EP0077005A1 - Patterned dry laid fibrous web products of enhanced absorbency - Google Patents
Patterned dry laid fibrous web products of enhanced absorbency Download PDFInfo
- Publication number
- EP0077005A1 EP0077005A1 EP82109199A EP82109199A EP0077005A1 EP 0077005 A1 EP0077005 A1 EP 0077005A1 EP 82109199 A EP82109199 A EP 82109199A EP 82109199 A EP82109199 A EP 82109199A EP 0077005 A1 EP0077005 A1 EP 0077005A1
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- EP
- European Patent Office
- Prior art keywords
- web
- compacted
- imprinting
- imprinted
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/26—Special paper or cardboard manufactured by dry method; Apparatus or processes for forming webs by dry method from mainly short-fibre or particle material, e.g. paper pulp
- D21H5/265—Treatment of the formed web
- D21H5/2657—Consolidation
- D21H5/2671—Compression of the web, optionally with the use of a binder
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
- A47L13/16—Cloths; Pads; Sponges
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/02—Patterned paper
Definitions
- the present invention relates to air laid (or dry laid) fibrous webs a portion of at least one surface being compacted by application of an imprinted pattern or design which pattern enhances the rate of absorption during use as well as improving the retention of liquid absorbed within the webs. More specifically, the invention relates to air laid cellulosic webs whose individual fibers are bonded together by an adhesive material essentially permeating said web, the bonded web having said pattern on at least one surface thereof, the compacted area thereof comprising at least about 40% of the total area per imprinted surface. Imprinting of the web surface(s) to this degree densifies those interior portions of the web underlying each compacted area thereby promoting capillary tension and wicking to enhance web absorbency and wiping characteristics.
- the invention relates to tissue, towel and napkin products of high bulk and rapid absorbency obtained from bonded air laid cellulosic fibrous webs, in accordance with the method disclosed here.
- a non-nesting pattern is imprinted on the web to prevent loss of final product size, e.g., product roll diameter.
- Fibrous webs particularly low basis weight webs between 8 and 60 lbs.-per ream (3,000 sq.ft.), for use ultimately as tissue, towel and napkin products, are fabricated conventionally by two alternate processes.
- the older wet laid process dispenses an aqueous slurry of pulped paper-making fibers, generally natural cellulose fibers, onto a moving foraminous support means, e.g., a fourdrinier wire, the aqueous medium being removed through the support means by vacuum means.
- the wet laid web is thermally dried and taken up on a parent roll. Because of the presence of water, the wet laid fibers bond naturally to one another by means of hydrogen bonding.
- Such conventionally prepared webs are sometimes creped to improve feel and enhance absorbency.
- the webs may be embossed to enhance softness and-to provide a more aesthetic appearance.
- the second, now conventional, yet relatively recent, process defiberizes cellulose pulp, the dry individual fibers being pneumatically transported to the dispensing means, and then dry laid (or air laid) onto the moving foraminous support means. Vacuum means below the support means is employed to ensure that the dry fibers remain on the web, which web has little inherent strength inasmuch as hydrogen bonds are not formed substantially in the absence of an aqueous medium.
- the dry, initially laid web is then sprayed with a synthetic bonding agent, such as a latex emulsion, preferably on both surfaces of the web.
- the bonding agent is cured by passing the thus treated web through a dryer, e.g., a through air dryer, before being taken up on a parent roll. These webs may also be creped and embossed.
- wet laid webs provide better wiping absorbency than dry laid webs. That is, under dynamic conditions-of use, wet laid webs absorb liquid at a faster rate and retain the liquid thus absorbed better that their dry laid counterpart.
- the slower rate of wiping absorbency associated with dry laid webs is primarily due to the greater volume of interstitial voids, existing within the reticulated structure of these webs.
- the greater void volume is occasioned by the larger size, on average, of individual pores, as well as by the greater degree of reticulation extent in the overall web structure.
- These interstitial voids provide a greater interstitial liquid holding capacity under static conditions, but permit absorbed liquid to be squeezed back out more easily under dynamic wiping conditions.
- a pattern imprinted on at least one surface of a dry laid web wherein the compressed areas comprise at least 40% of the total imprinted area improves web absorption rate and enhances water retention during use.
- patterned webs whether by imprinting or by embossing, have been produced to enhance the softness, improve the bulk, or to alter the strength and stretch characteristics of the web, as well as to impart an aesthetic design to the surface.
- a raised pattern is formed on a portion of a first web surface (the raised portion), with corresponding depressions in the remaining portion of said web surface (the depressed portion).
- These discontinuities in the first surface of the web are occasioned by passing the web between two cylindrical rolls, one of which is resilient, the other being inextensible and having a plurality of bosses thereon.
- the bosses contact the second surface of the web forming the raised areas (and depressions) on the first surface in contact with the resilient roll.
- the raises comprise about 20 to 30% of the total first surface area, the depressions accounting for the remaining area.
- Imprinting compresses certain portions of a web surface in intaglio, the other surface not being raised thereby. Necessarily, imprinting densifies the compressed surface portions substantially more than embossing.
- Imprinting as opposed to embossing, has heretofore been used in wet laid processing in conjunction with subsequent creping as disclosed in, for example, U.S. Patent 4,191,609 to Trokhan and U.S. Patent 4,125,659 to Klowak et al. In doing so the finally creped product exhibits greater softness, improved stretch and tensile strength, and enhanced bulk.
