EP0036252B1 - Textile printing process - Google Patents
Textile printing process Download PDFInfo
- Publication number
- EP0036252B1 EP0036252B1 EP19810300721 EP81300721A EP0036252B1 EP 0036252 B1 EP0036252 B1 EP 0036252B1 EP 19810300721 EP19810300721 EP 19810300721 EP 81300721 A EP81300721 A EP 81300721A EP 0036252 B1 EP0036252 B1 EP 0036252B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- disperse
- dyestuffs
- dyestuff
- alkali
- carboxylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/12—Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/15—Locally discharging the dyes
- D06P5/151—Locally discharging the dyes with acids or bases
Definitions
- This invention relates to an improved process for the resist or discharge printing of synthetic textile materials.
- Resist printing is a method of textile printing in which an undyed textile material is first printed with a substance (the resist) which prevents the uptake or fixation of a subsequently applied dyestuff, so that there is obtained a white pattern on a coloured ground, or a pattern of contrasting colour to the ground by incorporating suitable dyestuffs or colour-producing substances in the resist print paste.
- a substance the resist
- Discharge printing is a method of textile printing in which dyed textile material is printed with a chemical composition (the discharge) that destroys the dyestuff locally to give a white pattern, or in which a second dyestuff, applied simultaneously with the discharge, produces a pattern of contrasting colour.
- GB-A-1543724 describes and claims a process for producing discharge printing effects in a coloured ground shade on a synthetic textile material, which comprises applying to that area of the material where the ground shade and the discharge effect are wanted one or more disperse dyes which contain at least one carboxylic ester group but are free from carboxylic acid and sulphonic acid groups, and in a separate stage applying to the material where the discharge effect is wanted a printing paste which is alkaline or becomes alkaline on heating or steaming and which does not contain any reducing agent, thereafter heating or steaming the material and thereafter washing the material.
- stages 1 and 3 can be reversed, so that the dyestuff is applied to the textile material before the alkaline print paste.
- stage 5 in which the textile material is subjected to the action of heat or steam, the disperse dyestuff in contact with the alkali is converted into a water-soluble form, whilst the disperse dyestuff which is not in contact with the alkali is fixed on the textile material.
- the water-soluble form of the dyestuff is then removed from the textile material by the washing treatment of stage 6.
- stage 2 it would be desirable if, in the above process, the first drying operation (stage 2) could be eliminated so that stage 1 is followed immediately by stage 3.
- This "wet-on-wet" process would have the advantages that the process has one stage less, with consequent saving in drying plant occupation time, and also the saving in the energy used to effect drying.
- GB-A-1481741 describes the production of multicolour effects using alkali sensitive disperse dyes of a different type to GB-A-1543724 applied in conjunction with alkaline agents.
- wet-on-wet resist or discharge prints having sharp definition between the different coloured areas of the print can be obtained if the alkali used in the print paste is sodium or potassium silicate and if specific types of alkali dischargeable dyestuffs are applied.
- a process for producing resist or discharge printing effects on a synthetic textile material which comprises applying to the textile material, in either order (i) an alkaline printing paste which may contain one or more disperse dyestuffs free from sulphonic acid, carboxylic acid and carboxylic acid ester groups, the said dyestuffs being unaffected by alkali at the concentration present, and (ii) a printing paste or passing liquor containing at least one alkali dischargeable disperse dyestuff free from sulphonic acid and carboxylic acid groups, and free from carboxylic acid ester groups which if hydrolysed would leave free carboxylic acid groups attached to the dyestuff molecule, thereafter heating or steaming the material and thereafter washing the material characterised by the presence of sodium or potassium silicate in (i), a carboxylic acid in (ii), and without drying between the application of (i) and (ii).
