EP0159619A3 - Process for the catalytic epoxidation of low molecular weight olefins, and catalyst for performing said process - Google Patents

Process for the catalytic epoxidation of low molecular weight olefins, and catalyst for performing said process Download PDF

Info

Publication number
EP0159619A3
EP0159619A3 EP85104334A EP85104334A EP0159619A3 EP 0159619 A3 EP0159619 A3 EP 0159619A3 EP 85104334 A EP85104334 A EP 85104334A EP 85104334 A EP85104334 A EP 85104334A EP 0159619 A3 EP0159619 A3 EP 0159619A3
Authority
EP
European Patent Office
Prior art keywords
catalyst
molecular weight
low molecular
weight olefins
catalytic epoxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP85104334A
Other languages
German (de)
French (fr)
Other versions
EP0159619A2 (en
Inventor
Ezio Tempesti
Luigi Giuffrè
Giovanni Modica
Enzo Montoneri
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mira Lanza SpA
Original Assignee
Mira Lanza SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mira Lanza SpA filed Critical Mira Lanza SpA
Publication of EP0159619A2 publication Critical patent/EP0159619A2/en
Publication of EP0159619A3 publication Critical patent/EP0159619A3/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/04—Esters of boric acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)

Abstract

Catalytic epoxidation process of low molecular weight olefins, by means of a bimetallic boron-molybdenum reaction catalyst of the kind; in which Y is a bivalent residue of an aromatic or aliphatic hy­ drocarbon; X is a generic ligand, and in which the oxygen bridge between B and Mo is of the chemical covalent type.
Advantageously, the said catalyst may be supported on polymeric matrices, for its use in heterogeneous phase.
EP85104334A 1984-04-20 1985-04-10 Process for the catalytic epoxidation of low molecular weight olefins, and catalyst for performing said process Withdrawn EP0159619A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT12498/84A IT1180483B (en) 1984-04-20 1984-04-20 LOW MOLECULAR WEIGHT CATALYTIC EPOXIDATION PROCESS AND CATALYST FOR ITS IMPLEMENTATION
IT1249884 1984-04-20

Publications (2)

Publication Number Publication Date
EP0159619A2 EP0159619A2 (en) 1985-10-30
EP0159619A3 true EP0159619A3 (en) 1986-11-12

Family

ID=11140869

Family Applications (1)

Application Number Title Priority Date Filing Date
EP85104334A Withdrawn EP0159619A3 (en) 1984-04-20 1985-04-10 Process for the catalytic epoxidation of low molecular weight olefins, and catalyst for performing said process

Country Status (3)

Country Link
EP (1) EP0159619A3 (en)
JP (1) JPS60237079A (en)
IT (1) IT1180483B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5034470A (en) * 1990-09-04 1991-07-23 The Goodyear Tire & Rubber Company Process for the preparation of epoxidized synthetic cis-1,4-polyisoprene
NL9201482A (en) * 1992-08-20 1994-03-16 Dsm Nv Epoxidation Catalyst.
CA2208988A1 (en) * 1994-12-30 1996-07-11 Hoechst Aktiengesellschaft Epoxides produced by the oxidation of olefins with air or oxygen
KR101952716B1 (en) * 2017-09-04 2019-02-27 경희대학교 산학협력단 A method for preparing metal/molybdenum oxide nanoparticles
WO2024177646A1 (en) * 2023-02-24 2024-08-29 1S1 Energy, Inc. Catalysts including boronic, metal hydroxide, or metal oxide active-site groups

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4038290A (en) * 1975-04-04 1977-07-26 Texaco Development Corporation Boride catalyst for epoxidizing olefinic compounds

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4038290A (en) * 1975-04-04 1977-07-26 Texaco Development Corporation Boride catalyst for epoxidizing olefinic compounds

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
4TH INTERNATIONAL SYMPOSIUM ON HOMOGENEOUS CATALYSIS, Leningrad, SU, 24th-28th September 1984, pages 177-182, Elsevier Science Publishers B.V., Amsterdam, NL; E. TEMPESTI et al.: "New covalent boron (III) - molybdenum (VI) mixed oxo model compounds as eligible hetero bimetallic catalysts for propylene epoxidation" *
CHEMICAL ABSTRACTS, vol. 83, no. 15, 13th October 1975, page 491, abstract no. 131434f, Columbus, Ohio, US; & CS - A - 156 839 (L. CERVENY et al.) 15-01-1975 *

Also Published As

Publication number Publication date
IT1180483B (en) 1987-09-23
IT8412498A0 (en) 1984-04-20
JPS60237079A (en) 1985-11-25
EP0159619A2 (en) 1985-10-30

Similar Documents

Publication Publication Date Title
AU8053987A (en) Ethylene oxide catalyst and process for the catalytic production of ethylene oxide
AU643673B2 (en) Catalysts for the polymerization of olefins
DE3574937D1 (en) REACTOR FOR CARRYING OUT HETEROGENIC, CATALYZED CHEMICAL REACTIONS.
DE59007627D1 (en) Catalyst body and reactor for heterogeneous reaction control.
UA66814C2 (en) Method for production of vinyl acetate in the presence of a catalyst containing palladium, gold and third metal
ES8802122A1 (en) High yield, high resistance catalyst, particularly suitable for the oxidation of methyl alcohol to formaldehyde.
EP1176234A3 (en) Catalyst supports, supported catalysts, methods of making the same and methods of using the same
HU906343D0 (en) Process for epoxidation
EP0159619A3 (en) Process for the catalytic epoxidation of low molecular weight olefins, and catalyst for performing said process
BR9813104A (en) Vinyl acetate catalyst comprising metallic palladium and gold, and cupric acetate
ES8203236A1 (en) Process for increasing the activity and for extending the high-selectivity duration time of silver support catalysts for use in the synthesis of ethylene oxide.
EP0361620A3 (en) Alkoxylation using modified group iiib metal-containing bimetallic or polymetallic catalysts
EP0259105A3 (en) Proton catalysed reactions
ATE104341T1 (en) PREPARATION OF IMMUNOMARIAGE CATALYSTS.
AU576759B2 (en) Catalytic cracking catalyst and process
AU8019687A (en) Catalytic cracking catalyst and process
DE69114822D1 (en) Process for the metathesis of olefins and catalyst to be used.
DE3853619D1 (en) Chemical reaction in the presence of a supported copper catalyst.
EP0361619A3 (en) Alkoxylation catalysis
ATE128644T1 (en) CATALYST FOR THE METATHESIS OF OLEFINS.
DE3871555D1 (en) INTERMEDIATE METHOD FOR CATALYTICALLY IMPLEMENTING A FEED CONTAINING OLEFINS.
FR2655876B1 (en) REACTOR FOR CATALYST CHEMICAL REACTIONS.
DE50201397D1 (en) Process for the preparation of partial hydrolyzates of organometallic compounds or transition metal catalysts immobilized on inert support materials
JPS51125313A (en) Process for preparatiom of 3-4c unsaturated aldehydes
JPS5321103A (en) Isomerization of olefins

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Designated state(s): AT BE CH DE FR GB LI LU NL SE

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE CH DE FR GB LI LU NL SE

17P Request for examination filed

Effective date: 19861222

17Q First examination report despatched

Effective date: 19880229

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 19881222

RIN1 Information on inventor provided before grant (corrected)

Inventor name: MONTONERI, ENZO

Inventor name: TEMPESTI, EZIO

Inventor name: MODICA, GIOVANNI

Inventor name: GIUFFRE, LUIGI