EP0016914B1 - Alkanolamine- fatty acid condensate conditioner for flotation of coal and a flotation process therefor - Google Patents

Alkanolamine- fatty acid condensate conditioner for flotation of coal and a flotation process therefor Download PDF

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Publication number
EP0016914B1
EP0016914B1 EP80100373A EP80100373A EP0016914B1 EP 0016914 B1 EP0016914 B1 EP 0016914B1 EP 80100373 A EP80100373 A EP 80100373A EP 80100373 A EP80100373 A EP 80100373A EP 0016914 B1 EP0016914 B1 EP 0016914B1
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EP
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Prior art keywords
coal
flotation
fatty acid
conditioner
acid
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Expired
Application number
EP80100373A
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German (de)
English (en)
French (fr)
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EP0016914A1 (en
Inventor
Clarence Wilfred Meyer
Robert Douglas Hansen
Robert Eugene Hefner Jr.
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Dow Chemical Co
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Dow Chemical Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/004—Organic compounds
    • B03D1/01—Organic compounds containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/004—Organic compounds
    • B03D1/006—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00—Specified effects produced by the flotation agents
    • B03D2201/02—Collectors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00—Specified effects produced by the flotation agents
    • B03D2201/04—Frothers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00—Specified materials treated by the flotation agents; Specified applications
    • B03D2203/02—Ores
    • B03D2203/04—Non-sulfide ores
    • B03D2203/08—Coal ores, fly ash or soot

