EP0000405A1 - Peroxyketals, process for their production, their use in polymerisation reactions, in moulding compositions and mouldings - Google Patents
Peroxyketals, process for their production, their use in polymerisation reactions, in moulding compositions and mouldings Download PDFInfo
- Publication number
- EP0000405A1 EP0000405A1 EP78200047A EP78200047A EP0000405A1 EP 0000405 A1 EP0000405 A1 EP 0000405A1 EP 78200047 A EP78200047 A EP 78200047A EP 78200047 A EP78200047 A EP 78200047A EP 0000405 A1 EP0000405 A1 EP 0000405A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- peroxyketals
- general formula
- novel
- carbon atoms
- peroxyketal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/20—Peroxy compounds the —O—O— group being bound to a carbon atom further substituted by singly—bound oxygen atoms
- C07C409/22—Peroxy compounds the —O—O— group being bound to a carbon atom further substituted by singly—bound oxygen atoms having two —O—O— groups bound to the carbon atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
Definitions
- the invention relates to novel peroxyketals derived from alkoxyacetones and of the general formula: wherein R' represents a tert. alkyl group having 4-12 carbon atoms and R 2 a branched or a non-branched alkyl group having 1-12 carbon atoms or a substituted or unsubstituted cycloalkyl group having 5-12 carbon atoms, and to processes for the preparation of these peroxyketals as well as to the application thereof in chemical reactions taking place under the influence of free radicals, more particularly the compression moulding of unsaturated polyester resin moulding compounds. It is known that unsaturated polyester resins can be cured under the influence of free radicals.
- the ratio of reactive monomer to unsaturated polyester is generally 30-50% by weight of monomer to 70-50% by weight of polyester.
- the unsaturated polyester is obtained by condensation of approximately equivalent amounts of a divalent alcohol, such as ethylene glycol, propylene glycol, diethylene glycol, neopentyl glycol, dipropylene glycol and an unsaturated dibasic carboxylic acid or the anhydride thereof, such as maleic acid, maleic anhydride, fumaric acid, itaconic acid in the presence, if desired, of a saturated acid, such as phthalic acid, isophthalic acid, tetrachlorophthalic acid, malonic acid, adipic acid, sebacic acid, succinic acid and the like.
- a divalent alcohol such as ethylene glycol, propylene glycol, diethylene glycol, neopentyl glycol, dipropylene glycol
- an unsaturated dibasic carboxylic acid or the anhydride thereof such as maleic acid, maleic anhydride, fumaric acid, itaconic acid in the presence, if desired, of a saturated acid, such as
- mould release agents such as zinc stearate, calcium stearate and polyethylene
- fillers such as calcium carbonate
- clay such as titanium dioxide, ferric oxide, zinc oxide
- shrinkage reducing agents such as polyvinyl acetate and other thermoplastics
- reinforcing agents such as glass fibres.
- the curing of unsaturated polyester resin moulding compounds can be effected under pressure and at elevated temperature in the presence of radical generating organic peroxides.
- the known 2,2-diterbutyl peroxypropane, a peroxyketal derived from acetone or 2-propanone, is not suitable to be used for this purpose because it is too volatile and too hazardous.
- peroxyketals derived from alkyl-substituted acetones such as 2,2-ditert.butylperoxybutane, derived from methylethyl ketone and 2,2-ditert.butylperoxy-4-methylpentane, derived from methylisobutyl ketone are not suitable either, because the moulded articles prepared from polyester resin moulding compounds cured under pressure and at elevated temperature in the presence of the peroxyketals do not display a satisfactory gloss and have a relatively high residual styrene content.
- the United States Patent Specification 3 686 102 describes S-substituted peroxyketals and the use thereof as initiators in the polymerization of ethylenically unsaturated monomers, as curing catalysts in the curing of unsaturated polyester resins and as curing, cross-linking or vulcanizing catalysts for a-olefinic polymerisates or copolymerisates.
- Said patent specification mentions, inter alia, the use of 2,2-di(t-butylperoxy).-4-methoxy-4-methylpentane.
