EP0074501A3 - Process and catalyst for the conversion of oils that contain carbon precursors and heavy metals - Google Patents

Process and catalyst for the conversion of oils that contain carbon precursors and heavy metals Download PDF

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Publication number
EP0074501A3
EP0074501A3 EP82107433A EP82107433A EP0074501A3 EP 0074501 A3 EP0074501 A3 EP 0074501A3 EP 82107433 A EP82107433 A EP 82107433A EP 82107433 A EP82107433 A EP 82107433A EP 0074501 A3 EP0074501 A3 EP 0074501A3
Authority
EP
European Patent Office
Prior art keywords
catalyst
management
rccc
practiced
removal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP82107433A
Other versions
EP0074501A2 (en
EP0074501B1 (en
Inventor
Oliver J. Zandona
William P. Hettinger, Jr.
Stephen M. Kovach
Wayne H. Beck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ashland LLC
Original Assignee
Ashland Oil Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ashland Oil Inc filed Critical Ashland Oil Inc
Priority to AT82107433T priority Critical patent/ATE19263T1/en
Publication of EP0074501A2 publication Critical patent/EP0074501A2/en
Publication of EP0074501A3 publication Critical patent/EP0074501A3/en
Application granted granted Critical
Publication of EP0074501B1 publication Critical patent/EP0074501B1/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

An improved process and catalyst for economically converting carbo-metallic oils to lighter products. This process is practiced in accordance with effective metals management, carbon management and catalyst activity management combined with feed atomization-vaporization, efficient stripping of carbonaceous material from the coked catalyst, exothermic and endothermic removal of hydrocarbonaceous material to effectively maintain the RCC unit in heat balance. This reduced crude cracking process is practiced with a new and improved catalyst composition identified as RCCC-1 Special that is characterized by the following composition; at least 30 wt% rare earth exchanged "Y" faujasite crystalline zeolite with a silica to alumina ratio of at least 5 of a high lanthanum to cerium ratio and residual sodium content less than 0.30 wt%, is provided with a pore volume greater that 0.35 cc/gm and comprises a clay matrix material that may or may not be acidic with pore size openings in the range of 500 to 2,000 angstroms. The RCCC-1 Special can contain metal promoters to catalyze the endothermic removal of coke and the partial removal of hydrogen present in the carbonaceous material with carbon dioxide. In addition, metal additives to passivate and immobilize vanadium is comtemplated.
EP82107433A 1981-08-27 1982-08-16 Process and catalyst for the conversion of oils that contain carbon precursors and heavy metals Expired EP0074501B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT82107433T ATE19263T1 (en) 1981-08-27 1982-08-16 PROCESS AND CATALYST FOR THE CONVERSION OF OILS CONTAINING COKE PRECURSORS AND HEAVY METALS.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US296679 1981-08-27
US06/296,679 US4508839A (en) 1981-08-27 1981-08-27 Catalyst for the conversion of carbo-metallic containing oils

Publications (3)

Publication Number Publication Date
EP0074501A2 EP0074501A2 (en) 1983-03-23
EP0074501A3 true EP0074501A3 (en) 1983-07-27
EP0074501B1 EP0074501B1 (en) 1986-04-16

Family

ID=23143064

Family Applications (1)

Application Number Title Priority Date Filing Date
EP82107433A Expired EP0074501B1 (en) 1981-08-27 1982-08-16 Process and catalyst for the conversion of oils that contain carbon precursors and heavy metals

Country Status (8)