Definitions

  • This invention relates to the froth flotation of coal-containing ashes, coal sludge or coal-containing residues to recover coal containing a lower percentage of impurities and uses a condensation product of an alkanolamine and a fatty acid as a conditioner for the flotation of finely-divided coal.
  • the loading of the oil-type collector is generally 0.05 to 1 kilogram per 1000 kg of coal feed for bituminous coals of intermediate or low rank, with the loading being relatively greater for the flotation of lignite and anthracite coals.
  • good recovery of oxidized coals or lignite coals can only be effected at such high loadings of the oil-type collector that significant amounts of inert material are floated along with the combustible materials.
  • fatty amines can be utilized as co-collectors in the flotation of oxidized coals to effect enhanced recovery.
  • even these amine collectors float substantial amounts of ash along with the coal and effect only partial recovery of combustible material.
  • the present invention is a froth flotation process for beneficiating coal by classifying the coal to separate particles of flotation size and floating the sized coal in a frothing aqueous medium, characterized in that the frothing aqueous medium comprises a fuel oil collector, an effective amount of a conventional frothing agent and an effective amount of a condensation product, or an acid derivative of the condensation product, of an alkanolamine corresponding to the formula I wherein
  • the present invention also includes a conditioner for flotation of coal comprising the reaction product of:
  • the alkanolamine utilized as a component of the condensation product in the practice of this invention is an unsubstituted or N-alkyl substituted monoethanolamine; diethanolamine; triethanolamine; hydroxyethylethylenediamine; N,N'-di(hydroxyethyllethylenediamine; N,N-di(hydroxyethyl)ethylenediamine; N,N,N'-tri(hydroxyethyl)ethylenediamine; N,N,N',N'-tetra(hydroxyethyl)-ethylenediamine; and like compounds in which the ethylene moiety is replaced by a propylene group and/or the hydroxyethyl group is replaced by a ,B-hydroxyalkyl group having from 3 to 5 carbon atoms.
  • the hydroxyalkyl group is desirably a hydroxyethyl, 1-methyl(hydroxyethyl) or 1-ethyl(hydroxyethyl) group.
  • the above-identified unsubstituted alkanolamines bearing only hydroxyethyl and ethylene moieties are preferred.
  • Diethanolamine, triethanolamine and di-, tri- or tetra(hydroxyethyl)ethylenediamine are especially preferred alkanolamines, with diethanolamine being the most preferred.
  • the alkanolamine can be a single compound or a mixture of operable alkanolamines, with the latter being preferred for economic reasons.
  • These alkanolamines are available commercially or can be readily prepared by the reactions of alkylene oxides with ammonia or an alkylenediamine in a manner known to the art.
  • the fatty acid condensed with the alkanolamine can operably be a fatty acid having a saturated or unsaturated alkyl group.
  • the fatty acid can suitably bear hydroxyl substituents on its alkyl portion, but such substitution does not impart any substantial advantage.
  • Fatty acids such as oleic, lauric, linoleic, palmitic, stearic, myristic, mixtures thereof and other like fatty acids are operable.
  • the esters corresponding to the fatty acids, such as glycerides, are also operable, but less preferred.
  • Tall oil and tall oil heads are especially preferred mixtures of fatty acids. Tall oil and tall oil heads are well-known compositions described in the Kirk-Othmer, Encyclopedia of Chemical Technology, 2nd Ed., Vol. 19, pp. 614-629 (1969).
  • the fatty acid or corresponding ester and the alkanolamine can be readily reacted by mixing these reactants and heating until the desired degree of condensation has taken place as indicated by the water distilled overhead or infrared spectrophotometric analysis of the condensation product.
  • a reaction temperature of from about 120°C to about 250°C is operable.
  • the reaction is termed a condensation herein to distinguish it from the formation of the ammonium salt of the acid at lower temperatures.
  • the condensation product may be an ester, an amide or both.
  • the condensation product is operable, but less effective, as a conditioner for coal in the presence of a substantial amount of unreacted fatty acid and the uncondensed alkanolammonium salt of the acid.
  • conditioner indicates that the condensation product is primarily effective to enhance the hydrophobicity of the coal surface. However, the use of the descriptive term “conditioner” is not intended to exclude the possibility that this condensation product acts as a co-collector with the fuel oil.
  • the efficacy of the instant condensation product is greatest when the reactants are condensed in a specific range of mole ratios. At least a stoichiometric amount of the fatty acid or its equivalent (i.e., fatty ester) is desirably condensed with the alkanolamine, although a less than equimolar amount is operable.
  • the molar ratio of fatty acid or fatty ester to the alkanolamine is at least 0.8, and preferably from 1.5:1 to 5:1, more preferably 2:1 to 3:1.
  • the number of moles of fatty acid and ester in the condensate should not exceed the number of moles of alkanolamine multiplied by the average number of reactive sites on a molecule of the alkanolamine.
