EP0040927B1 - System for producing a liquid spray curtain for application to a moving web - Google Patents
System for producing a liquid spray curtain for application to a moving web Download PDFInfo
- Publication number
- EP0040927B1 EP0040927B1 EP81302126A EP81302126A EP0040927B1 EP 0040927 B1 EP0040927 B1 EP 0040927B1 EP 81302126 A EP81302126 A EP 81302126A EP 81302126 A EP81302126 A EP 81302126A EP 0040927 B1 EP0040927 B1 EP 0040927B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- liquid
- air
- outlets
- discharge
- curtain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
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- 239000007788 liquid Substances 0.000 title claims abstract description 211
- 239000007921 spray Substances 0.000 title claims abstract description 50
- 238000007599 discharging Methods 0.000 claims abstract description 7
- 238000004891 communication Methods 0.000 claims description 6
- 238000012423 maintenance Methods 0.000 claims description 3
- 230000003020 moisturizing effect Effects 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 4
- 239000007787 solid Substances 0.000 description 10
- 238000005507 spraying Methods 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 210000003027 ear inner Anatomy 0.000 description 5
- 230000035515 penetration Effects 0.000 description 5
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- 210000003128 head Anatomy 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000000889 atomisation Methods 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 239000011344 liquid material Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000032258 transport Effects 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
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- 238000005259 measurement Methods 0.000 description 1
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Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/02—Spray pistols; Apparatus for discharge
- B05B7/08—Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point
- B05B7/0807—Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point to form intersecting jets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/02—Spray pistols; Apparatus for discharge
- B05B7/08—Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point
- B05B7/0884—Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point the outlet orifices for jets constituted by a liquid or a mixture containing a liquid being aligned
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21G—CALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
- D21G7/00—Damping devices
Definitions
- This invention relates to a system for producing a continuous liquid spray curtain capable of uniformly covering essentially the entirety of a moving surface, without substantial streaking thereof.
- Prior art systems have been provided for spraying a liquid onto a moving surface.
- a plurality of hydraulic nozzles can be employed for liquid spraying, the number of nozzles employed being determined by the width of the surface to be sprayed.
- hydraulic nozzles emit a spray in a circular or elliptical pattern. This causes nonuniform coverage of the moving surface because the respective sprays emanating from adjacent hydraulic nozzles are difficult to interface one with the other over the entire width of the moving surface. Thus, streaking results due to these respective oversprayed or undersprayed areas.
- Streaking is a particular problem in certain applications, such as, for example, spraying a creping adhesive onto a cellulosic web, or onto a thermal drying cylinder, since nonuniform adhesion of the web to the thermal drying cylinder results in a nonuniformly creped sheet having substandard physical properties. Furthermore, the dried, creped web will not wind evenly into a parent roll on the papermaking reel if creping is nonuniform. This will lead to substantial problems when the parent roll is converted to product.
- the exit velocity of the liquid in a hydraulic nozzle system determines the requisite degree of atomization of the liquid.
- the liquid exit velocity is relatively high.
- the exit velocity is primarily a function of the liquid supply pressure. A high liquid supply pressure presents severe operating hazards to equipment and personnel.
- sonic nozzles typically spray particles of a smaller, more uniform size particle distribution than those produced by hydraulic spraying.
- One of the major problems which can result from the use of a plurality of sonic nozzles for spraying onto a moving surface is that the finer the spray which is produced, the lower the momentum of the spray particles. This, in turn, reduces the effect of penetration by the spray particles of the boundary air layer between the nozzle and the moving surface, resulting in a significantly higher level of spray migration and a lower solids addition to the moving surface.
- the same coverage problems associated with hydraulic nozzles are present herein because of the circular spray patterns produced by each adjacent sonic nozzle.
- the sonic nozzles exhibit plugging problems similar to those described above for hydraulic nozzles.
- U.S. Patent 1,888,791 describes an apparatus which discharges liquids through jets.
- This specification describes a system for producing a liquid spray curtain for application to a moving surface and comprising a liquid supply means comprising at least one liquid supply header for discharging a plurality of liquid streams, said liquid supply header comprising a liquid supply chamber, a liquid reservoir communicating with a plurality of outlets, a flow restriction between the supply chamber and the reservoir and an air supply means having a header comprising an air supply chamber having a converging outlet for directing air at a high velocity to contact liquid discharged by the liquid discharge means as set out in the first part of claim 1.
- the discharge liquid intersects air streams outside the discharge orifices at a substantially maximum angle with respect to the central axis of the liquid jets so that the air streams impede the progress of the liquid jet flow and create a back-pressure.
- Any change in the air velocity or impingement angle will change the back-pressure.
- any increase in the back-pressure such as caused by an increase in the air velocity, will result in a decrease in both the liquid velocity and in the amount of liquid sprayed.
- spray uniformity in both the lateral (coverage) and longitudinal (uniform rate) directions will be difficult to maintain.
- a nonuniform moisture profile typically exists in which the edges of the webs are much drier than the central portion. Coverage of these webs with moisturizing liquids to a desired moisture level can be accomplished by the addition of water to increase the moisture level at the edges of the web.
- Some prior art systems, such as sonic nozzles attempt to correct this problem by changing the flow rates of a plurality of individual sonic nozzles in a given system so as to alter the moisture profile of the web. Instead, the system provides a random, nonuniform, uncoordinated spray pattern.
- the converging outlet is defined between first and second sidewall members to be in the form of a continuous air exit slit that spans a plurality of the liquid outlets to provide an air curtain contacting liquid discharged from said plurality of liquid outlets, in that an air-flow guide member is located at the outermost end of the first sidewall member and in that means are provided for adjusting the position of the second sidewall relative to the first sidewall to adjust the magnitude of the slit and the direction of discharge of the air curtain such that its minimum contact angle with the liquid streams from the outlets measured from the center line of the liquid discharge outlets is between -10 0 and +30°.
