EA046017B1 - HERBICIDE COMPOSITIONS - Google Patents

Description

The present invention relates to the technical field of plant protection products which can be used to control undesirable plant growth on uncultivated soils, for the preparation of seeds or in plant crops, and which as herbicidal active substances contain a combination of at least two herbicides, wherein the compositions contain herbicidal active compounds (A) and (B), where (A) means one or more compounds (A) or agrochemically acceptable salts thereof [herbicide (A) or component (A)], and (B) means one or more herbicides (component B).

Compounds from the structural class of 3-phenylisoxazoline-5-carboxamides are known as herbicides (see, for example, WO 2012/130798 A). When applied, the compounds act against a wide range of weeds in the pre-emergence as well as post-emergence period, and can be used non-selectively to control unwanted plant growth or selectively used for cultivated plants.

The effectiveness of these herbicides against weeds is at a high level, however, in general, it depends on the application rate of the corresponding form of preparation, the spectrum of weeds, the weeds treated, climate and soil conditions, etc. Another criterion is the duration of action or decay period of the herbicide. Also, if necessary, attention should be paid to changes in weed susceptibility, which may occur with longer use of the herbicide or be geographically limited. The reduction in impact in individual plants can only be compensated to a limited extent by increasing herbicide application rates, for example, the selectivity of herbicides often deteriorates, or there is no improvement in impact with increasing application rates. Basically, there is a need for methods that make it possible to exert a herbicidal effect at a low consumption rate of active substances. Low application rates not only require less active ingredient to be used, but also usually reduce the amount of formulation excipients needed. Both reduce economic costs and increase environmental tolerance of herbicide treatments.

An opportunity to improve the application profile of a herbicide may be to combine the active ingredient with one or more other suitable active ingredients that have the desired additional properties. Of course, with the combined use of several active ingredients, phenomena of physical and biological incompatibility often arise, for example, insufficient stability in the co-composition, decomposition of the active ingredient or incompatibility of the active ingredients. On the contrary, what is desirable are combinations of active ingredients with a favorable action profile, high stability and a maximally unexpected enhanced synergistic effect, which makes it possible to reduce consumption rates compared to a single single exposure to the combined active ingredients.

It is an object of the present invention to provide alternative or preferred herbicidal compositions that have a good biological application profile and, if possible, possess several of the above-mentioned beneficial properties.

Surprisingly, it has been found that this problem can be achieved by using a composition containing herbicidal compounds (A) and (B), wherein (A) means one or more compounds (A) or agrochemically acceptable salts thereof [component (A)]. and (B) means one or more herbicides [component (B)] selected from the group of herbicidal active ingredients (B2) and (B7). The compositions according to the invention work particularly well together, for example when used to control unwanted plant growth in crops such as wheat (durum and soft wheat), corn, soybeans, sugar beets, sugar cane, cotton, rice, beans (as eg beans and broad beans), flax, barley, oats, rye, triticale, potatoes and millet (sorghum), uncultivated plants, rangeland and green space/lawn and plantation crops.

Thus, the subject of the present invention is a herbicidal composition containing herbicidal compounds (A) and (B), wherein component (A) is selected from:

A1, A2, A3, A4 and A5, or an agrochemically acceptable salt of these compounds, A1-A5 having the following definitions:

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and component (B) is selected from:

(B2.18) diflufenican, (CAS 83164-33-4), (B7.4) glufosinate, (CAS 51276-47-2), (CAS 35597-445), (CAS 77182-82-2), (CAS 70033-13-5), (B7.5) glyphosate, (CAS 1071-83-6), (CAS 69254-40-6), (CAS 34494-04-7), (CAS 38641-94-0), (CAS 40465-66-5), (CAS 39600-42-5), (CAS 70393-85-0), (CAS 81591-813).

The names of the above herbicides (common names) are presented in quotation marks with the designation Reg. CAS No. (Chemical Abstract Service Registry Number) (abbreviated as CAS). Reg. The CAS No. is a commonly used reference number which makes possible a specific arrangement of a named substance, since Reg. The CAS No. also differs between isomers, including stereoisomers, as well as salts and esters. For active ingredients that are present in different forms, the names of neutral compounds are presented in the above list accordingly. The CAS indicated in quotation marks apply to these as well as to all other known forms of the active substance. Below, only neutral compounds are named and, thus, all existing forms are listed, i.e. the specific form of the active substance is important under certain conditions, such as in the examples of the Table for biological effectiveness presented below.

The compositions according to the invention may contain other components, for example, other active substances against harmful organisms such as weeds, animals harmful to plants or fungi harmful to plants, in particular active substances from the group of herbicides, fungicides, insecticides, acaricides, nematicides and miticides and related substances, or also active ingredients of other types of plant protection products (for example, resistance inducers), plant growth regulators and/or additives and/or formulation auxiliaries customary for plant protection. In this case, the components are combined together (finished formulations) and used, or they can be prepared separately and used together, for example, by mixing in containers or sequential application.

The individual herbicidal active substances contained as component (A) are hereinafter referred to as compounds (A), active substances (A), components (A) or herbicides (A). Accordingly, the individual herbicidal active ingredients contained as component (B) are also referred to as compounds (B), active ingredients (B), components (B) or herbicides (B).

A preferred property of the combination of herbicides (A) and (B) according to the invention is that the active substances (A) and (B) are compatible with each other, i.e. they can be used together, there is no noticeable chemical incompatibility of the active substances (A) and/or (B), which leads to the decomposition of one or more active substances. In this way, a decrease in the content of the active substance in the composition or spray liquid is prevented. Good compatibility

- 2 046017 also affects the biological properties of active ingredients when used in combination. Thus, antagonistic effects are generally not observed in controlled weeds with combinations of active ingredients. The active substances (A) and (B) are therefore particularly suitable for use together or in addition to other plant protection products or agrochemicals. Possible combined use allows the use of preferential effects, such as expanding the range of controlled or treated weeds during use, reducing the application rate of individual herbicides (A) or (B) compared to the corresponding application rates of the corresponding herbicide for a single exposure. In this way, it is possible to influence the active substances and achieve good exposure conditions for growing cultivated plants. Another advantage is that it is often possible to significantly reduce or prevent the occurrence of weed resistance to active substances by combining active substances with different mechanisms of action.

Particularly advantageously, when the active substances (A) and (B) are used in combination, superadditive (= synergistic) effects unexpectedly occur in large numbers of economically important weeds. Moreover, the effect in combination is stronger than the expected sum of the effects of the individual herbicides used. Synergistic effects allow subsequent reduction in application rates, control of a wide range of weeds and weeds, rapid onset of herbicidal action, long continuous action, improved weed control with only one or a small number of applications, as well as an extension of the possible time period of application. Also, when using the product, the amount of harmful components such as nitrogen or butyric acid and their entry into the soil are partially reduced.

The named properties and advantages are necessary for practical weed control in order to prevent the appearance of undesirable competitive plants in agricultural crops and thus quantitatively and qualitatively maintain and/or increase productivity. These new agents according to the invention are significantly superior to the technical standard for the combinations described.

Synergistic effects are observed with the combined use of active substances (A) and (B), but can also often occur with time-shifted use (splitting). It is also possible to apply herbicides (A) or (B) or the herbicide composition (A) and (B) in several portions (sequential application). For example, one or more pre-emergence applications may be followed by a post-emergence application, or an early post-emergence application may be followed by a mid or late post-emergence application. In this case, it is preferable to use the active ingredients of the corresponding combinations together or at close intervals, if necessary, in several portions. Time-staggered use of the individual active ingredients of the combination is also possible and may be preferable in individual cases. It is also possible to introduce other plant protection agents into the application system, such as the other active substances mentioned (other herbicides, fungicides, insecticides, acaricides, etc.) and/or various auxiliary substances, stimulants and/or fertilizers.

When used in the pre-emergence or post-emergence period, depending on where these designations are used, the application of active substances may occur before or after the emergence of weeds on the surface of the earth, or the use of active substances to control weeds may occur before or after the emergence of crop plants.

Compounds (A), depending on the type and bond of the substituents, may be present in the form of stereoisomers. For example, if one or more asymmetrically substituted carbon or sulfoxide atoms are present, enantiomers and diastereomers can occur. Stereoisomers can arise when mixtures are prepared by conventional separation methods, for example, using chromatographic separation methods. It is also possible to selectively obtain stereoisomers using stereoselective reactions using optically active starting materials and/or auxiliary substances.

The invention also applies to all stereoisomers and their mixtures; compounds (A), however, do not have a specific definition. However, below, for the sake of brevity, we speak only about compounds (A), although they can be represented both by pure compounds and, if necessary, mixtures with various components of isomeric compounds.

Depending on the type of the above-mentioned substituents, compounds (A) have acidic properties and, together with inorganic or organic bases or metal ions, can also, if necessary, form internal salts or adducts. If compounds (A) contain hydroxy, carboxy or other groups that induce acidic properties, then these compounds can be converted by bases into salts. Suitable bases are, for example, hydroxides, carbonates, bicarbonates of alkali and alkaline earth metals, especially sodium, potassium, magnesium and calcium, also ammonia, primary, secondary and tertiary amines with (C ₁ -C ₄ -)-alkyl groups, mono-, di- and trialkanolamines (C ₁ -C ₄ )-alkanols, choline and chlorocholine, as well as organic amines such as trialkylamines, morpholine, piperidine or pyridine. These salts are compounds in which the acidic hydrogen is replaced by an agriculturally suitable cation, such as metal salts, in particular

- 3 046017 sti, alkali metal salts or alkaline earth metal salts, in particular sodium and potassium salts, or also ammonium salts, salts with organic amines or quaternary ammonium salts, for example with cations of the formula [NRR'RR'], where RR' respectively, independently of each other, represent an organic radical, in particular alkyl, aryl, arylalkyl or alkylaryl. Also taken into account are alkylsulfonium and alkylsulfoxonium salts, such as (C ₁ -C ₄ )trialkylsulfonium and (C1-C ₄ )-trialkylsulfonium salts.

Compound (A) during the addition of suitable inorganic or organic acids, such as, for example, mineral acids, such as HCl, HBr, H2SO4, H3PO4 or HNO3, or organic acids, such as carboxylic acids, such as formic acid , acetic acid, propionic acid, oxalic acid, lactic or salicylic acid, or sulfonic acids, such as p-toluenesulfonic acid, can form salts to an alkaline group, such as amino, alkylamino, dialkylamino, piperidino, morpholino or pyridino. These salts contain the conjugate base of the acid as an anion.

Suitable substituents that are present in deprotonated form, such as sulfonic acids or carboxylic acids, can form internal salts with groups that are protonated on their part, such as amino groups.

If a group is substituted several times by residues, it means that the group is substituted by one or more of the same or different residues mentioned.

Table 1b

Names according to IUPAC nomenclature, as well as structural formulas of compounds (A) (herbicide (A))

Connection No. IUPAC name Structural formula A1 (58)-3-(3,5-difluorophenyl)-M- [rel-(3R,5R)-5- (trifluoromethylsulfonylcarba moyl)tetrahydrofuran-3-yl]5-vinyl-4H-isoxazole-5 carboxamide ⁰ G NQ 1 yuDlG ¹¹ F -0 0 F ^H d% F F rel-(3R,5R) A2 (5R)-3 -(3,5 - difluorophenyl)-5 methyl l-N- [gel -(3 R, 5R)- 5 (methylsulfonylcarbamoyl)tetrahydrofuran-3-yl]-4Nizoxazol-5-carboxamide / " '' 7=° IZ -0 ⁴ o :ω

F

rel-(3R,5R) AZ (5 S)-3 -(3-fluoro-5-methyl(j)eHwi)-N-[rel-(3R,5R)-5(methoxycarbamoyl)tetrahydrofuran-3-yl]-5-vinyl-4Nizoxazol- 5-carboxamide o 0 Г°\^° Η N. _ο Tj ii ⁿ ° rel-(3R,5R) A4 (5 S)-3-(3,5-difluorophenyl)-M- [(3R)-5- (methyl sulfonylcarbamoyl)2,3-dihydro-3-yl]-5-VINYL-4Nisoxazole-5-carboxamide 0 I fV Yji ii ^H o ^§ o F A5 (5R)-3 -(3,5-difluorophenyl)-M[(3R)-5-(MeTOKCHKap6aMOHii)2,3-dihydro-3-yl]-5 -methyl-4Nisoxazole-5-carboxamide ⁰ /-H n rV'N'O'-f ^F Tji ' ^{n y} '° F

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The designation rel-(2R,4R) follows the IUPAC nomenclature and means that both cis-configurations of substituents are in the 2- and 4-positions.

In table 1b the compounds are represented by the chemical formulas of the main component, this component being present in chemical purity, preferably at least 95% by weight of the compound. Naturally, it is also possible to use compounds of lower purity. In particular, if the side components of the compounds consist predominantly or almost entirely of stereoisomers of the corresponding compounds (A), they are effectively used. Therefore, preferred herbicides (A) are also mixtures of two or more compounds (A) according to the invention.

If in the table 1b the stereochemical orientation is on the C-atom, then the main components of the compound mean a stereoisomer or stereoisomeric mixture, which on the said C-atom has an R or S configuration.

If the stereochemistry is not determined, then it is a racemate. If several stereocenters are present and, accordingly, the configurations are designated R or S, then they mean compounds with the named stereochemistry at the designated centers.

If R or S configurations are not indicated at several centers, then racemic mixtures are meant, i.e. The mirror stereoisomers present in them (enantiomers from a pair of enantiomers) are present in the mixture in equal proportions. If not indicated in more detail, then in table. 1b, racemic compounds (A) with several stereocenters contain diastereomeric components in approximately equal proportions. However, in practical applications, racemic compounds with several stereocenters are encountered, a mixture of diastereomers with varying numbers of diastereomeric components.

Preference is also given to the respectively mentioned compounds with a stereochemical purity of 60-100%, preferably 70-100%, particularly preferably 80-100%.

The named mixtures of stereoisomeric compounds (A) are also preferred.

Compounds (A) are known from a previously unpublished patent application under document number PCT/EP2018/065333 and can be prepared using the methods described there.

The consumption rate of the herbicide (A) lies in the range of 0.01-2000 g of active substance per hectare (hereinafter g a.i./ha), preferably 0.02-1000 g a.i./ha, especially preferably 0.5- 750 g a.i./ha). In the combinations according to the invention, within the stated application rates, compared to a single application, a lower application rate of the corresponding active substance is most often required, preferably 0.01-1000 g a.i./ha, especially preferably 0.02-500 g a.i. ./ha, and more preferably 5250 g a.i./ha.

In principle, all active substances of subgroups (B2) and (B7) are suitable as a combining partner (B) [= component (B) or herbicide (B)], and the name of the herbicidal active substance then goes under the general name (in English spelling) according to The Pesticide Manual 14th ed., British Crop Protection Council 2006, abbreviated PM or chemical name according to usual nomenclature (IUPAC or Chemical Abstracts).

A particularly preferred active ingredient (B7) is (B 7.5) glyphosate and certain binary compositions containing (A) one or more herbicidal compounds (A) or their agrochemically acceptable salts [herbicide (A)], as well as one herbicide (B) unexpectedly turned out to be especially useful. Preferred, especially preferred and most preferred binary systems are listed below as additional embodiments of the present invention.