- R' represents a tert.alkyl group having 4-12 carbon atoms and R 2 a branched or a non-branched alkyl group having 1-12 carbon atoms or a substituted or unsubstituted cycloalkyl group having 5-12 carbon atoms are excellently suitable to be used in reactions carried out under the influence of free radicals, such as the polymerization of unsaturated monomers and the vulcanization of elaso- mers, more particularly however, in the compression moulding of unsaturated polyester moulding compounds.
- the moulded products thus obtained have a very good gloss and a very low content of residual monomer.
- the peroxyketals according to the invention may be used in amounts of 0.05-5.0% by weight, and preferably in an amount of 0.2-2.0% by weight, calculated on the amount of unsaturated polyester resin.
- novel peroxyketals according to the invention can be obtained in a simple manner by reacting a hydroperoxide of the formula R'OOH with an alkoxy acetone of the general formula
- R ' and R 2 have the above-indicated meaning, in a molar ratio of 2:1, at a temperature in the range of -10° to + 50°C, preferably however at a temperature in the range of -5° to 15°C; in the presence of a strongly acid catalyst, such as sulphuric acid, hydrochloric acid, perchloric acid and para-toluene sulphonic acid.
- a strongly acid catalyst such as sulphuric acid, hydrochloric acid, perchloric acid and para-toluene sulphonic acid.
- the water evolved during the reaction may be removed by distillation.
- the peroxyketal formed can be extracted from the reaction mixture in a known manner with the aid of hexane or some other suitable solvent and subsequently isolated by distilling the solvent off under reduced pressure.
- starting hydroperoxides may be mentioned: t.butyl-, t.a myl-, t.octyl-, such as 2,4,4-trimethylpentyl-, and t. dodecyl- hydroperoxide.
- alkoxyketones may be mentioned: methoxyacetone, ethoxyacetone, n-butoxyacetone, n-hexyloxyacetone, n-octyloxyacetone, n-dodecyloxyacetone, isoprpoxyacetone, isobutoxyacetone, 2-ethyl- hexyloxyacetone,cyclopentyloxyacetone, cyclohexyloxyacetone, 4-tert. butylcyclohexyloxyacetone, cyclooktyloxyacetone, sand cyclododecyloxy- acetone.
- methoxyacetone methoxyacetone, ethoxyacetone, n-butoxyacetone, n-hexyloxyacetone, n-octyloxyacetone, n-dodecyloxyacetone, isoprpoxyacetone, isobutoxyacetone, 2-ethyl- hexy
- standard resin used in the examples is to be understood a commercial product prepared from 1.2 moles of maleic anhydride, 1 mole of phthalic anhydride, 1.0 mole of diethylene glycol and 1.3 moles of 1,2-propanediol, diluted with about 30% by weight of styrene. To stabilize this product 0.01% by weight of hydroquinone and 0.01% by weight of para- tert. butylcatechol were added to it. The product has an acid number of 30 and a viscosity at 20°C. of 2,400 Cp.
- the gloss was determined in accordance with DIN 67 530 at an angle of reflection of 45°.
- the residual styrene content was determined in accordance with DIN 67 530 at an angle of reflection of 45°.
- the resicual styrene content was determined in accordance with DIN 16 945.
- the liquid product obtained weighed 23.2 grammes and contained 90.7% of 2,2-bis(2,4,4-trimethylpentyl-2-peroxx)-1-me- thoxypropane, which was found via determining the active oxygen content.
- the structure was confirmed by IR and NMR analuses.
- a moulding compound of the following composition contained in a Z -blade mixer there were added, at a temperature of 20°C., 0.30 parts by weight of 1-methoxy-2,2-ditert.butylperoxy- propane. The compound was thickened by leaving it at room temperature for 3 days. Next the flow of the compound was determined. In a steel mould the compound was compressed into a moulding over a period of 60 seconds at a temperature of 140 C. and a load of 10 MPa/mm . Of the moulding thus obtained the gloss and the residual styrene content were determined.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
Abstract
Peroxyketals of the formula
<CHEM>
wherein R min represents a tert. alkyl group having 4-12 carbon atoms and R<2> a branched or a nonbranched alkyl group having 1-12 carbon atoms or a substituted or unsubstituted cycloalkyl group having 5-12 carbon atoms; their preparation from R min OOH and alkoxyacetones; their use in chemical reaction under the influence of free radicals, more particularly in curing unsaturated polyester resin moulding compounds; and the mouldings obtained.