- Patents 3,692,622 and 3,776,807 to Dunning and Dunning et al respectively disclose spot bonding of dry laid webs wherein 5 to 40% of the web surface is imprinted.
- U.S. Patents 4,207,367 and 4,138,848 a plurality of highly compressed, narrow regions, preferably about 30% of the surface, separate the high loft regions, the high loft regions being bonded only partially.
- the high degree of compaction enhances the absorbency rate and.wiping characteristics of said web without excessive reduction of product size, e.g., web roll diameter.
- Another object of the invention is to provide bulky cellulosic web products, for example, tissue, towel and napkin products, having an enhanced rate of absorbency and improved wiping performance, each surface of which has received an imprinted pattern, the compacted area of each imprinted surface representing at least 40%, preferably 50%, of same.
- a collateral object of.the present invention is to provide a method for the manufacture of the absorbent webs and web products of the present invention.
- an air laid . bonded web is imprinted with a depressed design, preferably with a non-nesting pattern to avoid loss of final product roll diameter.
- the bonded web to be imprinted is wetted optionally with a spray of water and subjected to an areal pressure of at least about 16 lbs./in 2 by platen means, said means having been heated to a temperature of between about 140 to about 180°C.
- at least one surface of the treated web must have a compacted area of at least about 40% of the total imprinted surface area, prefereably between 50% to 80% of the total imprinted surface area. Each side of the web may be so imprinted.
- the imprinting means is a pair of non-resilient clindrical rolls adapted for imprinting the web continuously. While the levels of compaction are analogous, the applied pressure is at least 100 lbs. per lineal inch. Again, the imprinting means are heated to 140 to 180°C., and a water spray is optional.
- the diameter of individual product rolls or the composite thickness of packaged product sheets of the present invention are preferably reduced not more than 10% as compared to unimprinted products. Depending on the pressure applied by the imprinting means, said reduction may approach between 20 and 30%. However, the wiping absorbency of products of the present invention is increased by at least about 25%, preferably about 40% or more, as ascertained by relative values of mirror wipe time between imprinted and unimprinted products.
- FIG. 1 a flow diagram of a process for making air laid webs, pulp sheets, laps or bales 10 are defiberized in defiberizer 11, here a hammermill, and transported pneumatically through line 12 to distributor 14 by blower 13.
- defiberizer 11 here a hammermill
- distributor 14 pneumatically through line 12 to distributor 14 by blower 13.
- Distributor arrangements are well known in the art.
- the individual fibers are dispersed onto an endless fourdrinier wire 15, which circles continuously about guide rolls 16.
- Vacuum means 17 draws and retains the loose fibers 18 onto the wire 15 to form a loose web 19 which has little integrity.
- the loose web 19 is typically pressed by consolidation rolls 21, which compaction increases web strength to a limited extent, and permits transfer of the pressed web 22 to a carrier wire 23.
- Wire 23 has larger perforations than wire 15 and is made typically from a synthetic plastic material. The use of a separate wire 23, then, is less likely to cause plugging with bonding material 26 from spray dispensing means 27, and will improve clean up. As shown in FIG.
- the once bonded web 29, partially dried in dryer 28, is transferred from carrier wire 23 to a second carrier wire 31 where a second spray means 33 dispenses additional bonding material 32 onto the second surface of the web. While two bonding applications are shown, one application will suffice where the web is porous and has a low basis weight, e.g., less than about 20 lbs. per 3000 sq. ft. ream. Additional information relating to a preferred process for bonding air laid webs is disclosed in commonly assigned U.S. Pat. Appl. S.N- 108,022 entitled “Methods of Applying Bonding Materials Onto Fibrous Webs", filed December 28, 1979 by Pauls et al. After each bonding application, the web is at least partially cured in dryers 28, 35. If complete drying is not achieved in dryer 35, a curing oven 40 is provided..
- the bonded, cured web 39, and before take up on parent roll 41, is then imprinted at an imprinting station, here a pair of cylindrical rolls 42, although this location is not.critical.
- station 42 can be situated between consolidation rolls 21 and bonding station 27, or between dryer 28 and bonding station 33.
- the imprinting station may be located anywhere following the consolidation rolls 21. It should be noted that when the web is imprinted before the curing step, the compressive force applied by the imprinting means need not be as high as post curing imprinting because the pattern is less likely to "spring back".
- station 42 may be included as a step in the converting operation '(not shown), either from parent rolls or individual product rolls.
- This failing of prior art products is attributed to the.inherently large pore volume between fibers in air laid webs.
- wet laid webs begin to bond as soon as they are laid.
- the high moisture content of the wet laid web which decreases from about 99% per weight water beneath the head box to between about 65% to 85% just prior to consolidation, facilitates densification of the web.
- the water "lubricates" the web and "plasticizes" the fibers so that the individual fibers can come into close physical relationship with one another.
- Air laid webs do not have water to lubricate the fibers, resulting in less dense webs with greater bulk and larger interstitial void volumes. While bulk is highly advantageous, the consequences of excessively large void volume are not.
- Compaction by the vacuum means 17 and the consolidation rolls 21 is not intended to highly densify the webs. Although it would be possible to increase the pressure of the consolidation rolls to highly compact the webs, the beneficial bulk provided by the air laid process would be lost. Furthermore, densification of the web by the consolidation rolls 21 would compromise the ability to disperse bonding agent 26, 32 through the web.