Particularly preferably, the compositions in the sense of the present invention are compositions as indicated in table. 2.1-2.5 below:

Table 2.1

Particularly preferred binary compositions containing (A1)

Binary composition Connection (A) Connection (B) Z3 A1 (Q2.18) Z20 A1 (Q7.5)

Table 2.2

Particularly preferred binary compositions containing (A2)

Binary composition Connection (A) Connection (B) Z32 A2 (Q2.18) Z49 A2 (Q7.5)

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Table 2.3

Particularly preferred binary compositions containing (A3)

Binary composition Connection(A) Connection (B) Z61 AZ (Q2.18) Z78 AZ (Q7.5)

Table 2.4

Particularly preferred binary compositions containing (A4)

Binary composition Connection(A) Connection (B) Z90 A4 (Q2.18) Z107 A4 (Q7.5)

Table 2.5

Particularly preferred binary compositions containing (A5)

Binary composition Connection (A) Connection (B) Z119 A5 (Q2.18) Z136 A5 (Q7.5)

Further, the combinations according to the invention can be used together with other active ingredients, such as the active ingredients mentioned above (herbicides, fungicides, insecticides, acaricides, etc.) and/or plant growth regulators or auxiliary substances from the group of additives commonly used for plant protection, such as stimulants and formulation excipients. Combinations of active ingredients of plant protection products that contain active ingredients (A) and (B) and, if necessary, other active ingredients are abbreviated as herbicidal combinations. Their forms of application, such as formulations or mixing in containers, constitute a herbicidal agent (composition).

The invention therefore also covers herbicidal preparations which contain combinations of the active substances according to the invention with additives customary for plant protection, such as stimulants and formulation auxiliaries, and, if appropriate, other active substances of plant protection agents.

The subject of the invention is also a use or method of use using a combination of active ingredients according to the invention as herbicides and plant growth regulators, preferably as herbicides and plant growth regulators with a synergistically active content of the corresponding combination of active ingredients.

The consumption rates of the herbicide (B) are, in principle, known and, as a rule, are in the range of 0.014000 g a.i./ha, mainly in the range of 0.02-2000 g a.i./ha, in particular 1 -2000 g a.i./ha.

In the mixtures according to the invention, within the mentioned application rates, lower application rates of the corresponding active substance are generally required compared to individual applications.

For active substances from group (B2), the application rate is preferably in the range of 1-4000 g a.i./ha, in particular in the range of 1-2000 g a.i./ha, and most preferably in the range of 1-400 g a.i./ha.

For the active substance from group (B7), the application rate is preferably in the range of 20-3500 g a.i./ha, in particular in the range of 20-2500 g a.i./ha, and most preferably in the range of 20-2000 g a.i./ha.

The ratio of components (A):(B) in terms of mass is, as a rule, depending on the current consumption rate, in the range 1:100000-2000:1, preferably 1:40000-750:1, in particular in the range 1: 15000-500:1 and even more preferably in the range of 1:300-400:1.

For active substances from groups (B2) (B7), the preferred mass ratio (A):(B) is:

(A):(B2) preferably in the range 400:1-1:400, in particular 200:1-1:200;

(A):(B7) preferably in the range of 10:1-1:200, in particular 1:1-1:100.

The herbicidal compositions according to the invention can also be combined with other herbicides and plant growth regulators, for example, to broaden the spectrum of action. As combining partners for the compounds according to the invention in mixed formulations or when mixing in containers, for example, known active substances are used, which are based, for example, on the inhibition of, for example, the enzyme acetolactate synthase, acetyl-CoA carboxylase, cellulose synthase, enolpyruvate-3- phosphate synthase, glutamine synthase, p-hydroxyphenylpyruvate dioxygenase, phytoene desaturase, photosystem I, photosystem II, protoporphyrinogen oxidase, as described, for example, in Weed Research 26 (1986) 441-445 or The Pesticide Manual, 14th ed., The British

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Crop Protection Council and the Royal Soc. of Chemistry, 2006, the corresponding e-Pesticide Manual Version 4 (2006) and the literature referenced therein. Other trade names and common names are listed in the Compendium of Pesticide Common Names (found online at http://www.alanwood.net/pesticides).

Known herbicides which can be combined with the compounds according to the invention include, for example, the following active substances (note: compounds which are either known by a generic name according to the International Organization for Standardization (ISO) or by a chemical name, if appropriate, together with the usual code number) and which contain all forms of application such as acids, salts, esters and isomers such as stereoisomers and optical isomers. In this case, some other forms of application should also be named: 2,4-D, acetochlor, acifluorfen, acifluorfen sodium, aclonifen, alachlor, alloxydim, alloxydim sodium, ametrine, amicarbazone, amidosulfuron, amitrol, anilofos, asulam, atrazine, azaphenidine , azimsulfuron, betflubutamide, benazoline, benazolin-ethyl, benfuresate, bensulfuron-methyl, bentazone, benzfendizone, benzobicyclone, benzofenap, bifenox, bilanafos, bispiribac-sodium, bromacil, bromobutide, bromophenoxime, bromoxynil, butachlor, butafenacil, butenachlor , butralin, butroxydim , Butyute, cafenstrol, carbetamide, Carpentrazone-ethyl, chlometoxifen, chloridazone, chlorimuron-ethyl, chlornitrophen, chlortoluron, chlorusulfuron, cynodon-ethyl, zinmetilin, tsinosulfuron, clothoxyim, tactine, clomeson, clomoprop, clipperoprop, clipperlide Methyl , cumyluron, cyanazine, cyclosulfamuron, cycloxydim, cyhalofop-butyl, desmedipham, dicamba, dichlobenil, dichlorprop, dichlorprop-R, diclofop-methyl, diclosulam, difenzoquat, diflufenican, diflufenzopyr, dikegulac-sodium, dimefuron, dimepiperate, dimethachlor, dimethamethrin , dimethenamid , triaziflam, diquat dibromide, dithiopyr, diuron, dimron, EPTS, esprocarb, ethalfluralin, etamethsulfuron-methyl, ethoxyphene, ethoxysulfuron, etobenzanide, fenoxaprop-ethyl, fenoxaprop-R-ethyl, fentrazamide, flamprop-Misopropyl, flamprop-M-methyl, flazasulfuron , florasulam, fluazifop, fluazifop-butyl, fluazifopbutyl, fluazolate, flucarbazone-sodium, flucetosulfuron, fluchloralin, flufenacet, flufenpyr, flumetsulam, flumiclorac-pentyl, flumioxazin, fluometkron, fluorochloridone, fluoroglycophen-ethyl, flupoxam , flupirsulfuron-methyl-sodium, fluridone , fluoroxypier, fluoxipir-butoxypropil, fluxipir-methyl, fluurpimidol, flurtamon, fluiazet-methyl, Fomesaphen, foramsulfuron, glucosinate, glucosinat-ammonium, glyphosate, halosfuron-methyl, galloxyphop-ethoxiep Methyl, haloxifop-r-methyl , hexazinone, imazamethabenz-methyl, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, indanofan, iodosulfuron-methyl-sodium, ioxynil, isoproturon, isouron, isoxaben, isoxachlortol, isoxaflutole, ketospiradox, lactofen, lenacyl, linuron, MCPA, mecoprop , mecoprop-R, mefenacet, mesosulfuron-methyl, mesotrione, metamifop, metamitron, metazachlor, metabenzathiazuron, methyldimron, metobromuron, metolachlor, methosulam, methoxuron, metribuzin, metsulfuron-methyl, molinate, monolinuron, naproanilide, napropamide, neburon, nicosulfuron, norflurazon , orbencarb, oryzalin, oxadiargyl, oxadiazone, oxasulfuron, oxaziclomefon, oxyfluorfen, paraquat, pelargonic acid, pendimethalin, pendralin, pentoxazone, petoxamide, phenmedipham, picloram, picolinafen, pinoxaden, piperophos, pretilachlor, primisulfuronmethyl, profluazole, profoxide im, prometrin, propachlor, propanil, propaquizafop quizafop, propisochlor, propoxycarbazone sodium, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyrafluphenethyl, pyrazolate, pyrazosulfuron-ethyl, pyrazoxifene, pyribenzoxime, pyributicarb, pyridafol, pyridate, pyrifthalide, pyriminobac-methyl, pyrithiobac-sodium , hinclorak, hinmerak , quinoclamine, hisalofop-ethyl, hisalofop-R-ethyl, hisalofop-R-tefuryl, rimsulfuron, sethoxydim, simazine, symetrine, Smetolachlor, sulcotrione, sulfentrazone, sulfometuron-methyl, sulfosate, sulfosulfuron, tebuthiuron, tepraloxydim, terbutylazine, terbu trin, tenylchlor , thiazopyr, thifensulfuron-methyl, thiobencarb, thiocarbazyl, tralkoxydim, triallate, triasulfuron, tribenuron-methyl, triclopyr, tridifan, trifloxysulfuron, trifluralin, triflusulfuron-methyl, tritosulfuron, WL 110547, i.e. 5-phenoxy-1[3-(trifluoromethyl)phenyl]-III-tetrazole; NOK-201, NOK-202, UBH-509; D-489; LS 82-556; KPP-300; NC324; NC-330; KH-218; DPX-N8189; SC-0774; TH-547, DOWCO-535; DK-8910; V-53482; PP-600; MVN-001; KIH-9201; ET-751; KIH-6127; KIH-2023 and KIH5996.

If the corresponding name (generic name) contains several forms of active substances, then the trade designation is preferably indicated with the name.

Each of the additional named active substances (= active substances (C*), (C1*), (C2*), etc.) can then advantageously be combined with one of the paired combinations according to the present invention, according to scheme (A)+ (B)+(C*) or also according to the scheme (A)+(B)+(C1*)+(C2*), etc.

Quantity indications are application rates (g a.i./ha = grams of active substance per hectare) and thus determine the ratio of components in a co-formulation, pre-mix, container mixing or sequential application of combined active substances.

Combinations can be used in both pre-emergence and post-emergence methods. This applies to both the pre- and post-emergence period, from the point of view of weed control.

- 7 046017 plants, and for selective control of weeds in relation to the pre- or post-emergence period of cultivated plants. Mixed forms are also taken into account, for example during the post-emergence period of cultivated plants to control weeds in their pre- or post-emergence period.

The herbicidal combinations according to the invention may contain other components, for example, other active substances against harmful organisms such as weeds, animals harmful to plants or fungi harmful to plants, in particular active substances from the group of herbicides, fungicides, insecticides, acaricides, nematicides, miticides and related substances.

The fungicidal compounds that can be used in conjunction with the herbicidal combinations according to the invention are preferably conventional active ingredients, for example (like herbicides, the compounds are generally represented by their generic names, the usual English spelling):

1) inhibitors of ergosterol biosynthesis: for example, (1.001) cyproconazole, (1.002) difenoconazole, (1.003) epoxiconazole, (1.004) fenhexamide, (1.005) fenpropidine, (1.006) fenpropimorph, (1.007) fenpyrazamine, (1.008) fluquinconazole, (1.009 ) flutriafol, (1.010) imazalil, (1.011) imazalil sulfate, (1.012) ipconazole, (1.013) metconazole, (1.014) myclobutanil, (1.015) paclobutrazol, (1.016) prochloraz, (1.017) propiconazole, (1.018) prothioc onazole, ( 1.019) pyrizoxazole, (1.020) pyroxamine, (1.021) tebuconazole, (1.022) tetraconazole, (1.023) triadimenol, (1.024) tridemorph, (1.025) triticonazole, (1.026) (^^^)-5-(4-chlorobenzyl) -2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol, (1.027) (^^^)-5-(4-chlorobenzyl)-2-( chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1 ylmethyl)cyclopentanol, (1.028) (2R)-2-(1-chlorocyclopropyl)-4-[(1R)-2,2 -dichlorocyclopropyl]-1-(1H1,2,4-triazol-1-yl)butan-2-ol (1.029) (2R)-2-(1-chlorocyclopropyl)-4-[(1S)-2,2- dichlorocyclopropyl]-1(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.030) (2R)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl] -1-(1H1,2,4-triazol-1-yl)propan-2-ol, (1.031)^)-2-(1-chlorocyclopropyl)-4-[(^)-2,2-dichlorocyclopropyl]- 1(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.032)^)-2-(1-chlorocyclopropyl)-4-[(^)-2,2-dichlorocyclopropyl]1 -(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.033)^)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-( 1H1,2,4-triazol-1-yl)propan-2-ol, (1.034)^)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2 -oxazol-4yl] (pyridin-3 -yl)methanol, yl] (pyridin-3 -yl)methanol, yl] (pyridin-3 -yl)methanol, (1.035) (1.036) (1.037)

^)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4[3-(4-chloro-2-fluorophenyl)-5-(2 ,4-difluorophenyl)-1,2-oxazole-41-({(2R,4S)-2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-1,3, (1.038) 1-({^^)-2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4dioxolan-2-yl}methyl)-1H-1,2,4-triazole, methyl-1,3- dioxolan-2-yl}methyl)-1H-1,2,4-triazole, (1.039) difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl-thiocyanate,

1-{[3-(2-chlorophenyl)-2-(2,4(1.040) 1-{[rel(2R,3R)-3-(2chlorophenyl)-2-(2,4-difluorophenyl)oxirane-2 -yl]methyl}-1H-1,2,4-triazol-5-yl-thiocyanate, (1.041) 1{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4- difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl-thiocyanate, (1.042) 2-[(2R,4R,5R)-1-(2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptαn-4-yl]-2,4-dihydro-3H-1,2,4triazol-3-thione, (1.043) 2-[(2R,4R,5S)- 1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4dihydro-3H-1,2,4-triazol-3-thione, (1.044)

2-[(2R,4S,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6 trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4 -triazol-3-thione, (1.045) 2-[(2R,4S,5S)-1-(2,4-dichlorophenyl)-5hydroxy-2,6,6-trimethylheptan-4-yl]-2,4- dihydro-3H-1,2,4-triazole-3-thione, (1.046) 2-[(2S,4R,5R)-1-(2,4dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptane- 4-yl]-2,4-dihydro-3H-1,2,4-triazol-3-thione, (1.047) 2[^^^)-1-(2,4-dichlorophenyl)-5-hydroxy-2 ,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazol-3thione, (1.048) 2-[(^^.5L)-1-(2.4-dichlorophenyl) -5-hydroxy-2.6.6-trimethylheptan-4-yl|-2.4-dihydro-3H1,2,4-triazol-3-thione, (1.049) 2-[^^^)-1-(2,4- dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]2,4-dihydro-3H-1,2,4-triazol-3-thione, (1.050) 2-[1-(2, 4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4yl]-2,4-dihydro-3H-1,2,4-triazol-3-thione, (1.051) 2-[2-chloro- 4-(2,4-dichlorophenoxy)phenyl]-1-(1H-1,2,4triazol-1-yl)propan-2-ol, (1.052) 2-[2-chloro-4-(4-chlorophenoxy) phenyl]-1-(1H-1,2,4-triazol-1-yl)butan-2ol, (1.053) 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H -1,2,4-triazol-1-yl)butan-2-ol, (1.054) 2[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4 -triazol-1-yl)pentap-2-ol, (1.055)chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1.056)

2-[4-(42-{[3-(2chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazol- 3-thione, (1.057) 2{[rel(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H -1,2,4-triazol-3thione, (1.058) 2-{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl} -2,4-dihydro-3H1,2,4-triazol-3-thione, (1.059) 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4 -triazol-1-ylmethyl)cyclopentanol, (1.060) yl]methyl}-1H-1,2,4-triazole,

5-(allylsulfanyl)-1-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxirane-2(1.061) 5-(allylsulfanyl)-1-{[rel(2R,3R)- 3-(2-chlorophenyl)-2-(2,4 difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazole, (1.062) 5-(allylsulfanyl)-1-{[rel( 2R,3S)-3-(2chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazole, (1.063) I-(2.5-dimethyl-4 -{[3(1,1,2,2-tetrafluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimido-formamide, (1.064) N'-(2,5dimethyl-4-{[3-( 2,2,2-trifluoroethoxy)phenyl]sulfanyl}-phenyl)-N-ethyl-N-methylimidoformamide, (1.065) N-(2,5-dimethyl-4-{[3-(2,2,3,3 -tetrafluoropropoxy)phenyl]sulfanyl}phenyl)-No.ethyl-No. methylimidoformamide, (1.066) No.-(2,5-dimethyl-4-{[3-(pentafluoroethoxy)phenyl]sulfanyl}phenyl)-No.