- alkali-dischargeable dyestuffs which are used in the process according to the present invention may be broadly classified as follows:
- miscellaneous dyestuffs C.I. Disperse Violet 88, C.I. Disperse Yellow 180, C.I. Disperse Violet 48, C.I. Disperse Blue 92, C.I. Disperse Yellow 93, C.I. Disperse Yellow 201, C.I. Disperse Yellow 88, C.I. Disperse Yellow 210, C.I. Disperse Red 203 and C.I. Disperse Yellow 202.
- dyestuffs which may be used in the present process are those which discharge only partially (i.e. do not give a white discharge) and which do not leave a weak enough stain to allow all shades of illumination to be used, but which do show an even residual shade that allows the use of such dyestuffs for limited illuminated shades and which may be used for shading purposes.
- miscellaneous dyestuffs of formulae Red which is disclosed in GB-A-859899, and Red which is disclosed in GB-A-1027968, together with C.I. Disperse Red 72, C.I. Disperse Blue 139, C.I. Disperse Orange 55, C.I. Disperse Red 329 and C.I. Disperse Violet 40.
- Any disperse dyestuff which undergoes chromophore destruction in the presence of alkali to an extent such as to make it suitable for a ground shade in discharge printing may be used in the present process, provided that it is free from -COOH, -S0 3 H and -COOR- groups as defined in claim 1.
- the sodium silicate which is used in the above process may be any of those grades of sodium silicate which are commercially available and is preferably a sodium silicate in which the molecular ratio of SiO 2 to Na 2 0 is from 1.65:1.0 to 4.0:1.0.
- the potassium silicate which is used preferably has a molecular ratio of Si0 2 to K 2 0 of from 2.0:1 to 4.0:1.
- the amount of sodium or potassium silicate which is used in the printing paste (I) must provide sufficient alkali to discharge the disperse dyestuff in the padding liquor or printing paste (ii), and may be from 50 to 300 parts by weight per 1000 parts by weight of printing paste.
- a sodium or potassium silicate having a high molecular ratio of SiO 2 to Na 2 0 or K 2 0 can be replaced in the printing paste by a smaller quantity of sodium or potassium silicate having a lower molecular ratio of Si0 2 to Na 2 0 or K 2 0, without affecting the result.
- the printing paste containing the sodium or potassium silicate may also contain a humectant such as ethylene glycol urea or, preferably, glycerol, a dye solvent such as polyethylene glycol, for example, a polyethylene glycol having a molecular weight in the region of 300, and a thickening agent.
- a humectant such as ethylene glycol urea or, preferably, glycerol
- a dye solvent such as polyethylene glycol, for example, a polyethylene glycol having a molecular weight in the region of 300
- a thickening agent e.glycerol
- suitable thickeners are starch derivatives such as starch ethers, carob-seed gum ethers, modified carboxymethylcelluloses and combinations of these, optionally in admixture with water-in-oil or oil-in-water emulsion.
- the padding liquor or print paste used to apply the alkali-dischargeable disperse dyestuff will also contain a carboxylic acid, for example, citric acid, to prevent premature interaction of the dyestuff with the alkaline sodium or potassium silicate, and may contain a thickener such as one of those thickeners already mentioned above.
- a carboxylic acid for example, citric acid
- a thickener such as one of those thickeners already mentioned above.
- adjuvants which are conventionally employed in the application of disperse dyestuffs to synthetic textile materials from such media, for example carriers, fixation assistants, level dyeing assistants, dispersing agents and antifoam agents.
- the heat treatment to which the textile material is subjected after the application of the print paste containing the sodium or potassium silicate and the print paste or padding liquor containing the disperse dyestuff can comprise a heat treatment for a short period at temperatures from 150° to 220°C. It is, however, preferred to subject the textile material to a steaming treatment, for example, saturated steam at 100°C for a few minutes followed by a dry heat treatment at 160° to 220°C or superheated steam at 150° to 200°C, or the use of saturated steam under pressure at 115° to 150°C.
- the synthetic textile material used in the process of the invention can be in the form of nonwoven fabric, felt, woven or knitted goods, or carpets.