- the outlet for air is in the form of a continuous air exit slit which spans a plurality of the liquid outlets, preferably all the liquid outlets, so as to provide an even spray across the whole width of the moving web or surface to be sprayed.
- the prior United States Specification uses individual air outlet apertures for each liquid outlet.
- the present invention utilises an airflow guide member located at the outermost end of a fixed sidewall member defining the air outlet and operative to deflect the airflow generally along the direction of a discharge of liquid rather than across the flow as used in the prior construction for benefits as previously explained.
- the position of the movable sidewall is adjustable carefully to tune the airflow to that required in the desired result in distributing the liquid.
- the liquid spray curtain is produced by discharging a plurality of streams of liquid to be sprayed from a discharge means at a relatively low discharge velocity.
- a continuous, high velocity air curtain is also discharged which is directed toward the liquid streams and contacts at a minimum contact angle /3, measured from the center line of said liquid discharge means of from about -10 0 and preferably from about -5°, up to about +30°, and more preferably up to about +10°.
- the high velocity air curtain contacts the low velocity liquid at the above prescribed minimum contact angle, the liquid velocity is substantially increased and the liquid is atomized, thereby forming a high velocity, continuous, uniform liquid spray curtain.
- the high velocity liquid spray curtain exhibits a relatively high boundary penetration level in a controlled, extensive particle range. Accordingly, essentially the entire moving surface is covered with the liquid spray in uniform manner, and without substantial interfacing or streaking problems, as previously described.
- Spraying of a relatively high total solids liquid can be accomplished when the invention is employed without the problems associated with the prior art.
- the total liquid flow rate can be decreased at a given total solids level. This will, in turn, decrease the total water consumption and the thermal drying costs associated with the prior art solution levels.
- the total amount of liquid sprayed on the moving surface using the apparatus of the present invention is preferably only up to about 50%, and more preferably up to about 25%, as compared to hydraulic nozzles at the same total solids level.
- the ratio of A X :A,, at a given total solids flow rate is generally at least about 30, and preferably at least about 60, and more preferably at least about 120.
- the liquid discharge velocity when using the present invention is relatively low and preferably is not greater than about (20 feet per second) 6 metres/sec, and more preferably not greater than about (5 feet per second) 1.5 metres/sec, and most preferably not more than about (2 feet per second) 0.6 metres/sec. This is in total contradistinction to the aforementioned prior art methods which employ substantially high liquid flow velocities, to overcome an impeding air flow and, in the case of the hydraulic and sonic nozzles, for overcoming the air boundary layer between the system and the surface.
- the discharge velocity of the air curtain is preferably at least about (600 feet per second) 180 metres/sec., and more preferably at least about (1,000 feet per second) 300 metres/sec., and most preferably at least about (1,200 feet per second) 365 metres/sec. Furthermore, the respective liquid and air velocities are maintained so that substantial atomization of the liquid will result.
- Moving surfaces of differing widths can be effectively sprayed by employing the preferred apparatus of this invention.
- accurate, controlled, uniform coverage, especially at the surface edges, is difficult to maintain since the spray pattern produced by these prior systems is discontinuous.
- the present system can provide for readily adjusting the width of the continuous spray curtain, depending on the width of the moving surface to be sprayed. This can be done by closing off or opening, in a controlled manner, only the outer-most liquid sprays so that the width of the curtain will correspond to the width of the moving surface. Such an adjustment can be made to quite a narrow tolerance range since the liquid discharge outlets are in close proximity one to the other.
- each liquid header system preferably includes labyrinth means which internally meters and longitudinally distributes the liquid flow, causing a constant span-wise pressure or static head to be maintained in a liquid reservoir which preferably extends across the entire longitudinal distance of the discharge means.
- labyrinth means which internally meters and longitudinally distributes the liquid flow, causing a constant span-wise pressure or static head to be maintained in a liquid reservoir which preferably extends across the entire longitudinal distance of the discharge means. The presence of this liquid reservoir ensures that a constant, static liquid head will be maintained at the discharge means and that the liquid spray curtain will therefore operate at steady-state conditions.
- Certain moving surfaces such as cellulosic webs on a paper machine, have a substantially nonuniform moisture profile, i.e., the moisture level is substantially lower at the edges than at the center.
- the previously described conventional systems are not capable of effectively controlling the spray from both a quality and quantity standpoint so that the moisture profile of the web cannot be modified to the extent that it becomes uniform across the entire web surface.
- an inverted moisture profile can be provided using the preferred system of the present invention in which more moisture is sprayed at the edges of the moving surface than in the interior portion thereof while, at the same time, maintaining the same total amount of liquid spray addition.
- Moisture profile measurement means can be provided for continuously monitoring the moisture profile of the web at a point upstream from the subject spray system. The flow rate can then be adjusted at various points in the individual liquid supply headers to compensate for these disparities.
- a system 10 for producing a liquid spray curtain is generally depicted therein attached to and supported by a beam 70 and includes a liquid supply means 20 and an air supply means 40.
- the liquid supply means in general, comprises at least one liquid supply header, in this case denoted “21" and “21' ", having a plurality of liquid supply lines 23 attached, at one end, thereto.
- the liquid supply lines 23 from each supply header are, at the other end, connected to a liquid supply conduit 22 which transports the liquid from a liquid storage means (not shown) employing a pump or other like means to provide the driving force for transporting the liquid.
- Air supply means 40 comprises an air supply header 41 to which a plurality of air supply lines 61 are connected. At the other end, the air supply lines 61 are connected to air supply conduit 60 which transports air, under pressure, employing a compressor or like means to provide the driving force.
- liquid supply headers 21 and 21' which discharge a plurality of liquid streams from discharge means 37 at a relatively low velocity, include inlet supply means 24 and 24' which supply the appropriate liquid to supply chambers 25 and 25'.
- liquid supply headers 21 and 21' are disposed at right angles one with respect to the other.