- 8 046017 ethyl-N-methylimido formamide, (1.067)

K'-(2,5-dimethyl-4-{3-[(1,1,2,2-tetrafluoroethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamide, (1.068) No.-(2, 5-dimethyl-4-{3-[(2,2,2trifluoroethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamide, (1.069) I-(2.5-dimethyl-4-{3[(2, 2,3,3-tetrafluoropropyl)-sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamide, (1.070) N'-(2,5dimethyl-4-{3-[(pentafluoroethyl)sulfanyl]phenoxy}phenyl) -N-ethyl-N-methyl-imidoformamide, (1.071) N'(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylimidoformamide,

N-(4-{[3(1.072) (difluoromethoxy)phenyl]sulfanyl}-2,5-dimethylphenyl)-N-ethyl-N-methylimidoformamide, (1.073) N'-(4{3-[(difluoromethyl)- sulfanyl]phenoxy}-2,5-dimethylphenyl)-N-ethyl-N-methylimidoformamide, (1.074) N'[5-bromo-6-(2,3-dihydro-1H-inden-2-yloxy)-2- methylpyridin-3-yl]-N-ethyl-N-methylimidoformamide, (1.075) N-{4-[(4,5-dichloro-1,3-thiazol-2-yl)oxy]-2,5-dimethylphenyl} -N-ethyl-N-methylimidoformamide, (1.076) N-{5-bromo-6-[(^)-1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl -Nmethylimidoformamide, (1.077) N-{5-bromo-6-[(^)-1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-Nethyl-N-methylimidoformamide, (1.078 ) N-{5-bromo-6-[(cis-4-isopropylcyclohexyl)oxy]-2methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide, N-{5-bromo-6-[(trans -4(1.079) isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide, (1.080) bromo-6-[1-(3,5-difluorophenyl)ethoxy]-2-methylpyridine -3-yl}-N-ethyl-N-methylimidoformamide, mefentrifluconazole, (1.082) ipfentrifluconazole.

N'-{5(1.081)

2) Complex I or II respiratory chain inhibitors, for example, (2.001) benzovindiflupyr, (2.002) bixafen, (2.003) boscalid, (2.004) carboxin, (2.005) fluopyram, (2.006) flutolanil, (2.007) fluxapyroxad, (2.008) furamethpyr, (2.009) isofetamide, (2.010) isopyrazam (antiepimeric enantiomer 1R,4S,9S), (2.011) isopyrazam (antiepimeric enantiomer 1S,4R,9R), (2.012) isopyrazam (antiepimeric racemate 1RS,4SR,9SR), ( 2.013) isopyrase (mixture of syn-epimeric racemate 1RS,4SR,9RS and anti-epimeric racemate 1RS,4SR,9SR), (2.014) isopyrase (syn-epimeric enantiomer 1R,4S,9R), (2.015) isopyrase (syn-epimeric enantiomer 1S ,4R,9S), (2.016) isopyrazam (syn-epimeric racemate 1RS,4SR,9RS), (2.017) penflufen, (2.018) penthiopyrad, (2.019) pidiflumetofen, (2.020) pyraziflumide, (2.021) sedaxane, (2.022) 1,3-dimethyl-H-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1H-pyrazol-4-carboxamide, (2.023) carboxamide, (2.024) carboxamide, (2.025)

1,3-dimethyl-N-[(3R)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazol-41,3-dimethyl-N-[^ )-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazol-41-methyl-3-(trifluoromethyl)-H-[2'-(trifluoromethyl)biphenyl- 2-yl]-1H-pyrazol-4 carboxamide, (2.026) 2-fluoro-6-(trifluoromethyl)-H-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) benzamide, (2.027)

-(difluoromethyl)-1-methyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) - 1H-pyrazol-4 carboxamide, (2.028) 3-(difluoromethyl) -1-methyl-N-[(3R)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1Hpyrazol-4-carboxamide, (2.029) 3-(difluoromethyl)- 1-methyl-H-[^)-1,1,3-trimethyl-2,3-dihydro-1H-inden4-yl]-1H-pyrazol-4-carboxamide, (2.030) 3-(difluoromethyl)-H- (7-fluoro-1,1,3-trimethyl-2,3-dihydro-1Ninden-4-yl)-1-methyl-1H-pyrazole-4-carboxamide, (2.031) 3-(difluoromethyl)-N-[ (3R)-fluoro-1,1,3-trimethyl2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide, (2.032) 3-(difluoromethyl)-N- [(3S)-7fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazol-4-carboxamide, (2.033) 5,8difluoro-N -[2-(2-fluoro-4-{[4-(trifluoromethyl)pyridin-2-yl]oxy}phenyl)ethyl]quinazolin-4-amine, (2.034) N(2-cyclopentyl-5-fluorobenzyl)- N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4carboxamide, (2.035) N(2-tert-butyl-5-methylbenzyl)-N-cyclopropyl-3-(difluoromethyl)- 5-fluoro-1-methyl1H-pyrazole-4-carboxamide, (2.036) N(2-tert-butylbenzyl)-H-cyclopropyl-3-(difluoromethyl)-5-fluoro-1methyl-1H-pyrazole-4-carboxamide, (2.037) N(5-chloro-2-ethylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.038) N(5-chloro-2-isopropylbenzyl) )-N-cyclopropyl-3(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.039) N[(^^)-9-(dichloromethylene)-1,2,3,4tetrahydro -1,4-methanonaphthalen-5-yl]-3 -(difluoromethyl)-1 -methyl-1H-pyrazole-4-carboxamide, (2.040) N[(1S,4R)-9-(dichloromethylene)-1,2 ,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-(difluoromethyl)-1-methyl-1Hpyrazole-4-carboxamide, (2.041) methyl-1H-pyrazole-4-carboxamide,

N-[1 -(2,4-dichlorophenyl)-1-methoxypropan-2-yl]-3 -(difluoromethyl)-1 (2.042) N[2-chloro-6-(trifluoromethyl)benzyl]-N-cyclopropyl- 3(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide,

H-|3-chloro-2-fluoro-6(2.043) (trifluoromethyl)benzyl]-H-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.044) N[5-chloro-2-(trifluoromethyl)benzyl]-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1Hpyrazole-4-carboxamide, (2.045) N-cyclopropyl-3-(difluoromethyl)- 5-fluoro-1-methyl-N-[5-methyl-2(trifluoromethyl)benzyl]-1H-pyrazole-4-carboxamide, (2.046) Ncyclopropyl-3-(difluoromethyl)-5-fluoro-N(2- fluoro-6-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.047)

N-cyclopropyl-3(difluoromethyl)-5-fluoro-H-(2-isopropyl-5-methylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.048) Ncyclopropyl-3-(difluoromethyl)-5- fluoro-H-(2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carbothioamide, (2.049) Ncyclopropyl-3-(difluoromethyl)-5-fluoro-H-(2-isopropylbenzyl)-1-methyl- 1H-pyrazole-4carboxamide, (2.050) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-H-(5-fluoro-2-isopropylbenzyl)-1-methyl 1H-pyrazol-4-carboxamide, (2.051) N-cyclopropyl- 3-(difluoromethyl)-N-(2-ethyl-4,5-dimethylbenzyl)-5fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.052) Ncyclopropyl-3-(difluoromethyl)-N-(2 -ethyl-5fluorobenzyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.053) Ncyclopropyl-3-(difluoromethyl)-N-(2ethyl-5-methylbenzyl)-5-fluoro-1- methyl-1H-pyrazole-4-carboxamide, (2.054) Ncyclopropyl-N-(2

- 9 046017 cyclopropyl-5-fluorobenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.055) Ncyclopropyl-N(2-cyclopropyl-5-methylbenzyl)-3- (difluoromethyl)-5-fluoro-1-methyl-N-pyrazole-4carboxamide, (2.056) N-cyclopropyl-N-(2-cyclopropylbenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide .

3) Complex III respiratory chain inhibitors, for example, (3.001) ametoctradine, (3.002) amisulbrom, (3.003) azoxystrobin, (3.004) coumethoxystrobin, (3.005) coumoxystrobin, (3.006) cyazofamide, (3.007) dimoxystrobin, (3.008) enoxastrobin, (3.009) famoxadone, (3.010) fenamidone, (3.011) flufenoxystrobin, (3.012) fluoxastrobin, (3.013) kresoxim-methyl, (3.014) metominostrobin, (3.015) orysastrobin, (3.016) picoxystrobin, (3.017) pyraclostrobin, (3.018) ) pyramethostrobin, (3.019) pyroxystrobin, (3.020) trifloxystrobin (3.021) (2E)-2-{2-[({[(1E)-1-(3-{[(E)-1-fluoro-2-phenylvinyl] oxy}phenyl)ethylidene]amino}oxy)methyl]phenyl}-2-(methoxyimino)-Nmethylacetamide, (3.022) (2E,32)-5-{[1-(4-chlorophenyl)-III-pyrazole-3 -yl]oxy}-2-(methoxyimino)-^3-dimethylpent-3enamide, (3.023) (2R)-2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N- methylacetamide, (3.024) (2S)2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-Nmethylacetamide, (3.025) ^S^^R^R^^m^^[( {3-[(isobutyryloxy)methoxy]-4-methoxypyridin-2-yl}carbonyl)amino]-6-methyl-4,9-dioxo-1,5dioxonan-7-yl-2-methylpropanoate, (3.026) 2- {2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N methylacetamide, (3.027) N(3-ethyl-3,5,5-trimethylcyclohexyl)-3-formamido-2-hydroxybenzamide, ( 3.028) (2E,3Z)-5-{ [ 1 -(4-chloro-2-fluorophenyl)-III-pyrazol-3-yl]oxy}-2-(methoxyimino)-^3-dimethylpent-3 enamide, ( 3.029) methyl {5-[3-(2,4-dimethylphenyl)-1H-pyrazol-1-yl]-2-methylbenzyl}carbamate.

4) Inhibitors of mitosis and cell division, for example, (4.001) carbendazim, (4.002) diethofencarb, (4.003) ethaboxam, (4.004) fluopicolide, (4.005) pencicuron, (4.006) thiabendazole, (4.007) thiophanate methyl, (4.008) zoxamide, (4.009) 3-chloro-4-(2,6-difluorophenyl)-6-methyl-5-phenylpyridazine, (4.010) 3-chloro5-(4-chlorophenyl)-4-(2,6-difluorophenyl)-6- methylpyridazine, (4.011) 3-chloro-5-(6-chloropyridin-3-yl)-6methyl-4-(2,4,6-trifluorophenyl)pyridazine, (4.012) 4-(2-bromo-4-fluorophenyl) -N(2,6-difluorophenyl)-1,3dimethyl-1H-pyrazol-5-amine, (4.013) 4-(2-bromo-4-fluorophenyl)-N(2-bromo-6-fluorophenyl)-1, 3-dimethyl-1H-pyrazol-5-amine, (4.014) 4-(2-bromo-4-fluorophenyl)-N(2-bromophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.015) 4 -(2-bromo-4-fluorophenyl)-N(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.016) 4-(2bromo-4-fluorophenyl)-N (2-chlorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.017) 4-(2-bromo-4-fluorophenyl)N(2-fluorophenyl)-1,3-dimethyl-III-pyrazole -5-amine, (4.018) 4-(2-chloro-4-fluorophenyl)-N(2,6-difluorophenyl)1,3-dimethyl-N-pyrazol-5-amine, (4.019) 4-(2- chloro-4-fluorophenyl)-N(2-chloro-6-fluorophenyl)-1,3-dimethyl1H-pyrazol-5-amine, (4.020) 4-(2-chloro-4-fluorophenyl)-N(2-chlorophenyl) )-1,3-dimethyl-1H-pyrazol-5-amine, (4.021) 4-(2-chloro-4-fluorophenyl)-N(2-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5- amine, (4.022) 4-(4chlorophenyl)-5-(2,6-difluorophenyl)-3,6-dimethylpyridazine, (4.023) N(2-bromo-6-fluorophenyl)-4-(2-chloro-4fluorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine, (4.024) N(2-bromophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-III-pyrazol-5-amine , (4.025) N(4-chloro-2,6-difluorophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethylIII-pyrazol-5-amine.

5) Compounds with multisite activity, for example, (5.001) Bordeaux mixture, (5.002) captafol, (5.003) captan, (5.004) chlorothalonil, (5.005) copper hydroxide, (5.006) copper naphthenate, (5.007) copper oxide, (5.008) ) copper oxychloride, (5.009) copper(2+)-sulfate, (5.010) dithianone, (5.011) dodine, (5.012) folpet, (5.013) mancozeb, (5.014) maneb, (5.015) metriam, (5.016) zincmethiram, (5.017) copper oxine, (5.018) propineb, (5.019) sulfur and sulfur compounds including calcium polysulfide, (5.020) thiram, (5.021) zineb, (5.022) ziram, (5.023) 6-ethyl-5,7- dioxo-6,7-dihydro-5H-pyrrolo[3',4':5,6][1,4]dithiino[2,3-c][1,2]thiazole-3-carbonitrile.

6) Compounds capable of inducing immune protection, for example, (6.001) acibenzolar-methyl, (6.002) isothianyl, (6.003) probenazole, (6.004) tiadinyl.

7) Inhibitors of amino acid biosynthesis and/or protein biosynthesis, for example, (7.001) cyprodinil, (7.002) kasugamycin, (7.003) kasugamycin hydrochloride hydrate, (7.004) oxytetracycline (7.005) pyrimethanil, (7.006) 3-(5-fluoro-3 ,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl)quinoline.

8) ATP production inhibitors, for example (8.001) silthiophame.

9) Cell wall synthesis inhibitors, for example, (9.001) benthiavalicarb, (9.002) dimethomorph, (9.003) flumorph, (9.004) iprovalicarb, (9.005) mandipropamide, (9.006) pyrimorph, (9.007) valifenalate, (9.008) (2E) -3-(4-tert-butylphenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-one, (9.009) (2Z)-3 -(4-tert-butylphenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)nrop-2-en-1-one.

10) Inhibitors of lipid and membrane synthesis, for example, (10.001) propamocarb, (10.002) propamocarb hydrochloride, (10.003) tolclofos-methyl.

11) Inhibitors of melanin biosynthesis, for example, (11.001) tricyclazole, (11.002) 2,2,2-trifluoroethyl{3-methyl-1-[(4-methylbenzoyl)amino]butan-2-yl}carbamate.

12) Inhibitors of nucleic acid synthesis, for example, (12.001) benalaxyl, (12.002) benalaxylM (kyralaxyl), (12.003) metalaxyl, (12.004) metalaxyl-M (mefenoxam).

13) Signal transduction inhibitors, for example, (13.001) fludioxonil, (13.002) iprodione, (13.003) procymidone, (13.004) proquinazid, (13.005) quinoxifene, (13.006) vinclozolin.

14) Compounds that can act as uncouplers, e.g. (14.001) fluazines,

- 10 046017 (14.002) meptyldinocap.

