EP0178006B1 - Liquid detergent compositions - Google Patents
Liquid detergent compositions Download PDFInfo
- Publication number
- EP0178006B1 EP0178006B1 EP85201533A EP85201533A EP0178006B1 EP 0178006 B1 EP0178006 B1 EP 0178006B1 EP 85201533 A EP85201533 A EP 85201533A EP 85201533 A EP85201533 A EP 85201533A EP 0178006 B1 EP0178006 B1 EP 0178006B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- composition according
- detergent
- range
- active
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 36
- 239000003599 detergent Substances 0.000 title claims abstract description 19
- 239000007788 liquid Substances 0.000 title claims abstract description 10
- -1 carboxylate salt Chemical class 0.000 claims abstract description 24
- 239000003792 electrolyte Substances 0.000 claims abstract description 11
- 150000003839 salts Chemical class 0.000 claims abstract description 11
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 9
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims abstract description 8
- 239000011149 active material Substances 0.000 claims description 16
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- 125000000129 anionic group Chemical group 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 150000001768 cations Chemical class 0.000 claims description 3
- 239000011236 particulate material Substances 0.000 claims description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 claims 1
- 238000000518 rheometry Methods 0.000 abstract description 4
- 239000002001 electrolyte material Substances 0.000 abstract description 3
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 229910052783 alkali metal Inorganic materials 0.000 description 7
- 125000002947 alkylene group Chemical group 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000035945 sensitivity Effects 0.000 description 4
- 238000009472 formulation Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 239000004150 EU approved colour Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 150000005215 alkyl ethers Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000006172 buffering agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229940006093 opthalmologic coloring agent diagnostic Drugs 0.000 description 1
- GCJJVHOLSYKCKF-UHFFFAOYSA-N pentadecyl benzenesulfonate Chemical compound CCCCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GCJJVHOLSYKCKF-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- FODHIQQNHOPUKH-UHFFFAOYSA-N tetrapropylene-benzenesulfonic acid Chemical compound CC1CC11C2=C3S(=O)(=O)OC(C)CC3=C3C(C)CC3=C2C1C FODHIQQNHOPUKH-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Definitions
- the present invention relates to liquid detergent compositions and in particular to aqueous built liquid detergent compositions comprising a detergent active-based suspending system capable of suspending undissolved material.
- Aqueous built liquid detergent compositions are well known and a vast amount of formulations have been described in the prior art.
- Such compositions comprise one or more detergent-active compounds and one or more builder salts in an aqueous medium which is capable of suspending undissolved builder and/or adjuvant materials.
- compositions of the above type which have reduced sensitivity to electrolyte material and which tolerate larger quantities of such material without giving rise to unacceptable viscosities.
- FR 2 014 084 (Hoechst) describes unstructured detergent compositions which comprise fatty alcohol polyalkylene oxide carboxylate salts.
- the present invention provides an aqueous built liquid detergent composition capable of suspending particulate material, which comprises from 1% to 15% by weight of synthetic anion detergent-active material and from 5% to 30% by weight of electrolyte salts, characterized in that it comprises from 0.5-10% by weight of a fatty alcohol polyalkylene oxide carboxylate salt or a mixture of such salts according to the formula:
- R is an aliphatic hydrocarbon group having 8-20 carbon atoms or an aliphatic-aromatic hydrocarbon group having 4-20 carbon atoms in the aliphatic part; n is a number in the range of from 2 to 3 inclusive; x is a number in the range of from 1 to 16 inclusive; y is a number in the range of from 0 to 2 inclusive; and M is a cation.
- R will normally comprise a mixture of aliphatic hydrocarbon groups of different lengths which may be straight or branched, saturated or unsaturated.
- R is a straight saturated aliphatic hydrocarbon group having from 1-14 carbon atoms.
- the number of ethylene and/or propylene oxide units (x) ma range from 1-16, in particular from 1-12.
- the alkylene oxide portion comprises from 2-5 ethylene oxide units.
- M is a cation and is selected from the group of hydrogen, sodium, potassium, ammonium, mono-, di- and triethanol ammonium, the alkali metal cations being preferred.
- the fatty alcohol polyalkylene oxide carboxylate salt or a mixture of such salts is included in an amount of from 0.5-10%, partly replacing the synthetic anionic detergent-active material.
- the preferred amount depends on the rheology of the composition without the carboxylate salt compound, and the rheology which is aimed at. In general the best results are obtained when the fatty alcohol polyalkylene oxide carboxylate salt is included in an amount of from 2-5% by weight, replacing about an equivalent amount of synthetic anionic detergent active material.
- the invention relates to aqueous liquid built compositions on the basis of synthetic anionic detergent-active material and electrolyte salts.
- Suitable synthetic anionic detergent-active materials comprise the well-known anionic detergents of the alkylaryl sulphonate type, the alkyl- and alkylether sulphate type, the alkane- and alkene sulphonate type, etc. Numerous other examples can be found in Schwartz, Perry “Detergents and Surface-Active Agents", Vol. 11, 1958.