- Liquid supply chambers 25 and 25' have located therewithin labyrinth means 26 and 26' for internally metering and longitudinally distributing the liquid flow.
- labyrinth means 26 and 26' comprise, preferably, first compartments 27 and 27', in which the liquid is initially collected, the liquid being restrained from flowing freely by first barrier means 29 and 29'.
- Liquid supply orifices 30 and 30' are also provided which permit a reduced flow of liquid to the second compartment 28 and 28', where the liquid is again collected.
- the flow is restricted in this case by second barrier means 31 and 31'.
- the liquid then moves to a liquid reservoir means 33 and 33' from labyrinth means 26 and 26', respectively, through liquid supply slots 32 and 32' in the respective second barrier means 31 and 31'.
- Both the liquid reservoir means and the liquid supply slots, respectively extend along the entire longitudinal distance of the liquid supply headers 21 and 21'.
- discharge means 37 having an exit orifice 37', which is adapted for liquid communication with said reservoir, to provide a continuous, uniform flow rate of liquid.
- liquid flow tubes 38 and 38' (in phantom) are preferably disposed within discharge means 37 for further controlling the discharge of the liquid.
- the discharge means 37 preferably __has a narrowed end section 36 which provides, if necessary, means for readily maintaining liquid flow tubes 38 and 38' in proper position and alignment.
- liquid flow tubes 38 and 38' are preferably in individual and alternative communication with the liquid in a pair of liquid supply headers 21 and 21', respectively. This permits a more controlled liquid flow and allows the system to continue in operation even if one of the headers requires maintenance.
- air supply means 40 comprises an air supply header 41, which discharges a continuous, high velocity air curtain, from exit air slit-50, for contact with said liquid streams, as hereinafter provided.
- the air supply header 41 includes means denoted "43" and "51” for adjusting the respective magnitudes of the exit air slit 50 and the air contact angle /3, as hereinafter described.
- Exit air slit 50 is preferably continuous along the entire longitudinal extent of the system 10.
- Air supply chamber 49 is formed within the confines of said air supply header 41 and converges at its outermost end to form a continuous exit air slit 50.
- the header 41 comprises a first sidewall member 46, a pair of endwall members 45 (only one shown), and a floor member 47, respectively, joined one to the other, and a second sidewall member 42 adapted for movement to a plurality of positions with respect to said first sidewall member 46.
- the supply pressure of the air in conduit 60 substantially controls the velocity of the air being emitted from air slit 50.
- the air supply pressure in conduit 60 is maintained at from about (5 psig) 0.34 bar, up to about (40 psig) 2.76 bar, and more preferably from about (10 psig) 0.69 bar, up to about (25 psig) 1.72 bar.
- the quantity of air emitted from exit air slit 50 is controlled by the magnitude of the opening of slit 50.
- the quantity of air emitted from slit 50 controls the penetration of the liquid spray curtain with respect to the boundary air layer.
- the magnitude of slit 50 is chosen depending on the viscosity and quantity of the spray liquid, the distance from the spray exit to the moving surface, and the velocity of the moving surface.
- the magnitude of exit air slit 50 is maintained at a slit opening of from about (0.002 inch) 0.005 cm, up to about (1.010 inch) 0.025 cm, and more preferably from about (0.003 inch) 0.0076 cm, up to about (0.006 inch) 0.015 cm.
- second sidewall member 42 With respect to first sidewall member 46, depends upon air slit adjustment means 43, such as nut-and-bolt arrangement 43a passing through bracing member 43b.
- Bracing member 43b is connected to second sidewall member 42 by attachment means 43c, which, in this case, is a nut-and-bolt assembly.
- An air flow guide means 48 is located at the outermost end of first sidewall member 46.
- Guide means 48 is disposed with respect to the center line 37a of liquid discharge means 37 such that when said second sidewall member 42 is positioned with respect to air guide means 48, a high velocity, continuous air curtain is discharged from said exit slit which will contact said liquid streams at the previously described minimum contact angle.
- air flow guide means 48 is disposed parallel to the center line of said liquid discharge means 37.
- adjustment means 51 which is preferably a screw arrangement. As shown in Figure 2, adjustment means 51 is connected to bracing member 43b and air supply header 41, respectively.
- Means 44 is preferably in the form of screen means which modifies the inlet air so that it assumes a uniform span-wise pressure distribution and a uniform exit velocity.
- the liquid spray curtain which is emitted is capable of uniformly covering essentially the entirety of the moving surface on which it is sprayed.
- the liquid spray curtain is formed by discharging a plurality of liquid streams from discharge means 37 and, in this case, through liquid flow tubes 38 and 38', at low discharge velocity.
- the continuous air curtain is discharged from air slit 50, and is directed toward the discharging liquid streams emanating from discharge means 37.
- a high velocity, continuous, uniform liquid spray curtain (not shown) is formed, without impeding the liquid flow, but, contrarily, the liquid velocity, after the liquid exits from the orifices, is substantially increased, causing atomization of the liquid.
- the spray curtain exhibits a high boundary layer penetration level over a controlled, extensive particle size range without causing substantial streaking when sprayed onto a moving surface, and without exhibiting interfacing problems between the respective spray streams.
- the total amount of liquid being discharged from liquid discharge means 37 can be substantialy lower than for the same liquid, at the same total solids level, employing, for example, a hydraulic nozzle system.
- the use of a lower amount of liquid results to a large extent from the use of a larger number of individual discharge means 37, preferably including liquid flow tubes 38 and 38', having a relatively large total cross-sectional flow area per unit length of said header means 21 and 21', i.e., A X , and a lower solution velocity.
- the preferred A x of the discharge orifice 37' is from about (0.01 square inch per foot) 0.02 cm 2 /metre to about (0.09 square inch per foot) 0.18 cm 2 /metre, and more preferably from about (0.02 square inch per foot) 0.04 cm 2 /metre to about (0.06 square inch per foot) 0.12 cm 2 /metre.