- synthetic textile materials there may be mentioned secondary cellulose acetate and cellulose triacetate, polypropylene, acrylic, polyamide, and preferably aromatic polyester textile material.
- the alkali-dischargeable disperse dyestuff can be used together with a reactive dye whose reactive groups, such as sulphato- ethylsulphone groups, form a dye-fibre bond with the hydroxyl groups of the cellulose textile material which is hydrolysed under the alkaline conditions in those areas where the alkaline print paste is applied, or a reactive dyestuff containing one or more phosphonic acid groups which does not fix on cellulose in the presence of alkali.
- a reactive dye whose reactive groups, such as sulphato- ethylsulphone groups, form a dye-fibre bond with the hydroxyl groups of the cellulose textile material which is hydrolysed under the alkaline conditions in those areas where the alkaline print paste is applied, or a reactive dyestuff containing one or more phosphonic acid groups which does not fix on cellulose in the presence of alkali.
- the disperse. dyestuff or dyestuffs which are optionally used in the alkaline printing paste containing sodium or potassium silicate can be any of the disperse dyestuffs free from -S0 3 H, --COOH and ⁇ COOR groups (as defined in claim 1) and not adversely affected by alkali which are conventionally employed in colouring synthetic textile materials. Examples of such dyestuffs are given in, for example, the Third Edition of the Colour Index which was published in 1971.
- a resist print paste comprising: is printed on to a woven polyethylene terephthalate textile material, and without drying the textile material is then coated over all, including that part which has already been printed with the above resist paste, with the following print paste comprising:
- the textile material is then dried on drying cylinders for 2 minutes at approximately 95°C, high temperature steamed at 170°C, for 8 minutes, washed off using the six-stage washing sequence described above and finally dried.
- the resulting blue on white pattern has excellent definition.
- sodium silicate used in the above example is replaced by the same amount of a sodium silicate in which the molecular ratio of Si0 2 to Na 2 0 is 1.65:1.0 a similar result is obtained; the amount of this latter sodium silicate can also be reduced to 100 parts without adverse effect on the sharpness of the resulting print.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Coloring (AREA)
Description
- This invention relates to an improved process for the resist or discharge printing of synthetic textile materials.
- Resist printing is a method of textile printing in which an undyed textile material is first printed with a substance (the resist) which prevents the uptake or fixation of a subsequently applied dyestuff, so that there is obtained a white pattern on a coloured ground, or a pattern of contrasting colour to the ground by incorporating suitable dyestuffs or colour-producing substances in the resist print paste.
- Discharge printing is a method of textile printing in which dyed textile material is printed with a chemical composition (the discharge) that destroys the dyestuff locally to give a white pattern, or in which a second dyestuff, applied simultaneously with the discharge, produces a pattern of contrasting colour.
- GB-A-1543724 describes and claims a process for producing discharge printing effects in a coloured ground shade on a synthetic textile material, which comprises applying to that area of the material where the ground shade and the discharge effect are wanted one or more disperse dyes which contain at least one carboxylic ester group but are free from carboxylic acid and sulphonic acid groups, and in a separate stage applying to the material where the discharge effect is wanted a printing paste which is alkaline or becomes alkaline on heating or steaming and which does not contain any reducing agent, thereafter heating or steaming the material and thereafter washing the material.
- The above process is typically carried out in the following 7 stages in which the textile material is:-
- 1. Printed with an alkaline print paste.
- 2. Dried.
- 3. Padded with the disperse dyestuff.
- 4. Dried.
- 5. Heat treated or steamed.
- 6. Washed.
- 7. Dried.
- Alternatively, stages 1 and 3 can be reversed, so that the dyestuff is applied to the textile material before the alkaline print paste.
- During stage 5, in which the textile material is subjected to the action of heat or steam, the disperse dyestuff in contact with the alkali is converted into a water-soluble form, whilst the disperse dyestuff which is not in contact with the alkali is fixed on the textile material. The water-soluble form of the dyestuff is then removed from the textile material by the washing treatment of stage 6.
