapor phase stream is first cooled through the use of heat exchangers represented by the indirect heat exchange means 9 and is then passed via line 8 into a first vapor-
liquid separation zone 10. The reaction zone effluent stream is cooled sufficiently prior to passage intozone 10 such that a very large percentage of the readily condensable C6-Plus hydrocarbons enter the separation zone in a liquid phase state. A liquid hydrocarbon phase comprising these C6- plus hydrocarbons and dissolved lighter hydrocarbons and hydrogen is removed from the separation zone inline 12 and admixed with a stream or rich absorption zone liquid carried byline 13. This admixture of liquid phase hydocar- bons is then passed into the debutanizer column 2 throughline 40. The debatanizer column separates the entering hydrocarbons into the C4- minus stream removed overhead and a Cs-plus stream removed as a net bottoms stream through line 41. The benzene column 43 separates these C5-Plus hydrocarbons. A net overhead stream which is rich in benzene is removed through line 42. A net bottoms stream comprising C7-plus compounds is removed through line 44. The C7- plus stream is divided into the product stream removed throughline 45 and a stream passed into anabsorber 15 throughline 16 as a lean absorption liquid. Alternatively, a portion of the C5 hydrocarbons charged to column 2 may be removed overhead vialine 3 and recycled to the reactor. This may be desired to increase the purity of the benzene stream removed overhead in line 42. - The uncondensed portion of the reactor effluent stream is removed from the
separation zone 10 through line 11. This stream contains hydrogen and an equilbrium concentration of all hydrocarbons present in the reactor effluent. This vapor phase material is then compressed to a substantially higher pressure in the compressing means 14. Multiple stage compression with interstage cooling is normally employed to achieve the required compression. The compressed vapor stream is then passed into a lower part of theabsorber 15. The vapors pass upward countercurrent to descending absorpition liquid, which results in the removal of some light hydrocarbons and substantially all benzene from the rising vapor but may release toluene to the vapor. There is thereby produced a high pressure stream carried byline 17 which comprises an admixture of hydrogen and Cl-C7 hydrocarbons except benzene. The total removal of aromatics may be desired as described below. - The relatively high pressure gas stream carried by
line 17 is passed into amembrance separation zone 20 together with a gas stream carried by line 37. The gas which passes through the selective permeation membrane ofzone 20 is withdrawn inline 21. This gas is compressed inmeans 22 and injected into a secondmembrane separation zone 23. The gas which passes through the membrane of thesecond zone 23 is removed from the process throughline 24 as a hydrogen-rich off-gas stream. As used herein, the term "rich" is intended to indicate a concentration of the specified compound or class of compounds in excess of 50 mole percent. The gases which do not permeate the membrane ofseparation zone 23 are removed inline 18 and recycled to the first separation zone via line 37. The gas which does not permeate the membrane ofzone 20 is removed inline 25 and passed through anoptional driver 26 to ensure the removal of water which may freeze out in the subsequent low temperature operations. - The resultant dry high pressure gas is carried by
line 27 and passes through indirect heat exchange means 28, 29 and 30 in which it is cooled to successively lower temperatures. This cooling causes a partial condensation of the material flowing throughline 27 prior to its passage into a second vapor-liquid separator 19. A vapor stream comprising hydrogen, methane, and ethane is removed throughline 31 from the separator and is employed as coolant in the indirect heat exchange means 29 prior to being removed from the process. Optionally, a portion of this material may be recycled to the membrane separation zone vialine 36 although this is not preferred. The liquid phase material collected in the separator comprises methane, propane, butane, and any higher molecular weight hydrocarbons which are present in the stream ofline 27. This liquid is removed inline 32 and passed through aflash valve 38 in to theflash separator 33. The reduction in pressure produces a vapor phase stream comprising methane and ethane removed inline 34 as a light ends off-gas stream and a liquid phase stream comprising propane and butane removed inline 35. This relatively low temperature liquid is used as coolant in indirect heat exchage means 30 and 28 and is then recycled to the reaction zone through lines 4 and 6. - The invention may be applied to the separation of hydrogen and Ce-plus hydrocarbons from the effluent streams of processes other than those which produce mainly aromatic products. Such processes are described in the previously cited references. However, the preferred embodiment of the invention is a process for the separation of the