- a critical feature of this invention is the minimum contact angle f5 at which a continuous, high velocity air curtain is directed with respect to the liquid being discharged at low velocity from discharge means 37.
- the use of the present invention provides that a continuous air curtain contacts the liquid at an angle which will impel the liquid at a high velocity and will form a continuous, uniform liquid spray curtain having a relatively high boundary layer penetration level over a controlled, extensive particle-size range.
- the minimum contact angle is preferably controlled, as in Figure 2, by air flow guide means 48 disposed in a plane substantially parallel to the center line 37a of discharge means 37.
- the air flow guide means in conjunction with movable sidewall means 42, adjust to cause the air to be discharged so as to produce the requisite minimum contact angles previously described.
- a continuous, uniform, low velocity liquid stream is emitted from discharge means 37 due, to the most part, to the maintenance of a positive static pressure head on said discharge means.
- the static head on discharge means 37 is, in turn, maintained by the positive static pressure within liquid reservoirs 33 and 33'. More specifically, by employing a liquid reservoir which extends below the entire extent of the inlet portions of discharge means 37, the reservoirs 33 and 33' are substantially filled with liquid under pressure, and all of the discharge means 37 will, in turn, be filled with liquid under pressure, which will result in the uniform, continuous discharge of said liquid from said discharge means.
- the positive pressure which is maintained in the liquid reservoir 33, 33' is a direct consequence of labyrinths 26 and 26' which internally meter the liquid flow and facilitate the liquid communication to discharge means 37.
- the longitudinal extent of the liquid spray curtain can be adjusted, depending on the width of the moving surface to be sprayed, by providing, such as by inserting within discharge means 37, or by substituting for liquid flow tubes 38 and 38' which are hollow in construction, means for plugging said liquid streams, at points beyond the width of the moving surface, so that the liquid 15 cannot pass therethrough.
- the moisture profile of a moving surface having a lower moisture content at its edges than at its central portion can be adjusted employing the present system.
- a means can be provided for measuring the moisture profile of the moving surface at a point prior to the subject linear nozzle system.
- the liquid flow rate to the innermost points in the respective headers is reduced, thereby producing a liquid spray curtain having a moisture profile in which the outer edges of the moving surface are moisturized to a much greater extent than the central portion thereof, and a moisture profile results.
- the spray liquid can comprise any liquid material which can be effectively discharged from discharge means 37 without causing substantial plugging thereof.
- the magnitude of the liquid materials which can be employed is far more substantial than those liquids which can be sprayed from hydraulic and sonic systems.
- the present method requires only a low exit velocity and the area of liquid flow is substantially greater than in the previously described prior art systems.
- various aqueous liquid solutions are employed as the liquid. Water, itself, can also be sprayed on a moving surface in order to moisturize the same, as described above.
- a liquid adhesive solution can be sprayed on a cellulosic papermaking web, and after being sprayed with the subject liquid spray curtain, the web can be adhered to a thermal drying cylinder and then uniformly creped to produce a soft, bulky cellulosic web product. Furthermore, this same liquid curtain can also be sprayed directly onto a moving surface crossing the thermal drying cylinder.
- Typical creping adhesives include various natural and synthetic materials which are well-known in the papermaking art. Exemplary materials include carboxymethyl cellulose, polyvinyl alcohol and animal glue.
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Abstract
Description
- This invention relates to a system for producing a continuous liquid spray curtain capable of uniformly covering essentially the entirety of a moving surface, without substantial streaking thereof.
- Prior art systems have been provided for spraying a liquid onto a moving surface. For example, a plurality of hydraulic nozzles can be employed for liquid spraying, the number of nozzles employed being determined by the width of the surface to be sprayed. However, hydraulic nozzles emit a spray in a circular or elliptical pattern. This causes nonuniform coverage of the moving surface because the respective sprays emanating from adjacent hydraulic nozzles are difficult to interface one with the other over the entire width of the moving surface. Thus, streaking results due to these respective oversprayed or undersprayed areas. Streaking is a particular problem in certain applications, such as, for example, spraying a creping adhesive onto a cellulosic web, or onto a thermal drying cylinder, since nonuniform adhesion of the web to the thermal drying cylinder results in a nonuniformly creped sheet having substandard physical properties. Furthermore, the dried, creped web will not wind evenly into a parent roll on the papermaking reel if creping is nonuniform. This will lead to substantial problems when the parent roll is converted to product.
- Another serious problem associated with certain nozzles, such as hydraulic nozzles, is plugging of the nozzle tips. Plugging terminates liquid flow, causing widespread streaking to occur due to the aforementioned nonuniform spray application. Hydraulic nozzles operate at a relatively high solution flow rate. Therefore, if an adhesive is the liquid material sprayed, a total solids level must be selected at a given liquid flow rate which will not provide too large an amount of adhesive to be sprayed onto the moving surface. This will cause a boardy sheet to be formed. Thus, a lower, overall total solids liquid must be employed at a higher total solution flow rate in order to supply the prescribed amount of solids add-on to the surface to be sprayed. This results in the use of much higher water consumption level, as well as a substantial increase in the thermal energy required for drying purposes.
- The exit velocity of the liquid in a hydraulic nozzle system determines the requisite degree of atomization of the liquid. In the case of a hydraulic nozzle, the liquid exit velocity is relatively high. The exit velocity is primarily a function of the liquid supply pressure. A high liquid supply pressure presents severe operating hazards to equipment and personnel.
- Another approach in spraying a liquid onto a moving surface is the use of sonic nozzles. These nozzles typically spray particles of a smaller, more uniform size particle distribution than those produced by hydraulic spraying. One of the major problems which can result from the use of a plurality of sonic nozzles for spraying onto a moving surface is that the finer the spray which is produced, the lower the momentum of the spray particles. This, in turn, reduces the effect of penetration by the spray particles of the boundary air layer between the nozzle and the moving surface, resulting in a significantly higher level of spray migration and a lower solids addition to the moving surface. Furthermore, the same coverage problems associated with hydraulic nozzles are present herein because of the circular spray patterns produced by each adjacent sonic nozzle. Finally, the sonic nozzles exhibit plugging problems similar to those described above for hydraulic nozzles.