Country Link
US (1) US4508839A (en)
EP (1) EP0074501B1 (en)
JP (2) JPS5843235A (en)
AT (1) ATE19263T1 (en)
AU (1) AU557148B2 (en)
CA (1) CA1189845A (en)
DE (1) DE3270631D1 (en)
MX (1) MX161785A (en)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4877514A (en) * 1981-12-07 1989-10-31 Ashland Oil, Inc. Carbo-metallic oil conversion process and catalysts
US4480047A (en) * 1983-04-07 1984-10-30 Ashland Oil, Inc. High performance catalysts for carbometallic oil conversion and their manufacturing and use
US4515683A (en) * 1983-09-15 1985-05-07 Ashland Oil, Inc. Passivation of vanadium accumulated on catalytic solid fluidizable particles
US4479870A (en) * 1984-02-29 1984-10-30 Jop Inc. Use of lift gas in an FCC reactor riser
IN162877B (en) * 1984-06-13 1988-07-16 Ashland Oil Inc
CN87100803A (en) * 1986-02-24 1987-10-07 恩格尔哈德公司 The modified version hydroconversion process
US4802971A (en) * 1986-09-03 1989-02-07 Mobil Oil Corporation Single riser fluidized catalytic cracking process utilizing hydrogen and carbon-hydrogen contributing fragments
US4863585A (en) * 1986-09-03 1989-09-05 Mobil Oil Corporation Fluidized catalytic cracking process utilizing a C3-C4 paraffin-rich Co-feed and mixed catalyst system with selective reactivation of the medium pore silicate zeolite component thereofo
US4752375A (en) * 1986-09-03 1988-06-21 Mobil Oil Corporation Single riser fluidized catalytic cracking process utilizing a C3-4 paraffin-rich co-feed and mixed catalyst system
US4826586A (en) * 1986-09-03 1989-05-02 Mobil Coil Corporation Single riser fluidized catalytic cracking process utilizing a C3-4 paraffin-rich co-feed and mixed catalyst system
AU607435B2 (en) * 1986-09-03 1991-03-07 Mobil Oil Corporation Process for fluidized catalytic cracking with reactive fragments
AU605188B2 (en) * 1986-09-03 1991-01-10 Mobil Oil Corporation Processing of activated heavy hydrocarbon feeds
US4853105A (en) * 1986-09-03 1989-08-01 Mobil Oil Corporation Multiple riser fluidized catalytic cracking process utilizing hydrogen and carbon-hydrogen contributing fragments
FR2605643B1 (en) * 1986-10-24 1989-08-18 Total France METHOD AND DEVICE FOR CATALYTIC CRACKING IN A FLUIDIZED BED OF A HYDROCARBON LOAD
FR2624762B1 (en) * 1987-12-21 1990-06-08 Total France METHOD AND DEVICE FOR REGENERATING A FLUIDIZED BED CATALYST
US4913801A (en) * 1988-06-17 1990-04-03 Betz Laboratories, Inc. Passivation of FCC catalysts
US5064524A (en) * 1988-06-17 1991-11-12 Betz Laboratories, Inc. Passivation of FCC catalysts
US5194413A (en) * 1992-04-27 1993-03-16 W. R. Grace & Co.-Conn. Catalytic cracking catalysts and additives
US5646082A (en) * 1993-06-24 1997-07-08 Cosmo Research Institute Crystalline aluminosilicate, process for producing the same, and catalyst employing the same for catalytic cracking of hydrocarbon oil
US5641395A (en) * 1995-03-03 1997-06-24 Ashland Inc. Process and compositions for Mn containing catalyst for carbo-metallic hydrocarbons
CO5930067A1 (en) * 2006-12-06 2008-06-27 Ecopetrol Sa VANADIUM TRAP FOR THE CATALYTIC BREAK PROCESS AND ITS PREPARATION
JP5192493B2 (en) * 2007-01-03 2013-05-08 サウディ ベーシック インダストリーズ コーポレイション Zeolite / kaolin catalyst composition

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3591488A (en) * 1969-06-11 1971-07-06 Exxon Research Engineering Co High silica crystalline zeolites and processes for their preparation
US3706654A (en) * 1969-11-12 1972-12-19 Gulf Research Development Co Fluid catalytic cracking processes and means
GB2063294A (en) * 1979-11-14 1981-06-03 Ashland Oil Inc High metal carbo-metallic oil conversion
GB2063293A (en) * 1979-11-14 1981-06-03 Ashland Oil Inc Carbo-metallic oil conversion with controlled CO:CO2 ratio in regeneration
US4298459A (en) * 1979-11-05 1981-11-03 Standard Oil Company (Indiana) Fluid catalytic cracking of heavy petroleum fractions

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3867308A (en) * 1973-12-10 1975-02-18 Grace W R & Co Process for preparing a petroleum cracking catalyst
US4022714A (en) * 1975-07-17 1977-05-10 W. R. Grace & Co. Silica hydrosol bound cracking catalysts
US4198319A (en) * 1977-02-16 1980-04-15 Filtrol Corporation Method of producing zeolitic catalysts with silica alumina matrix
US4261861A (en) * 1979-07-23 1981-04-14 Uop Inc. FCC Catalyst production from used FCC catalyst

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3591488A (en) * 1969-06-11 1971-07-06 Exxon Research Engineering Co High silica crystalline zeolites and processes for their preparation
US3706654A (en) * 1969-11-12 1972-12-19 Gulf Research Development Co Fluid catalytic cracking processes and means
US4298459A (en) * 1979-11-05 1981-11-03 Standard Oil Company (Indiana) Fluid catalytic cracking of heavy petroleum fractions
GB2063294A (en) * 1979-11-14 1981-06-03 Ashland Oil Inc High metal carbo-metallic oil conversion
GB2063293A (en) * 1979-11-14 1981-06-03 Ashland Oil Inc Carbo-metallic oil conversion with controlled CO:CO2 ratio in regeneration

Also Published As

Publication number Publication date
ATE19263T1 (en) 1986-05-15
JPS5843235A (en) 1983-03-12
EP0074501A2 (en) 1983-03-23
EP0074501B1 (en) 1986-04-16
AU557148B2 (en) 1986-12-11
US4508839A (en) 1985-04-02
CA1189845A (en) 1985-07-02
MX161785A (en) 1990-12-27
JPS62275193A (en) 1987-11-30
JPH0129837B2 (en) 1989-06-14
JPS6123021B2 (en) 1986-06-04
DE3270631D1 (en) 1986-05-22
AU8747882A (en) 1983-03-03

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