  • reactive sites refers to the exchangeable hydrogen substituents on the amine group and the reactive hydroxyl substituents on the hydroxyalkyl group, which will react with the fatty acid or fatty acid ester to produce amides and esters respectively.
  • Acid derivatives of the above-described condensation products are operable, as well as the condensates themselves, in the instant flotation process. These derivatives are prepared by adding an inorganic or organic acid to the condensate so as to reduce the pH of the resulting mixture.
  • the derivative may be either salt, partial salt or an acid complex.
  • the organic acid derivatives are generally more readily dispersed in the aqueous flotation medium than are the parent compounds. These derivatives may exhibit greater activity or less activity than their parent compounds, but this relationship is not fully understood.
  • Common inorganic acids which can be used to prepare the acid derivatives include phosphoric, nitric, boric, hydrochloric, hydrobromic and sulfuric acids. These inorganic acid derivatives are operable, but not preferred.
  • Organic acids which can be used include aliphatic mono-, di-, or tricarboxylic acids; lower alkyl carboxylic acids; mono- or dihydroxy lower alkyl carboxylic acids; amino-substituted carboxylic acids and unsaturated aliphatic carboxylic acids.
  • Representative examples of these organic acids are formic, acetic, hydroxyacetic, propionic, butyric, isovaleric, lactic, gluconic, aminoacetic, malonic, succinic, adipic, malic, tartaric, glutaric, fumaric, citric, salicylic, benzoic and naphthenic acids.
  • Fatty acids are operable, but not preferred.
  • Acetic acid, and other lower alkyl organic carboxylic acids, especially the C 1 to C 4 organic acids, are preferred for this purpose.
  • 0.5 mole of acetic or propionic acid is added per mole of a condensate prepared from 1 equivalent of diethanolamine condensed with two equivalents of tall oil fatty acid. Titration with a base, as well as infrared and proton magnetic resonance spectroscopy of the resulting acetic or propionic acid derivative of this condensate indicate that an acid complex is formed and not a salt.
  • the loading of condensation product in the flotation medium which effects the greatest recovery of combustible carbonaceous matter with a tolerable amount of inert matter is affected by the size, grade, degree of oxidation and inert matter content of the coal feed, as well as the loading of frother and other adjuvants.
  • the term "effective amount of a condensation product" is used herein to denote the amount of said product required to increase the recovery of coal by froth flotation in the presence of fuel oil and a frother.
  • the condensate is advantageously employed in a ratio of from 0.001 to 1.0, preferably 0.002 to 0.2 kilogram of condensate per 1000 kg of coal flotation feed.
  • the instant condensation product can be utilized in conjunction with co-collectors or other adjuvants, such as activators, conditioning reagents, dispersing reagents, frothing reagents and depressing reagents.
  • Fuel oil is employed in the flotation medium as a collector. Representative fuel oils include diesel oil, kerosene, Bunker C fuel oil and mixtures thereof. The fuel oil can generally be advantageously employed in a ratio of from 0.02 to 2.5 kilograms fuel oil per 1000 kg of coal flotation feed.
  • the optimal loading of fuel oil in the flotation medium is influenced by numerous factors, such as the size, degree of oxidation and grade of the coal to be floated and the loading of condensate and frother. Therefore, the loading of the fuel oil should be optimized empirically to effect the greatest selectivity and recovery during flotation.
  • the conditioner is charged to the floatlon medium dispersed in part or all of the fuel oil charge.
  • a frothing agent is present in the floation medium to promote formation of a froth.
  • Conventional frothers such as pine oil, cresol, C 4 to C ⁇ alkanols containing one or two tertiaryl or one quaternary carbon atom, e.g., isomers of amyl alcohol, are suitable for this purpose.
  • methyl isobutyl carbinol and polypropylene glycol alkyl or phenyl ethers are preferred as frothers, with polypropylene glycol methyl ethers having a weight average molecular weight between about 200 and about 600 being most preferred.
  • the optimal loading of frother in the flotation medium is influenced by a number of factors, most important of which is the rank and degree of oxidation of the coal. Generally, a ratio of from 0.05 to 0.5 kilogram frother per 1000 kg of coal feed is advantageous.
  • the coal to be floated by the instant process can suitably be anthracite, bituminous or subbituminous.
  • This process is preferably employed to float coal which cannot be floated with conventional frothers alone and is particularly effective in the flotation of bituminous coal of intermediate or low grade, where the surface of the coal is oxidized to an extent which significantly impedes the flotation of the coal using conventional agents.
  • the size of the coal particles to be separated by flotation is important as generally particles larger than about 0,6 mm (28 mesh U.S. Sieve Size) are difficult to float.
  • coal particles larger than 0,6 mm (28 mesh) advantageously larger than 0,149 mm (100 mesh) are separated from both the inert material mined therewith and more finely divided coal by gravimetric separation techniques.