- It would be desirable if, in the above process, the first drying operation (stage 2) could be eliminated so that stage 1 is followed immediately by stage 3. This "wet-on-wet" process would have the advantages that the process has one stage less, with consequent saving in drying plant occupation time, and also the saving in the energy used to effect drying.
- However, using printing pastes containing the alkaline agents which are normally employed, i.e. sodium hydroxide, sodium carbonate, sodium bicarbonate or potassium carbonate, it is found that the "wet-on-wet" technique gives prints having poor definition, because the alkali bleeds out of the print paste during the subsequent drying and fixation stages to give an unsightly dull white halo at the boundary between the originally applied alkaline resist and the subsequently applied dyestuff. This effect is known as "haloing", and prints which exhibit it are not commercially acceptable.
- GB-A-1481741 describes the production of multicolour effects using alkali sensitive disperse dyes of a different type to GB-A-1543724 applied in conjunction with alkaline agents.
- It has now been found that wet-on-wet resist or discharge prints having sharp definition between the different coloured areas of the print can be obtained if the alkali used in the print paste is sodium or potassium silicate and if specific types of alkali dischargeable dyestuffs are applied.
- According to the present invention there is provided a process for producing resist or discharge printing effects on a synthetic textile material which comprises applying to the textile material, in either order (i) an alkaline printing paste which may contain one or more disperse dyestuffs free from sulphonic acid, carboxylic acid and carboxylic acid ester groups, the said dyestuffs being unaffected by alkali at the concentration present, and (ii) a printing paste or passing liquor containing at least one alkali dischargeable disperse dyestuff free from sulphonic acid and carboxylic acid groups, and free from carboxylic acid ester groups which if hydrolysed would leave free carboxylic acid groups attached to the dyestuff molecule, thereafter heating or steaming the material and thereafter washing the material characterised by the presence of sodium or potassium silicate in (i), a carboxylic acid in (ii), and without drying between the application of (i) and (ii).
- The alkali-dischargeable dyestuffs which are used in the process according to the present invention may be broadly classified as follows:
- A. Dyestuffs which contain one or more lactone rings which open in the presence of alkali with formation of the water-soluble alkali metal salts of the corresponding hydroxy carboxylic acid. Opening of the lactone ring may be accompanied by destruction of the chromophoric system of the dyestuff.
- Examples of this class are the dyestuff of the formula:
- Also in this general class are the dyestuffs of the formulae:
- These unsymmetrically substituted compounds having the above-disclosed formulae may be obtained by reaction of equimolar quantities of hydroquinone and a compound of formula:
- There may also be used in the process of the present invention the dyestuff of formula:
- Other dyestuffs in class A which may be used in the present process are those which contain the coumarin ring system.
- Examples of this class are the dyestuff of the formula:
- B. Methine dyestuffs containing at least one
- C. Azo dyestuffs derived from anilines having at least two electron-withdrawing groups ortho and/or para to the amino group as diazo components and para-coupling amine coupling components, for example
- D. Dyestuffs containing groups which are capable of water-soluble salt formation in the presence of strong alkali, including azopyridone dyestuffs and dyestuffs containing phenolic hydroxyl groups or primary or secondary sulphonamide groups, for example:
- the dyestuff of formula:
- the dyestuff of formula:
- the dyestuff of formula:
- the anthraquinone dyestuff of formula:
- the dyestuff of formula:
- E. Dyestuffs derived from 2-aminothiophenes as diazo components and para-coupling amines as coupling components, the thiophene nucleus being substituted by at least two electron-withdrawing groups, for example:
- F. Azo dyestuffs derived from 2-amino-5-nitrothiazole as diazo component and a para-coupling amine as coupling component, for example the dyestuffs of formulae:
- the dyestuff offormula:
- the dyestuff offormula:
- Also usable in the process and having excellent alkaline discharge properties are the miscellaneous dyestuffs C.I. Disperse Violet 88, C.I. Disperse Yellow 180, C.I. Disperse Violet 48, C.I. Disperse Blue 92, C.I. Disperse Yellow 93, C.I. Disperse Yellow 201, C.I. Disperse Yellow 88, C.I. Disperse Yellow 210, C.I. Disperse Red 203 and C.I. Disperse Yellow 202.
