EA201390135A1 - ASYMMETRIC MEMBRANES FOR APPLICATION IN NANO-FILTRATIONS - Google Patents

ASYMMETRIC MEMBRANES FOR APPLICATION IN NANO-FILTRATIONS

Info

Publication number
EA201390135A1
EA201390135A1 EA201390135A EA201390135A EA201390135A1 EA 201390135 A1 EA201390135 A1 EA 201390135A1 EA 201390135 A EA201390135 A EA 201390135A EA 201390135 A EA201390135 A EA 201390135A EA 201390135 A1 EA201390135 A1 EA 201390135A1
Authority
EA
Eurasian Patent Office
Prior art keywords
membranes
filtrations
nano
application
asymmetric membranes
Prior art date
Application number
EA201390135A
Other languages
Russian (ru)
Other versions
EA027868B1 (en
Inventor
Эндрю Гай Ливингстоун
Йогеш Суреш Бхоле
Original Assignee
Империал Инновейшнз Лимитед
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Империал Инновейшнз Лимитед filed Critical Империал Инновейшнз Лимитед
Publication of EA201390135A1 publication Critical patent/EA201390135A1/en
Publication of EA027868B1 publication Critical patent/EA027868B1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B01D69/142—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes with "carriers"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
    • B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/027—Nanofiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0004—Organic membrane manufacture by agglomeration of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0006—Organic membrane manufacture by chemical reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/0011—Casting solutions therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/0011—Casting solutions therefor
    • B01D67/00113—Pretreatment of the casting solutions, e.g. thermal treatment or ageing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0079—Manufacture of membranes comprising organic and inorganic components
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0079—Manufacture of membranes comprising organic and inorganic components
    • B01D67/00793—Dispersing a component, e.g. as particles or powder, in another component
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0097—Storing or preservation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/125—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B01D69/1411—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes containing dispersed material in a continuous matrix
    • B01D69/14111—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes containing dispersed material in a continuous matrix with nanoscale dispersed material, e.g. nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/30—Cross-linking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/022—Asymmetric membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/022—Asymmetric membranes
    • B01D2325/0231—Dense layers being placed on the outer side of the cross-section

Abstract

Раскрыты усовершенствованные, полностью покрытые тонким слоем асимметричные мембраны для нанофильтрации органического растворителя и способы их приготовления и использования. Мембраны получают из полибензимидазолов путем инверсии фаз, а затем подвергают поперечному сшиванию путем добавления сшивающих агентов. Они стабилизируют мембраны и позволяют поддерживать нанофильтрацию растворителя, даже в растворителях, из которых мембраны были образованы путем инверсии фаз, а также в сильнокислых и сильноосновных растворителях.Disclosed are advanced, asymmetrical membranes for nanofiltration of organic solvent and methods for their preparation and use, completely covered with a thin layer. Membranes are prepared from polybenzimidazoles by phase inversion, and then cross-linked by the addition of crosslinking agents. They stabilize the membranes and allow the nanofiltration of the solvent to be maintained, even in solvents from which the membranes were formed by phase inversion, as well as in strongly acidic and strongly basic solvents.

EA201390135A 2010-07-19 2011-07-19 Asymmetric membranes for use in nanofiltration EA027868B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1012080.6A GB201012080D0 (en) 2010-07-19 2010-07-19 Asymmetric membranes for use in nanofiltration
PCT/GB2011/051361 WO2012010886A1 (en) 2010-07-19 2011-07-19 Asymmetric membranes for use in nanofiltration

Publications (2)

Publication Number Publication Date
EA201390135A1 true EA201390135A1 (en) 2013-10-30
EA027868B1 EA027868B1 (en) 2017-09-29

Family

ID=42735131

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201390135A EA027868B1 (en) 2010-07-19 2011-07-19 Asymmetric membranes for use in nanofiltration

Country Status (18)