15) Additional compounds, for example, (15.001) abscisic acid, (15.002) benthiazole, (15.003) betoxazine, (15.004) capsimycin, (15.005) carvone, (15.006) quinomethionate, (15.007) kufraneb, (15.008) cyflufenamide, (1 5.009 ) cymoxanil, (15.010) cyprosulfamide, (15.011) flutianyl, (15.012) phosetyl aluminum, (15.013) phosetyl calcium, (15.014) phosetyl sodium, (15.015) methyl isothiocyanate, (15.016) metrafenone, (15.017) mil diomycin, ( 15.018) natamycin, (15.019) nickeldimethyldithiocarbamate, (15.020) nitrotal-isopropyl, (15.021) oxamocarb, (15.022) oxathiapiproline, (15.023) oxyphenthiine, (15.024) pentachlorophenol and salts, (15.025) phosphonic acid and its salts, (15.026) propamocarb-phosetylate, (15.027) pyriophenone (chlazaphenone) (15.028) tebufloquin, (15.029) teclophthalam, (15.030) tolnifanide, (15.031) l-(4-{4-[(5R)-5-(2,6-difluorophenyl )-4,5-dihydro-1,2-oxazol-3-yl]-1,3thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazole -1-yl]ethanone, (15.032) 1-(4-{4[^)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1, 3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3(trifluoromethyl)-1H-pyrazol-1-shftanone, (15.033) 2-(6-benzylpyridin-2-yl)quinazoline , (15.034) 2,6dimethyl-1H,5H-[1,4]dithiino[2,3-с:5,6-с ^g ]dipyrrole-1,3,5,7(2H,6H)-tetron, ( 15.035) 2-[3,5-bis(difluoromethyl)-III-pyrazol-1-yl]-1-[4-(4-{5-[2-(prop-2-yn-1-yloxy)phenyl] -4,5-dihydro-1,2-oxazol3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanone, (15.036) 2-[3,5-bis(difluoromethyl)-1H -pyrazol-1-yl]-1-[4(4-{5-[2-chloro-6-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazole -3-yl}-1,3-thiazol-2-yl)piperidin-1shftanone, (15.037) 2-[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]-1-[4-( 4-{5-[2-fluoro-6-(prop-2-yn-1yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl )piperidin-1-shftanone, (15.038) 2-[6-(3fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline, (15.039) 2-{(5R)-3-[2-(1 -{[3,5bis(difluoromethyl)-1H-pyrazol-1-schfcetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5yl} -3-chlorophenyl methanesulfonate, (15.040) 2-{^)-3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1yl]acetyl}piperidin-4-yl)-1 ,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorophenyl methanesulfonate, (15.041) 2-{2-[(7,8-difluoro-2- methylquinolin-3-yl)oxy]-6-fluorophenyl}propan-2-ol, (15.042) 2-{2fluoro-6-[(8-fluoro-2-methylquinolin-3-yl)oxy]phenyl}propan-2 -ol, (15.043) 2-{3-[2-(1-{[3,5bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4 -yl]-4,5-dihydro-1,2-oxazol-5yl}-3-chlorophenyl-methanesulfonate, (15.044) 2-{3-[2-(1-{[3,5-bis(difluoromethyl)- 1H-pyrazol-1yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}phenyl methanesulfonate, (15.045) 2- phenylphenol and its salts, (15.046) 3-(4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1yl)quinoline, (15.047) 3-(4,4-difluoro-3,3 -dimethyl-3,4-dihydroisoquinolin-1-yl)quinoline, (15.048) 4-amino5-fluoropyrimidin-2-ol (tautomeric form: 4-amino-5-fluoropyrimidin-2(III)-one), (15.049) 4-oxo-4-[(2phenylethyl)amino]butyric acid, (15.050) 5-amino-1,3,4-thiadiazol-2-thiol, (15.051) 5-chloro-N'-phenylI-(prop-2 -up-1-yl)thiophene-2-sulfonohydrazide. (15.052) 5-fluoro-2-[(4-fluorobenzyl)oxy]pyrimidin-4-amine, (15.053) 5-fluoro-2-[(4-methylbenzyl)oxy]pyrimidin-4-amine, (15.054) 9-fluoro -2,2-dimethyl-5(quinolin-3-yl)-2,3-dihydro-1,4-benzoxazepine, (15.055) but-3-in-1-yl{6-[({[(2) -(1-methyl-1H-tetrazol-5yl)(phenyl)methylep]amino}oxy)methyl]pyridin-2-yl}carbamate, (15.056) ethyl (22)-3-amino-2-cyano-3phenylacrylate, ( 15.057) phenazine-1-carboxylic acid, (15.058) propyl 3,4,5-trihydroxybenzoate, (15.059) quinolin-8-ol, (15.060) quinolin-8-ol sulfate (2:1), (15.061) tert- butyl {6-[({[(1-methyl-1Htetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamate, (15.062) 5-fluoro-4-imino-3methyl -1)sulfonyl]-3,4-dihydropyrimidin-2(1H)-one.

Preferred fungicides are selected from the group consisting of benalaxyl, bitertanol, bromuconazole, captafol, carbendazim, carpropamide, cyazofamide, cyproconazole, diethofencarb, edifenphos, fenpropimorph, fentin, fluquinconazole, fosetyl, fluoroimide, folpet, iminoctadine, iprodionema, and provalicarb, kasugamycin, maneb, nabam, pencicuron, prochloraz, propamocarb, propineb, pyrimethanil, spiroxamine, quintozene, tebuconazole, tolylfluanide, triadimefon, triadimenol, trifloxystrobin, zineb.

Insecticides, acaricides, nematicides, miticides and related active substances are, for example, (by analogy with herbicides and fungicides, the compounds are, where possible, indicated by their common names, here in their usual spelling).

(1) Acetylcholinesterase (AChE) inhibitors, preferably carbamates selected from alanicarb, aldicarb, bendiocarb, benfuracarb, butocarboxyme, butoxycarboxyme, carbaryl, carbofuran, carbosulfan, etiophencarb, phenobucarb, formatenate, furatiocarb, isoprocarb, methiocarb, methomyl , metolcarb, oxamyl, pirimicarb, propoxur, thiodicarb, thiophanox, triazamate, trimetacarb, CMS and xylylcarb, or organophosphates selected from acephate, azametifos, azinphos-ethyl, azmnphos-methyl, cadusafos, chlorethoxyphos, chlorfenvinphos, chlormephos, chlorpyrifos-methyl, coumaphos, cyanophos, demeton^-methyl, diazinon, dichlorvos/DDVP, dicrotophos, dimethoate, dimethylvinphos, disulfoton, EPN, ethion, ethopros, famfour, fenamiphos, fenitrothion, fenthion, fosthiazate, heptenophos, imitsiaphos, isofenphos, isopropyl-O-(methoxyaminothiophosphoryl) salicylate, Isohation, Malation, Mekarbam, Metamidophos, Metidation, Mevinfos, Monocrotofos, Ladia, Omeetoate, Oxydemeton-Meadtila, Paration Methyl, Fentiat, Forata, Fosalon, Fosmet, Phospamidon, Foxhamiphos Methys, Prophetos, Pyracles, Rustyfosa, Rustyfos Lofos, pyridafention, quinalphos, sulfotep, tebupirimphos, temephos, terbufos, tetrachlorvinphos,

- 11 046017 thiometon, triazophos, triclorfon and vamidothione.

(2) GABA-mediated chloride channel blockers, predominantly cyclodiene organochlorins selected from chlordane and endosulfan, or phenylpyrazoles (fiproles) selected from ethiprole and fipronil.

(3) Sodium channel modulators, preferably pyrethroids selected from acrinathrin, allethrin, d-cis-trans-allethrin, d-trans-allethrin, bifenthrin, bioallethrin, bioallethrin-Bcyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin , lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(^)-trans-isomer], deltamethrin, empenthrin [(B2)-(^)- isomer], esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucitrinate, flumethrin, tau-fluvalinate, galfenprox, imiprotrin, cadetrin, momfluorothrin, permethrin, phenothrin [(^)-trans-isomer], prallethrin, pyrethrin (pyrethrum), resmethrin, silafluofen , tefluthrin, tetramethrin, tetramethrin [(^)-isomer], tralomethrin and transfluthrin, or DDT or methoxychlor.

(4) Competitive nicotinic acetylcholine receptor (nAChR) modulators, preferably neonicotinoids selected from acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam, or nicotine or sufoximine selected from sulfoxaflor, or butenolide selected from flupyradifurone.

(5) Allosteric modulators of nicotinic acetylcholine receptors (nAChRs), predominantly spinosyn, selected from spinetoram and spinosad.

(6) Allosteric modulators of glutamate-gated chloride channels (GluCl), predominantly avermectin/milbemycin, selected from abamectin, emamectin benzoate, lepimectin and milbemectin.

(7) Juvenile hormone agonists, preferably juvenile hormone analogs selected from hydroprene, kinoprene and methoprene, or fenoxycarb or pyriproxyfen.

(8) Various non-specific (multisite) inhibitors, preferably alkyl halides selected from methyl bromide and other alkyl halides, or chloropicrin, or sulfuryl fluoride, or borax, or potassium tartrate or methyl isocyanate generator, selected from diazomet and metam.

(9) Chordotonal organ TRPV channel modulators selected from pymetrozine and pyrifluquinazone.

(10) Mite growth inhibitors selected from clofentesine, hexythiazox, difluvidazine and etoxazole.

(11) Microbes that destroy the intestinal membrane of insects, selected from Bacillus thuringiensis Subspezies israelensis, Bacillus sphaericus, Bacillus thuringiensis Subspezies aizawai, Bacillus thuringiensis Subspezies kurstaki, Bacillus thuringiensis Subspezies tenebrionis, and B1.-plant proteins selected from Cry1Ab, Cry1Ac, Cry1Fa, O u1A .105, Cry2Ab, VIP3A, mCry3A, Cry3Ab, Cry3Bb and Cry34Ab1/35Ab1.

(12) Mitochondrial ATP synthase inhibitors, preferably ATP disruptors selected from diafenthiuron, or organozinc compounds selected from azocyclotine, cyhexatin and phenbutatin oxide, or propargite or tetradiphone.

(13) Uncouplers of oxidative phosphorylation by disrupting the proton gradient, selected from chlorfenapyr, DNOC and sulfuramide.

(14) A nicotinic acetylcholine receptor channel blocker selected from bensultap, cartar hydrochloride, thioclam and thiaosultap sodium.

(15) Chitin biosynthesis inhibitors, type 0, selected from bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.

(16) Chitin biosynthesis inhibitors, type 1, selected from buprofezin.

(17) Juvenile disruptors (particularly in the order Dipteren, i.e. Diptera), selected from cyromazine.

(18) Ecdysone receptor agonists selected from chromafenozide, halofenozide, methoxyfenozide and tebufenozide.

(19) Octopamine receptor agonists selected from amitraz.

(20) Mitochondrial complex-III electron transport inhibitors selected from hydramethylnon, acequinocyl, and fluacripyrim.

(21) Mitochondrial complex-1 electron transport inhibitors, predominantly METI acaricides selected from phenazaquin, fenpyroximate, pyrimidifene, pyridabene, tebufenpyrad and tolfenpyrad, or rotenone (Derris).

(22) Voltage-gated sodium channel blockers selected from indoxacarb and metaflumizone.

(23) Acetyl-CoA carboxylase inhibitors, preferably tetronic and tetramic acid derivatives, selected from spirodiclofen, spiromesifen and spirotetramate.

(24) Inhibitors of electron transport of mitochondrial complex-IV, preferably phos

- 12 046017 fins selected from aluminum, calcium phosphide, phosphine and zinc phosphide, or cyanides selected from calcium, potassium and sodium.

(25) Mitochondrial complex-II electron transport inhibitors, preferably beta-ketonitrile derivatives selected from cyanopyrafen and cyflumetofen, or carboxanilides selected from piflubumide.

(28) Ryanodine receptor modulators, predominantly diamides selected from chlorantraniliprole, cyantraniliprole, and flubendiamide.

(29) Chordotonal organ modulators (with undefined target structure) selected from flonicamid.

(30) Additional active ingredients selected from acinonapyr, afidopyropene, afoxolaner, azadirachtin, benclothiaz, benzoximate, benzpyrimoxane, biphenazate, broflanilide, bromopropylate, quinomethionate, chlorprallethrin, cryolite, cyclaniliprole, cycloxapride, cygalodiamide, dichloromesothiase, dicofol a, epsilon-metofluthrin, epsilon -momfluthrin, flometoquin, fluazaindolizine, fluensulfone, flufenerim, flufenoxystrobin, flufiprole, fluhexaphone, fluopyram, flupirimine, fluralaner, fluxamethamide, fufenozide, guadipyr, heptafluthrin, imidaclotis, iprodione, kappa-bifenthrin, kappa- tefluthrin, lotilaner, meperfluthrin, oxazosulfil, paihongding , pyridalyl, pyrifluquinazone, pyriminostrobin, spirobudiclofen, spiropidione, tetramethylfluthrin, tetraniliprole, tetrachlorantraniliprole, tigolaner, thioxazafen, thiofluoximate, triflumesopyrim and iodomethane; in addition, preparations based on Bacillus firmus (I-1582, BioNeem, Votivo), as well as the following compounds: 1-{2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl} -3-(trifluoromethyl)-1H-1,2,4-triazol-5-amine (known from WO2006/043635) (CAS 885026-50-6), (1'-[(2E)-3-(4- chlorophenyl)prop-2-en-1-yl]-5-fluorospiro[indole-3,4'piperidin]-1(2H)-yl}(2-chloropyridin-4-yl)methanone (known from WO 2003/106457 ) (CAS 637360-23-7), 2-chloro-N-[2-{1-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]piperidin-4-yl} -4(trifluoromethyl)phenyl]isonicotinamide (known from WO 2006/003494) (CAS 872999-66-1), 3-(4-chloro2,6-dimethylphenyl)-4-hydroxy-8-methoxy-1,8-diazaspiro [4.5]dec-3-en-2-one (known from WO 2010052161) (CAS 1225292-17-0), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-2-oxo-1 ,8-diazaspiro[4.5]dec3-en-4-yl-ethyl carbonate (known from EP 2647626) (CAS-1440516-42-6), 4-(but-2-yn-1-yloxy)-6-(3 ,5dimethylpiperidin-1-yl)-5-fluoropyrimidine (known from WO2004/099160) (CAS 792914-58-0), PF1364 (known from JP2010/018586) (CAS Reg. No. 1204776-60-2), (3E) -3-[1-[(6-chloro-3-pyridyl)methyl]-2pyridylidene]-1,1,1-trifluoropropan-2-one (known from WO2013/144213) (CAS 1461743-15-6), N -[3(benzylcarbamoyl)-4-chlorophenyl]-1-methyl-3-(pentafluoroethyl)-4-(trifluoromethyl)-III-pyrazole-5carboxamide (known from WO2010/051926) (CAS 1226889-14-0), 5 -bromo-4-chloro-N-[4-chloro-2-methyl-6(methylcarbamoyl)phenyl]-2-(3-chloro-2-pyridyl)pyrazole-3-carboxamide (known from CN103232431) (CAS 1449220- 44-3), 4-[5-(3,5-dichlorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N(cis-1-oxido-3-thietanyl )benzamide, 4-[5-(3,5-dichlorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3isoxazolyl]-2-methyl-N-(trans-1-oxido-3-thietanyl)benzamide and 4-[^)-5-(3,5-dichlorophenyl)-4,5dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N-(cis-1-oxido-3-thiethanyl)benzamide ( known from WO 2013/050317 A1) (CAS 1332628-83-7), K-[3-chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl]-K-ethyl-3-[(3 ,3,3trifluoropropyl)sulfinyl]propanamide, (+)-N-[3-chloro-1-(3-pyridinyl)-III-pyrazol-4-yl]-N-ethyl-3 [(3,3,3- trifluoropropyl)sulfinyl]propanamide and (-)-N-[3-chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl]-Nethyl-3-[(3,3,3-trifluoropropyl)sulfinyl] propanamide (known from WO 2013/162715 A2, WO 2013/162716 A2, US 2014/0213448 A1) (CAS 1477923-37-7), 5-[[(2E)-3-chloro-2-propen-1-yl ]amino]-1-[2,6dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-III-pyrazole-3-carbonitrile (known from CN 101337937 A) (CAS 1105672-77-2) , 3-bromo^-[4-chloro-2-methyl-6[(methylamino)thioxomethyl]phenyl]-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxamide, (liudaibenjiaxuanane, known from CN 103109816 A) (CAS 1232543-85-9); Ν-[4-χλορ-2-[[(1,1dimethylethyl)amino]carbonyl]-6-methylphenyl]-1-(3-chloro-2-pyridinyl)-3-(fluoromethoxy)-1H-pyrazole-5carboxamide ( known from WO 2012/034403 A1) (CAS 1268277-22-0), No.[2-(5-amino-1,3,4-thiadiazol-2yl)-4-chloro-6-methylphenyl]-3-bromo- 1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxamide (known from WO 2011/085575 Al) (CAS 1233882-22-8), 4-[3-[2,6-dichloro-4 -[(3,3-dichloro-2-propen-1yl)oxy]phenoxy]propoxy]-2-methoxy-6-(trifluoromethyl)pyrimidine (known from CN 101337940 A) (CAS 1108184-52-6); (2E)- and 2(2)-2-[2-(4-cyanophenyl)-1-[3-(trifluoromethyl)phenyl]ethylidene]-N-[4(difluoromethoxy)phenyl]hydrazinecarboxamide (known from CN 101715774 A ) (CAS 1232543-85-9); cyclopropanecarboxylic acid-3-(2,2-dichloroethenyl)-2,2-dimethyl-4-(N-benzimidazol-2-yl)phenyl ester (known from CN 103524422 A) (CAS 1542271-46-4); (4aS)-7-chloro-2,5-dihydro-2[[(methoxycarbonyl)[4-[(trifluoromethyl)thio]phenyl]amino]carbonyl]indeno[1,2-e][1,3,4] Oxadiazine 4a(3H) - carboxylic acid methyl ester (known from CN 102391261 A) (CAS 1370358-69-2); 6deoxy-3-O-ethyl-2,4-di-O-methyl-1-[No[4-[1-[4-(1,1,2,2,2-pentafluoroethoxy)phenyl]-III-1 ,2,4-triazol-3yl]phenyl]carbamate]-a-E-mannopyranose (known from US 2014/0275503 Al) (CAS 1181213-14-8); 8-(2-cyclopropylmethoxy-4-trifluoromethylphenoxy)-3-(6-trifluoromethylpyridazin-3-yl)-3azabicyclo[3.2.1]octane (CAS 1253850-56-4), (8-anti)-8-(2-cyclopropylmethoxy -4