- Other dyestuffs which may be used in the present process are those which discharge only partially (i.e. do not give a white discharge) and which do not leave a weak enough stain to allow all shades of illumination to be used, but which do show an even residual shade that allows the use of such dyestuffs for limited illuminated shades and which may be used for shading purposes.
- Examples of such dyestuffs are (with reference to the previously defined classes):
- In Class A:
- In Class C:
- The dyestuff of formula:
- The dyestuff of formula:
- The dyestuff of formula:
- The dyestuff of formula:
- and the dyestuff of formula:
- The dyestuff of formula:
- In Class D:
- The dyestuff of formula:
- the dyestuff of formula:
- the dyestuff of formula:
- the dyestuff of formula:
- and the dyestuff of formula:
- The dyestuff of formula:
- Also included in the group of partially dischargeable dyestuffs are the miscellaneous dyestuffs of formulae:
- Any disperse dyestuff which undergoes chromophore destruction in the presence of alkali to an extent such as to make it suitable for a ground shade in discharge printing may be used in the present process, provided that it is free from -COOH, -S03H and -COOR- groups as defined in claim 1.
- The sodium silicate which is used in the above process may be any of those grades of sodium silicate which are commercially available and is preferably a sodium silicate in which the molecular ratio of SiO2 to Na20 is from 1.65:1.0 to 4.0:1.0. The potassium silicate which is used preferably has a molecular ratio of Si02 to K20 of from 2.0:1 to 4.0:1.
- The amount of sodium or potassium silicate which is used in the printing paste (I) must provide sufficient alkali to discharge the disperse dyestuff in the padding liquor or printing paste (ii), and may be from 50 to 300 parts by weight per 1000 parts by weight of printing paste.
- It is found that a sodium or potassium silicate having a high molecular ratio of SiO2 to Na20 or K20 can be replaced in the printing paste by a smaller quantity of sodium or potassium silicate having a lower molecular ratio of Si02 to Na20 or K20, without affecting the result.
- The printing paste containing the sodium or potassium silicate may also contain a humectant such as ethylene glycol urea or, preferably, glycerol, a dye solvent such as polyethylene glycol, for example, a polyethylene glycol having a molecular weight in the region of 300, and a thickening agent. The latter must be stable to the other ingredients of the paste, and examples of suitable thickeners are starch derivatives such as starch ethers, carob-seed gum ethers, modified carboxymethylcelluloses and combinations of these, optionally in admixture with water-in-oil or oil-in-water emulsion.
- The padding liquor or print paste used to apply the alkali-dischargeable disperse dyestuff will also contain a carboxylic acid, for example, citric acid, to prevent premature interaction of the dyestuff with the alkaline sodium or potassium silicate, and may contain a thickener such as one of those thickeners already mentioned above. There may also be present any of those adjuvants which are conventionally employed in the application of disperse dyestuffs to synthetic textile materials from such media, for example carriers, fixation assistants, level dyeing assistants, dispersing agents and antifoam agents.
- The heat treatment to which the textile material is subjected after the application of the print paste containing the sodium or potassium silicate and the print paste or padding liquor containing the disperse dyestuff can comprise a heat treatment for a short period at temperatures from 150° to 220°C. It is, however, preferred to subject the textile material to a steaming treatment, for example, saturated steam at 100°C for a few minutes followed by a dry heat treatment at 160° to 220°C or superheated steam at 150° to 200°C, or the use of saturated steam under pressure at 115° to 150°C.