Description
- Novel peroxyketals derived from alkoxyacetones.
- The invention relates to novel peroxyketals derived from alkoxyacetones and of the general formula:
- By unsaturated polyester resins are to be understood solutions of unsaturated polyesters in reactive monomers containing one or more CH2= CH <groups, such as styrene, vinyl toluene, methyl methacrylate, diallylphthalate, and divinyl benzene. The ratio of reactive monomer to unsaturated polyester is generally 30-50% by weight of monomer to 70-50% by weight of polyester.
- The unsaturated polyester is obtained by condensation of approximately equivalent amounts of a divalent alcohol, such as ethylene glycol, propylene glycol, diethylene glycol, neopentyl glycol, dipropylene glycol and an unsaturated dibasic carboxylic acid or the anhydride thereof, such as maleic acid, maleic anhydride, fumaric acid, itaconic acid in the presence, if desired, of a saturated acid, such as phthalic acid, isophthalic acid, tetrachlorophthalic acid, malonic acid, adipic acid, sebacic acid, succinic acid and the like.
- If such polyester resins are employed as moulding compounds, then it is desirable that they should contain thickeners, more particularly chemical thickeners, such as magnesium oxide and hydroxide or oxides and hydroxides of other metals of the second group of the periodic system. These thickeners are generally added in amounts of 0.5 to 25 parts, and preferably 1 to 5 parts per 100 parts of unsaturated polyester resin. Into the unsaturated polyester resin moulding compounds there may, besides thickeners, be incorporated mould release agents, such as zinc stearate, calcium stearate and polyethylene; fillers, such as calcium carbonate; clay; pigments, such as titanium dioxide, ferric oxide, zinc oxide; shrinkage reducing agents, such as polyvinyl acetate and other thermoplastics; and reinforcing agents, such as glass fibres.
- The curing of unsaturated polyester resin moulding compounds can be effected under pressure and at elevated temperature in the presence of radical generating organic peroxides. The known 2,2-diterbutyl peroxypropane, a peroxyketal derived from acetone or 2-propanone, is not suitable to be used for this purpose because it is too volatile and too hazardous. The peroxyketals derived from alkyl-substituted acetones, such as 2,2-ditert.butylperoxybutane, derived from methylethyl ketone and 2,2-ditert.butylperoxy-4-methylpentane, derived from methylisobutyl ketone are not suitable either, because the moulded articles prepared from polyester resin moulding compounds cured under pressure and at elevated temperature in the presence of the peroxyketals do not display a satisfactory gloss and have a relatively high residual styrene content.
- The United States Patent Specification 3 686 102 describes S-substituted peroxyketals and the use thereof as initiators in the polymerization of ethylenically unsaturated monomers, as curing catalysts in the curing of unsaturated polyester resins and as curing, cross-linking or vulcanizing catalysts for a-olefinic polymerisates or copolymerisates. Said patent specification mentions, inter alia, the use of 2,2-di(t-butylperoxy).-4-methoxy-4-methylpentane. This peroxyketal, however, has the disadvantage that the preparation thereof from tert.butylhydroperoxide and 4-methoxy-4-methyl-2-pentanone in an acid medium is readily attended with the formation of carbonium ions, which give rise to undesirable side reactions, as a result of which the yield of the peroxyketal desired is considerably reduced. Moreover, the starting ketone causes skin and eye irritation.
- It has now been found that peroxyketals derived from methoxyacetone which have not been described before and are of the general formula
-
- wherein R' and R 2 have the above-indicated meaning, in a molar ratio of 2:1, at a temperature in the range of -10° to + 50°C, preferably however at a temperature in the range of -5° to 15°C; in the presence of a strongly acid catalyst, such as sulphuric acid, hydrochloric acid, perchloric acid and para-toluene sulphonic acid. If desired, the water evolved during the reaction may be removed by distillation. The peroxyketal formed can be extracted from the reaction mixture in a known manner with the aid of hexane or some other suitable solvent and subsequently isolated by distilling the solvent off under reduced pressure.