- 13 046017 trifluoromethylphenoxy)-3-(6-trifluoromethylpyrvdazin-3-yl)-3-azabicyclo[3.2.1]octane (CAS 933798-27-7), (8-syn)-8-(2-cyclopropylmethoxy-4 -trifluoromethylphenoxy)-3-(6-trifluoromethylpyrvdazin-3-yl)-3azabicyclo[3.2.1]octane (known from WO 2007040280 Al, WO 2007040282 Al) (CAS 934001-66-8), N-[3chloro-1 - (3-pyridinyl)-III-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)thio]-propanamide (known from WO 2015/058021 A1, WO 2015/058028 A1) ( CAS 1477919-27-9) and ^[4-(aminothioxomethyl)-2-methyl-6[(methylamino)carbonyl]phenyl]-3-bromo-1-(3-chloro-2-pyridinyl)-1H-pyrazol- 5-Carboxamide (known from CN 103265527 A) (CAS 1452877-50-7), 5-(1,3-dioxan-2-yl)-4-[[4-(trifluoromethyl)phenyl]methoxy]pyrimidine (known from WO 2013/115391 Al) (CAS 1449021-97-9), 3-(4-chloro-2,6-dimethylphenyl)-8methoxy-1-methyl-1,8-diazaspiro[4.5]decane-2,4-dione (known from WO 2014/187846 A1) (CAS 163876558-8), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-1-methyl-2-oxo-1,8-diazaspiro[4.5] dec-3-en-4-yl-ethyl carboxylic acid ester (known from WO 2010/066780 A1, WO 2011151146 A1) (CAS 122902300-0), 4-[(5S)-5-(3,5-dichloro- 4-fluorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-N-[(4R)-2ethyl-3-oxo-4-isoxazolidinyl]-2-methyl-benzamide (known from WO 2011 /067272, WO2013/050302) (CAS 1309959-62-3).

Insecticides that can preferably be used in conjunction with herbicides are the following: acetamiprid, acrinatrine, aldicarb, amitraz, acinphos-methyl, cyfluthrin, carbaryl, cypermethrin, deltamethrin, endosulfan, etoprofos, fenamiphos, fenthion, fipronil, imidacloprid, methamidophos, methiocarb , niclosamide, oxydemeton-methyl, prothiophos, silafluofen, thiacloprid, thiodicarb, tralomethrine, triazophos, trichlorfon, triflumuron, terbufos, fonofos, phorate, chlorpyrifos, carbofuran, tefluthrin.

The combinations of active substances according to the invention are suitable for the control of a wide range of weeds in uncultivated plants, on roads, in parks, in industrial areas (industrial weed control) or in plantation crops in both temperate, subtropical and tropical climates. Examples of plantation crops are oil palms, nuts (e.g. almonds, hazelnuts, walnuts, macadamias), coconut, berries, rubber tree, citrus fruits (e.g. oranges, lemons, tangerines), bananas, pineapple, cotton, sugarcane, tea, coffee, cocoa, etc. They are also suitable for use in fruit crops (for example, pome fruits such as apples, pears, cherries, mangoes, kiwis) and in viticulture. Products can also be used for seed preparation (burn-down, no-till or zero-till methods) or for post-harvest treatment (chemical fallow). Possible applications of combinations of active ingredients also include weed control in tree crops, e.g. young Christmas trees or eucalyptus plantations, respectively before planting or after transplanting (also for over-top treatment).

The agents according to the invention are also used to control unwanted plant growth in economically important crops such as wheat (durum and soft wheat), corn, soybeans, sugar beets, sugar cane, cotton, rice, beans (such as bush beans and beans), flax, barley, oats, rye, triticale, potatoes and millet (sorghum), rangeland and green space/lawn and plantation crops. Plantation crops also include fruits (apples, pears, quinces), currants (blackberries, raspberries), citruses, plums (cherries, nectarines, almonds), nuts (walnuts, pecans, hazelnuts, cashews, macadamia) , mango, cocoa, coffee, grapes (table and regular grapes), palm trees (like oil palms, date palm, coconut palms), eucalyptus, kaki persimmon, persimmon persimmon, rubber tree, pineapple, bananas, avocado, lychee, forest crops ( eucalyptus, pine, spruce, chalk, etc.).

The herbicidal combinations of active substances according to the invention, in the appropriate form of application (= herbicidal agent), have a synergistic herbicidal effect and selectivity and a positive effect on the spectrum of weeds. They have excellent herbicidal activity against a wide range of economically important mono- and dicotyledonous annual weeds. The active ingredients also work well against perennial weeds that are difficult to control and that can re-sprout from rhizomes, rhizomes or other organs.

For use, the combination of active substances can be applied to plants (for example, weeds such as mono- or dicotyledonous weeds or unwanted crops), to seed material (for example, grains, seeds or vegetative reproductive organs such as tubers or sprouts with buds) or on the soil on which plants grow (for example, on a cultivated surface).

In this case, the substances can be applied, for example, in the pre-sowing (if necessary, also when applying fertilizers to the soil), pre-emergence and/or post-emergence period. It is preferable to use it during the method after sowing in the pre-emergence period or in the post-emergence period for treating plantation crops against weeds that have not yet emerged or have already emerged. Also, use in weed-management systems can include several separate applications (sequential application).

- 14 046017

In particular, examples can be given of some representatives of mono- and dicotyledonous weeds that can be controlled using combinations of active substances according to the invention, without limiting them to the name of specific species.

Monocot weed species include, for example, the species Aegilops, Agropyron, Agrostis, Alopecurus, Apera, Avena, Brachiaria, Bromus, Cynodon, Dactyloctenium, Digitaria, Echinochloa, Eleocharis, Eleusine, Eragrostis, Eriochloa, Festuca, Fimbristylis, Imperata, Ischaemum, Heteranthera, Imperata, Ischaemum, Leptochloa, Lolium, Monochoria, Panicum, Paspalum, Phalaris, Phleum, Roa, Rottboellia, Sagittaria, Scirpus, Setaria, Sorghum, Sphenoclea and Cyperus.

For dicotyledonous weed species, the spectrum of action extends to species such as, for example, Abutilon, Amaranthus, Ambrosia, Anoda, Anthemis, Aphanes, Artemisia, Atriplex (Quinoa), Bellis (Daisy), Bidens (Train), Capsella (Shepherd's Purse), Carduus (Thistle), Cassia (Cassia), Centaurea (Cornflower), Chenopodium (Marigold), Cirsium (Thistle), Convolvulus (Boundweed) , Datura (Datura), Desmodium (Desmodium), Emex (Emex), Erodium (Stork), Erysimum (Yellowweed), Euphorbia (Euphorbia), Galeopsis (Pikulnik), Galinsoga (Galinzoga), Galium (Bedstraw), Geranium (Geranium) , Hibiscus, Ipomoea, Kochia, Lamium, Lepidium, Lindernia, Matricaria, Mentha, Mercurialis, Mullugo , Myosotis (Forget-me-not), Papaver (Poppy), Pharbitis (Farbitis), Plantago (Plantain), Polygonum (Knotweed), Portulaca (Purslane), Ranunculus (Buttercup), Raphanus (Radish), Rorippa (Zherushnik), Rotala (Rotala) , Rumex (Sorrel), Salsola (Hodgepodge), Senecio (Grasswort), Sesbania (Sesbania), Sida (Sida), Sinapis (Mustard), Solanum (Nightshade), Sonchus (Sowthistle), Sphenoclea (Sphenoclea), Stellaria (Starweed) , Taraxacum (Dandelion), Thlaspi (Yarutka), Trifolium (Clover), Urtica (Nettle), Veronica (Veronica), Viola (Viola), Xanthium (Cocklebur).

If the combinations of active substances according to the invention are applied to the soil surface before sprouting, the growth of weed sprouts is completely stopped, or the weeds grow to the cotyledon stage, but then their growth stops and they eventually die within 3-4 weeks after the start of growth.

When applying active substances to the green parts of plants during post-emergence application, growth stops after treatment, and weeds at the stage of growth at which they were at the time of application or die completely after a certain period of time, thus eliminating competition very early and for a long period in the form of harmful weeds.

The herbicides according to the invention are characterized by rapid application and long-lasting herbicidal action. The rain resistance of the active substances in the combinations according to the invention is generally sufficient. A particular advantage is that the effective dosages of compounds (A) and (B) used in combination can be so low that their impact on the soil also remains optimally low. Thus, their use is possible not only in sensitive crops, but also practically prevents contamination of groundwater. By using the combination of active ingredients according to the invention, the required consumption rate of the active ingredients can be significantly reduced.

Through the combined use of herbicides (A) and (B), technologically usable properties are achieved that exceed those expected for combinations of individual herbicides. For example, herbicidal activity on certain weed species exceeds the expected value that can be determined using standard methods, such as the Colby method or other extrapolation methods.

A synergistic effect is always present if the action, here the herbicidal effect of the combination of active ingredients is greater than the sum of the effects of the separately applied active ingredients. The expected effect for a given combination of two active ingredients can be calculated according to S.R. Colby (Calculating Synergistic and Antagonistic Responses of Herbicide Combination, Weeds 15 (1967), 20-22 (see below)).

Therefore, synergistic effects make it possible, for example, to reduce the application rates of individual active ingredients, increase the effect at the same application rate, control new unregistered weed species (gaps), prolong the residual effect, enhance the prolonged action, increase the speed of action, increase the period of application and/or reduce necessary applications in individual cases and - as a result for the consumer - an economically and environmentally preferable weed control system.

Although according to the invention the compounds of general formula (I) show excellent herbicidal activity against mono- and dicotyledonous weeds, many economically important crop plants are only slightly dependent on the structure of these compounds according to the invention and their application rates

- 15 046017 or not damaged at all. Economically important crops are, for example, dicotyledonous crops of the species Arachis (peanut), Beta (beet), Brassica (cabbage), Cucumis (cucumber), Cucurbita (pumpkin), Helianthus (sunflower), Daucus (carrot), Glycine ), Gossypium (cotton), Ipomoea (morning glory), Lactuca (lettuce), Linum (flax), Lycopersicon (tomato), Nicotiana (tobacco), Phaseolus (bean), Pisum (pea), Solanum (potato), Vicia (pea ), or monocotyledonous crops of the species Allium (allium), Ananas (pineapple), Asparagus (asparagus), Avena (oats), Hordeum (barley), Oryza (rice), Panicum (millet), Saccharum (sugar cane), Secale (rye) ), Sorghum (sorghum), Triticale (triticale), Triticum (triticum) and Zea (corn).

In addition, the agents according to the invention partly have excellent properties for regulating the growth of crop plants. They intervene and regulate plant metabolism and this can be used to specifically influence plant components and to facilitate harvesting, such as by triggering desiccation and growth arrest. They further make it possible to generally regulate and retard unwanted vegetative growth without destroying the plant. Retarded vegetative growth plays an important role in many mono- and dicotyledonous crops; for example, this way can reduce or completely prevent storage losses.

Due to their herbicidal and plant growth-regulating properties, the agents can be used to control weeds in known or new plant crops, in tolerant crop plants modified by traditional mutagenesis, or modified by genetic engineering. Transgenic plants are generally distinguished by particularly advantageous properties, in addition to their resistance to the agents of the invention, for example by their resistance to plant diseases or their pathogens, such as certain insects or microorganisms such as fungi, bacteria or viruses. Other special properties generally relate to the harvested crop, regarding quantity, quality, storage stability, composition and special components. Thus, transgenic plants with increased starch content or altered starch properties, or plants with a different fatty acid composition in the harvested crop are known. Other special properties include tolerance or resistance to abiotic stress factors such as heat, cold, drought, high salt content and ultraviolet radiation.

It is advantageously possible to use the combinations of active substances according to the invention as herbicides in industrial crops that are resistant to the phytotoxic effects of herbicides or have become resistant due to genetic engineering methods.

Traditional methods of obtaining new plants with modified properties compared to plants still found today consist, for example, in classical methods of breeding and generating mutants. Alternatively, new plants with modified properties can be created using genetic engineering methods (see, for example, EP-A-0221044, EP-A0131624). Several cases have described, for example, genetically engineered modifications of crop plants to modify starch synthesized in plants (e.g. WO 92/11376, WO 92/14827, WO 91/19806), transgenic crop plants that are resistant to other herbicides, for example, to sulfonylurea (EP-A-0257993, US-A-5013659), transgenic crop plants that have the ability to produce Bacillus thuringiensis toxins (Bt toxins), which make plants resistant to certain pests (EP-A0142924, EP -A-0193259), transgenic crop plants with modified fatty acid composition (WO 91/13972), genetically modified crop plants with new constituents or secondary substances, such as new phytoalexins, which cause increased disease resistance (EPA 309862, EPA0464461), genetically modified plants with reduced photorespiration that have higher yields and higher stress resistance (EPA 0305398).

Transgenic crop plants that produce pharmaceutically or diagnostically important proteins (molecular pharming);

transgenic crops that have higher yields or better quality;

transgenic crop plants that differ in a combination of, for example, the above-mentioned new properties (gene stacking).

Numerous molecular biology techniques that can be used to create new transgenic plants with altered properties are known in principle; see, for example, B. I. Potrykus und G. Spangenberg (ed.) Gene Transfer to Plants, Springer Lab Manual (1995), ed. Springer Verlag Berlin, Heidelberg, or Christou, Trends in Plant Science 1 (1996) 423-431).

For such genetic manipulations, nucleic acid molecules can be introduced into plasmids, which allow mutagenesis, or sequence alteration, by recombination of DNA sequences. For example, standard methods can be used to exchange bases, remove partial sequences, or add natural or synthetic sequences. To connect DNA fragments to each other, adapters can be attached to the fragments.