- the invention disclosed herein can be used with air laid webs of between about 8 and about 60 lbs. per ream (3000 sq. ft.) basis weight which have been consolidated by rolls 21 with pressures of between 50 and 300 lbs./ lineal inch, and then bonded with a latex emulsion bonding agent, the bonding agent typically representing between about 10 to 30%, preferably between 15 and 25%, of the web basis weight.
- a latex emulsion bonding agent typically representing between about 10 to 30%, preferably between 15 and 25%, of the web basis weight.
- such webs have a bulk of between 0.7 to about 1.2 mils/lb./ream and a wet MD tensile strength of at least 200 gms. per 3 inch strip. Dry CD tensile is between 500 and 1500 gms. per 3 inch strip.
- test is being used herein to determine gross differences in absorbency rate so that the standard deviations of individual measurements are neglible by comparison.
- Caliper was measured with a Testing Machines, Inc. (Amityville, New York) Model 551M micrometer having a two inch anvil.
- FIG. 3 and 4 are photomicrographs of a conventional uncompacted air laid web and a compacted air laid web, respectively, each enlarged 74 times.
- the densified web of FIG. 4 has much smaller interstitial voids between fibers as compared to the uncompacted web.
- capillary tension and wiping absorbency is increased in the web of FIG. 4 web as demonstrated by reduction in mirror wipe time. Note, however, that a significant loss in caliper occurs as a consequence of the compaction. This loss is more than about 80% in each instance.
- a web 50 representative of the invention was prepared using a pair of etched plates each having raised areas representing 69% of the plate. That is, about 69% of each surface of the web was compacted.
- the web so treated had a grid pattern illustrated in FIG. 2.
- the compacted areas 51 were about 5/16 inch square (dimension x) and the non-compacted surfaces 52, e.g., the essentially uncompacted zones which appear as intersecting ribs or bridge regions, were about 1/16" wide (dimension y).
- the depth of the compacted areas is dependent upon the pressure applied by the plates.
- the uncompacted web (Table I) had a basis weight of 43 lbs./ream, and a caliper of 44.6 mils.
- the imprinting of the web does not reduce the caliper of the non-compacted portions of the web, that is, dimension C 1 , remains about 44 mils. However, some reduction occurs, typically less than about 10%, but possibly approaching 20 to 30%. A compression load of about seven tons was applied between the plates for about 20 seconds.
- the caliper C, of the imprinted web was measured as 31 mils with the Model 551M Micrometer, as compared to 44.6 mils for the uncompacted web and as compared to less than 9.04 mils for the compacted webs.
- the loss in caliper is about 30% versus about at least 80% for the totally compacted webs.
- Conversleyrelative to the wet laid web, the caliper of the imprinted web is about 30% greater.
- Mirror wipe time for the imprinted web was measured at 17 seconds, which is an improvement of 46.9% over the - conventional dry laid web.
- the actual pattern is not critical, it is essential that at least 40%, preferably more than 50%, of the area of one web surface be compacted. If both surfaces of web are compacted, each should be compacted to at least 40%, each preferably more than 50%.
- the plates or cylinders are heated to between 140 and 180°C., with water sprayed on the towel before pressing. The spray of water is not critical to the process, but it does aid in retention of the compaction.
- the grid pattern of FIG. 2 is not critical to the concept of improved web absorbency rate by high compaction imprinting, the grid pattern does affect the end product beneficially in that the grid pattern prevents nesting of the compacted zones within one another when the web is taken up on a product roll.
- the roll of the invention web has essentially the same diameter as conventional products, which is preferred.
- FIG. 6 illustrates an alternate embodiment of the web of the present invention. Although only one surface has received an imprinted pattern, both surfaces may be imprinted if desired.
- web 60 has compacted area 61 and a plurality of non-compacted areas.
- the web of FIG. 6 has contiguous compacted channel regions 61, which regions likewise represent at least 40% of the surface of the web so imprinted.
- densified zones here indicated by numeral 63, exist beneath the compacted area 61. These contiguous channel regions are desirable because they provide pathways for lateral wicking.
- Table I The data of Table I is reproduced graphically in FIG. 5.
- This graph a plot of compacted web density versus Mirror Wipe Time, shows that the improvement in MWT is rapid until a density of about 0.35 g./cc. is achieved, which value corresponds to a compression force of about 15 lbs./in. 2 . Thereafter, MWT increases slightly, an asymptote being reached at about 0.80 g./cc. It is believed that analogous relationships between MWT and web density are applicable to the product of this invention.
- the reduction in absorbency at the higher density values in FIG. 5 apparently occurs because the interstitial voids are too small to permit large amounts of water to be absorbed.
- the preferred densities of the densified web region are between about 0.20 to about 0.50 g./cc., which would correspond roughly to MWT's below 14 and 13 seconds, respectively, for the webs of this invention. It should be noted that the optimal density of 0.35 g./cc. provides essentially equal abosrbency as compared to conventional wet laid webs, that is, an MWT of about 11.5 seconds.