- alkylaryl sulphonates are used, in which the alkyl chain contains 10-18 carbon atoms, such as n-dodecyl benzene sulphonate, tetrapropylene benzene sulphonate, n-pentadecyl benzene sulphonate, and linear C, 2 --Cis alkylbenzene sulphonate in which the aliphatic group is obtained from cracked wax polymers, all in the form of their sodium or potassium salts.
- n-dodecyl benzene sulphonate such as n-dodecyl benzene sulphonate, tetrapropylene benzene sulphonate, n-pentadecyl benzene sulphonate, and linear C, 2 --Cis alkylbenzene sulphonate in which the aliphatic group is obtained from cracked wax polymers, all in the form of their sodium or potassium
- the total amount of synthetic anionic detergent active materials must lie within the range of 1-15% by weight, but preferably is 6-12% by weight of the total composition.
- Nonionic detergents usually consist of a hydrophobic moiety which has been reacted with an alkylene oxide.
- Suitable examples are primary or secondary, straight or branched chain Ca-Ge alcohols condensed with 1-30 moles of alkylene oxide; mono- or dialkyl phenols with an alkyl group of 9-18 carbon atoms condensed with 1-30 moles of alkylene oxide; Go-Ge fatty acid mono- or dialkylol amides condensed with 1-30 moles of alkylene oxide; block copolymers of different or identical alkylene oxides and so on.
- the alkylene oxide is ethylene oxide, but propylene oxide or a mixture of ethylene oxide and propylene oxide can also be used. Further suitable examples can be found in the text book of M. Schick "Nonionic Surfactants".
- the amount of nonionic detergent-active material which can be included in the composition ranges up to 5%, but such amounts should be less than the amount of synthetic anionic detergent active material.
- the electrolytes which are used in the present invention are those which cause partial salting out of the detergent active material.
- Typical examples are builder salts, such as the alkali metal ortho- and pyrophosphates, the alkali metal ammonium tripolyphosphates, such as sodium tripolyphosphate, the alkali metal citrates, alkyli metal salts of nitrilo triacetate and alkali metal salts of carboxy methyloxy succinate.
- builder salts such as the alkali metal ortho- and pyrophosphates, the alkali metal ammonium tripolyphosphates, such as sodium tripolyphosphate, the alkali metal citrates, alkyli metal salts of nitrilo triacetate and alkali metal salts of carboxy methyloxy succinate.
- Suitable examples of electrolytes are also buffering agents, such as the alkanol amines, in particular triethanol amine, alkali metal carbonates, alkali metal borates, alkali metal silicates, and so on.
- compositions of the invention may further contain all ingredients usually encountered in such products, such as alkali metal sulphites, for improving detergency; enzymes, either alone or in combination with enzyme stabilizers, such as polyalcohols or alkanol amines with borax; fluorescers, further builders, such as zeolites; abrasives, such as calcite; soil-suspending agents; anti-redeposition agents; hydrotropes, corrosion inhibitors; foam boosters or depressors; opacifying agents; perfumes; colouring agents; bleaching agents, optionally in combination with bleach precursors; fluorescers.
- enzymes either alone or in combination with enzyme stabilizers, such as polyalcohols or alkanol amines with borax
- fluorescers further builders, such as zeolites
- abrasives such as calcite
- soil-suspending agents such as calcite
- soil-suspending agents such as calcite
- anti-redeposition agents such as
- the products of the present invention can be prepared using conventional techniques. In this respect it has been found that it is advantageous to shear the product at the end of the production process to its maximum stable viscosity, e.g. by post-stirring or passing the product through a desintegrator or similar high-shear exerting equipment. Further shear exerted on the product thus treated during pumping and bottling does not affect the viscosity of the product.
- compositions were prepared according to the formulations listed in Table 1, having good physical stability and clearly showing the increased tolerance to high electrolyte levels.