- 16 046017 ters or linkers, see, for example, B. Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2. Ed. Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY; or Winnacker Gene und Klone, VCH Weinheim 2. Edition 1996.

Producing plant cells with reduced gene product activity can, for example, be achieved by expressing at least one corresponding antisense RNA, one sense RNA for RNAi extraction, or expressing at least a corresponding engineered ribosome specific transcript of said gene product.

In addition, DNA molecules that span the total encoded sequence of the gene product, including any flanking sequences present, can be used, as well as DNA molecules that span only a portion of the encoded sequence, which portion must be long enough to produce an antisense effect in cells. It is also possible to use DNA sequences that indicate a high degree of homology to the encoded sequences, but are not completely identical.

When nucleic acid molecules are expressed in plants, the synthetic protein can be localized in any compartment of the plant cell. But to achieve localization to a specific compartment, the encoded region can, for example, bind to DNA sequences that provide localization to one specific compartment. Such sequences are known to one skilled in the art (see, for example, Braun et al., EMBO J. 11 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad. Sci. USA 85 (1988), 846-850; Sonnewald et al., Plant J. 1 (1991), 95-106). Expression of nucleic acid molecules can also occur in plant cell organelles.

Transgenic plant cells can be regenerated by known methods into whole plants. In transgenic plants we can basically talk about plants of any species, i.e. both monocots and dicots. Thus, commercially available transgenic plants may have altered properties due to increased expression, suppression or inhibition of homologous (= natural) genes or gene sequences, or expression of heterologous (= extraneous) genes or gene sequences.

According to the invention, combinations of active ingredients can advantageously be used in transgenic crops that are tolerant to the active ingredients used or have become tolerant to them.

According to the invention, combinations of active ingredients that are resistant to growth agents, such as dicamba, or to herbicides that inhibit essential plant enzymes, such as acetolactate synthase (ADS), EPSP synthase, glutamine synthase (GS) can be used advantageously in transgenic crops according to the invention. ) or hydroxyphenylpyruvate dioxygenase (HPDH), or to herbicides from the group of sulfonylureas, glyphosate, glufosinate or benzoyloxazole and similar active ingredients.

Therefore, the subject of the invention is also a method for controlling undesirable plant growth, optionally in useful plants, in uncultivated plants or plantation crops, characterized in that one or more herbicides of type (A) with one or more herbicides of type (B) are applied to weeds. plants, plant parts or plant seeds (seed material) or onto a cultivated surface.

The subject of the invention is also the use of new combinations of compounds (A)+(B) for the control of weeds, if necessary, in crops of useful plants, especially in uncultivated plants and plantation crops, as well as for the control of weeds before sowing further useful plants , especially for preparing seeds (using burn-down methods (burning out vegetation)).

The combinations of active ingredients according to the invention can be present either as mixed compositions of the two components, optionally with other active ingredients, additives and/or conventional formulation auxiliaries, which are diluted in the usual manner with water for use, or prepared in the form of so-called mixtures in containers after general dilution of the separately or partially separated components obtained with water.

Compounds (A) and (B) or combinations thereof can be formulated in various ways, depending on what biological and/or chemical-physical parameters are specified. As general formulation options, the following are taken into account: spray powders (WP), water-soluble powder (SP), emulsifiable concentrate (EC), water-soluble concentrate, aqueous solution (SL), emulsions (EW) type oil-in-water and water-in-oil emulsions, loose or emulsified solutions, oil-based or water-based dispersions, oil-based dispersions (OD), suspoemulsions, suspension concentrates (SC), oil-miscible solutions, capsule suspensions (CS ), pollination agents (DP), disinfectants, granulates for soil application or spreading, granulates (GR) in the form of micro granules, granules for spreading, granulates for desorption and absorption, water-dispersible granulates (WG), water-soluble granulates (SG) , ultra-small volume formulations, microcapsules or waxes.

The object of the invention is therefore also herbicidal and plant growth regulating agents.

- 17 046017 va, which contain combinations of active substances according to the invention.

The individual types of compositions are, in principle, known to the person skilled in the art and are described, for example, in: Winnacker-Kuchler, Chemische Technologie, vol. 7, published by C. Hanser Verlag Munchen, 4th Ed. 1986; van Valkenburg, Pesticide Formulations, Marcel Dekker N.Y. 1973; K. Martens, Spray Drying Handbook, 3rd ed. 1979, G. Goodwin Ltd. London.

Necessary formulation auxiliaries, such as inerts, surfactants, solvents and other additives, are also known and described, for example, in: Watkins, Handbook of Insecticide Dust Diluents and Carriers, 2oe Ed., Darland Books, Caldwell N.J. ; H.v. Olphen, Introduction to Clay Colloid Chemistry; 2oe Ed., J. Wiley & Sons, N.Y. Marsden, Solvents Guide, 2oe Ed., Interscience, N.Y. 1963; McCutcheon's, Detergents and Emulsifiers Annual, MC Publ. Corp., Ridegewood N.J.; Sisley and Wood, Encyclopedia of Surface Active Agents, Chem. Publ. Co. Inc., N.Y. 1964; Schonfeldt, Grenzflachenaktive Athylenoxideddukte, Wiss. Verlagsgesellschaft, Stuttgart 1976, WinnackerKuchler, Chemische Technologie, volume 7, pp. Hanser Verlag Munchen, 4. Aufl. 1986.

Based on these formulations, it is also possible to obtain combinations with other pesticide active substances, such as other herbicides, fungicides, insecticides or other pest control agents (e.g. acaricides, nematicides, molluscicides, rodenticides, aphicides, avidides, larvicides, ovicides, bactericides, virucides, etc.), as well as protective agents, fertilizers and/or growth regulators, for example, in the form of ready-made formulations or in the form of mixtures in containers.

Powders for spraying are preparations that are uniformly dispersed in water, which, along with the active substance, in addition to a diluent or inert substance, also contain nonionic and/or ionic surfactants (wetting agents, dispersants), for example, polyoxyethylated alkylphenols, polyoxethylated aliphatic alcohols, polyoxethylated aliphatic amines, fatty alcohol polyglycol ether sulfates, alkanesulfonates, alkylbenzenesulfonates, sodium lignin sulfonic acid, sodium 2,2'dinaphthylmethane-6,6-disulfonic acid, sodium dibutylnaphthalene sulfonic acid or also sodium oleolmethyl taurine acid. For the production of spray powders, the herbicidal active substances are finely ground, for example using conventional equipment such as a hammer mill, a blower mill or an air jet mill, and either directly or subsequently mixed with formulation auxiliaries.

Emulsifiable concentrates are obtained by dissolving the biologically active substance in an organic solvent, for example, butanol, cyclohexanone, dimethylformamide, xylene, or also in high-boiling aromatic compounds or hydrocarbons, or mixtures of an organic solvent using one or more ionic and/or nonionic surfactants (emulsifiers). As emulsifiers, for example, you can use: Calcium salts of alkylaryl sulfonic acid, such as Ca dodecylbenzenesulfonate or nonionic emulsifiers, such as polyglycol fatty acid ester, alkylaryl polyglycol ether, polyglycol fatty alcohol ether, propylene oxide-ethylene oxide condensation products, alkyl polyether, sorbitan ester, such as sorbitan a fatty acid ester or, for example, a polyoxyethylene sorbitan fatty acid ester.

Pollinating agents are obtained by grinding the biologically active substance with finely ground solids such as talc, natural clays such as kaolin, bentonite and pyrophyllite, or diatomaceous earth.

Suspension concentrates can be water or oil based. They can be obtained, for example, by wet grinding using standard bead mills, if necessary with the addition of a surfactant, as, for example, already mentioned in other types of formulations.

Emulsions, for example oil-in-water (EW) emulsions, can be prepared using stirrers, colloid mills and/or static mixers using aqueous organic solvents and, if necessary, surfactants, as for example already mentioned in other types of formulations .

Granulates can be produced by spraying the active ingredient onto granular inert adsorbents or applying a concentrate of the active ingredient using binders such as polyvinyl alcohol, sodium polyacrylic acid or also mineral oils onto the surface of a filler such as sand, kaolinite or granular inert material. Also for the production of granulates for fertilizers, the relevant active substances are crushed in the usual way, optionally mixed with fertilizers.

Water-dispersible granulates are typically produced by processes such as spray drying, fluidized bed granulation, disk granulation, high-speed mixer granulation and non-solid inert extrusion.

Agrochemical compositions contain, as a rule, 0.1-99 wt.%, in particular 0.2-95 wt.%, active ingredients of types (A) and/or (B), and depending on the type of formulation, the following concentrates are usually used :

In dusting powders, the concentration of active substance is, for example, 10-95% by weight of the residue to 100% by weight of the usual components of the formulation. In emulsifiable concentrations

- 18 046017 consumption, the concentration of the biologically active substance can be approximately 1-90, preferably 5-80 wt.%.

Powdered compositions most often contain 1-20 wt.% of the active substance, solutions for scattering contain approximately 0.05-80 wt.%, preferably 2-50 wt.% of the active substance.

In granulates such as water-dispersible granulates, the active component content depends in part on whether the active compound is present in liquid or solid form and what granulating auxiliaries and fillers are used. Typically, the water content of the dispersible granulates is 1-95% by weight, preferably 10-80% by weight.

In addition, the named compounds of active ingredients, if necessary, contain the usual adhesive, wetting, dispersing, emulsifying agents, penetration enhancing agents, preservatives, frost protection agents and solvents, fillers, carriers, dyes, defoamers, brake evaporators and agents, influencing pH level and viscosity.

For use, the conventionally present compositions are diluted with water in the usual manner, for example in the form of sprayable powders, emulsifiable concentrates, dispersions and water-dispersible granulates. Pulverized compositions, soil granules or granulates, and spray solutions are generally not diluted with other inert substances before use.

The active substances can be applied to plants, plant parts, plant seeds or a cultivated surface (soil), preferably to green plants and plant parts and, if necessary, additionally to soil.

A possible application is the joint application of the active substances in the form of mixing in a container, whereby the optimal concentrations of the compositions of the individual active substances are mixed together in a tank of water and the resulting liquids are used for spraying.

The advantage of the general herbicidal composition of the herbicidal mixtures according to the invention with components i) and ii) is easy usability, since the number of components is already in the correct ratio to each other. In addition, the excipients in the composition can be optimally coordinated with each other, while when mixing different formulations in containers, undesirable combinations of excipients may arise.

A. Examples of general preparative forms.

a) Prepare a powdered preparation by mixing 10 parts by weight (= parts by weight) of the active substance (A) or (B) or a mixture of active substances (A)+(B) (and, if necessary, additional components of the active substance) and/or their salts and 90 wt. parts of talc as an inert substance and crushed in a hammer crusher.

b) A water-dispersible, wettable powder is obtained by mixing 25 wt. parts of active substance/mixture of active substances, 64 wt. parts of kaolin-containing quartz as an inert substance, 10 wt. parts of potassium ligninsulfonic acid and 1 wt. part of sodium oleoylmethyl taurine as a wetting agent and dispersant and grinding in a pin crusher.

c) A dispersion concentrate that is easily dispersible in water is obtained by mixing 20 wt. parts of active substance / mixture of active substances with 6 wt. parts of alkylphenol polyglycol ether (© Triton X 207), 3 wt. parts of isotridecanol polyglycol ether (8 EO) and 71 wt. part of paraffinic mineral oil (boiling range, for example, approximately 255-277°C) and grinding in a friction ball mill to a grinding fineness of 5 microns.

d) The emulsifiable concentrate is obtained from 15 wt. parts of active substance/mixture of active substances, 75 wt. parts of cyclohexanone as a solvent and 10 wt. parts of ethoxylated nonylphenol as an emulsifier.

e) Water-dispersible granulate is prepared by mixing 75 wt. parts of active substance/mixture of active substances, 10 wt. parts of calcium lignin sulfonic acid, 5 wt. parts of sodium lauryl sulfate, 3 wt. parts of polyvinyl alcohol and 7 wt. parts of kaolin, grinding in a pin crusher, and granulating the powder in a vortex bed by spraying water as a granulating liquid.

f) Water-dispersible granulate is also obtained by homogenization:

wt. parts of the active substance/mixture of active substances;

wt. parts of 2,2'-dinaphthylmethane-6,6'-disulfonic acid sodium;

wt. parts of sodium oleoylmethyl taurine;

wt. parts of polyvinyl alcohol;

wt. parts of calcium carbonate; and wt. parts of water in a colloid mill and preliminary grinding, subsequent grinding in a bead mill and spraying the suspension thus obtained in a scrubber using a mononozzle and drying.

B. Biological examples.

When using the combinations according to the invention, the herbicidal effect on weed species often exceeds the formal sum of the effects of the herbicides present

- 19 046017 when applied separately. Alternatively, in some cases it can be observed that a negligible application rate is required for a combination of herbicides, compared with the same effect on weed species provided by individual preparations. Such an increase in impact or efficiency, or savings in application rate, indicates a synergistic effect.

If the observed effect values already exceed the formal sum of the values compared to experiments with individual application, then in this case they also exceed the expected Colby value, which is calculated using the following formula and also indicate synergism (see, for example, S. R. Colby; edition Weeds 15 (1967) pp. 20-22).

E ^C = A+B-(A-B/100). This means:

A = effect of the active substance (A) in% at a consumption rate of a g a.i./ha; B = effect of the active substance (B) in% at the application rate b g a.i./ha; E ^C = expected value of the effect of the combination (A) + (B) in% at a combined application rate of a + b g a.i./ha.

The observed values ( ^EA ) of the tests indicate, at appropriate low dosages, an effect of the combination that is above the expected Colby value (A).

1. Effect on weeds in the post-emergence period.

Seeds or parts of rhizomes of mono- or bicotyledonous weed plants were placed in pots in sandy loam, covered with soil and grown in a greenhouse, controlling growth conditions (temperature, air humidity, water supply). Three weeks after sowing, the test plants were treated with the products according to the invention at the third leaf stage. The products according to the invention, present in the form of spray powder or in the form of emulsion concentrates, were sprayed at different dosages with a water consumption rate calculated at 300-800 l/ha on the green parts of the plants. After approximately 3-4 weeks, the test plants were in the greenhouse, under optimal growth conditions, and the effect of the drugs was visually assessed, compared to the untreated control group. The products according to the invention also have good herbicidal effectiveness in the post-emergence period against a wide range of economically important weeds and weeds.

In this case, the effect of the combinations according to the invention is often observed, which exceeds the formal sum of the effects of the separate application of herbicides. The observed test values indicate, at suitable low dosages, an effect of the combination that is above the Colby expected value.

2. Herbicidal effect in the pre- and post-emergence period (field test).

According to the greenhouse tests of section 1, the tests were carried out on small plots of land in the open ground. Visual assessment is carried out similarly to the test in section 1.

3. Herbicidal effect and tolerance by cultivated plants (field test).

Cultivated plants were grown in the open ground on small plots of land under natural open ground conditions, and seeds or parts of rhizomes of common weeds were spread out or natural weed overgrowth was used. Treatment with the means according to the invention was carried out after the germination of weeds and cultivated plants, as a rule, at the stage of the 2-4th leaf; Partially (as indicated) individual active ingredients or combinations of active ingredients were applied as a pre-emergence treatment or as a sequential partial pre-emergence and/or post-emergence treatment.

In plantation crops, as a rule, only the soil between individual cultivated plants was treated with active substances.

After application, for example, 2, 4, 6 and 8 weeks after application, the effect of the drugs was visually assessed in comparison with the untreated control group. The products according to the invention also have synergistic herbicidal effectiveness against a wide range of economically important weeds and weeds during field testing. The comparison shows that the combinations according to the invention have a herbicidal effect much more often, with significant superiority, compared to the sum of the actions of the individual herbicides and therefore indicate synergy. In addition, the effects at most sites during the observation time exceed the Colby expected value and therefore also indicate synergy. Cultivated plants, on the contrary, had only minor or no damage after treatment with herbicides.