effluent stream of dehydrocyclodimerization reaction zone which comprises the steps of partially condensing a vapor phase dehydrocyclodimerization reaction zone effluent stream, which comprises hydrogen, methane, ethane, propane, butane, benzene, toluene and xylene, and separating the resultant fluids in a first vapour-liquid separation zone into a vapor phase first process stream, which comprises hydrogen and Cl-C7 hydrocarbons, and a condensate stream which comprises benzene, toluene and xylenes; passing the condensate stream into a fractionation zone, and recovering benzene, toluene and xylenes from the fractionation zone; compressing the first process stream to a pressure above about 430 psig (2965 kPag); removing benzene from the first process stream in an absorption zone; passing the first process stream into a membrane separation zone in which the first process stream is contacted with a hydrogen selective permeation membrane under membrane separation conditions, and thereby producing a hydrogen-rich effluent stream which is removed from the process and a vapor phase second process stream, which comprises methane, ethane and propane; forming a vapor phase third process stream comprising methane and a liquid phase fourth process stream, comprising ethane and propane, by partially condensing the second process stream by indirect heat exchange against a coolant medium followed by vapor-liquid separation in a second separation zone operated at a pressure above about 400 psig (2758 kPag); flashing the fourth process stream to a subtantially lower pressure and thereby forming a vapor phase sixth process stream comprising methane, and a liquid phase fifth process stream, which comprises propane, with the fifth and sixth process streams being substantially coller than the second process stream; and employing the fifth process stream as at least a part of the previously referred to coolant medium used to partially condense the second process stream.
- It is believed that those skilled in the art of petroleum and petrochemical process design may determine proper operating conditions, vessel designs, and operating procedures for the subject process through the use of standard process design techniques after having now been appraised of the overall flow of the process. These design techniques should include a recognition that it is undesirable to pass compounds which may tend to freeze or otherwise solidify into the low temperature portion of the process. For this reason, the absorption zone is provided to remove benzene from the gas stream entering this section of the process. Likewise, a drying zone may be provided. However, it is greatly preferred that the membrane employed in the membrane separation zone will allow water to permeate with the hydrogen at a rate sufficient to dry the gas stream. This is a significant advantage to the use of membranes as the drying zone would not be required. The function of a drying zone would be to prevent the passage of any residual water remaining after the membrane separation step in the low temperature equipment. The drying zone could be required to remove the small amount of water which may be dissolved within the feed stream to the process and any water which may be present on regenerated catalyst passed into the process or released from stripping steam used to seal catalyst passageways, etc. Such a drying zone would preferably be a swing bed desiccant-type system. It is preferred to use two beds of a suitable absorbent alumina, with facilities being provided to regenerate one of these beds while the other bed is on-stream.
- If the chosen membrane material employed in the membrane separation zone is adversely affected by the presence of aromatics in the gas stream then the gas stream should be treated to remove the aromatics. This may be done by contacting the gas with an aromatic-free absorption liquid in the absorption zone. The aromatic-free liquid would have to be supplied from an external source not shown in the drawing. A suitable liquid would be a stream of C7 to C10 paraffins. This aromatic-free liquid could be employed as the only absorption liquid. It could also be used as a finishing absorption liquid by contacting the gas stream with the aromatic-free liquid after the gas stream has been treated with the C7-plus bottoms liquid of the benzene column. This may be done in an upper section of the absorption column.
- The configuration of the membrane separation zone may depart from that shown on the drawing. For instance, a single membrane separation unit or three or more points could be employed in the zone as described in the previously cited references. The type of selective (semipermeable) membrane unit employed is dependent on the cost, quality and suitablity of the individual units. The membrane units may be either the hollow fiber or spiral-wound type. Suitable membranes are available commercially and are being applied to a number of industrial processes. Further information is availabJe from U.S. Patents 4,209,307; 4,230,463; and 4,268,278 and the previously cited references.