- As examples of starting hydroperoxides may be mentioned: t.butyl-, t.a myl-, t.octyl-, such as 2,4,4-trimethylpentyl-, and t. dodecyl- hydroperoxide.
- As examples of alkoxyketones may be mentioned: methoxyacetone, ethoxyacetone, n-butoxyacetone, n-hexyloxyacetone, n-octyloxyacetone, n-dodecyloxyacetone, isoprpoxyacetone, isobutoxyacetone, 2-ethyl- hexyloxyacetone,cyclopentyloxyacetone, cyclohexyloxyacetone, 4-tert. butylcyclohexyloxyacetone, cyclooktyloxyacetone, sand cyclododecyloxy- acetone. The invention will be further described in the following examples, which illustrate the subject invention and are not in limitation thereof.
- By the term standard resin used in the examples is to be understood a commercial product prepared from 1.2 moles of maleic anhydride, 1 mole of phthalic anhydride, 1.0 mole of diethylene glycol and 1.3 moles of 1,2-propanediol, diluted with about 30% by weight of styrene. To stabilize this product 0.01% by weight of hydroquinone and 0.01% by weight of para- tert. butylcatechol were added to it. The product has an acid number of 30 and a viscosity at 20°C. of 2,400 Cp. To determine the flow of a moulding compound 5 grammes of this material were placed between two flat plates and over a period of 60 seconds subjected to a compression moulding load of 10 kg/cm at a temperature of 140°C. The resulting diameter of the compression moulded compound is a measure of the flow.
- The gloss was determined in accordance with DIN 67 530 at an angle of reflection of 45°. The residual styrene content was determined in accordance with DIN 67 530 at an angle of reflection of 45°. The resicual styrene content was determined in accordance with DIN 16 945.
- Into a 3-neck 250-ml flask provided with a drain cock, a stirrer and a thermomenter there were charged 18.9 grammes of a 70%-methoxyacetone and 30.9 grammes of 93%-tert.butylhydroperoxide. Subsequently, the contents of the flash were cooled down to 0 C., after which over a period of 30 minutes and at a temperature in the range of 0°-5°C., 30.8 grammes of 70% - H2SO4 were added, with stirring. The stirring was continued for 45 minutes at 0°C. To isolate the peroxyketal formed 110 ml of hexane were added to the reaction mixture. After the aqueous lower layer had been drained off, the organic upper layer was washed 5 times with 5 ml of 4N KOH solution and subsequently with water until neutral.
- Finally, the hexane was distilled off under reduced pressure and at a temperature of 20°C. The liquid product obtained weighed 31.6 grammes and contained 96.2% of 1-methoxy-2,2-ditert.butylperoxypropane, which was found by determination of the active oxygen content. The structure was confirmed by IR and NMR analyses. Likewise, the following peroxyketals were synthesized and their contents determinised. 1-ethoxy-2,2-ditert.butylperoxypropane (content 100%) 1-n-oktyloxy-2,2-ditert.butylperoxypropane (content 72.1%) 1-n.dodecgloxy-2,2-ditert.butylperoxypropane (content 81.5%) f-isopropoxy-2,2-ditert.butylperoxypropane (content.92.3%) 1-(2-ethylhexyloxy)-2,2-ditert.butylperoxypropane (content 75.4%) 1-(cyclohexyloxy-2,2-ditert.butyperoxypropane (content 64.7%) 1-(4. tert.butylcyclohexyloxy)-2,2-ditert.butyl-peroxypropane (content 68.9%) 1-cyclododecyloxy-2,2-ditert.butylperoxypropane (content 70.5%).
- Into a 3-neck 250 ml flask provided with a drain cock, a stirrer and a thermometer there were chareged 14.4. grammes of a 70%-methoxyacetone and 32.2 grammes of 95.1%-2,4,4-trimethylpentyl-2-hydroperoxide. Subsequently, the contents of the flask were cooled to 10°C., after which over a period of 15 minutes and at a temperature of 10° C. 24.9 grammes of 70%-H2SO4 were added, with stirring. The stirring was continued for 4 hours at the same temperature. Next, 24.8 grammes of water were added. After the aqueous, sulphuric acid-containing layer had been drained off, the organic layer was washed 5 times with 30 ml of 2 N KOH solution and subsequently with water until neutral. Then the organic layer was dissolved in petroleum ether having a boiling point of 48 -60°c., and stirred for 1 hour at 20°-25°C. while adding a solution of 3.1 grammes of Na2S03 and 0.9 grammes of Na2s205 in 50 ml of water. Next, the aqueous phase was drained off and the petroleum ether evaporated off under reduced pressure. The liquid product obtained weighed 23.2 grammes and contained 90.7% of 2,2-bis(2,4,4-trimethylpentyl-2-peroxx)-1-me- thoxypropane, which was found via determining the active oxygen content. The structure was confirmed by IR and NMR analuses.