- The final washing stage of the process is conveniently carried out in the following sequence:-
- (i) Cold water rinse.
- (ii) Treatment in an aqueous alkaline bath at the pH above 8.0 and at a temperature from 50° to 85°C.
- (iii) Rinse in water at 60°C.
- (iv) Treatment in an aqueous bath containing 0.2% of sodium hydroxide and 0.2% of sodium hydrosulphite at 60°C.
- (v) Treatment in an aqueous solution containing 0.2% of a non-ionic detergent at 60°C.
- (vi) Cold water rinse, after which the. textile material is dried.
- The synthetic textile material used in the process of the invention can be in the form of nonwoven fabric, felt, woven or knitted goods, or carpets. As examples of synthetic textile materials there may be mentioned secondary cellulose acetate and cellulose triacetate, polypropylene, acrylic, polyamide, and preferably aromatic polyester textile material. If desired, the synthetic textile material can be in the form of a blend or union with a cellulose textile material, for example a polyethylene= terephthalate/cotton blend or union. In the case of such blends or unions the alkali-dischargeable disperse dyestuff can be used together with a reactive dye whose reactive groups, such as sulphato- ethylsulphone groups, form a dye-fibre bond with the hydroxyl groups of the cellulose textile material which is hydrolysed under the alkaline conditions in those areas where the alkaline print paste is applied, or a reactive dyestuff containing one or more phosphonic acid groups which does not fix on cellulose in the presence of alkali.
- The disperse. dyestuff or dyestuffs which are optionally used in the alkaline printing paste containing sodium or potassium silicate can be any of the disperse dyestuffs free from -S03H, --COOH and ―COOR groups (as defined in claim 1) and not adversely affected by alkali which are conventionally employed in colouring synthetic textile materials. Examples of such dyestuffs are given in, for example, the Third Edition of the Colour Index which was published in 1971.
- The invention is illustrated by the following Examples in which parts and percentages are by weight.
-
- Dyestuff of the formula:
- The textile material is then dried on drying cylinders for 2 minutes at approximately 95°C, high temperature steamed at 170°C, for 8 minutes, washed off using the six-stage washing sequence described above and finally dried.
- The resulting blue on white pattern has excellent definition.
- If the above procedure is repeated using sodium carbonate, sodium hydroxide or potassium carbonate in place of sodium silicate the resulting prints have poor definition, bleeding-out of the alkali producing an unacceptable dull white halo round the edge of the blue areas of the print.
- If the sodium silicate used in the above example is replaced by the same amount of a sodium silicate in which the molecular ratio of Si02 to Na20 is 1.65:1.0 a similar result is obtained; the amount of this latter sodium silicate can also be reduced to 100 parts without adverse effect on the sharpness of the resulting print.
- Instead of the white resist print paste used in the first stage of this Example there is used a similar print paste containing, in addition to the ingredients specified above, one of the following disperse dyestuffs which are not sensitive to alkali: C.I. Disperse Yellow 63, C.I. Disperse Orange 96, C.I. Disperse Red 91, C.I. Disperse Red 210, C.I. Disperse Red 303, C.I. Disperse Blue 185, C.I. Disperse Blue 83, C.I. Disperse Red 11, C.I. Disperse Blue 95 and C.I. Disperse Violet 26. In each case there is obtained a final print having the appropriately coloured pattern on a blue ground shade. The prints have excellent definition with no haloing effect, no bleeding of the illuminant dyestuff and with bright illuminant shades.
- The words "Calgon", "Manutex" and "Solvitose" are Registered Trade Marks.
- The procedure is repeated except that the dyestuff used in the second print paste is replaced by an equal weight of any one of the other dyestuffs hereinbefore specifically identified.
- In each case there is obtained a pattern having excellent definition between the discharged and undischarged areas of the print.