- The vapor stream which remains after the partial condesation of the reactor effluent stream is preferably compressed from a pressure under about 70 psig (483 kPag) to a pressure greater than 300 psig (2068 kPag). This initial compression step is preferably sufficient to provide a high enough pressure that the remaining vapors will flow through the subsequent zones without any additional compression. This of course does not refer to recompression of recycled permeate streams, which have relatively low pressures after passing through the membrane. The use of a single compression step in this manner is a central feature of the subject process flow. It is therefore further preferred that this compression step raises the gas stream to a pressure in the range of 350 to 850 psig (2143 to 5861 kPag), with pressures above 430 psig (2965 kPag) being highly preferred. The "pressure drops" experienced by the flowing gas streams may be significant with pressure drops of 30 psi (207 kPa) across a membrane separation stage being expected for the non-permeate gas. Nevertheless, it is preferred that the pressure drop through the process is held to a practial minimum. For instance, the vapor-liquid separation zone in which the partially condensed nonpermeate mateirals are separated (second separation zone) should be operated at a presure within 75 psi (517 kPa) of the pressure at which gases are charged to the membrane separation zone. If practical, the pressure of the condensed non- permeate hydrocarbons prior to being flashed is within 75 psi (517 kPa) of the pressure of the gases charged to the membrane separation zone.
- The vapor-liquid separation zones employed within the process preferably comprise a suitably sized vertically oriented vessel having a demisting pad or other liquid entrainment removal means provided at the upper end. The various fractionation columns employed in the process are preferably trayed fractionation columns having sieve-type trays and being of relatively standard design. For instance, a properly designed column having 15 trays will function as the stripping column, while the first or debutanizer column may contain 22 trays and the benzene or second column may contain 55 trays. If the membrane can withstand the presence of aromatics, then the liquid employed as the lean absorption liquid is preferably a portion of the net bottoms stream of the second fractionation column as shown in the drawing. However, it is within the scope of the subject process that a sidecut stream removed from this or another column could be employed as the lean absorption liquid stream. Other variations in the arrangement of the fractionation columns are also possible. For instance, it is possible to replace the portion of the feed stream charged to the top of the debutanizer column with an overhead condensing system. The entire single feed stream would then flow directly into the reactor.
Claims (10)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/659,925 US4548619A (en) | 1984-10-11 | 1984-10-11 | Dehydrocyclodimerization process |
US659925 | 1984-10-11 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0178172A2 EP0178172A2 (en) | 1986-04-16 |
EP0178172A3 EP0178172A3 (en) | 1986-06-11 |
EP0178172B1 true EP0178172B1 (en) | 1988-03-02 |
Family
ID=24647397
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP85307249A Expired EP0178172B1 (en) | 1984-10-11 | 1985-10-10 | Process for recovering hydrogen and hydrocarbons from the effluent stream of a hydrogen-producing hydrocarbon conversion process |
Country Status (8)
Country | Link |
---|---|
US (1) | US4548619A (en) |
EP (1) | EP0178172B1 (en) |
JP (1) | JPS6191291A (en) |