Abstract
Description
- The present invention relates to air laid (or dry laid) fibrous webs a portion of at least one surface being compacted by application of an imprinted pattern or design which pattern enhances the rate of absorption during use as well as improving the retention of liquid absorbed within the webs. More specifically, the invention relates to air laid cellulosic webs whose individual fibers are bonded together by an adhesive material essentially permeating said web, the bonded web having said pattern on at least one surface thereof, the compacted area thereof comprising at least about 40% of the total area per imprinted surface. Imprinting of the web surface(s) to this degree densifies those interior portions of the web underlying each compacted area thereby promoting capillary tension and wicking to enhance web absorbency and wiping characteristics. Most specifically, the invention relates to tissue, towel and napkin products of high bulk and rapid absorbency obtained from bonded air laid cellulosic fibrous webs, in accordance with the method disclosed here. Preferably, a non-nesting pattern is imprinted on the web to prevent loss of final product size, e.g., product roll diameter.
- Fibrous webs, particularly low basis weight webs between 8 and 60 lbs.-per ream (3,000 sq.ft.), for use ultimately as tissue, towel and napkin products, are fabricated conventionally by two alternate processes. The older wet laid process dispenses an aqueous slurry of pulped paper-making fibers, generally natural cellulose fibers, onto a moving foraminous support means, e.g., a fourdrinier wire, the aqueous medium being removed through the support means by vacuum means. The wet laid web is thermally dried and taken up on a parent roll. Because of the presence of water, the wet laid fibers bond naturally to one another by means of hydrogen bonding. Such conventionally prepared webs are sometimes creped to improve feel and enhance absorbency. Similarly, the webs may be embossed to enhance softness and-to provide a more aesthetic appearance.
- The second, now conventional, yet relatively recent, process defiberizes cellulose pulp, the dry individual fibers being pneumatically transported to the dispensing means, and then dry laid (or air laid) onto the moving foraminous support means. Vacuum means below the support means is employed to ensure that the dry fibers remain on the web, which web has little inherent strength inasmuch as hydrogen bonds are not formed substantially in the absence of an aqueous medium. The dry, initially laid web is then sprayed with a synthetic bonding agent, such as a latex emulsion, preferably on both surfaces of the web. The bonding agent is cured by passing the thus treated web through a dryer, e.g., a through air dryer, before being taken up on a parent roll. These webs may also be creped and embossed.
- Generally speaking, wet laid webs provide better wiping absorbency than dry laid webs. That is, under dynamic conditions-of use, wet laid webs absorb liquid at a faster rate and retain the liquid thus absorbed better that their dry laid counterpart. The slower rate of wiping absorbency associated with dry laid webs is primarily due to the greater volume of interstitial voids, existing within the reticulated structure of these webs. The greater void volume is occasioned by the larger size, on average, of individual pores, as well as by the greater degree of reticulation extent in the overall web structure. These interstitial voids provide a greater interstitial liquid holding capacity under static conditions, but permit absorbed liquid to be squeezed back out more easily under dynamic wiping conditions. The net result is an appeared slower rate of wiping absorbency for dry laid webs. The advantages of greater void volume or bulk present in dry laid webs are several. Less fiber per ream is required to fabricate the web. The greater void size provides greater static liquid holding capacity, and typically contributes to a softer feeling web. Finally, dried laid webs have greater wet strength than conventional wet laid webs, and, hence, do not break apart as readily during use.. Thus, substantial improvement in wiping or dynamic absorbency characteristics would greatly improve product acceptance and usefulness.
- Applicants have found that a pattern imprinted on at least one surface of a dry laid web wherein the compressed areas comprise at least 40% of the total imprinted area improves web absorption rate and enhances water retention during use. Heretofore, patterned webs, whether by imprinting or by embossing, have been produced to enhance the softness, improve the bulk, or to alter the strength and stretch characteristics of the web, as well as to impart an aesthetic design to the surface.
- Embossing and imprinting as used in this application are distinguished below, although terminology in the art is not uniform and does overlap.
- In conventional embossing, a raised pattern is formed on a portion of a first web surface (the raised portion), with corresponding depressions in the remaining portion of said web surface (the depressed portion). These discontinuities in the first surface of the web are occasioned by passing the web between two cylindrical rolls, one of which is resilient, the other being inextensible and having a plurality of bosses thereon. The bosses contact the second surface of the web forming the raised areas (and depressions) on the first surface in contact with the resilient roll. Typically, the raises comprise about 20 to 30% of the total first surface area, the depressions accounting for the remaining area. Surface depressions are also formed on the second surface where the bosses come into contact with the web, these depressions being in alignment with the raises on the first surface. Embossing of this nature may result in products having a raised area approaching 60%, as in U.S. Patent 3,337,388 to Wosaba, which embossing improves softness, bulkiness and sponginess.
- Imprinting, on the other hand, as the term is used herein, compresses certain portions of a web surface in intaglio, the other surface not being raised thereby. Necessarily, imprinting densifies the compressed surface portions substantially more than embossing.
- Imprinting, as opposed to embossing, has heretofore been used in wet laid processing in conjunction with subsequent creping as disclosed in, for example, U.S. Patent 4,191,609 to Trokhan and U.S. Patent 4,125,659 to Klowak et al. In doing so the finally creped product exhibits greater softness, improved stretch and tensile strength, and enhanced bulk.