- Other prior art systems have attempted to provide a plurality of sprays from a common source. U.S. Patent 1,888,791, for example, describes an apparatus which discharges liquids through jets. This specification describes a system for producing a liquid spray curtain for application to a moving surface and comprising a liquid supply means comprising at least one liquid supply header for discharging a plurality of liquid streams, said liquid supply header comprising a liquid supply chamber, a liquid reservoir communicating with a plurality of outlets, a flow restriction between the supply chamber and the reservoir and an air supply means having a header comprising an air supply chamber having a converging outlet for directing air at a high velocity to contact liquid discharged by the liquid discharge means as set out in the first part of claim 1. With this prior proposal the discharge liquid intersects air streams outside the discharge orifices at a substantially maximum angle with respect to the central axis of the liquid jets so that the air streams impede the progress of the liquid jet flow and create a back-pressure. Any change in the air velocity or impingement angle will change the back-pressure. For example, any increase in the back-pressure, such as caused by an increase in the air velocity, will result in a decrease in both the liquid velocity and in the amount of liquid sprayed. Thus, since the velocity and amount of liquid sprayed, respectively, will be changed by changes in the back-pressure, spray uniformity in both the lateral (coverage) and longitudinal (uniform rate) directions will be difficult to maintain. Therefore, higher relative liquid pressures and velocities than desired must be maintained in order for the system to function since small variations in either the air or liquid discharge velocity will result in substantial changes in the lateral and longitudinal spray pattern. This results in the aforementioned streaking, uniformity and coverage problems. Finally, the air stream emanates from individual sets of jets. Therefore, the air stream is discontinuous over the entire longitudinal extent of the apparatus. A discontinuous air stream will create a discontinuous spray flow pattern, resulting in streaking. and nonuniform coverage of the surface being sprayed.
- With respect to certain moving surfaces, such as cellulosic webs, and the like, a nonuniform moisture profile typically exists in which the edges of the webs are much drier than the central portion. Coverage of these webs with moisturizing liquids to a desired moisture level can be accomplished by the addition of water to increase the moisture level at the edges of the web. Some prior art systems, such as sonic nozzles, attempt to correct this problem by changing the flow rates of a plurality of individual sonic nozzles in a given system so as to alter the moisture profile of the web. Instead, the system provides a random, nonuniform, uncoordinated spray pattern.
- The above described problems associated with prior art systems have been overcome by use of the apparatus of the present invention, which is characterised in that the converging outlet is defined between first and second sidewall members to be in the form of a continuous air exit slit that spans a plurality of the liquid outlets to provide an air curtain contacting liquid discharged from said plurality of liquid outlets, in that an air-flow guide member is located at the outermost end of the first sidewall member and in that means are provided for adjusting the position of the second sidewall relative to the first sidewall to adjust the magnitude of the slit and the direction of discharge of the air curtain such that its minimum contact angle with the liquid streams from the outlets measured from the center line of the liquid discharge outlets is between -100 and +30°. As compared with the prior United States Specification No. 1888791 referred to. above, the outlet for air is in the form of a continuous air exit slit which spans a plurality of the liquid outlets, preferably all the liquid outlets, so as to provide an even spray across the whole width of the moving web or surface to be sprayed. In contrast thereto the prior United States Specification uses individual air outlet apertures for each liquid outlet. Additionally the present invention utilises an airflow guide member located at the outermost end of a fixed sidewall member defining the air outlet and operative to deflect the airflow generally along the direction of a discharge of liquid rather than across the flow as used in the prior construction for benefits as previously explained. In order to control accurately the amount and direction of discharge of the air forming the air curtain the position of the movable sidewall is adjustable carefully to tune the airflow to that required in the desired result in distributing the liquid.
- The liquid spray curtain is produced by discharging a plurality of streams of liquid to be sprayed from a discharge means at a relatively low discharge velocity. At the same time, a continuous, high velocity air curtain is also discharged which is directed toward the liquid streams and contacts at a minimum contact angle /3, measured from the center line of said liquid discharge means of from about -100 and preferably from about -5°, up to about +30°, and more preferably up to about +10°. When the high velocity air curtain contacts the low velocity liquid at the above prescribed minimum contact angle, the liquid velocity is substantially increased and the liquid is atomized, thereby forming a high velocity, continuous, uniform liquid spray curtain. The high velocity liquid spray curtain exhibits a relatively high boundary penetration level in a controlled, extensive particle range. Accordingly, essentially the entire moving surface is covered with the liquid spray in uniform manner, and without substantial interfacing or streaking problems, as previously described.
- Spraying of a relatively high total solids liquid can be accomplished when the invention is employed without the problems associated with the prior art. Thus, the total liquid flow rate can be decreased at a given total solids level. This will, in turn, decrease the total water consumption and the thermal drying costs associated with the prior art solution levels.
- The total amount of liquid sprayed on the moving surface using the apparatus of the present invention is preferably only up to about 50%, and more preferably up to about 25%, as compared to hydraulic nozzles at the same total solids level.
- the use of a higher total solids liquid results, to a great degree, from the subject liquid discharge means having a substantially higher total cross-sectional flow area per unit length (Ax) than that of a comparable hydraulic discharge means (Ah). The ratio of AX:A,, at a given total solids flow rate is generally at least about 30, and preferably at least about 60, and more preferably at least about 120.
- The liquid discharge velocity when using the present invention is relatively low and preferably is not greater than about (20 feet per second) 6 metres/sec, and more preferably not greater than about (5 feet per second) 1.5 metres/sec, and most preferably not more than about (2 feet per second) 0.6 metres/sec. This is in total contradistinction to the aforementioned prior art methods which employ substantially high liquid flow velocities, to overcome an impeding air flow and, in the case of the hydraulic and sonic nozzles, for overcoming the air boundary layer between the system and the surface.