AU (1) | AU569963B2 (en) |
CA (1) | CA1249504A (en) |
DE (1) | DE3561717D1 (en) |
IN (1) | IN164703B (en) |
NO (1) | NO162905C (en) |
Families Citing this family (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4654063A (en) * | 1984-12-21 | 1987-03-31 | Air Products And Chemicals, Inc. | Process for recovering hydrogen from a multi-component gas stream |
US4654047A (en) * | 1985-08-23 | 1987-03-31 | Air Products And Chemicals, Inc. | Hybrid membrane/cryogenic process for hydrogen purification |
US4690695A (en) * | 1986-04-10 | 1987-09-01 | Union Carbide Corporation | Enhanced gas separation process |
GB2195654A (en) * | 1986-09-30 | 1988-04-13 | Shell Int Research | Process for recovery of hydrocarbons from a fluid feed |
GB2201159A (en) * | 1986-12-05 | 1988-08-24 | Shell Int Research | Process and apparatus for the dehydrogenation of organic compounds |
JPS63296820A (en) * | 1987-05-29 | 1988-12-02 | Ube Ind Ltd | Production of high-purity hydrogen or helium |
US4836833A (en) * | 1988-02-17 | 1989-06-06 | Air Products And Chemicals, Inc. | Production and recovery of hydrogen and carbon monoxide |
US4892564A (en) * | 1988-03-24 | 1990-01-09 | Cooley Thomas E | Membrane process for hydrocarbon liquid recovery |
US4882037A (en) * | 1988-08-15 | 1989-11-21 | Uop | Process for treating a temperature-sensitive hydrocarbonaceous stream containing a non-distillable component to produce a selected hydrogenated distillable light hydrocarbonaceous product |
FR2636249B1 (en) * | 1988-09-12 | 1992-05-15 | Air Liquide | HYDROGEN RECOVERY PROCESS AND PLANT |
FR2636341A1 (en) * | 1988-09-12 | 1990-03-16 | Air Liquide | METHOD AND INSTALLATION FOR RECOVERING THE HEAVIEST HYDROCARBONS OF A GASEOUS MIXTURE |
FR2659029B1 (en) * | 1990-03-02 | 1993-03-12 | Equip Ind Chimiques | PROCESS FOR SEPARATING A GASEOUS MIXTURE OBTAINED IN OIL REFINERIES AND INSTALLATION FOR ITS IMPLEMENTATION. |
FR2659964B1 (en) * | 1990-03-20 | 1992-06-05 | Inst Francais Du Petrole | PROCESS FOR FRACTIONATING A GASEOUS MIXTURE CONTAINING HYDROGEN LIGHT ALIPHATIC HYDROCARBONS AND LIGHT AROMATIC HYDROCARBONS. |
US5082481A (en) * | 1990-04-10 | 1992-01-21 | Lummus Crest, Inc. | Membrane separation process for cracked gases |
US5262198A (en) * | 1991-04-08 | 1993-11-16 | Aluminum Company Of America | Method of producing a carbon coated ceramic membrane and associated product |
US5452581A (en) * | 1994-04-01 | 1995-09-26 | Dinh; Cong X. | Olefin recovery method |
US5980609A (en) * | 1997-01-24 | 1999-11-09 | Membrane Technology And Research, Inc. | Hydrogen recovery process |
US5769926A (en) * | 1997-01-24 | 1998-06-23 | Membrane Technology And Research, Inc. | Membrane separation of associated gas |
US5785739A (en) * | 1997-01-24 | 1998-07-28 | Membrane Technology And Research, Inc. | Steam cracker gas separation process |
US5755855A (en) * | 1997-01-24 | 1998-05-26 | Membrane Technology And Research, Inc. | Separation process combining condensation, membrane separation and flash evaporation |
US5861049A (en) * | 1997-01-24 | 1999-01-19 | Membrane Technology And Research, Inc. | Chlorine separation process combining condensation, membrane separation and flash evaporation |
US5772733A (en) * | 1997-01-24 | 1998-06-30 | Membrane Technology And Research, Inc. | Natural gas liquids (NGL) stabilization process |
US6159272A (en) * | 1997-01-24 | 2000-12-12 | Membrane Technology And Research, Inc. | Hydrogen recovery process |
US6085549A (en) * | 1998-04-08 | 2000-07-11 | Messer Griesheim Industries, Inc. | Membrane process for producing carbon dioxide |
US6128919A (en) * | 1998-04-08 | 2000-10-10 | Messer Griesheim Industries, Inc. | Process for separating natural gas and carbon dioxide |