Country Link
US (2) US20130118983A1 (en)
EP (1) EP2595733B1 (en)
JP (1) JP6055406B2 (en)
KR (1) KR102101707B1 (en)
CN (1) CN103079685B (en)
AU (1) AU2011281326B2 (en)
BR (1) BR112013001380B8 (en)
CA (1) CA2805780C (en)
CL (1) CL2013000167A1 (en)
EA (1) EA027868B1 (en)
ES (1) ES2870873T3 (en)
GB (1) GB201012080D0 (en)
IL (1) IL224282B (en)
MX (1) MX2013000770A (en)
MY (1) MY171822A (en)
SG (1) SG187556A1 (en)
UA (1) UA115963C2 (en)
WO (1) WO2012010886A1 (en)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201012080D0 (en) 2010-07-19 2010-09-01 Imp Innovations Ltd Asymmetric membranes for use in nanofiltration
US9199199B2 (en) * 2012-10-05 2015-12-01 Uop Llc Separation membrane
CN103022530A (en) * 2012-12-14 2013-04-03 辽宁师范大学 Porous membrane and preparation method as well as application thereof in fuel battery
CN103055723A (en) * 2012-12-18 2013-04-24 辽宁师范大学 Cross-linking type polybenzimidazole porous separation membrane and preparation method and application thereof
WO2015059921A1 (en) * 2013-10-23 2015-04-30 Akron Polymer Systems Inc. Resin composition, method of manufacturing resin composition, substrate, method of manufacturing electronic device and electronic device
US9987599B2 (en) * 2013-11-02 2018-06-05 Council Of Scientific & Industrial Research Asymmetric membranes based on BuPBI
PL3089813T3 (en) 2013-12-30 2019-09-30 3M Innovative Properties Company Use of an asymmetric composite membrane for pervaporation and cartridge comprising said membrane
CN107921370B (en) 2015-07-01 2022-03-29 3M创新有限公司 Polymeric ionomer separation membranes and methods of use thereof
WO2017004492A1 (en) 2015-07-01 2017-01-05 3M Innovative Properties Company Pvp- and/or pvl-containing composite membranes and methods of use
CN107847867B (en) 2015-07-01 2021-06-25 3M创新有限公司 Composite membranes having improved performance and/or durability and methods of use thereof
KR101979683B1 (en) 2017-02-17 2019-05-17 한양대학교 산학협력단 Thin-film composite membrane for organic solvent nanofiltration and preparation method thereof
WO2017178482A1 (en) * 2016-04-11 2017-10-19 Basf Se Porous thermoplastic membranes
US10258977B2 (en) * 2016-04-18 2019-04-16 Muhammad Akhyar Furrukh Development of nanofiltration system with La/SnO2—TiO2 nanoparticles
GB201609873D0 (en) * 2016-06-06 2016-07-20 Imp Innovations Ltd Process
KR20180097894A (en) 2017-02-24 2018-09-03 한양대학교 산학협력단 Thin-film composite membrane for organic solvent nanofiltration and preparation method thereof
WO2019034993A1 (en) 2017-08-16 2019-02-21 3M Innovative Properties Company Composite membranes with improved performance and/or durability and methods of use
US20200368690A1 (en) 2017-08-16 2020-11-26 3M Innovative Properties Company Polymeric ionomer separation membranes and methods of use
WO2019036423A1 (en) 2017-08-16 2019-02-21 3M Innovative Properties Company Pvp- and/or pvl-containing composite membranes and methods of use
CN111629816A (en) * 2017-11-09 2020-09-04 加州大学评议会 Asymmetric composite membranes and uses thereof
CN109962274A (en) * 2017-12-14 2019-07-02 中国科学院大连化学物理研究所 A kind of high temperature resistant compound proton exchange membrane and preparation method thereof
KR101979685B1 (en) 2018-11-06 2019-05-17 한양대학교 산학협력단 Thin-film composite membrane for organic solvent nanofiltration and preparation method thereof
JPWO2020189712A1 (en) * 2019-03-19 2020-09-24
JP2022535416A (en) 2019-06-05 2022-08-08 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア Biofouling resistant coatings and methods of making and using the same
CN111514768B (en) * 2020-05-11 2021-07-13 苏州大学 Solvent-resistant polymer nanofiltration membrane as well as preparation method and application thereof
CN112387134B (en) * 2020-10-29 2021-11-23 吉林大学 Solvent-resistant nanofiltration membrane as well as preparation method and application thereof
WO2022243976A1 (en) * 2021-05-20 2022-11-24 King Abdullah University Of Science And Technology Metal-polymer coordination membranes for molecular sieving
CN113299959B (en) * 2021-06-04 2022-07-08 中国科学院化学研究所 Composite proton exchange membrane and preparation method and application thereof