- In dry formed webs surface imprinting, as hereinbefore defined, has been performed to improve the application of bonding agent to the web. In U.S. Patent 4,127,637 to Pietreniak et al between about 15 to 40% of the web surface is compressed by cylindrical rolls prior to bonding, the pattern being then stabilized with binder to retain the differential density. The web is then creped to improve softness and bulk. Similarily, U.S. 4,135,024 to Callahan et al imprints one web surface, simultaneously applying binder to the other web surface, thereby enhancing permeation of the binder into said web. U.S. Patents 3,692,622 and 3,776,807 to Dunning and Dunning et al respectively disclose spot bonding of dry laid webs wherein 5 to 40% of the web surface is imprinted. In Baker, Jr., U.S. Patents 4,207,367 and 4,138,848, a plurality of highly compressed, narrow regions, preferably about 30% of the surface, separate the high loft regions, the high loft regions being bonded only partially.
- Finally, embossing and imprinting are employed to laminate two webs together as disclosed in U.S. Patents 3,867,225 to Nystrand.
- It is an object of the present invention to provide an air laid fibrous web product having enhanced wiping absorbency rate characteristics.
- It is another object of the invention to provide a bulky, absorbent cellulosic web product having a high degree of perceived softness.
- It is a further object of the invention to provide a dry laid fibrous web product at least one surface of which has been imprinted with a design, the compacted area of each imprinted surface representing at least 40%, preferably 50%, of each surface area. The high degree of compaction enhances the absorbency rate and.wiping characteristics of said web without excessive reduction of product size, e.g., web roll diameter.
- Another object of the invention is to provide bulky cellulosic web products, for example, tissue, towel and napkin products, having an enhanced rate of absorbency and improved wiping performance, each surface of which has received an imprinted pattern, the compacted area of each imprinted surface representing at least 40%, preferably 50%, of same.
- A collateral object of.the present invention is to provide a method for the manufacture of the absorbent webs and web products of the present invention.
- These and other advantages and objects of the invention will be readily perceived upon inspection of the drawings, and upon a reading of the detailed description of the invention, a summary of which follows.
- To obtain the soft, bulky products of the invention which have improved wiping absorbency properties, an air laid . bonded web is imprinted with a depressed design, preferably with a non-nesting pattern to avoid loss of final product roll diameter. In one embodiment of the method, the bonded web to be imprinted is wetted optionally with a spray of water and subjected to an areal pressure of at least about 16 lbs./in2 by platen means, said means having been heated to a temperature of between about 140 to about 180°C. To improve wiping absorbency at least one surface of the treated web must have a compacted area of at least about 40% of the total imprinted surface area, prefereably between 50% to 80% of the total imprinted surface area. Each side of the web may be so imprinted.
- In the preferred embodiment of the method, the imprinting means is a pair of non-resilient clindrical rolls adapted for imprinting the web continuously. While the levels of compaction are analogous, the applied pressure is at least 100 lbs. per lineal inch. Again, the imprinting means are heated to 140 to 180°C., and a water spray is optional.
- The diameter of individual product rolls or the composite thickness of packaged product sheets of the present invention are preferably reduced not more than 10% as compared to unimprinted products. Depending on the pressure applied by the imprinting means, said reduction may approach between 20 and 30%. However, the wiping absorbency of products of the present invention is increased by at least about 25%, preferably about 40% or more, as ascertained by relative values of mirror wipe time between imprinted and unimprinted products.
-
- Fig. 1 is a schematic diagram of a conventional dry laid papermaking operation, incorporating the imprinting means of the present invention.
- FIG. 2 is a representation of a product web fabricated in accordance with the method of the present invention. The representation shown is not drawn to scale.
- FIGS. 3 and 4 are photomicrographs of conventional unimprinted and 100% compacted webs respectively, each enlarged 74 times.
- FIG. 5 is a graph of absorbency rate as measured by mirror wipe time versus web density for totally compacted webs.
- FIG. 6 is a representation of an alternate embodiment of the product web fabricated in accordance with the method of the present invention.