- Akypo is the trade-name for a series of fatty alcohol polyglycolether carboxylates sold by Chem-Y, The Netherlands.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT85201533T ATE56470T1 (de) | 1984-10-12 | 1985-09-25 | Fluessige reinigungsmittelzusammensetzungen. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8425785 | 1984-10-12 | ||
| GB848425785A GB8425785D0 (en) | 1984-10-12 | 1984-10-12 | Liquid detergent compositions |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0178006A2 EP0178006A2 (en) | 1986-04-16 |
| EP0178006A3 EP0178006A3 (en) | 1988-07-20 |
| EP0178006B1 true EP0178006B1 (en) | 1990-09-12 |
Family
ID=10568081
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP85201533A Expired - Lifetime EP0178006B1 (en) | 1984-10-12 | 1985-09-25 | Liquid detergent compositions |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0178006B1 (enrdf_load_stackoverflow) |
| JP (1) | JPS6197395A (enrdf_load_stackoverflow) |
| AT (1) | ATE56470T1 (enrdf_load_stackoverflow) |
| AU (1) | AU579191B2 (enrdf_load_stackoverflow) |
| BR (1) | BR8505035A (enrdf_load_stackoverflow) |
| CA (1) | CA1232817A (enrdf_load_stackoverflow) |
| DE (1) | DE3579658D1 (enrdf_load_stackoverflow) |
| GB (1) | GB8425785D0 (enrdf_load_stackoverflow) |
| ZA (1) | ZA857798B (enrdf_load_stackoverflow) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4797225A (en) * | 1986-09-08 | 1989-01-10 | Colgate-Palmolive Company | Nonaqueous liquid nonionic laundry detergent composition containing an alkali metal dithionite or sulfite reduction bleaching agent and method of use |
| DE3905938A1 (de) * | 1989-02-25 | 1990-08-30 | Huels Chemische Werke Ag | Detergentienzusammensetzungen mit erhoehter viskositaet |
| US7037884B2 (en) | 1994-02-23 | 2006-05-02 | Ecolab Inc. | Alkaline cleaners based on alcohol ethoxy carboxylates |
| AU681774B2 (en) | 1994-02-23 | 1997-09-04 | Ecolab Inc. | Alkaline cleaners based on alcohol ethoxy carboxylates |
| NL9401510A (nl) * | 1994-09-16 | 1996-05-01 | Chem Y | Surfactantsamenstelling, surfactantconcentraat in vloeibare vorm en waterig bleekmiddel met verhoogde viscositeit en reinigende werking. |
| TW294720B (enrdf_load_stackoverflow) * | 1994-09-30 | 1997-01-01 | Unilever Nv | |
| DE19852973C1 (de) * | 1998-11-17 | 2000-07-20 | Cognis Deutschland Gmbh | Herstellung niedrigviskoser wäßriger Detergenszubereitungen |
| WO2013129652A1 (ja) * | 2012-03-02 | 2013-09-06 | 花王株式会社 | 皮膚洗浄剤組成物 |
| WO2013129653A1 (ja) * | 2012-03-02 | 2013-09-06 | 花王株式会社 | 皮膚洗浄剤組成物 |
| JP6121098B2 (ja) * | 2012-03-07 | 2017-04-26 | 花王株式会社 | 皮膚洗浄剤組成物 |
| WO2018127390A1 (en) * | 2017-01-06 | 2018-07-12 | Unilever N.V. | Stain removing composition |
| CN110621769A (zh) * | 2017-05-10 | 2019-12-27 | 荷兰联合利华有限公司 | 洗衣洗涤剂组合物 |
| CN110914397B (zh) | 2017-05-10 | 2021-04-13 | 荷兰联合利华有限公司 | 洗衣洗涤剂组合物 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2014084A1 (enrdf_load_stackoverflow) * | 1968-07-31 | 1970-04-10 | Hoechst Ag | |
| NL7201735A (enrdf_load_stackoverflow) * | 1971-02-16 | 1972-08-18 | ||
| FR2436213A1 (fr) * | 1978-09-13 | 1980-04-11 | Oreal | Composition de traitement des matieres fibreuses a base de polymeres cationiques et anioniques |
| US4443362A (en) * | 1981-06-29 | 1984-04-17 | Johnson & Johnson Baby Products Company | Detergent compounds and compositions |
-
1984
- 1984-10-12 GB GB848425785A patent/GB8425785D0/en active Pending
-
1985
- 1985-09-25 DE DE8585201533T patent/DE3579658D1/de not_active Expired - Fee Related
- 1985-09-25 AT AT85201533T patent/ATE56470T1/de active
- 1985-09-25 EP EP85201533A patent/EP0178006B1/en not_active Expired - Lifetime
- 1985-10-04 CA CA000492347A patent/CA1232817A/en not_active Expired
- 1985-10-07 AU AU48344/85A patent/AU579191B2/en not_active Ceased
- 1985-10-09 ZA ZA857798A patent/ZA857798B/xx unknown
- 1985-10-10 BR BR8505035A patent/BR8505035A/pt not_active IP Right Cessation
- 1985-10-11 JP JP60226672A patent/JPS6197395A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| ATE56470T1 (de) | 1990-09-15 |
| DE3579658D1 (de) | 1990-10-18 |
| BR8505035A (pt) | 1986-07-29 |
| ZA857798B (en) | 1987-06-24 |
| EP0178006A2 (en) | 1986-04-16 |
| AU579191B2 (en) | 1988-11-17 |
| CA1232817A (en) | 1988-02-16 |
| EP0178006A3 (en) | 1988-07-20 |
| GB8425785D0 (en) | 1984-11-21 |
| AU4834485A (en) | 1986-04-17 |
| JPS6197395A (ja) | 1986-05-15 |
| JPH0357958B2 (enrdf_load_stackoverflow) | 1991-09-03 |
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