  • a substantial fraction of the coal in the flotation feed comprises particles larger than 0,6 mm 128 mesh)
  • the sized coal flotation feed optionally is first washed and then mixed with sufficient water to prepare an aqueous slurry having a solids concentrate which promotes rapid flotation.
  • a solids concentration between 2 to 20 weight percent solids, more preferably from 5 to 10 weight percent, is preferred.
  • the aqueous coal slurry is advantageously conditioned with the condensation product, a frother, fuel oil and any other adjuvants by mixing with the slurry in a manner known to the art.
  • the desired intimate contact can conveniently be attained by introducing the conditioner and fuel oil to the slurry upstream from the flotation cell.
  • the frother should be introduced to the slurry shortly before or during flotation to provide maximum frothing.
  • the coal is operably floated at the natural pH of the coal in the aqueous slurry, which can vary from 3.0 to 9.5 depending upon the composition of the feed.
  • a pH adjusting composition is optionally used as necessary to adjust and maintain the pH of the aqueous coal slurry prior to and during flotation to a value from 4 to 8, preferably 4 to 7, which normally promotes the greatest coal recovery.
  • the pH adjusting composition can operably be an alkaline material, such as soda ash, lime, ammonia, potassium hydroxide or magnesium hydroxide, with sodium hydroxide being preferred.
  • a carboxylic acid such as acetic acid, or a mineral acid such as sulfuric acid or hydrochloric acid are operable to adjust the pH.
  • the conditioned and pH-adjusted aqueous coal slurry is aerated in a conventional flotation machine or bank of rougher cells to float the coal. Any suitable rougher flotation unit can employed.
  • a 200 gram charge of comminuted coal is diluted with deionized water to a slurry of 6.67 percent solids.
  • the coal is a low grade, bituminous coal having a highly oxidized surface as indicated by the high oxygen content (14.3 percent) of the coal as determined by elemental analysis techniques.
  • the fraction of the coal feed consisting of particles larger than 0.71 mm (25 mesh) is separated before dilution, comminuted and then recombined with the remainder of the coal.
  • the comminuted coal feed is more than 90 percent particles smaller than 0.177 mm (80 mesh).
  • the coal as charged to the slurry contains about 14.7 percent ash.
  • This aqueous coal slurry is introduced into a flotation machine having a three-liter cell.
  • the pH of the slurry is determined to be about 4.
  • the coal slurry is agitated for about seven minutes to thoroughly wet the coal, at which time a refined kerosene is added to the slurry to effect a loading of about 2.5 kilograms of kerosene per 1000 kg of coal feed.
  • a condensate prepared from a molar ratio of 1 part diethanolamine (DEA) to 2 parts tall oil fatty acid (TOFA) is introduced with the kerosene into the aqueous coal slurry in a loading of about 0.125 kilogram of condensate per 1000 kg of coal feed.
  • DEA diethanolamine
  • TOFA tall oil fatty acid
  • the tall oil fatty acid reactant according to analysis by conventional methods contains 39 percent rosin acids, 29.3 percent oleic acid, 23 percent linoleic acid, 3.7 percent conjugated linoleic acid, 1.8 percent stearic acid and about 3.2 percent other acids and components.
  • Two control flotation runs not embodying the present invention are also made in which kerosene is the collector added to the slurry.
  • the slurry is agitated for one minute to condition the coal.
  • a frothing agent is then added to the slurry to effect a loading of 0.2 kilogram frother per 1000 kg of coal feed.
  • Methyl isobutyl carbinol (MIBC) and a polypropylene glycol methyl ether having a weight average molecular weight of about 400 (D-1012) are each employed as frothers in separate runs.
  • the aqueous coal slurry is conditioned by agitation for one minute, after which aeration of the medium is initiated and continued for four minutes.
  • a frothy concentrate is collected during aeration.
  • the collected concentrate is first dried in an oven and then weighed.
  • the percent recovery of coal by flotation is determined from the weight of coal in the concentrate divided by the weight of coal (i.e., total weight less weight of ash) in the 200 gram charge.
  • a one-gram sample of the concentrate is completely burned and the ash content of the concentrate is determined from the weight of the material remaining after combustion.
  • Table I tabulates the identity of the conditioner and frothing agent for each run as well as the percent recovery of coal and ash content in the concentrate.
  • Example 2 A series of runs are performed in the same manner as Example 1, with the exception of minor differences disclosed hereinafter. After the pH of the aqueous coal slurry is measured, it is adjusted in two separate runs to pH values of 7 and 9, respectively, by the addition of sodium hydroxide. The pH of the coal slurry in a third run is measured, but not adjusted. The coal in each of the three slurries is then floated in the presence of DEA/TOFA, kerosene and PPGME frother in the manner and at the loadings set out in Example 1. The results and identifying parameters for each run are tabulated in Table II.