- It is not only important for the liquid flow rate to be low, it is also important for the discharge velocity of the air curtain to be substantially higher than that of the discharge velocity of the liquid. The discharge velocity of the air curtain is preferably at least about (600 feet per second) 180 metres/sec., and more preferably at least about (1,000 feet per second) 300 metres/sec., and most preferably at least about (1,200 feet per second) 365 metres/sec. Furthermore, the respective liquid and air velocities are maintained so that substantial atomization of the liquid will result.
- Moving surfaces of differing widths can be effectively sprayed by employing the preferred apparatus of this invention. In the aforementioned prior art systems, accurate, controlled, uniform coverage, especially at the surface edges, is difficult to maintain since the spray pattern produced by these prior systems is discontinuous. The present system, on the other hand, can provide for readily adjusting the width of the continuous spray curtain, depending on the width of the moving surface to be sprayed. This can be done by closing off or opening, in a controlled manner, only the outer-most liquid sprays so that the width of the curtain will correspond to the width of the moving surface. Such an adjustment can be made to quite a narrow tolerance range since the liquid discharge outlets are in close proximity one to the other.
- In order substantially to eliminate prior art problems associated with variabilities in the respective flow rates as, for example, caused by disparities in the liquid or air supply pressure, certain modifications have been provided. Specifically, each liquid header system preferably includes labyrinth means which internally meters and longitudinally distributes the liquid flow, causing a constant span-wise pressure or static head to be maintained in a liquid reservoir which preferably extends across the entire longitudinal distance of the discharge means. The presence of this liquid reservoir ensures that a constant, static liquid head will be maintained at the discharge means and that the liquid spray curtain will therefore operate at steady-state conditions.
- Certain moving surfaces, such as cellulosic webs on a paper machine, have a substantially nonuniform moisture profile, i.e., the moisture level is substantially lower at the edges than at the center. The previously described conventional systems are not capable of effectively controlling the spray from both a quality and quantity standpoint so that the moisture profile of the web cannot be modified to the extent that it becomes uniform across the entire web surface. By varying the liquid flow supply at various points in the respective individual headers, an inverted moisture profile can be provided using the preferred system of the present invention in which more moisture is sprayed at the edges of the moving surface than in the interior portion thereof while, at the same time, maintaining the same total amount of liquid spray addition. Moisture profile measurement means can be provided for continuously monitoring the moisture profile of the web at a point upstream from the subject spray system. The flow rate can then be adjusted at various points in the individual liquid supply headers to compensate for these disparities.
- The invention will be further described, by way of example, with reference to the accompanying drawings, in which:
- Figure 1 is a sectional view of a liquid spray curtain system embodying the invention supported by a beam and including liquid and air supply means;
- Figure 2 is a detailed, enlarged sectional view of the system of Figure 1; and
- Figure 3 is a detailed, sectional view taken along line 3-3 of Figure 2.
- Referring now to Figure 1, a
system 10 for producing a liquid spray curtain is generally depicted therein attached to and supported by abeam 70 and includes a liquid supply means 20 and an air supply means 40. The liquid supply means, in general, comprises at least one liquid supply header, in this case denoted "21" and "21' ", having a plurality ofliquid supply lines 23 attached, at one end, thereto. Theliquid supply lines 23 from each supply header are, at the other end, connected to aliquid supply conduit 22 which transports the liquid from a liquid storage means (not shown) employing a pump or other like means to provide the driving force for transporting the liquid. - Air supply means 40 comprises an
air supply header 41 to which a plurality ofair supply lines 61 are connected. At the other end, theair supply lines 61 are connected toair supply conduit 60 which transports air, under pressure, employing a compressor or like means to provide the driving force. - As set forth in Figures 2 and 3,
liquid supply headers 21 and 21', which discharge a plurality of liquid streams from discharge means 37 at a relatively low velocity, include inlet supply means 24 and 24' which supply the appropriate liquid to supplychambers 25 and 25'. Preferably,liquid supply headers 21 and 21' are disposed at right angles one with respect to the other.Liquid supply chambers 25 and 25' have located therewithin labyrinth means 26 and 26' for internally metering and longitudinally distributing the liquid flow. Specifically, labyrinth means 26 and 26' comprise, preferably, first compartments 27 and 27', in which the liquid is initially collected, the liquid being restrained from flowing freely by first barrier means 29 and 29'.Liquid supply orifices 30 and 30' are also provided which permit a reduced flow of liquid to thesecond compartment 28 and 28', where the liquid is again collected. The flow is restricted in this case by second barrier means 31 and 31'. The liquid then moves to a liquid reservoir means 33 and 33' from labyrinth means 26 and 26', respectively, throughliquid supply slots 32 and 32' in the respective second barrier means 31 and 31'. Both the liquid reservoir means and the liquid supply slots, respectively, extend along the entire longitudinal distance of theliquid supply headers 21 and 21'. When the reservoir is filled with liquid, it remains in liquid communication with discharge means 37, having an exit orifice 37', which is adapted for liquid communication with said reservoir, to provide a continuous, uniform flow rate of liquid. The liquid moves to discharge means 37 from reservoir 33', throughexit passageway 15.Liquid flow tubes 38 and 38' (in phantom) are preferably disposed within discharge means 37 for further controlling the discharge of the liquid. The discharge means 37 preferably __has anarrowed end section 36 which provides, if necessary, means for readily maintainingliquid flow tubes 38 and 38' in proper position and alignment. As depicted in Figures 2 and 3,liquid flow tubes 38 and 38' are preferably in individual and alternative communication with the liquid in a pair ofliquid supply headers 21 and 21', respectively. This permits a more controlled liquid flow and allows the system to continue in operation even if one of the headers requires maintenance. - As depicted in Figure 2, air supply means 40 comprises an