US6165350A (en) * | 1998-05-22 | 2000-12-26 | Membrane Technology And Research, Inc. | Selective purge for catalytic reformer recycle loop |
US6171472B1 (en) | 1998-05-22 | 2001-01-09 | Membrane Technology And Research, Inc. | Selective purge for reactor recycle loop |
US6190536B1 (en) | 1998-05-22 | 2001-02-20 | Membrane Technology And Research, Inc. | Catalytic cracking process |
US6011192A (en) * | 1998-05-22 | 2000-01-04 | Membrane Technology And Research, Inc. | Membrane-based conditioning for adsorption system feed gases |
US6190540B1 (en) | 1998-05-22 | 2001-02-20 | Membrane Technology And Research, Inc. | Selective purging for hydroprocessing reactor loop |
US6179996B1 (en) | 1998-05-22 | 2001-01-30 | Membrane Technology And Research, Inc. | Selective purge for hydrogenation reactor recycle loop |
US6264828B1 (en) | 1998-05-22 | 2001-07-24 | Membrane Tehnology And Research, Inc. | Process, including membrane separation, for separating hydrogen from hydrocarbons |
US6183628B1 (en) | 1999-03-19 | 2001-02-06 | Membrane Technology And Research, Inc. | Process, including PSA and membrane separation, for separating hydrogen from hydrocarbons |
US6592749B1 (en) | 1999-03-19 | 2003-07-15 | Membrane Technology And Research, Inc. | Hydrogen/hydrocarbon separation process, including PSA and membranes |
US6296687B2 (en) * | 1999-04-30 | 2001-10-02 | Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of Natural Resources | Hydrogen permeation through mixed protonic-electronic conducting materials |
US6589303B1 (en) | 1999-12-23 | 2003-07-08 | Membrane Technology And Research, Inc. | Hydrogen production by process including membrane gas separation |
US6544316B2 (en) * | 2000-05-19 | 2003-04-08 | Membrane Technology And Research, Inc. | Hydrogen gas separation using organic-vapor-resistant membranes |
US6361582B1 (en) * | 2000-05-19 | 2002-03-26 | Membrane Technology And Research, Inc. | Gas separation using C3+ hydrocarbon-resistant membranes |
US6579341B2 (en) * | 2000-05-19 | 2003-06-17 | Membrane Technology And Research, Inc. | Nitrogen gas separation using organic-vapor-resistant membranes |
US6572680B2 (en) * | 2000-05-19 | 2003-06-03 | Membrane Technology And Research, Inc. | Carbon dioxide gas separation using organic-vapor-resistant membranes |
US6592650B2 (en) * | 2000-05-19 | 2003-07-15 | Membrane Technology And Research, Inc. | Gas separation using organic-vapor-resistant membranes and PSA |
US7780747B2 (en) * | 2003-10-14 | 2010-08-24 | Advanced Technology Materials, Inc. | Apparatus and method for hydrogen generation from gaseous hydride |
MY142221A (en) * | 2005-04-06 | 2010-11-15 | Cabot Corp | Method to produce hydrogen or synthesis gas |
JP2009061420A (en) * | 2007-09-07 | 2009-03-26 | Air Liquide Japan Ltd | Manufacturing method of gas component and condensable component, and manufacturing system thereof |
FR2951959B1 (en) * | 2009-11-02 | 2012-03-23 | Air Liquide | METHOD AND DEVICE FOR SEPARATING GAS MIXTURES BY PERMEATION |
US9517933B2 (en) | 2013-09-23 | 2016-12-13 | Uop Llc | Process for catalytic reforming |
US20160115023A1 (en) * | 2014-10-22 | 2016-04-28 | Uop Llc | Recovery of hydrogen from fractionation zone offgas |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2992283A (en) * | 1959-07-30 | 1961-07-11 | Exxon Research Engineering Co | Preparation of aromatic and saturated hydrocarbons |
US3101261A (en) * | 1960-04-12 | 1963-08-20 | Exxon Research Engineering Co | Process for the recovery of hydrogen from hydrocarbon gas streams |
US3450500A (en) * | 1965-08-03 | 1969-06-17 | United Aircraft Corp | Method for catalytically reforming hydrogen-containing carbonaceous feed-stocks by simultaneous abstractions through a membrane selectively permeable to hydrogen |