- Into a 3-neck, 500-ml flask provided with a stirrer, a thermometer and a distillation set up suitable for the azeotropic removal of water, there were charged 58.5 grammes of 92%-tert. butylhydroperoxide, 75 grammes of toluene, 33.6 grammes of 78.4% -methoxyacetone, 3 grammes of 4-N sulphuric acid and 2 drops of a defoamer. Subsequently, the mixture was heated to a temperature of 30°C and the reaction water removed by azeotropic distillation under reduced pressure. After 2 hours, during which 13.2 grammes of water had been distilled off, the reaction was completed. Next, the reaction mixture was washed twice with 40 ml of 4 N NaOH and 40 ml of water. There were obtained 156.2 grammes of reaction product containing 37% of 1-methoxy-22-ditert.butylperoxypropane.
- To a moulding compound of the following composition:
- Corresponding measurements were carried out on moulding compounds containing the same amounts by weight of other peroxyketals according to che invention and on moulding compounds containing the same amounts by weight of the known compounds 2,2-ditert.butylperoxybutane and 2,2-ditert.butylperoxy-4-methyl pentane.
-
- To a moulding compound of the composition described in Example II and contained in a Z-blade mixer there were added at a temperature of 20°C., 0.2 parts by weight of 2,2 bis (2,4,4-trimethylpentyl-2-peroxy)-1-methoxy-propane, calculated on the unsaturated polyester resin. To thicken the compound it was stored for 3 days at room temperature. Subsequently, the flow of the compound was determined. In a steel mould the compound was compressed into a moulding over a period of 60 seconds, at a temperature of 60°C, and a load of 10 MPa/mm . Of this moulding the gloss and the residual styrene content were determined.
- Corresponding measurements were carried out on moulding compounds containing different amount by weight of 2,2 bis(2,4,4-trimethylpentyl-2-peroxy)-1-methoxpropane.
-
Claims (11)
3. Novel peroxyketals according to claim -1, wherein R' represents tert.butyl and R2 stands for methyl, ethyl, n-oktyl, n-dodecyl, isopropyl, 2-ethylhexyl, cyclohexyl, 4-tert.butylcyclohexyl or cyclododecyl.
4. Novel peroxyketals according to claim 1, wherein R' represents 2,4,4-trimethylpentyl and R2 methyl.
5. A process for the preparation of the novel peroxyketals according to any one of the preceding claims, characterized in that a hydroperoxide having the general formula R'OOH is brought into reaction with an alkoxyacetone of tne general formula
wherein the symbols R and R 2 have the above defined meaning, in the presence of a strongly acid catalyst in a molar ratio of 2:1 at a temperature in the range of -10° to + 50°C.
6. A process according to claim 5, characterized in that the water evolved during the reaction is distilled off azeotropically under reduced pressure.
7. A process for carrying out chemical reactions under the influence of free radicals, characterized in that as radical generating compound a peroxyketal of the general formula according to claim 1,2,3 or 4 is used.
8. A process according to claim 7, characterized in that an unsaturated polyester resin is cured under pressure in the presence of a peroxyketal having the general formula of claim 1,2,3 or 4.
9. Moulding compounds suitable to be used in the process according to claim 8, characterized in that into the moulding compound there is not only incorporated an unsaturated polyester resin, but also a peroxyketal having the general formula according to claim 1,2,3 or 4 and in an amount which is sufficiently high to effect curing.
10. A moulding compound according to claim 9, characterized in that it is made to contain 0.05 to 5% by weight, and preferably 0.2 to 2.0% by weight of peroxyketal, calculated on the unsaturated polyester resin.