Family Cites Families (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3708A (en) 1844-08-16 Keeping
USRE26065E (en) 1966-07-19 Folybenzimidazoles and their preparation
US439A (en) 1837-10-23 Machiste fob maiciotg beices
US2895948A (en) 1955-10-28 1959-07-21 Du Pont Polybenzimidazoles
US3313783A (en) 1962-07-20 1967-04-11 Teijin Ltd Process for preparation of polybenzimidazoles
US3408336A (en) 1965-08-12 1968-10-29 Monsanto Co Heat stabilized polybenzimidazoles
US3433772A (en) 1965-12-30 1969-03-18 Celanese Corp Process for preparing polybenzimidazoles
US3549603A (en) 1968-07-09 1970-12-22 Celanese Corp Process for the polymerization of aromatic polybenzimidazoles
US3555389A (en) 1968-10-10 1971-01-12 Power Control Corp Direct current motor control system
US3509108A (en) 1969-03-04 1970-04-28 Celanese Corp Preparation of polybenzimidazoles
US3720607A (en) 1970-04-15 1973-03-13 Celanese Corp Reverse osmosis process employing polybenzimidazole membranes
US3699038A (en) 1970-04-22 1972-10-17 Celanese Corp Production of improved semipermeable polybenzimidazole membranes
US3737402A (en) 1971-09-01 1973-06-05 Unifilm Corp Flatting agents,flatting compositions and method for their preparation
US3708439A (en) 1971-09-28 1973-01-02 Upjohn Co Polybenzimidazoles
US3841492A (en) 1972-01-19 1974-10-15 Celanese Corp Production of semipermeable polybenzimidazole membranes
JPS5419396B2 (en) * 1972-02-10 1979-07-14
US4020142A (en) 1975-08-21 1977-04-26 Celanese Corporation Chemical modification of polybenzimidazole semipermeable
US4154919A (en) 1976-08-31 1979-05-15 Acurex Corporation Linear and cross-linked polybenzimidazoles
US4312976A (en) 1980-07-15 1982-01-26 Celanese Corporation Single-stage melt polymerization process for the production of high molecular weight polybenzimidazole
US4448687A (en) 1982-12-17 1984-05-15 Celanese Corporation Process for the production of semipermeable polybenzimidazole membranes with low temperature annealing
US4532041A (en) 1983-05-13 1985-07-30 Exxon Research And Engineering Co. Asymmetric polyimide reverse osmosis membrane, method for preparation of same and use thereof for organic liquid separations
JPS59230604A (en) * 1983-05-13 1984-12-25 エクソン・リサ−チ・アンド・エンジニアリング・カンパニ− Crossed polyimide reverse osmosis membrane, manufacture thereof and use thereof for separating organic liquid
US4734466A (en) 1985-01-16 1988-03-29 Hoechst Celanese Corporation Modified polybenzimidazole polymer membranes
US4693824A (en) 1985-09-23 1987-09-15 Celanese Corporation Process for the production of polybenzimidazole ultrafiltration membranes
US4693825A (en) 1985-09-23 1987-09-15 Celanese Corporation Method for the preparation of polybenzimidazole membranes
US4666996A (en) * 1986-01-24 1987-05-19 Celanese Corporation Crosslinking of polybenzimidazole polymer with divinyl sulfone
US4828699A (en) 1987-08-20 1989-05-09 Hoechst Celanese Corporation Process for the production of microporous polybenzimidazole articles
DE3842819A1 (en) 1988-12-20 1990-06-21 Hoechst Ag METHOD FOR SEPARATING METAL-ORGANIC COMPOUNDS AND / OR METAL-CARBONYLES FROM THEIR SOLUTIONS IN ORGANIC MEDIA
US5067970A (en) 1990-05-11 1991-11-26 W. R. Grace & Co.-Conn. Asymmetric polyimide membranes
CA2052982A1 (en) * 1990-10-31 1991-12-28 Imperial Oil Reverse osmosis process for recovery of c3-c6 aliphatic hydrocarbon from oil
US5288818A (en) 1991-08-20 1994-02-22 Exxon Chemical Patents Inc. Method for separating a water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
US5215667A (en) 1991-08-20 1993-06-01 Exxon Chemical Patents Inc. Method for separating water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
US5395979A (en) 1993-02-25 1995-03-07 Exxon Chemical Patents Inc. Method for separating catalyst from a hydroformylation reaction product using alkylated ligands
US5410012A (en) 1993-03-05 1995-04-25 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Poly(N-arylenebenzimidazoles) via aromatic nucleophilic displacement
US5298669A (en) 1993-03-23 1994-03-29 Exxon Chemical Patent Inc. Perstraction sweep stream for a membrane reactor
US5264166A (en) 1993-04-23 1993-11-23 W. R. Grace & Co.-Conn. Polyimide membrane for separation of solvents from lube oil
US5360530A (en) 1993-04-23 1994-11-01 Mobil Oil Corporation Lubricating oil dewaxing using membrane separation of cold solvent from dewaxed oil and recycle of cold solvent to filter feed
US5494566A (en) 1994-05-26 1996-02-27 Mobil Oil Corporation Lubricating oil dewaxing with membrane separation of cold solvent
US5651877A (en) 1996-04-16 1997-07-29 Mobil Oil Corporation Lubricating oil dewaxing with membrane separation
US6180008B1 (en) 1998-07-30 2001-01-30 W. R. Grace & Co.-Conn. Polyimide membranes for hyperfiltration recovery of aromatic solvents
CA2300519C (en) * 1999-03-19 2008-02-12 Bend Research, Inc. Solvent-resistant microporous polybenzimidazole membranes
US6623639B2 (en) * 1999-03-19 2003-09-23 Bend Research, Inc. Solvent-resistant microporous polybenzimidazole membranes
US6503295B1 (en) 2000-09-20 2003-01-07 Chevron U.S.A. Inc. Gas separations using mixed matrix membranes
GB2369311B (en) 2000-11-24 2002-12-11 Membrane Extraction Tech Ltd Separating phase transfer agents
GB2373743B (en) 2001-03-27 2004-11-03 Membrane Extraction Tech Ltd Solvent exchange process
US20030131731A1 (en) 2001-12-20 2003-07-17 Koros William J. Crosslinked and crosslinkable hollow fiber mixed matrix membrane and method of making same
DE10239701A1 (en) 2002-08-29 2004-03-11 Celanese Ventures Gmbh Production of polymer membrane, used in membrane electrode unit for fuel cell, uses phosphorus and/or sulfur oxy-acid in liquid for hydrolyzing membrane made by heating mixture of polyphosphoric acid and polyazole or precursors
US7604129B2 (en) * 2002-10-03 2009-10-20 The Regents of the Univeristy of Colorado, a body corporate Lyotropic liquid crystal nanofiltration membranes
GB0229423D0 (en) 2002-12-18 2003-01-22 Avecia Ltd Process
DE102004008628A1 (en) * 2004-02-21 2005-09-08 Celanese Ventures Gmbh High performance membrane electrode assembly and its application in fuel cells
WO2006009520A1 (en) * 2004-07-20 2006-01-26 National University Of Singapore Polyimide membranes
KR20080003789A (en) 2005-03-09 2008-01-08 더 리전츠 오브 더 유니버시티 오브 캘리포니아 Nanocomposite membranes and methods of making and using same
GB2437519B (en) 2006-04-28 2010-04-21 Imp Innovations Ltd Method for separation
US20080143014A1 (en) * 2006-12-18 2008-06-19 Man-Wing Tang Asymmetric Gas Separation Membranes with Superior Capabilities for Gas Separation
US20100244306A1 (en) 2006-12-18 2010-09-30 Uop Llc Asymmetric gas separation membranes with superior capabilities for gas separation
US20090126566A1 (en) * 2007-11-15 2009-05-21 Chunqing Liu Polymer Functionalized Molecular Sieve/Polymer Mixed Matrix Membranes
CN102186565A (en) * 2008-10-15 2011-09-14 新加坡国立大学 Dual-layer hollow fibers with enhanced flux as forward osmosis membranes for water reuses and protein enrichment
WO2010077876A2 (en) * 2008-12-16 2010-07-08 National University Of Singapore Chemically-modified polybenzimidazole membranous tubes
GB201012080D0 (en) 2010-07-19 2010-09-01 Imp Innovations Ltd Asymmetric membranes for use in nanofiltration