- Referring to FIG. 1, a flow diagram of a process for making air laid webs, pulp sheets, laps or bales 10 are defiberized in
defiberizer 11, here a hammermill, and transported pneumatically throughline 12 todistributor 14 byblower 13. Distributor arrangements are well known in the art. - The individual fibers are dispersed onto an
endless fourdrinier wire 15, which circles continuously about guide rolls 16. Vacuum means 17 draws and retains theloose fibers 18 onto thewire 15 to form aloose web 19 which has little integrity. Theloose web 19 is typically pressed by consolidation rolls 21, which compaction increases web strength to a limited extent, and permits transfer of the pressedweb 22 to acarrier wire 23.Wire 23 has larger perforations thanwire 15 and is made typically from a synthetic plastic material. The use of aseparate wire 23, then, is less likely to cause plugging withbonding material 26 from spray dispensing means 27, and will improve clean up. As shown in FIG. 1, the once bondedweb 29, partially dried indryer 28, is transferred fromcarrier wire 23 to asecond carrier wire 31 where a second spray means 33 dispensesadditional bonding material 32 onto the second surface of the web. While two bonding applications are shown, one application will suffice where the web is porous and has a low basis weight, e.g., less than about 20 lbs. per 3000 sq. ft. ream. Additional information relating to a preferred process for bonding air laid webs is disclosed in commonly assigned U.S. Pat. Appl. S.N- 108,022 entitled "Methods of Applying Bonding Materials Onto Fibrous Webs", filed December 28, 1979 by Pauls et al. After each bonding application, the web is at least partially cured indryers dryer 35, a curingoven 40 is provided.. - As shown in FIG. 1, the bonded, cured
web 39, and before take up onparent roll 41, is then imprinted at an imprinting station, here a pair ofcylindrical rolls 42, although this location is not.critical. Alternatively, for example,station 42 can be situated between consolidation rolls 21 andbonding station 27, or betweendryer 28 andbonding station 33. Indeed, the imprinting station may be located anywhere following the consolidation rolls 21. It should be noted that when the web is imprinted before the curing step, the compressive force applied by the imprinting means need not be as high as post curing imprinting because the pattern is less likely to "spring back". In another alternate embodiment,station 42 may be included as a step in the converting operation '(not shown), either from parent rolls or individual product rolls. Preferably, it is less expensive to imprint webs before take-up on parent rolls rather than on individual product rolls during conversion because less capital investment is required. However, treatment of individual product rolls provides some additional flexibility in making products with several designs, which may be dictated by marketing considerations. If both sides of the web are to be imprinted, a second pair of cylindrical rolls is preferred. When platen means are used, however, only one pair of plates is necessary, each plate being provided with an etched surface. - Air laid products made in accordance with the process of FTG. 1, including webs imprinted (or embossed as hereinbefore defined) to achieve aesthetic improvement wherein the compacted surface area of the webs represents less than about 40% of the total surface area, are notably poor in absorption properties. This failing of prior art products is attributed to the.inherently large pore volume between fibers in air laid webs. As discussed above, wet laid webs begin to bond as soon as they are laid. The high moisture content of the wet laid web, which decreases from about 99% per weight water beneath the head box to between about 65% to 85% just prior to consolidation, facilitates densification of the web. The water "lubricates" the web and "plasticizes" the fibers so that the individual fibers can come into close physical relationship with one another. Air laid webs do not have water to lubricate the fibers, resulting in less dense webs with greater bulk and larger interstitial void volumes. While bulk is highly advantageous, the consequences of excessively large void volume are not. Compaction by the vacuum means 17 and the consolidation rolls 21 is not intended to highly densify the webs. Although it would be possible to increase the pressure of the consolidation rolls to highly compact the webs, the beneficial bulk provided by the air laid process would be lost. Furthermore, densification of the web by the consolidation rolls 21 would compromise the ability to disperse
bonding agent - The invention disclosed herein can be used with air laid webs of between about 8 and about 60 lbs. per ream (3000 sq. ft.) basis weight which have been consolidated by
rolls 21 with pressures of between 50 and 300 lbs./ lineal inch, and then bonded with a latex emulsion bonding agent, the bonding agent typically representing between about 10 to 30%, preferably between 15 and 25%, of the web basis weight. Typically, such webs have a bulk of between 0.7 to about 1.2 mils/lb./ream and a wet MD tensile strength of at least 200 gms. per 3 inch strip. Dry CD tensile is between 500 and 1500 gms. per 3 inch strip. Applicants test these webs for absorbency rate using a mirror wipe test. In this test, a given amount of distilled water, 1.4 ml., is placed on a flat 24" x 36" mirror. A sheet of given size, 11 inches square, is used to remove the water under hand applied pressure, the time therefore being measured with a stop watch. The time required, mirror wipe time (MWT), is a measure of the rate of absorbency of the product. Although this test appears, at first inspection, to be more subjective than mechanical test methods known in the art, applicants, through extensive usage, have found that the test achieves nearly the same degree of accuracy. More importantly, applicants have found that the test is more indicative of consumer utilization than the mechanical test procedure. - Furthermore, it should be understood that the test is being used herein to determine gross differences in absorbency rate so that the standard deviations of individual measurements are neglible by comparison.
-
- Caliper was measured with a Testing Machines, Inc. (Amityville, New York) Model 551M micrometer having a two inch anvil.
- FIG. 3 and 4 are photomicrographs of a conventional uncompacted air laid web and a compacted air laid web, respectively, each enlarged 74 times.. As readily seen in the photographs, the densified web of FIG. 4 has much smaller interstitial voids between fibers as compared to the uncompacted web. Hence, capillary tension and wiping absorbency is increased in the web of FIG. 4 web as demonstrated by reduction in mirror wipe time. Note, however, that a significant loss in caliper occurs as a consequence of the compaction. This loss is more than about 80% in each instance.
- In FIG. 2, a
web 50 representative of the invention was prepared using a pair of etched plates each having raised areas representing 69% of the plate. That is, about 69% of each surface of the web was compacted. The web so treated had a grid pattern illustrated in FIG. 2. As shown therein, the compactedareas 51 were about 5/16 inch square (dimension x) and thenon-compacted surfaces 52, e.g., the essentially uncompacted zones which appear as intersecting ribs or bridge regions, were about 1/16" wide (dimension y). The depth of the compacted areas is dependent upon the pressure applied by the plates. The uncompacted web (Table I) had a basis weight of 43 lbs./ream, and a caliper of 44.6 mils. Ideally, the imprinting of the web does not reduce the caliper of the non-compacted portions of the web, that is, dimension C1, remains about 44 mils. However, some reduction occurs, typically less than about 10%, but possibly approaching 20 to 30%. A compression load of about seven tons was applied between the plates for about 20 seconds. - The caliper C, of the imprinted web was measured as 31 mils with the Model 551M Micrometer, as compared to 44.6 mils for the uncompacted web and as compared to less than 9.04 mils for the compacted webs. The loss in caliper is about 30% versus about at least 80% for the totally compacted webs. Conversleyrelative to the wet laid web, the caliper of the imprinted web is about 30% greater. Mirror wipe time for the imprinted web was measured at 17 seconds, which is an improvement of 46.9% over the - conventional dry laid web.