4. Special test examples.

The following abbreviations have been used in the description and tables below:

g a.i./ha = grams of active substance (active ingredient) (= 100% active substance) per hectare;

the sum of the effects of individual applications is indicated as E ^A ;

the expected value according to Colby is accordingly indicated below E ^C ;

the biological results of the compositions according to the invention are presented in table. 3.1-3.8.

The visual assessment time period is given in days after application (DAT).

- 20 046017

Table 3.1

Synergistic effect (A) for herbicidal binary compositions in the post-emergence period containing herbicides from group B2

Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Digitaria sanguinalis (B2.18) diflufenican 270 90 thirty 20 20 20 A1 15 5 thirty 10 A1 + (B2.18) diflufenican 15+270 15 + 90 15 + 30 5 + 90 5 + 30 ^EA = 85 (E ^s = 44) Δ41 ^EA = 80 (E ^s = 44) Δ36 ^EA = 80 (E ^s = 44) Δ36 ^EA = 40 (E ^s = 28) Δ 12 ^EA = 45 ( E ^c = 28) Δ 17 Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Echinochloa crus-galli (B2.18) diflufenican 270 90 thirty 15 10 10 A1 5 1.67 15 15 A1 + (B2.18) diflufenican 5+270 5 + 90 5 + 30 1.67 + 30 E ^A = 80 (E ^c = 28) Δ52 E ^a = 30 (E ^c = 23) Δ 7 E ^a = 30 (E ^c = 23) Δ 7 E ^a = 30 (E ^c = 23) Δ 7 Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Setaria faberi (B2.18) diflufenican 270 90 thirty 0 0 0 A1 15 5 1.67 85 15 0 A1 + (B2.18) diflufenican 15+270 15 + 90 15 + 30 5+270 5 + 90 1.67 + 270 ^EA = 95 (E ^s = 85) Δ 10 ^EA = 95 (E ^s = 85) Δ 10 ^EA = 90 (E ^s = 85) Δ 5 ^EA = 70 (E ^s = 15) Δ55 E ^l ~ 45 (E ^s ~ 15) Δ30 E ^A = 20 (E ^s = 0) Δ20

- 21 046017

Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Setaria viridis (B2.18) diflufenican 270 10 A1 15 5 1.67 90 75 10 A1 + (B2.18) diflufenican 15+270 5+270 1.67 + 270 E ^A = 98 (E ^c = 91) Δ 7 E ^A = 93 (E ^c = 78) Δ 16 E ^A = 25 (E ^c = 19) Δ 6 Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Eleusine indica (B2.18) diflufenican 270 thirty 20 15 A1 15 5 40 40 A1 + (B2.18) diflufenican 15 +270 15 + 30 5 + 30 E ^A = 70 (E ^c = 52) Δ 18 E ^A = 70 (E ^c = 49) Δ21 E ^A = 55 (E ^c = 49) Δ 6 Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Sorghum halepense (B2.18) diflufenican 270 90 thirty 15 0 0 A1 15 5 1.67 45 10 0 A1 + (B2.18) diflufenican 15+270 15 + 90 15 + 30 5+270 5 + 90 5 + 30 1.67 + 270 1.67 + 90 1.67 + 30 _ii shj1t||t||t||t||t| >>>>>>> II || II II II II II II II, tse e OO o OO ¹ / η o o o o o o II || II II II II II II _{o o} _ — — LJ ^>|> >>>>>>> έ |.J — ° O 'J. oh oh and oh oh and

- 22 046017

Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Abutilon theophrasti (B2.18) diflufenican A1 A1 + (B2.18) diflufenican 270 90 thirty 45 15 5 45 + 270 45 + 90 15 + 30 5 + 90 30 10 10 30 10 0 ^EA = 85 (E ^s = 51) Δ34 ^EA = 85 (E ^s = 37) Δ48 ^EA = 35 (E ^s = 19) Δ 16 ^EA = 20 (E ^s = 10) Δ 10 Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Ipomoea purpurea (B2.18) diflufenican 270 90 thirty 65 45 10 A1 45 15 5 100 0 A1 + (B2.18) diflufenican 45 + 270 15+270 15 + 30 5+270 5 + 90 5 + 30 ^EA = 85 (E ^s = 69) Δ 16 ^EA = 85 (E ^s = 65) Δ20 ^EA = 50 (E ^s = 10) Δ40 ^EA = 70 (E ^s = 65) Δ 5 ^EA = 75 (E ^c = 45) Δ30 E ^a = 35 (E ^c = 10) Δ25 Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Euphorbia heterophylla (B2.18) diflufenican 270 90 thirty 55 55 25 A1 45 15 5 35 10 0 A1 + (B2.18) diflufenican 45 + 270 45 + 90 15+270 15 + 30 5+270 E ^a = 85 (E ^c = 71) Δ 14 E ^A = 75 (E ^c = 71) Δ 4 E ^A = 70 (E ^c = 59) Δ 11 E ^A = 50 (E ^c = 32) Δ 18 E ^A = 98 (E ^c = 55) Δ43 Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Polygonum convulvulus (B2.18) diflufenican 270 90 thirty thirty 20 10 A1 5 50 A1 + (B2.18) diflufenican 5+270 5 + 90 5 + 30 E ^A = 97 (E ^c = 65) Δ32 E ^A = 93 (E ^c = 60) Δ33 E ^A = 85 (E ^c = 55) Δ30

- 23 046017

Current Consumption rate Herbicidal effect 28 DAT [%] against substance/substances (Z3) [g a.i./ha] Alopecurus myosuroides (sensitiver Biotyp) 15 60 Al 5 0 270 0 (B2.18) diflufenican 90 0 thirty 0 15+270 E ^A = 90 (E ^c = 60) Δ30 15 + 90 E ^A = 90 (E ^c = 60) Δ 30 A1 15 + 30 E ^A = 70 (E ^c = 60) Δ 10 (B2.18) diflufenican 5+270 E ^a = 20 (E ^c = 0) Δ 20 5 + 90 E ^A = 10(E ^c = 0) Δ 10 5 + 30 E ^a = 30(E ^c = 0) Δ 30 Current Consumption rate Herbicidal effect 28 DAT [%] against substance/substances (Z3) [g a.i./ha] Alopecurus myosuroides (resistenter Biotyp) A1 15 60 90 10 (B2.18) diflufenican thirty 0 A1 15 + 90 E ^A = 70 (E ^c = 64) Δ 6 + (B2.18) diflufenican 15 + 30 E ^a = 80 (E ^c = 60) Δ 20 Current Consumption rate Herbicidal effect 28 DAT [%] substance/substances [g a.i./ha] against (Z3) Avena fatua 15 85 A1 5 50 1.67 0 270 10 (B2.18) diflufenican 90 0 thirty 0 15 + 270 E ^a = 93 (E ^c = 86.5) Δ 6.5 15 + 90 E ^a = 93 (E ^c = 85) Δ 8 15 + 30 E ^A = 90 (E ^c = 85) Δ 5 A1 5+270 E ^a = 85 (E ^c = 55) Δ 30 + 5 + 90 E ^A = 60 (E ^c = 50) Δ 10 (B2.18) diflufenican 5 + 30 E ^A = 85 (E ^c = 50) Δ 35 1.67 + 270 E ^A = 20 (E ^c = 10) Δ 10 1.67 + 90 E ^a = 20 (E ^c = 0) Δ 20 1.67 + 30 E ^A = 10(E ^c = 0) Δ 10

- 24 046017

Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Galium aparine Al 45 15 5 50 thirty 0 (B2.18) diflufenican 90 270 thirty 20 thirty 10 A1 + (B2.18) diflufenican 45 + 90 15+270 5 + 90 5 + 30 E ^A = 70 (E ^c = 60) A 10 E ^A = 60 (E ^c = 51) A 9 E ^A = 30 (E ^c = 20) A 10 E ^A = 20 (E ^c = 10) A 10 Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Lamium purpureum A1 45 15 5 70 50 20 (B2.18) diflufenican thirty 90 0 10 A1 + (B2.18) diflufenican 45 + 30 15 + 90 15 + 30 5 + 90 E ^A = 80 (E ^c = 70) A 10 E ^A = 70 (E ^c = 55) A 15 E ^A = 60 (E ^c = 50) A 10 E ^A = 60 (E ^c = 28) A 32 Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Lolium rigidum (resistenter Biotyp) A1 15 5 0 0 (B2.18) diflufenican 270 90 40 0 A1 + (B2.18) diflufenican 15+270 15 + 90 5 + 90 E ^A = 50 (E ^c = 40) A 10 E ^a = 40 (E ^c = 0) A 40 E ^a = 20 (E ^c = 0) A 20 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Papaver rhoeas A1 15 5 70 40 (B2.18) diflufenican 270 thirty A1 + (B2.18) diflufenican 15+270 5+270 E ^a = 85 (E ^c = 79) A 6 E ^a = 80 (E ^c = 58) A 22

- 25 046017

Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Phalaris minor Al 15 5 60 0 (B2.18) diflufenican 270 90 thirty 20 10 10 A1 + (B2.18) diflufenican 15+270 15 + 90 15 + 30 5+270 E ^A = 85 (E ^c = 68) Δ 17 E ^A = 80 (E ^c = 64) Δ 16 E ^a = 85 (E ^c = 64) Δ 21 E ^A = 30 (E ^c = 20) Δ 10 Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Roa annua A1 15 5 80 thirty (B2.18) diflufenican thirty 270 0 20 A1 + (B2.18) diflufenican 15 + 30 5+270 E ^A = 95 (E ^c = 80) Δ 15 E ^a = 70 (E ^c = 44) Δ 26 Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Polygonum convolvulus A1 15 5 70 0 (B2.18) diflufenican 270 90 thirty 60 thirty 0 A1 + (B2.18) diflufenican 15+270 15 + 90 15 + 30 5+270 5 + 90 5 + 30 E ^a = 95 (E ^c = 88) Δ 7 E ^a = 85 (E ^c = 79) Δ 6 E ^A = 85 (E ^c = 70) Δ 15 E ^a = 80 (E ^c = 60) Δ 20 E ^a = 50 (E ^c = 30) Δ 20 E ^A = 70 (E ^c = 0) Δ 70

- 26 046017

Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Stellaria media Al 45 15 5 85 50 0 (B2.18) diflufenican 90 270 thirty 20 40 20 Al + (B2.18) diflufenican 45 + 90 15+270 15 + 90 15 + 30 5 + 90 5 + 30 Q\ О О ι/Ί О О — сч сч сч <<<<<< ОО О ⁴ О ⁴ О ⁴ О ⁴ О ⁴ 00 с- <о <о сч сч II II II II II II И ш ж sch sch O O in o o O', 00 00 00 Tf- Tf II II II II II II <,<<<<< Search sch sch Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Veronica hederifolia A1 5 0 (B2.18) diflufenican 90 60 A1 + (B2.18) diflufenican 5 + 90 E ^A = 70 (E ^c = 60) A 10 Active substance/substances (Z3) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Viola tricolor A1 45 15 5 thirty 20 0 (B2.18) diflufenican 270 90 thirty 20 A1 + (B2.18) diflufenican 45 + 270 15+270 5+270 5 + 90 E ^a = 70 (E ^c = 51) A 19 E ^A = 60 (E ^c = 44) A 16 E ^a = 50 (E ^c = 30) A 20 E ^a = 40 (E ^c = 20) A 20 Active substance/substances (Z32) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Abutilon theophrasti (B2.18) diflufenican 270 90 thirty thirty 10 10 A2 15 20 A2 + (B2.18) diflufenican 15+270 15 + 90 15 + 30 E ^a = 70 (E ^c = 44) A 26 E ^a = 70 (E ^c = 28) A 42 E ^A = 45 (E ^C = 28) A 17

- 27 046017

Active substance/substances (Z32) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Amaranthus palmeri (res.) (B2.18) diflufenican 270 thirty 50 10 A2 15 5 65 15 A2 + (B2.18) diflufenican 5+270 15 + 30 5 + 30 E ^a = 85 (E ^c = 58) Δ 27 E ^a = 98 (E ^c = 69) Δ 29 E ^a = 97 (E ^c = 24) Δ 73 Active substance/substances (Z32) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Bidens pilosa (B2.18) diflufenican 270 90 thirty thirty 20 10 A2 15 10 A2 + (B2.18) diflufenican 15+270 15 + 90 15 + 30 E ^a = 65 (E ^c = 37) Δ 28 E ^a = 50 (E ^c = 28) Δ 22 E ^a = 35 (E ^c = 19) Δ 16 Active substance/substances (Z32) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Brachiaria platyphylla (B2.18) diflufenican 270 90 thirty 20 20 10 A2 15 5 100 A2 + (B2.18) diflufenican 15+270 5+270 15 + 90 15 + 30 E ^a = 75 (E ^c = 28) Δ 47 E ^A = 30 (E ^c = 20) Δ 10 E ^a = 75 (E ^c = 28) Δ 47 E ^A = 70 (E ^c = 19) Δ 51 Active substance/substances (Z32) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Digitaria sanguinalis (B2.18) diflufenican 270 90 thirty 20 20 10 A2 15 10 A2 + (B2.18) diflufenican 15+270 15 + 90 15 + 30 E ^a = 70 (E ^c = 28) Δ 42 E ^a = 99 (E ^c = 28) Δ 71 E ^A = 45 (E ^c = 19) Δ26

- 28 046017

Active substance/substances (Z32) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Echinochloa crus-galli (B2.18) diflufenican 270 90 thirty 10 10 10 A2 5 20 A2 + (B2.18) diflufenican 5+270 5 + 90 5 + 30 E ^a = 93 (E ^c = 28) Δ 65 E ^a = 95 (E ^c = 28) Δ 67 E ^A = 85 (E ^c = 19) Δ57 Active substance/substances (Z32) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Eleusine indica (B2.18) diflufenican 270 90 thirty 20 10 10 A2 15 5 45 35 A2 + (B2.18) diflufenican 15+270 5+270 15 + 90 15 + 30 E ^a = 99 (E ^c = 56) Δ 43 E ^a = 75 (E ^c = 48) Δ 27 E ^A = 98 (E ^C = 51) A47 E ^A = 98 (E ^C = 51) A47 Active substance/substances (Z32) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Kochia scoparia (B2.18) diflufenican 270 90 thirty 25 A2 15 5 20 20 A2 + (B2.18) diflufenican 15+270 5+270 15 + 90 5 + 90 E ^A = 80 (E ^c = 44) Δ 36 E ^A = 80 (E ^c = 44) Δ 36 E ^a = 85 (E ^c = 40) Δ 45 E ^a = 60 (E ^c = 40) Δ 20 Active substance/substances (Z32) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Pharbitis purpurea (B2.18) diflufenican 270 90 thirty 35 20 20 A2 5 75 A2 + (B2.18) diflufenican 5+270 5 + 90 5 + 30 E ^A = 97 (E ^c = 84) Δ 13 E ^A = 98 (E ^c = 80) Δ 18 E ^A = 97 (E ^c = 80) Δ 17