Also Published As

Publication number Publication date
MX2013000770A (en) 2013-07-05
BR112013001380B8 (en) 2022-08-02
US10328396B2 (en) 2019-06-25
CN103079685B (en) 2016-03-30
ES2870873T3 (en) 2021-10-27
CL2013000167A1 (en) 2013-12-06
KR102101707B1 (en) 2020-04-20
JP2013532578A (en) 2013-08-19
EP2595733A1 (en) 2013-05-29
UA115963C2 (en) 2018-01-25
US20130118983A1 (en) 2013-05-16
CN103079685A (en) 2013-05-01
CA2805780A1 (en) 2012-01-26
EP2595733B1 (en) 2021-04-14
US20170165614A1 (en) 2017-06-15
SG187556A1 (en) 2013-03-28
KR20140085372A (en) 2014-07-07
AU2011281326B2 (en) 2015-03-26
CA2805780C (en) 2021-08-10
EA027868B1 (en) 2017-09-29
GB201012080D0 (en) 2010-09-01
JP6055406B2 (en) 2016-12-27
IL224282B (en) 2018-01-31
WO2012010886A1 (en) 2012-01-26
AU2011281326A1 (en) 2013-02-21
MY171822A (en) 2019-10-31
BR112013001380B1 (en) 2021-01-12
BR112013001380A2 (en) 2016-05-17

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