- While the actual pattern is not critical, it is essential that at least 40%, preferably more than 50%, of the area of one web surface be compacted. If both surfaces of web are compacted, each should be compacted to at least 40%, each preferably more than 50%. In the preferred embodiment, the plates or cylinders are heated to between 140 and 180°C., with water sprayed on the towel before pressing. The spray of water is not critical to the process, but it does aid in retention of the compaction.
- Although the grid pattern of FIG. 2 is not critical to the concept of improved web absorbency rate by high compaction imprinting, the grid pattern does affect the end product beneficially in that the grid pattern prevents nesting of the compacted zones within one another when the web is taken up on a product roll. Thus, the roll of the invention web has essentially the same diameter as conventional products, which is preferred.
- FIG. 6 illustrates an alternate embodiment of the web of the present invention. Although only one surface has received an imprinted pattern, both surfaces may be imprinted if desired. In this
embodiment web 60 has compactedarea 61 and a plurality of non-compacted areas. In contradistinction to the contiguousnon-compacted bridge regions 52 of the web of FIG. 2, the web of FIG. 6 has contiguous compactedchannel regions 61, which regions likewise represent at least 40% of the surface of the web so imprinted. As before, densified zones, here indicated bynumeral 63, exist beneath the compactedarea 61. These contiguous channel regions are desirable because they provide pathways for lateral wicking. - The data of Table I is reproduced graphically in FIG. 5. This graph, a plot of compacted web density versus Mirror Wipe Time, shows that the improvement in MWT is rapid until a density of about 0.35 g./cc. is achieved, which value corresponds to a compression force of about 15 lbs./in.2. Thereafter, MWT increases slightly, an asymptote being reached at about 0.80 g./cc. It is believed that analogous relationships between MWT and web density are applicable to the product of this invention. The reduction in absorbency at the higher density values in FIG. 5 apparently occurs because the interstitial voids are too small to permit large amounts of water to be absorbed. For this reason, the preferred densities of the densified web region are between about 0.20 to about 0.50 g./cc., which would correspond roughly to MWT's below 14 and 13 seconds, respectively, for the webs of this invention. It should be noted that the optimal density of 0.35 g./cc. provides essentially equal abosrbency as compared to conventional wet laid webs, that is, an MWT of about 11.5 seconds.
- The above disclosure is exemplary of the invention, and is not intended to be limiting except as respects the claims which are appended below.
Claims (27)
whereby the portions of the web product underlying the compacted regions are compressed and densified reducing thereby the interstitial voids between adjacent fibers within said densified portions so that wiping absorbency is enhanced by increasing capillary tension and promoting wicking.
an improvement to enhance the rate of absorbency, the improvement comprising the step of imprinting at least one surface of the web, each imprinted web surface having a pattern characterised by a compacted area of at least 40% of the total imprinted surface area, the imprinting being performed at any step in the method subsequent to the consolidation of the loose web under-a pressure sufficient to densify the portions of the web underlying the compacted areas to at least 0.1 g./cc.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT82109199T ATE22713T1 (en) | 1981-10-05 | 1982-10-05 | DRY-LAID INCREASED ABSORBENT PATTERNED FIBER WEB PRODUCTS. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US30901581A | 1981-10-05 | 1981-10-05 | |
US309015 | 1981-10-05 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0077005A1 true EP0077005A1 (en) | 1983-04-20 |
EP0077005B1 EP0077005B1 (en) | 1986-10-08 |
Family
ID=23196302
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP82109199A Expired EP0077005B1 (en) | 1981-10-05 | 1982-10-05 | Patterned dry laid fibrous web products of enhanced absorbency |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0077005B1 (en) |
JP (1) | JPS58144197A (en) |
AT (1) | ATE22713T1 (en) |
CA (1) | CA1193919A (en) |
DE (1) | DE3273640D1 (en) |
DK (1) | DK439282A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0093393A2 (en) * | 1982-05-04 | 1983-11-09 | The James River Corporation | A process for manufacturing embossed nonwoven fibrous products |
WO1995012032A1 (en) * | 1993-10-28 | 1995-05-04 | KRØYER, Ingelise, Kobs (heiress of KRØYER, Karl, Kristian, Kobs (deceased)) | Mechanical partial neutralization of hydrogen bonds for production of a softer and more silky air-laid fibrous product |
WO1995012030A1 (en) * | 1993-10-28 | 1995-05-04 | KRØYER, Ingelise, Kobs | Modified latex |