US3537978A (en) * | 1968-12-27 | 1970-11-03 | Universal Oil Prod Co | Separation method |
US3574089A (en) * | 1969-01-27 | 1971-04-06 | Universal Oil Prod Co | Gas separation from hydrogen containing hydrocarbon effluent |
GB1381112A (en) * | 1971-04-20 | 1975-01-22 | Petrocarbon Dev Ltd | Separation of gas mixtures |
US3761389A (en) * | 1972-08-28 | 1973-09-25 | Mobil Oil Corp | Process of converting aliphatics to aromatics |
US3843740A (en) * | 1972-11-21 | 1974-10-22 | Mobil Oil | Production of aromatics |
US4070165A (en) * | 1975-12-15 | 1978-01-24 | Uop Inc. | Pretreatment of raw natural gas prior to liquefaction |
US4180689A (en) * | 1976-12-20 | 1979-12-25 | The British Petroleum Company Limited | Process for converting C3 -C12 hydrocarbons to aromatics over gallia-activated zeolite |
US4264338A (en) * | 1977-11-02 | 1981-04-28 | Monsanto Company | Method for separating gases |
US4180388A (en) * | 1978-03-20 | 1979-12-25 | Monsanto Company | Processes |
NL190156C (en) * | 1979-03-14 | 1993-11-16 | Shell Int Research | PROCESS FOR PREPARING AN AROMATIC HYDROCARBON MIXTURE |
US4238204A (en) * | 1979-06-18 | 1980-12-09 | Monsanto Company | Selective adsorption process |
US4229188A (en) * | 1979-06-18 | 1980-10-21 | Monsanto Company | Selective adsorption process |
US4347394A (en) * | 1980-12-10 | 1982-08-31 | Chevron Research Company | Benzene synthesis |
US4367135A (en) * | 1981-03-12 | 1983-01-04 | Monsanto Company | Processes |
US4381418A (en) * | 1981-12-04 | 1983-04-26 | Uop Inc. | Catalytic dehydrogenation process |
US4381417A (en) * | 1981-12-04 | 1983-04-26 | Uop Inc. | Catalytic dehydrogenation process |
US4466946A (en) * | 1982-03-12 | 1984-08-21 | Standard Oil Company (Indiana) | CO2 Removal from high CO2 content hydrocarbon containing streams |
US4398926A (en) * | 1982-04-23 | 1983-08-16 | Union Carbide Corporation | Enhanced hydrogen recovery from low purity gas streams |
US4444988A (en) * | 1982-07-22 | 1984-04-24 | Mobil Oil Corporation | Use of liquefied propane and butane or butane recycle to control heat of reaction of converting olefins to gasoline and distillate |
-
1984
- 1984-10-11 US US06/659,925 patent/US4548619A/en not_active Expired - Fee Related
-
1985
- 1985-09-09 IN IN738/DEL/85A patent/IN164703B/en unknown
- 1985-09-11 AU AU47347/85A patent/AU569963B2/en not_active Ceased
- 1985-10-02 CA CA000492082A patent/CA1249504A/en not_active Expired
- 1985-10-09 NO NO854008A patent/NO162905C/en unknown
- 1985-10-10 EP EP85307249A patent/EP0178172B1/en not_active Expired
- 1985-10-10 DE DE8585307249T patent/DE3561717D1/en not_active Expired
- 1985-10-11 JP JP60226677A patent/JPS6191291A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
AU4734785A (en) | 1986-04-17 |
NO162905B (en) | 1989-11-27 |
DE3561717D1 (en) | 1988-04-07 |
US4548619A (en) | 1985-10-22 |
NO162905C (en) | 1990-03-07 |
AU569963B2 (en) | 1988-02-25 |
NO854008L (en) | 1986-04-14 |
IN164703B (en) | 1989-05-13 |
CA1249504A (en) | 1989-01-31 |
JPS6191291A (en) | 1986-05-09 |
EP0178172A2 (en) | 1986-04-16 |
EP0178172A3 (en) | 1986-06-11 |
JPH0137438B2 (en) | 1989-08-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0178172B1 (en) | Process for recovering hydrogen and hydrocarbons from the effluent stream of a hydrogen-producing hydrocarbon conversion process | |
US4528412A (en) | Dehydrocyclodimerization process | |
US4547205A (en) | Dehydrocyclodimerization process | |
US4642402A (en) | Process for conversion of light aliphatic hydrocarbons to aromatics | |
US5012037A (en) | Integrated thermal swing-pressure swing adsorption process for hydrogen and hydrocarbon recovery | |