  • Example 1 Seven flotation runs are performed in the same manner as Example 1, except for the condensation product employed as a conditioner.
  • the condensation product is prepared in each case by condensing the tall oil fatty acid of Example 1 with an alkanolamine selected from diethanolamine (DEA), triethanolamine (TEA) and a mixture of hydroxyethyl-substituted ethylene diamines (HEEDA).
  • the HEEDA mixture consists of about 10 percent aminoethylethanolamine, about 75 percent di(hydroxyethyl)ethylenediamine, about 12 percent tri(hydroxyethyl)ethylenediamine and about 3 percent tetra(hydroxyethyl)ethylenediamine.
  • the alkanolamine (AA) and tall oil fatty acid (TOFA) are condensed in the molar ratio tabulated hereinafter.
  • the coal in each of the three slurries is floated with 0.125 kilogram of the condensation product per 1000 kg of coal feed, along with kerosene and PPGME frother in the manner and at the loadings set out in Example 1.
  • the results and identifying parameters for each run are tabulated in Table III.
  • Example 2 Fourteen flotation runs are performed in the general manner of Example 1, with the exception that different coals are employed. Seven different raw coals, having the ash contents tabulated hereinafter, are each floated in a pair of runs in which a 1:2 condensate of DEA / TOFA is employed in only one of the pair, the other run acting as a control.
  • the coal in each case is introduced as an aqueous slurry into a flotation machine.
  • the pH of the slurry is measured and then PPGME frother, kerosene and the DEA/TOFA condensate are introduced into the slurry at the loadings of kilograms per 1000 kg of coal feed specified in Table IV.
  • the concentrate is recovered and the ash content and recovery of coal determined in the manner previously described.
  • Example 1 In the general manner of Example 1, five flotation runs are performed using an 8 percent dispersion of a 1:2 condensate of DEA/TOFA or an acetic acid or propionic acid derivative thereof in #1 diesel oil as the conditioner collector. These acid derivatives consist of 0.5 mole of acetic or propionic acid for each mole of the condensate. These derivatives are believed to be hydrogen bonded acid complexes of the condensate, inasmuch as the acetic acid introduced is titratable stoichiometrically with 0.085 normal KOH. Infrared and proton magnetic resonance spectroscopic analysis also indicate that an acid complex with hydrogen bonding is present.
  • the slurry is agitated while #1 diesel oil containing the conditioner is charged to the slurry to effect a loading equivalent to about 1.5 kilograms of diesel oil per 1000 kg of coal feed and 0.12 kilogram of the condensate per 1000 kg of coal.
  • a small amount (0.04 cm 3 ) of a conventional frother (D-1012) is added to the slurry and the slurry agitated for 10 seconds.
  • the results and identifying parameters for each run are tabulated in Table V.
  • condensation products of diethanolamine and fatty acids are known in the art, but generally an excess of at least an equimolar amount of diethanolamine relative to fatty acid is employed in preparing these condensates.
  • the term "condensation product" is employed herein to distinguish this product from the ammonium salt of the fatty acid produced at lower reaction temperatures.
  • the condensation product in the subject novel composition is prepared using 2 moles of fatty acid for each mole of diethanolamine.
  • the claimed composition is prepared by adding the water-soluble lower alkanoic acids, i.e., formic, acetic, propionic or butyric acids or a mixture thereof to the above-described condensation product at a temperature which does not effect substantial additional condensation.
  • the temperature during addition of this lower alkanoic acid is operably from 10°C to 100°C, preferably from 20°C to 50°C.
  • Substantially all of this lower alkanoic acid added to the composition can be titrated with an alkali metal hydroxide, which suggests that a hydrogen-bonded acid complex is formed and not a salt.
  • Analysis of infrared and proton magnetic resonance spectroscopy supports the theory that the resulting composition is an acid complex, but this structural elucidation is not definitive and the instant composition is not limited thereby.
  • the Cl--C4 alkanoic acid derivative of the diethanolamine/fatty acid condensate is charged to the flotation medium dispersed in fuel oil.
  • the alkanoic acid derivative comprises from 0.1 to 70, more preferably from 0.25 to 50 volume percent of the total fuel oil dispersion.
  • This fuel oil dispersion is believed to be a novel composition.
  • a composition of the alkanoic acid derivative and frothing agent and optionally further comprising fuel oil is believed novel.
  • a 1:2 condensate of DEA/TOFA and an acetic acid derivative thereof is employed in a coal flotation plant.
  • the acetic acid derivative consists of 0.5 mole of acetic acid for each mole of condensate.
  • the conditioner is added to #1 diesel oil in a quantity sufficient to effect an increase of 10 percent in volume.
  • the mixture of conditioner and #1 diesel oil is introduced at a rate of 200 cubic centimeters per minute to the tank used to collect the smaller than 0,149 mm (100 mesh) coal prior to introduction to the four banks of Daniel flotation cells. In one instance, diesel oil alone is introduced for purposes of comparison.
  • the pH of the coal slurry in the collecting tank is determined for each run.