EP0745717A1 (en) | 1995-06-01 | 1996-12-04 | Kaysersberg | Method of finishing a dry-formed web and web thus finished |
WO2000036217A1 (en) * | 1998-12-17 | 2000-06-22 | Kimberly-Clark Worldwide, Inc. | Compressed absorbent fibrous structures |
US6432272B1 (en) | 1998-12-17 | 2002-08-13 | Kimberly-Clark Worldwide, Inc. | Compressed absorbent fibrous structures |
FR2839918A1 (en) * | 2002-05-27 | 2003-11-28 | Adco Mfg | Packaging material, for foodstuffs, has a polyethylene barrier layer between layers of compressed cardboard and absorbent paper with a corrugated surface |
WO2010001294A2 (en) * | 2008-06-30 | 2010-01-07 | Kimberly-Clark Worldwide, Inc. | Patterned self-warming wipe substrates |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5938893A (en) * | 1997-08-15 | 1999-08-17 | The Procter & Gamble Company | Fibrous structure and process for making same |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3017304A (en) * | 1956-05-24 | 1962-01-16 | Personal Products Corp | Absorbent fibrous structure and method of production |
US3616157A (en) * | 1969-08-08 | 1971-10-26 | Johnson & Johnson | Embossed nonwoven wiping and cleaning materials |
GB1372502A (en) * | 1971-10-07 | 1974-10-30 | Johnson & Johnson | Non-woven fabric |
US4135024A (en) * | 1976-08-16 | 1979-01-16 | Scott Paper Company | Method of treating a low integrity dry-formed nonwoven web and product made therefrom |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3867225A (en) * | 1969-01-23 | 1975-02-18 | Paper Converting Machine Co | Method for producing laminated embossed webs |
US3905863A (en) * | 1973-06-08 | 1975-09-16 | Procter & Gamble | Process for forming absorbent paper by imprinting a semi-twill fabric knuckle pattern thereon prior to final drying and paper thereof |
US3908659A (en) * | 1974-03-14 | 1975-09-30 | Procter & Gamble | Absorbent pad structure, diaper construction utilizing same and methods of manufacture thereof |
US4191609A (en) * | 1979-03-09 | 1980-03-04 | The Procter & Gamble Company | Soft absorbent imprinted paper sheet and method of manufacture thereof |
-
1982
- 1982-10-04 DK DK439282A patent/DK439282A/en not_active Application Discontinuation
- 1982-10-04 CA CA000412745A patent/CA1193919A/en not_active Expired
- 1982-10-05 JP JP57174098A patent/JPS58144197A/en active Pending
- 1982-10-05 DE DE8282109199T patent/DE3273640D1/en not_active Expired
- 1982-10-05 AT AT82109199T patent/ATE22713T1/en not_active IP Right Cessation
- 1982-10-05 EP EP82109199A patent/EP0077005B1/en not_active Expired
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3017304A (en) * | 1956-05-24 | 1962-01-16 | Personal Products Corp | Absorbent fibrous structure and method of production |
US3616157A (en) * | 1969-08-08 | 1971-10-26 | Johnson & Johnson | Embossed nonwoven wiping and cleaning materials |
GB1372502A (en) * | 1971-10-07 | 1974-10-30 | Johnson & Johnson | Non-woven fabric |
US4135024A (en) * | 1976-08-16 | 1979-01-16 | Scott Paper Company | Method of treating a low integrity dry-formed nonwoven web and product made therefrom |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0093393A2 (en) * | 1982-05-04 | 1983-11-09 | The James River Corporation | A process for manufacturing embossed nonwoven fibrous products |
EP0093393A3 (en) * | 1982-05-04 | 1985-12-27 | The James River Corporation | A process for manufacturing embossed nonwoven fibrous products |
WO1995012032A1 (en) * | 1993-10-28 | 1995-05-04 | KRØYER, Ingelise, Kobs (heiress of KRØYER, Karl, Kristian, Kobs (deceased)) | Mechanical partial neutralization of hydrogen bonds for production of a softer and more silky air-laid fibrous product |
WO1995012030A1 (en) * | 1993-10-28 | 1995-05-04 | KRØYER, Ingelise, Kobs | Modified latex |
EP0745717A1 (en) | 1995-06-01 | 1996-12-04 | Kaysersberg | Method of finishing a dry-formed web and web thus finished |
WO2000036217A1 (en) * | 1998-12-17 | 2000-06-22 | Kimberly-Clark Worldwide, Inc. | Compressed absorbent fibrous structures |
US6432272B1 (en) | 1998-12-17 | 2002-08-13 | Kimberly-Clark Worldwide, Inc. | Compressed absorbent fibrous structures |
FR2839918A1 (en) * | 2002-05-27 | 2003-11-28 | Adco Mfg | Packaging material, for foodstuffs, has a polyethylene barrier layer between layers of compressed cardboard and absorbent paper with a corrugated surface |
WO2010001294A2 (en) * | 2008-06-30 | 2010-01-07 | Kimberly-Clark Worldwide, Inc. | Patterned self-warming wipe substrates |
WO2010001294A3 (en) * | 2008-06-30 | 2010-03-04 | Kimberly-Clark Worldwide, Inc. | Patterned self-warming wipe substrates |
US7924142B2 (en) | 2008-06-30 | 2011-04-12 | Kimberly-Clark Worldwide, Inc. | Patterned self-warming wipe substrates |
Also Published As
Publication number | Publication date |
---|---|
DE3273640D1 (en) | 1986-11-13 |
DK439282A (en) | 1983-04-06 |
JPS58144197A (en) | 1983-08-27 |
CA1193919A (en) | 1985-09-24 |
EP0077005B1 (en) | 1986-10-08 |
ATE22713T1 (en) | 1986-10-15 |
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