11. Mouldings obtained by using the process according to claim 8.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL7707887A NL7707887A (en) | 1977-07-15 | 1977-07-15 | NEW METHOXYACETONE DERIVED PERCETALS. |
NL7707887 | 1977-07-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0000405A1 true EP0000405A1 (en) | 1979-01-24 |
Family
ID=19828881
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP78200047A Ceased EP0000405A1 (en) | 1977-07-15 | 1978-06-19 | Peroxyketals, process for their production, their use in polymerisation reactions, in moulding compositions and mouldings |
Country Status (6)
Country | Link |
---|---|
US (2) | US4287371A (en) |
EP (1) | EP0000405A1 (en) |
JP (1) | JPS5419907A (en) |
CA (1) | CA1119619A (en) |
IT (1) | IT1097524B (en) |
NL (1) | NL7707887A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0233476A2 (en) * | 1986-02-19 | 1987-08-26 | ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.) | Peroxide free radical initiators containing hindered amine light stabilizer groups |
WO2000009478A1 (en) * | 1998-08-12 | 2000-02-24 | Akzo Nobel N.V. | Peroxides, their preparation process and use |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110128314B (en) * | 2019-06-12 | 2020-11-10 | 江西师范大学 | Method for continuously producing 2, 2-bis (tert-butyl peroxide) butane |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL302783A (en) * | 1963-02-14 | 1900-01-01 | ||
US3763275A (en) * | 1970-06-03 | 1973-10-02 | Pennwalt Corp | Curing processes employing beta-substituted diperoxyketals |
DE2317965A1 (en) * | 1972-04-10 | 1973-10-25 | Pennwalt Corp | DI AND TETRA (PEROXY) KETALS AND ACETALS |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL154730B (en) * | 1965-05-21 | 1977-10-17 | Montedison Spa | PROCESS FOR PREPARING PEROXYACETALS OR PEROXYKETALS. |
US3686102A (en) * | 1970-06-03 | 1972-08-22 | Pennwalt Corp | Curing and polymerizing processes employing beta-substituted diperoxyketals |
-
1977
- 1977-07-15 NL NL7707887A patent/NL7707887A/en not_active Application Discontinuation
-
1978
- 1978-06-19 EP EP78200047A patent/EP0000405A1/en not_active Ceased
- 1978-07-14 IT IT25730/78A patent/IT1097524B/en active
- 1978-07-14 CA CA000307396A patent/CA1119619A/en not_active Expired
- 1978-07-14 JP JP8597578A patent/JPS5419907A/en active Pending
-
1979
- 1979-10-22 US US06/087,031 patent/US4287371A/en not_active Expired - Lifetime
-
1981
- 1981-02-12 US US06/233,794 patent/US4376842A/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL302783A (en) * | 1963-02-14 | 1900-01-01 | ||
US3763275A (en) * | 1970-06-03 | 1973-10-02 | Pennwalt Corp | Curing processes employing beta-substituted diperoxyketals |
DE2317965A1 (en) * | 1972-04-10 | 1973-10-25 | Pennwalt Corp | DI AND TETRA (PEROXY) KETALS AND ACETALS |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0233476A2 (en) * | 1986-02-19 | 1987-08-26 | ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.) | Peroxide free radical initiators containing hindered amine light stabilizer groups |
EP0233476A3 (en) * | 1986-02-19 | 1990-09-19 | Pennwalt Corporation | Peroxide free radical initiators containing hindered amine light stabilizer groups |
WO2000009478A1 (en) * | 1998-08-12 | 2000-02-24 | Akzo Nobel N.V. | Peroxides, their preparation process and use |
US6384287B1 (en) | 1998-08-12 | 2002-05-07 | Akzo Nobel Nv | Peroxides, their preparation process and use |
Also Published As
Publication number | Publication date |
---|---|
US4376842A (en) | 1983-03-15 |
IT7825730A0 (en) | 1978-07-14 |
IT1097524B (en) | 1985-08-31 |
US4287371A (en) | 1981-09-01 |
JPS5419907A (en) | 1979-02-15 |
NL7707887A (en) | 1979-01-17 |
CA1119619A (en) | 1982-03-09 |
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