air supply header 41, which discharges a continuous, high velocity air curtain, from exit air slit-50, for contact with said liquid streams, as hereinafter provided. Theair supply header 41 includes means denoted "43" and "51" for adjusting the respective magnitudes of the exit air slit 50 and the air contact angle /3, as hereinafter described. Exit air slit 50 is preferably continuous along the entire longitudinal extent of thesystem 10. - The air from
air supply line 61 enters centralair supply chamber 49 through an inlet means 44.Air supply chamber 49 is formed within the confines of saidair supply header 41 and converges at its outermost end to form a continuous exit air slit 50. Theheader 41 comprises afirst sidewall member 46, a pair of endwall members 45 (only one shown), and afloor member 47, respectively, joined one to the other, and asecond sidewall member 42 adapted for movement to a plurality of positions with respect to saidfirst sidewall member 46. By properly positioning movablesecond sidewall member 42 with respect to first sidewall member, such as position "42a" (in phantom), exit slit 50 can be adjusted to said plurality of set magnitudes. - The supply pressure of the air in
conduit 60 substantially controls the velocity of the air being emitted from air slit 50. Preferably, the air supply pressure inconduit 60 is maintained at from about (5 psig) 0.34 bar, up to about (40 psig) 2.76 bar, and more preferably from about (10 psig) 0.69 bar, up to about (25 psig) 1.72 bar. - The quantity of air emitted from exit air slit 50 is controlled by the magnitude of the opening of
slit 50. The quantity of air emitted fromslit 50, to a great extent, controls the penetration of the liquid spray curtain with respect to the boundary air layer. The magnitude ofslit 50 is chosen depending on the viscosity and quantity of the spray liquid, the distance from the spray exit to the moving surface, and the velocity of the moving surface. Preferably, the magnitude of exit air slit 50 is maintained at a slit opening of from about (0.002 inch) 0.005 cm, up to about (1.010 inch) 0.025 cm, and more preferably from about (0.003 inch) 0.0076 cm, up to about (0.006 inch) 0.015 cm. - The relative position of
second sidewall member 42 with respect tofirst sidewall member 46, depends upon air slit adjustment means 43, such as nut-and-bolt arrangement 43a passing through bracingmember 43b. Bracingmember 43b is connected tosecond sidewall member 42 by attachment means 43c, which, in this case, is a nut-and-bolt assembly. - An air flow guide means 48 is located at the outermost end of
first sidewall member 46. Guide means 48 is disposed with respect to thecenter line 37a of liquid discharge means 37 such that when saidsecond sidewall member 42 is positioned with respect to air guide means 48, a high velocity, continuous air curtain is discharged from said exit slit which will contact said liquid streams at the previously described minimum contact angle. Preferably, air flow guide means 48 is disposed parallel to the center line of said liquid discharge means 37. The movement ofsidewall member 42 to various positions with respect to guide means 48 within the limits of angle 0, as previously described herein, is preferably provided employing adjustment means 51, which is preferably a screw arrangement. As shown in Figure 2, adjustment means 51 is connected to bracingmember 43b andair supply header 41, respectively. Thus, by moving adjustment means 51 to position "51'" (in phantom),sidewall 42 can also be moved to position "42'" (in phantom) with respect to guide means 48, thereby adjusting the magnitude of angle /i. - In order to reduce the variations in the inlet air flow, a means "44" for creating a pressure drop and thereby reducing the pressure peaks in the inlet air flow can be provided.
Means 44 is preferably in the form of screen means which modifies the inlet air so that it assumes a uniform span-wise pressure distribution and a uniform exit velocity. - In use, the liquid spray curtain which is emitted is capable of uniformly covering essentially the entirety of the moving surface on which it is sprayed. The liquid spray curtain is formed by discharging a plurality of liquid streams from discharge means 37 and, in this case, through
liquid flow tubes 38 and 38', at low discharge velocity. At the same time, the continuous air curtain is discharged from air slit 50, and is directed toward the discharging liquid streams emanating from discharge means 37. The air and liquid, respectively, intersect at the minimum contact angle described above. When the continuous, high velocity air curtain contacts the low velocity liquid streams, a high velocity, continuous, uniform liquid spray curtain (not shown) is formed, without impeding the liquid flow, but, contrarily, the liquid velocity, after the liquid exits from the orifices, is substantially increased, causing atomization of the liquid. The spray curtain exhibits a high boundary layer penetration level over a controlled, extensive particle size range without causing substantial streaking when sprayed onto a moving surface, and without exhibiting interfacing problems between the respective spray streams. - When, as described in the preceding discussion, an aqueous solution of a processing liquid, such as a creping adhesive, and the like, is employed, the total amount of liquid being discharged from liquid discharge means 37 can be substantialy lower than for the same liquid, at the same total solids level, employing, for example, a hydraulic nozzle system. The use of a lower amount of liquid results to a large extent from the use of a larger number of individual discharge means 37, preferably including
liquid flow tubes 38 and 38', having a relatively large total cross-sectional flow area per unit length of said header means 21 and 21', i.e., AX, and a lower solution velocity. Thus, if a 1% solution is employed, for example, the preferred Ax of the discharge orifice 37' is from about (0.01 square inch per foot) 0.02 cm2/metre to about (0.09 square inch per foot) 0.18 cm2/metre, and more preferably from about (0.02 square inch per foot) 0.04 cm2/metre to about (0.06 square inch per foot) 0.12 cm2/metre. - At the same time, a high velocity air stream is supplied from