US4831207A (en) | Chemical processing with an operational step sensitive to a feedstream component | |
EP0284228B1 (en) | Chemical processing with an operational step sensitive to a feedstream component | |
US5278344A (en) | Integrated catalytic reforming and hydrodealkylation process for maximum recovery of benzene | |
US4229602A (en) | Dehydrocyclization process | |
KR20020077458A (en) | Process for producing para-xylene | |
US5157200A (en) | Process for the fractionation of a gaseous mixture containing hydrogen light aliphatic hydrocarbons and light aromatic hydrocarbons | |
US5258563A (en) | Process for the production of benzene from light hydrocarbons | |
US4677235A (en) | Production of aromatic hydrocarbons from natural gas | |
CA1271201A (en) | Product recovery method for dehydrocyclodimerization process | |
US6179996B1 (en) | Selective purge for hydrogenation reactor recycle loop | |
US4795844A (en) | Process for conversion of light olefins to LPG and aromatics | |
US4009218A (en) | Alkylaromatic hydrocarbon dehydrogenation process | |
US4648959A (en) | Hydrogenation method for adsorptive separation process feedstreams | |
US4410754A (en) | Butylene isomerization process | |
CA1265539A (en) | Hydrocarbon dehydrogenation process with oxidative reheat | |
US20150136653A1 (en) | Process for pyrolysis and gasification of a coal feed | |
JPH0259813B2 (en) | ||
US20140364671A1 (en) | Catalyst moisture sensitivty management | |
Fukase et al. | A new process of light naphtha aromatization using a zeolite-based catalyst with long-time stability | |
GB2287250A (en) | Gasoline production using dehydrocyclodimerisation |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): BE DE FR GB IT NL SE |
|
PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
AK | Designated contracting states |
Kind code of ref document: A3 Designated state(s): BE DE FR GB IT NL SE |
|
17P | Request for examination filed |
Effective date: 19860816 |
|
17Q | First examination report despatched |
Effective date: 19870514 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): BE DE FR GB IT NL SE |
|
REF | Corresponds to: |
Ref document number: 3561717 Country of ref document: DE Date of ref document: 19880407 |
|
ITF | It: translation for a ep patent filed |
Owner name: MODIANO & ASSOCIATI S.R.L. |
|
ET | Fr: translation filed | ||
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 19910927 Year of fee payment: 7 Ref country code: GB Payment date: 19910927 Year of fee payment: 7 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 19911007 Year of fee payment: 7 |
|
ITTA | It: last paid annual fee | ||
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 19911031 Year of fee payment: 7 Ref country code: DE Payment date: 19911031 Year of fee payment: 7 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 19911211 Year of fee payment: 7 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Effective date: 19921010 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Effective date: 19921011 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Effective date: 19921031 |
|
BERE | Be: lapsed |
Owner name: UOP INC. Effective date: 19921031 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Effective date: 19930501 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 19921010 |
|
NLV4 | Nl: lapsed or anulled due to non-payment of the annual fee | ||
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Effective date: 19930630 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Effective date: 19930701 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST |
|
EUG | Se: european patent has lapsed |
Ref document number: 85307249.4 Effective date: 19930510 |