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT81300721T ATE11310T1 (en) | 1980-03-13 | 1981-02-20 | PROCESS FOR PRINTING TEXTILES. |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB8008597 | 1980-03-13 | ||
GB8008597 | 1980-03-13 | ||
GB8014139 | 1980-04-29 | ||
GB8014139 | 1980-04-29 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0036252A2 EP0036252A2 (en) | 1981-09-23 |
EP0036252A3 EP0036252A3 (en) | 1981-11-18 |
EP0036252B1 true EP0036252B1 (en) | 1985-01-16 |
Family
ID=26274812
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19810300721 Expired EP0036252B1 (en) | 1980-03-13 | 1981-02-20 | Textile printing process |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0036252B1 (en) |
DE (1) | DE3168222D1 (en) |
ES (1) | ES500294A0 (en) |
PT (1) | PT72662B (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3041014A1 (en) * | 1980-10-31 | 1982-06-16 | Cassella Ag, 6000 Frankfurt | METHOD FOR PRODUCING ETCH RESERVE PRINTING OF TEXTILE MATERIALS |
DE3312488A1 (en) * | 1983-04-07 | 1984-10-11 | Basf Ag, 6700 Ludwigshafen | METHOD FOR PRODUCING ALKALINE ACIDABLE COLORINGS AND PRINTS |
US4559781A (en) * | 1983-10-31 | 1985-12-24 | Allied Corporation | Master cylinder |
JPS6219105A (en) * | 1985-07-18 | 1987-01-27 | ワイケイケイ株式会社 | Production of face fastener having pattern and character surface |
DE3718565A1 (en) * | 1987-06-03 | 1988-12-15 | Basf Ag | METHOD FOR PRODUCING PRINT PRINTS |
GB8920004D0 (en) | 1989-09-05 | 1989-10-18 | John Green & Son Plc | Printing of fabrics |
ITSA20120006A1 (en) * | 2012-05-10 | 2013-11-11 | Oz Anadolu Kimya Sanayi Ve Ticaret Anonim Sirketi | INNOVATION IN CORRODENT PASTES FOR TEXTILE PRINTING. |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2322323A (en) * | 1941-04-16 | 1943-06-22 | Celanese Corp | Discharge printing of textiles |
ZA744836B (en) * | 1973-08-16 | 1975-08-27 | Hoechst Ag | Process for obtaining multicolor effects |
ZA745027B (en) * | 1973-08-16 | 1975-08-27 | Hoechst Ag | Process for obtaining irregular shadow dyeings on polyester fibres and mixtures thereof |
GB1543724A (en) * | 1975-08-13 | 1979-04-04 | Ici Ltd | Process for the production of discharge printing effects on synthetic textile materials |
GB1512321A (en) * | 1976-01-05 | 1978-06-01 | Ici Ltd | Colouration process for cellulose textile materials |
DE2836391C2 (en) * | 1978-08-19 | 1988-04-14 | Cassella Ag, 6000 Frankfurt | Process for dyeing and printing synthetic hydrophobic fiber material |
DE3064390D1 (en) * | 1979-07-18 | 1983-09-01 | Ici Plc | Substituted 2,7-dioxo-2,7-dihydrobenzo(1:2-b; 5,6-b1)difuran or dipyrrole dyestuffs, processes for their preparation and their use for the colouration of aromatic polyester textile materials |
-
1981
- 1981-02-20 EP EP19810300721 patent/EP0036252B1/en not_active Expired
- 1981-02-20 DE DE8181300721T patent/DE3168222D1/en not_active Expired
- 1981-03-12 ES ES500294A patent/ES500294A0/en active Granted
- 1981-03-13 PT PT7266281A patent/PT72662B/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0036252A3 (en) | 1981-11-18 |
PT72662A (en) | 1981-04-01 |
PT72662B (en) | 1982-03-19 |
ES8207251A1 (en) | 1982-09-01 |
DE3168222D1 (en) | 1985-02-28 |
EP0036252A2 (en) | 1981-09-23 |
ES500294A0 (en) | 1982-09-01 |
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