air supply header 41. The velocity of the air exiting from the air slit 50 must be significantly higher than the velocity of the liquid exiting from discharge means 37. The magnitude of this difference has been previously described. A critical feature of this invention is the minimum contact angle f5 at which a continuous, high velocity air curtain is directed with respect to the liquid being discharged at low velocity from discharge means 37. Instead of impeding the flow of the discharging liquid, the use of the present invention provides that a continuous air curtain contacts the liquid at an angle which will impel the liquid at a high velocity and will form a continuous, uniform liquid spray curtain having a relatively high boundary layer penetration level over a controlled, extensive particle-size range. The minimum contact angle is preferably controlled, as in Figure 2, by air flow guide means 48 disposed in a plane substantially parallel to thecenter line 37a of discharge means 37. The air flow guide means in conjunction with movable sidewall means 42, adjust to cause the air to be discharged so as to produce the requisite minimum contact angles previously described. - A continuous, uniform, low velocity liquid stream is emitted from discharge means 37 due, to the most part, to the maintenance of a positive static pressure head on said discharge means. The static head on discharge means 37 is, in turn, maintained by the positive static pressure within
liquid reservoirs 33 and 33'. More specifically, by employing a liquid reservoir which extends below the entire extent of the inlet portions of discharge means 37, thereservoirs 33 and 33' are substantially filled with liquid under pressure, and all of the discharge means 37 will, in turn, be filled with liquid under pressure, which will result in the uniform, continuous discharge of said liquid from said discharge means. As previously described, the positive pressure which is maintained in theliquid reservoir 33, 33' is a direct consequence oflabyrinths 26 and 26' which internally meter the liquid flow and facilitate the liquid communication to discharge means 37. - The longitudinal extent of the liquid spray curtain can be adjusted, depending on the width of the moving surface to be sprayed, by providing, such as by inserting within discharge means 37, or by substituting for
liquid flow tubes 38 and 38' which are hollow in construction, means for plugging said liquid streams, at points beyond the width of the moving surface, so that the liquid 15 cannot pass therethrough. - The moisture profile of a moving surface having a lower moisture content at its edges than at its central portion can be adjusted employing the present system. Specifically, a means can be provided for measuring the moisture profile of the moving surface at a point prior to the subject linear nozzle system. By increasing the liquid flow to the outermost points in the subject system, i.e., to the outermost points in the liquid header, the liquid flow rate to the innermost points in the respective headers is reduced, thereby producing a liquid spray curtain having a moisture profile in which the outer edges of the moving surface are moisturized to a much greater extent than the central portion thereof, and a moisture profile results.
- The spray liquid can comprise any liquid material which can be effectively discharged from discharge means 37 without causing substantial plugging thereof. The magnitude of the liquid materials which can be employed is far more substantial than those liquids which can be sprayed from hydraulic and sonic systems. The present method requires only a low exit velocity and the area of liquid flow is substantially greater than in the previously described prior art systems. Typically, various aqueous liquid solutions are employed as the liquid. Water, itself, can also be sprayed on a moving surface in order to moisturize the same, as described above.
- In a preferred method, a liquid adhesive solution can be sprayed on a cellulosic papermaking web, and after being sprayed with the subject liquid spray curtain, the web can be adhered to a thermal drying cylinder and then uniformly creped to produce a soft, bulky cellulosic web product. Furthermore, this same liquid curtain can also be sprayed directly onto a moving surface crossing the thermal drying cylinder. Typical creping adhesives include various natural and synthetic materials which are well-known in the papermaking art. Exemplary materials include carboxymethyl cellulose, polyvinyl alcohol and animal glue.
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT81302126T ATE10261T1 (en) | 1980-05-19 | 1981-05-13 | SYSTEM FOR GENERATION OF A CURTAIN-SHAPED LIQUID SPRAY FOR APPLICATION ON RUNNING WEBS. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15102380A | 1980-05-19 | 1980-05-19 | |
US151023 | 1980-05-19 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0040927A1 EP0040927A1 (en) | 1981-12-02 |
EP0040927B1 true EP0040927B1 (en) | 1984-11-14 |
Family
ID=22537014
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP81302126A Expired EP0040927B1 (en) | 1980-05-19 | 1981-05-13 | System for producing a liquid spray curtain for application to a moving web |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0040927B1 (en) |
JP (1) | JPS57500636A (en) |
AT (1) | ATE10261T1 (en) |
CA (1) | CA1174530A (en) |
DE (1) | DE3167158D1 (en) |
WO (1) | WO1981003372A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5115972A (en) * | 1991-02-06 | 1992-05-26 | Minnesota Mining And Manufacturing Company | Spray die for producing spray fans |
GB9519692D0 (en) * | 1995-09-27 | 1995-11-29 | Quillin Helen | Atomising nozzle |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US958999A (en) * | 1909-12-16 | 1910-05-24 | Oscar Fordice | Hydrocarbon-burner. |
US1888791A (en) * | 1930-09-27 | 1932-11-22 | Harry C Cole | Spraying method and machine |
JPS522408B2 (en) * | 1971-09-10 | 1977-01-21 | ||
US4072772A (en) * | 1973-08-09 | 1978-02-07 | Ppg Industries, Inc. | Linear curtain spray applicator |
JPS516362A (en) * | 1974-07-05 | 1976-01-19 | Hitachi Plant Eng & Constr Co | Gesuiodeitono kyokyusochi |
-
1981
- 1981-05-11 JP JP56501813A patent/JPS57500636A/ja active Pending
- 1981-05-11 WO PCT/US1981/000664 patent/WO1981003372A1/en unknown
- 1981-05-12 CA CA000377396A patent/CA1174530A/en not_active Expired
- 1981-05-13 DE DE8181302126T patent/DE3167158D1/en not_active Expired
- 1981-05-13 EP EP81302126A patent/EP0040927B1/en not_active Expired
- 1981-05-13 AT AT81302126T patent/ATE10261T1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
WO1981003372A1 (en) | 1981-11-26 |
CA1174530A (en) | 1984-09-18 |
EP0040927A1 (en) | 1981-12-02 |
JPS57500636A (en) | 1982-04-15 |
DE3167158D1 (en) | 1984-12-20 |
ATE10261T1 (en) | 1984-11-15 |
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