EA200101024A1 - CATALYTIC COMPOSITIONS ON SUBSTRATES FOR POLYMERIZATION OF OLEFINS WITH ACTIVITY DELAYS, METHOD OF THEIR PREPARATION AND THEIR APPLICATION - Google Patents

CATALYTIC COMPOSITIONS ON SUBSTRATES FOR POLYMERIZATION OF OLEFINS WITH ACTIVITY DELAYS, METHOD OF THEIR PREPARATION AND THEIR APPLICATION

Info

Publication number
EA200101024A1
EA200101024A1 EA200101024A EA200101024A EA200101024A1 EA 200101024 A1 EA200101024 A1 EA 200101024A1 EA 200101024 A EA200101024 A EA 200101024A EA 200101024 A EA200101024 A EA 200101024A EA 200101024 A1 EA200101024 A1 EA 200101024A1
Authority
EA
Eurasian Patent Office
Prior art keywords
application
preparation
olefins
polymerization
substrates
Prior art date
Application number
EA200101024A
Other languages
Russian (ru)
Other versions
EA004472B1 (en
Inventor
Эдмунд М. Карнахан
Дейвид Р. Нейтхамер
Рави Б. Шанкар
Original Assignee
Бп Кемикэлз Лимитед
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Бп Кемикэлз Лимитед filed Critical Бп Кемикэлз Лимитед
Publication of EA200101024A1 publication Critical patent/EA200101024A1/en
Publication of EA004472B1 publication Critical patent/EA004472B1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

В заявке описаны катализатор на подложке и способы его приготовления и его применение, которые характеризуются применением металлорганических катализаторов с элементами группы с 4 по 10 со специально подобранными диенами, которые, когда их объединяют с сокатализатором, образуют катализатор на подложке, демонстрирующий в процессе газофазной полимеризации улучшенный кинетический профиль.Отчет о международном поиске был опубликован 2001.04.05.The application describes a catalyst on a substrate and methods for its preparation and its application, which are characterized by the use of organometallic catalysts with elements of groups 4 to 10 with specially selected dienes, which, when combined with a cocatalyst, form a catalyst on the substrate, demonstrating improved gas-phase polymerization kinetic profile. The international search report was published on 2001.04.05.

EA200101024A 1999-04-20 2000-03-28 Delayed activity supported olefin polymerization catalyst compositions and method for making and using the same EA004472B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13016699P 1999-04-20 1999-04-20
PCT/US2000/008198 WO2000063262A2 (en) 1999-04-20 2000-03-28 Delayed activity supported olefin polymerization catalyst compositions and method for making and using the same

Publications (2)

Publication Number Publication Date
EA200101024A1 true EA200101024A1 (en) 2002-04-25
EA004472B1 EA004472B1 (en) 2004-04-29

Family

ID=22443365

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200101024A EA004472B1 (en) 1999-04-20 2000-03-28 Delayed activity supported olefin polymerization catalyst compositions and method for making and using the same

Country Status (15)

Country Link
US (2) US20020160907A1 (en)
EP (1) EP1230279A2 (en)
JP (1) JP2002542348A (en)
KR (1) KR20010110790A (en)
CN (1) CN1357012A (en)
AR (1) AR023575A1 (en)
AU (1) AU4038100A (en)
BR (1) BR0009878A (en)
CA (1) CA2370281A1 (en)
EA (1) EA004472B1 (en)
EG (1) EG22010A (en)
NO (1) NO20015110L (en)
TW (1) TW574227B (en)
WO (1) WO2000063262A2 (en)
ZA (1) ZA200002016B (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EA004472B1 (en) 1999-04-20 2004-04-29 Бп Кемикэлз Лимитед Delayed activity supported olefin polymerization catalyst compositions and method for making and using the same
EP1930348A1 (en) * 2006-12-05 2008-06-11 Ineos Manufacturing France SAS Supported catalyst system
KR20170032766A (en) 2015-09-15 2017-03-23 주식회사 엘지화학 Method for oligomerization of olefins
CN112041351B (en) 2018-03-30 2023-12-29 陶氏环球技术有限责任公司 Highly soluble bis-borates as dinuclear cocatalysts for olefin polymerization
WO2019191098A1 (en) 2018-03-30 2019-10-03 Dow Global Technologies Llc Olefin polymerization activators
US11787880B2 (en) 2018-03-30 2023-10-17 Dow Global Technologies Llc Highly soluble alkyl substituted carbenium borate as co-catalysts for olefin polymerizations
JP7304880B2 (en) 2018-03-30 2023-07-07 ダウ グローバル テクノロジーズ エルエルシー Dinuclear olefin polymerization activator
KR20200138271A (en) 2018-03-30 2020-12-09 다우 글로벌 테크놀로지스 엘엘씨 Olefin polymerization activator
WO2019199824A1 (en) 2018-04-12 2019-10-17 Exxonmobil Chemical Patents Inc. Heterophasic copolymers and polymerization methods
US20230151127A1 (en) * 2020-05-29 2023-05-18 Dow Global Technologies Llc Attenuated hybrid catalysts

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5272236A (en) * 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
US5470993A (en) * 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
WO1995000526A1 (en) * 1993-06-24 1995-01-05 The Dow Chemical Company Titanium(ii) or zirconium(ii) complexes and addition polymerization catalysts therefrom
US5486632A (en) * 1994-06-28 1996-01-23 The Dow Chemical Company Group 4 metal diene complexes and addition polymerization catalysts therefrom
JPH11503113A (en) * 1995-03-10 1999-03-23 ザ ダウ ケミカル カンパニー Supported catalyst component, supported catalyst, production method, polymerization method, complex compound, and production method thereof
US6268444B1 (en) * 1996-08-08 2001-07-31 Dow Chemical Company 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process
CN1192033C (en) * 1998-10-08 2005-03-09 陶氏化学公司 Bridged metal complexes
EA004472B1 (en) 1999-04-20 2004-04-29 Бп Кемикэлз Лимитед Delayed activity supported olefin polymerization catalyst compositions and method for making and using the same

Also Published As

Publication number Publication date
AR023575A1 (en) 2002-09-04
BR0009878A (en) 2002-10-15
WO2000063262A2 (en) 2000-10-26
US20040235646A1 (en) 2004-11-25
ZA200002016B (en) 2001-10-22
NO20015110L (en) 2001-12-04
US7012121B2 (en) 2006-03-14
CA2370281A1 (en) 2000-10-26
EP1230279A2 (en) 2002-08-14
EG22010A (en) 2002-05-31
KR20010110790A (en) 2001-12-13
JP2002542348A (en) 2002-12-10
AU4038100A (en) 2000-11-02
NO20015110D0 (en) 2001-10-19
TW574227B (en) 2004-02-01
US20020160907A1 (en) 2002-10-31
EA004472B1 (en) 2004-04-29
CN1357012A (en) 2002-07-03
WO2000063262A3 (en) 2001-04-05

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Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG MD TJ TM

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): RU