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EP80100373A 1979-01-25 1980-01-24 Alkanolamine- fatty acid condensate conditioner for flotation of coal and a flotation process therefor Expired EP0016914B1 (en)

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Application Number Priority Date Filing Date Title
US694279A 1979-01-25 1979-01-25
US6942 1979-01-25

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EP0016914A1 EP0016914A1 (en) 1980-10-15
EP0016914B1 true EP0016914B1 (en) 1983-07-27

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EP (1) EP0016914B1 (https=)
JP (1) JPS5599356A (https=)
AU (1) AU534531B2 (https=)
CA (1) CA1144664A (https=)
DE (1) DE3064345D1 (https=)
ZA (1) ZA80388B (https=)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58104651A (ja) * 1981-12-15 1983-06-22 ザ・ダウ・ケミカル・カンパニ− 石炭の泡だて浮遊選鉱法の助剤としての脂肪酸とヒドロキシアルキル化ポリアルキレンポリアミンとの縮合物
CA1211870A (en) * 1982-10-14 1986-09-23 Robert O. Keys Promotors for froth flotation of coal
US4523991A (en) * 1982-12-27 1985-06-18 The Dow Chemical Company Carrier particle for the froth flotation of fine ores
US4504385A (en) * 1982-12-30 1985-03-12 Sherex Chemical Company, Inc. Ester-alcohol frothers for froth flotation of coal
CN85107378A (zh) * 1984-09-13 1987-03-18 陶氏化学公司 从原煤中回收有用煤的起泡剂组合物和泡沫浮选方法
EP0310720A1 (en) * 1987-10-09 1989-04-12 The Dow Chemical Company Process for using fatty esters of alkanolamine hydroxyalkylates as oxidized coal conditioners
US4826588A (en) * 1988-04-28 1989-05-02 The Dow Chemical Company Pyrite depressants useful in the separation of pyrite from coal
US8318423B2 (en) 2004-07-06 2012-11-27 Focus Diagnostics, Inc. Methods and compositions for detecting rhinoviruses
JP6141740B2 (ja) * 2013-10-08 2017-06-07 三井造船株式会社 褐炭の脱灰選炭方法および脱灰選炭装置

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE386083B (sv) * 1975-01-15 1976-08-02 Berol Kemi Ab Forfarande for flotation av bly-, uran- och sellsynta jordartsmineral ur malmer
US4268379A (en) * 1977-12-23 1981-05-19 American Cyanamid Company Selective flocculation for increased coal recovery by froth flotation
CA1112378A (en) * 1978-01-19 1981-11-10 Nalco Chemical Company Flotation of deep mined coal with water-in-oil emulsions of sodium polyacrylate

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JPS5599356A (en) 1980-07-29
DE3064345D1 (en) 1983-09-01
AU534531B2 (en) 1984-02-02
CA1144664A (en) 1983-04-12
AU5486280A (en) 1980-07-31
EP0016914A1 (en) 1980-10-15
JPS6255901B2 (https=) 1987-11-21
ZA80388B (en) 1981-08-26

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