- 29 046017

Active substance/substances (Z32) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Polygonum convolvulus (B2.18) diflufenican 90 thirty thirty 20 A2 5 80 A2 + (B2.18) diflufenican 5 + 90 5 + 30 E ^A = 97 (E ^c = 86) Δ 11 E ^a = 98 (E ^c = 84) Δ 14 Active substance/substances (Z32) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Setaria viridis (B2.18) diflufenican 270 90 thirty 80 50 50 A2 5 1.7 100 A2 + (B2.18) diflufenican 5+270 5 + 90 1.7 + 90 5 + 30 1.7 + 30 Μ Μ Μ Μ Μ > > > > > II II II II II οο ο σ, ο ο ο. σ-, ·ο. ο ·ο. l-dl-d II II II II II '7ι 'U, 'L CO O Όι O Όι ΙΟ > > > > > Active substance/substances (Z32) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Sorghum halepense (B2.18) diflufenican 270 90 thirty 20 10 10 A2 15 5 1.7 15 0 0 A2 + (B2.18) diflufenican 15+270 5+270 15 + 90 5 + 90 1.7 + 90 15 + 30 5 + 30 y y y y y y >>>>>>> II II II II II II II οο Ο ΙΟ ο ο οο ο Όι Ό Όι Όι Ο Ό ι CO II II II II II II II — ΙΟ — — ΙΟ ΙΟ OJ Ο 4ο ο Ο 4ο ο Ι Ο >>>>>>> but 00 Ο OS OS ο, ω υ> οι ο, σ\ Active substance/substances Z61 Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Abutilon theophrasti (B2.18) diflufenican thirty 10 AZ 15 10 AZ + (B2.18) diflufenican 15 + 30 E ^A = 30 (E ^c = 19) Δ 11

- 30 046017

Active substance/substances Z61 Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Amaranthus palmeri (res.) (B2.18) diflufenican 90 thirty thirty 10 AZ 15 5 10 10 AZ + (B2.18) diflufenican 15 + 90 5 + 90 15 + 30 5 + 30 Μ Μ Μ Μ >>>> II II II II σ -з II II II II 3 3 ο ο >>>> η— ¹ Η-* and - σ ο 'l Active substance/substances Z61 Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Brachiaria platyphylla (B2.18) diflufenican thirty 10 AZ 1.7 10 AZ + (B2.18) diflufenican 1.7 + 30 E ^a = 35 (E ^c = 19) Δ 16 Active substance/substances Z61 Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Eleusine indica (B2.18) diflufenican 270 20 AZ 5 70 AZ + (B2.18) diflufenican 5+270 E ^a = 93 (E ^c = 76) Δ 17 Active substance/substances Z61 Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Kochia scoparia (B2.18) diflufenican 270 90 thirty 25 AZ 45 15 5 20 10 20 AZ + (B2.18) diflufenican 45 + 270 15+270 5+270 45 + 90 15 + 90 jj jj jj > > > > > II II II II II ψ. 'l '7, σ· σ l-dl-d II II II II II > > > > > o o b e Active substance/substances Z61 Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Sorghum halepense (B2.18) diflufenican 270 90 thirty 20 10 10 AZ 5 1.7 75 thirty AZ + (B2.18) diflufenican 5+270 1.7 + 270 5 + 90 5 + 30 m Ό (Ί (Ч < < < < Ο Tf OO OO OO Tf- II II II II SHCH SHCH ---' S--' S--' S-? § O'J II II II II < < < < and and and

- 31 046017

Active substance/substances (Z90) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against EpoMUS sterilis A4 16 4 90 thirty (B2.18) diflufenican 270 thirty 100 A4 + (B2.18) diflufenican 16 + 270 16 + 30 4 + 270 E ^A = 98 (E ^c = 91) A = 7 E ^A = 98 (E ^c = 90) A = 8 E ^A = 60 (E ^c = 37) A = 23 Active substance/substances (Z90) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Centaurea cyanus A4 16 4 1 40 thirty 10 (B2.18) diflufenican 90 thirty 50 50 A4 + (B2.18) diflufenican 16 + 90 16 + 30 4 + 30 1+30 E ^A = 90 (E ^c = 70) A = 20 E ^A = 75 (E ^c = 70) A = 5 E ^A = 70 (E ^c = 65) A = 5 E ^A = 60 (E ^c = 55) A = 5 Active substance/substances (Z90) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Centaurea cyanus A4 16 4 1 40 30 0 (B2.18) diflufenican 270 90 thirty 40 thirty 10 A4 + (B2.18) diflufenican 16 + 270 16 + 90 16 + 30 4 + 90 4 + 30 1+270 2 ci it сз 2 II II II ¹¹ II II <<<<<< Tj- OO 40 gt; g- o 40 il sn II II II ¹¹ II II o o O 5+ o o Ш ww W _ww z ζ ζ Ό 'Ή CH 55 Ό 00 04 04 40 1/L II II II ¹¹ II II <<<<<< w d ww _ww Active substance/substances (Z90) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Galium aparine A4 16 4 60 40 (B2.18) diflufenican 270 90 thirty 50 40 40 A4 + (B2.18) diflufenican 16 + 270 16 + 90 4 + 90 4 + 30 E ^a = 85 (E ^c = 80) A = 5 E ^a = 85 (E ^c = 76) A = 9 E ^A = 75 (E ^c = 64) A = 11 E ^A = 70 (E ^c = 64) A = 6 Active substance/substances (Z90) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Galium aparine A4 16 20 (B2.18) diflufenican 270 90 thirty 20 20 10 A4 + (B2.18) diflufenican 16 + 270 16 + 90 16 + 30 E ^A = 85 (E ^c = 36) A = 49 E ^A = 60 (E ^c = 36) A = 24 E ^A = 40 (E ^c = 28) A = 12

- 32 046017

Active substance/substances (Z90) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Lamium purpureum L. A4 16 thirty (B2.18) diflufenican thirty 10 A4 + (B2.18) diflufenican 16 + 30 E ^A = 50 (E ^c = 37) A = 13 Active substance/substances (Z90) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Lolium rigidum A4 16 10 (B2.18) diflufenican thirty 0 A4 + (B2.18) diflufenican 16 + 30 E ^A = 20 (E ^c = 10) A = 10 Active substance/substances (Z90) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Matricaria inodora A4 4 10 (B2.18) diflufenican 90 10 A4 + (B2.18) diflufenican 4 + 90 E ^A = 30 (E ^c = 19) A = 11 Active substance/substances (Z90) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Viola tricolor A4 16 4 1 40 thirty thirty (B2.18) diflufenican 90 270 thirty 50 60 50 A4 + (B2.18) diflufenican 16 + 90 4 + 270 4 + 30 1+90 й и и и > > > > II II II II OOO'/l II II II II ο ο <ι <ι '7, IJ Ο '—' S—' S—' S—' > > > > II II II II 71 '7! CC '71 Active substance/substances (Z90) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Viola tricolor A4 4 0 (B2.18) diflufenican 270 40 A4 + (B2.18) diflufenican 4 + 270 E ^A = 60 (E ^c = 40) A = 20 Active substance/substances (Z119) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Alopecurus myosuroides A5 16 4 Ί0 50 (B2.18) diflufenican thirty 270 20 20 A5 + (B2.18) diflufenican 16 + 30 4 + 270 E ^A = 88 (E ^c = 76) A = 12 E ^A = 70 (E ^c = 60) A = 10

- 33 046017

Active substance/substances (Z119) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Alopecurus myosuroides A5 16 4 40 40 (B2.18) diflufenican 90 thirty 270 10 10 20 A5 + (B2.18) diflufenican 16 + 90 16 + 30 4 + 270 E ^A = 60 (E ^c = 46) Δ = 14 E ^A = 98 (E ^c = 46) Δ = 52 E ^A = 70 (E ^c = 52) Δ = 18 Active substance/substances (Z119) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Centaurea cyanus A5 16 50 (B2.18) diflufenican thirty 10 A5 + (B2.18) diflufenican 16 + 30 E ^A = 60 (E ^c = 55) Δ = 5 Active substance/substances (Z119) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Galium aparine A5 1 thirty (B2.18) diflufenican 270 20 A5 + (B2.18) diflufenican 1+270 E ^a = 50 (E ^c = 44) Δ = 6 Active substance/substances (Z119) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Lamium purpureum L. A5 16 4 60 50 (B2.18) diflufenican 270 thirty 20 10 A5 + (B2.18) diflufenican 16 + 270 16 + 30 4 + 270 4 + 30 E ^A = 80 (E ^c = 68) Δ = 12 E ^A = 70 (E ^c = 64) Δ = 6 E ^A = 75 (E ^c = 60) Δ = 15 E ^A = 70 (E ^c = 55) Δ = 15 Active substance/substances (Z119) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Lolium rigidum A5 16 60 (B2.18) diflufenican thirty 10 A5 + (B2.18) diflufenican 16 + 30 E ^A = 70 (E ^c = 64) Δ = 6 Active substance/substances (Z119) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Lolium rigidum A5 16 thirty (B2.18) diflufenican thirty 0 A5 + (B2.18) diflufenican 16 + 30 E ^A = 50 (E ^c = 30) Δ = 20

- 34 046017

Active substance/substances (Z119) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Lolium rigidum (resistenter Biotyp) A5 16 1 20 0 (B2.18) diflufenican 90 thirty 100 A5 + (B2.18) diflufenican 16 + 90 16 + 30 1+30 E ^A = 40 (E ^c = 28) Δ = 12 E ^a = 30 (E ^c = 20) Δ = 10 E ^A = 10 (E ^c = 0) Δ = 10 Active substance/substances (Z119) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Phalaris minor A5 4 70 (B2.18) diflufenican 270 20 A5 + (B2.18) diflufenican 4 + 270 E ^a = 85 (E ^c = 76) Δ = 9 Active substance/substances (Z119) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Phalaris minor A5 16 4 40 thirty (B2.18) diflufenican 90 thirty 270 10 10 20 A5 + (B2.18) diflufenican 16 + 90 16 + 30 4 + 270 E ^a = 80 (E ^c = 46) Δ = 34 E ^a = 80 (E ^c = 46) Δ = 34 E ^a = 50 (E ^c = 44) Δ = 6 Active substance/substances (Z119) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Roa annua L. A5 4 20 (B2.18) diflufenican 270 20 A5 + (B2.18) diflufenican 4 + 270 E ^A = 50 (E ^c = 36) Δ = 14 Active substance/substances (Z119) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Viola tricolor A5 16 4 1 thirty 20 thirty (B2.18) diflufenican 270 90 thirty 60 50 50 A5 + (B2.18) diflufenican 16 + 270 16 + 90 16 + 30 4 + 90 4 + 30 1+90 1+30 f Μ Μ Μ Μ Μ Μ II II II II II II II , ΟΟ <| I II II II II II II , _7| — — CJ IJ IJ W

- 35 046017

Active substance/substances (Z119) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Viola tricolor A5 16 10 1 0 (B2.18) diflufenican 270 40 90 thirty thirty thirty A5 16 + 270 E ^a = 80 (E ^c = 46) Δ = 34 + 16 + 90 E ^A = 70 (E ^c = 37) Δ = 33 (B2.18) diflufenican 16 + 30 E ^A = 70 (E ^c = 37) Δ = 33 1+90 E ^A = 50 (E ^c = 30) Δ = 20 1+30 E ^A = 40 (E ^c = 30) Δ = 10

Table 3.2

Synergistic effect for herbicidal binary compositions in the post-emergence period containing herbicides from group B7

Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Digitaria sanguinalis (B7.4) glufosinate (CAS 77182-82-2) 450 50 75 15 Al 15 5 thirty 10 Al+ (B7.4) glufosinate (CAS 77182-82-2) 5+450 15 + 50 E ^a = 85 (E ^c = 78) Δ 7 E ^A = 70 (E ^c = 41) Δ30 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Echinochloa crus-galli (B7.4) glufosinate (CAS 77182-82-2) 150 50 35 15 Al 5 15 Al+ (B7.4) glufosinate (CAS 77182-82-2) 5 + 50 5 + 150 E ^A = 45 (E ^c = 28) Δ 17 E ^A = 70 (E ^c = 45) Δ25 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Eleusine indica (B7.4) glufosinate (CAS 77182-82-2) 450 50 70 10 Al 15 1.67 40 20 Al+ (B7.4) glufosinate (CAS 77182-82-2) 15 + 50 1.67 + 450 E ^a = 80 (E ^c = 46) Δ34 E ^a = 100 (E ^c = 76) Δ 24

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Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Setaria faberi (B7.4) glufosinate (CAS 77182-82-2) 50 10 Al 15 5 85 15 Al+ (B7.4) glufosinate (CAS 77182-82-2) 15 + 50 5 + 50 E ^A = 95 (E ^c = 87) Δ 9 E ^a = 35 (E ^c = 24) Δ 12 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Setaria viridis (B7.4) glufosinate (CAS 77182-82-2) 50 10 Al 15 5 1.67 90 75 10 Al+ (B7.4) glufosinate (CAS 77182-82-2) 5 + 50 15 + 50 1.67 + 50 E ^A = 85 (E ^c = 78) Δ 8 E ^A = 96 (E ^c = 91) Δ 5 E ^A = 25 (E ^c = 19) Δ 6 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Sorghum halepense (B7.4) glufosinate (CAS 77182-82-2) 150 50 35 10 Al 15 5 1.67 45 10 0 Al+ (B7.4) glufosinate (CAS 77182-82-2) 5 + 50 45 + 150 15 + 50 1.67 + 50 1.67 + 150 ^EA = 45 (E ^s = 19) Δ26 ^EA = 93 (E ^s = 64) Δ29 ^EA = 85 (E ^s = 51) Δ34 ^EA = 20 (E ^s = 10) Δ 10 ^EA = 45 ( E ^c = 35) Δ 10 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Abutilon theophrasti (B7.4) glufosinate (CAS 77182-82-2) 450 90 Al 15 5 100 Al+ (B7.4) glufosinate (CAS 77182-82-2) 5+450 15+450 E ^A = 100 (E ^c = 90) Δ 10 E ^a = 100 (E ^c = 91) Δ 9

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Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Euphorbia heterophylla (B7.4) glufosinate (CAS 77182-82-2) 150 50 15 15 Al 45 15 5 35 10 0 Al+ (B7.4) glufosinate (CAS 77182-82-2) 45 + 150 15 + 150 45 + 50 5 + 150 5 + 50 ^EA = 75 (E ^s = 45) AZO ^EA = 45 (E ^s = 23) A 22 ^EA = 95 (E ^s = 45) A 50 ^EA = 70 (E ^s = 15) A 55 ^EA = 40 (E ^c = 15) A 25 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Ipomoea purpurea (B7.4) glufosinate (CAS 77182-82-2) 450 150 50 80 70 20 Al 45 15 5 100 0 Al+ (B7.4) glufosinate (CAS 77182-82-2) 15+450 45 + 150 15 + 50 5+450 45 + 50 5 + 50 E ^A = 85 (E ^c = 80) A 5 E ^a = 85 (E ^c = 73) A 12 E ^A = 80 (E ^c = 20) A 60 E ^A = 90 (E ^c = 80) A 10 E ^A = 70 (E ^c = 28) A 42 E ^A = 50 (E ^c = 20) AZO Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Polygonum convulvulus (B7.4) glufosinate (CAS 77182-82-2) 450 150 50 45 40 10 Al 15 5 93 50 Al+ (B7.4) glufosinate (CAS 77182-82-2) 5 + 50 5 + 150 15+450 E ^a = 85 (E ^c = 55) AZO E ^a = 85 (E ^c = 70) A 15 E ^a = 100 (E ^c = 96) A 4

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Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Alopecurus myosuroides (sensitiver Biotyp) Al 15 5 60 0 (B7.4) glufosinate (CAS 77182-82-2) 450 150 50 40 20 0 Al+ (B7.4) glufosinate (CAS 77182-82-2) 15+450 15 + 150 15 + 50 5+450 5 + 150 E ^A = 97 (E ^c = 76) A 21 E ^a = 90 (E ^c = 68) A 22 E ^a = 80 (E ^c = 60) A 20 E ^a = 85 (E ^c = 40) A 45 E ^A = 30(E ^c = 20) A 10 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Alopecurus myosuroides (resistenter Biotyp) Al 15 5 60 10 (B7.4) glufosinate (CAS 77182-82-2) 450 150 thirty 10 Al+ (B7.4) glufosinate (CAS 77182-82-2) 15+450 15 + 150 5+450 E ^A = 85 (E ^c = 72) A 13 E ^A = 70 (E ^c = 64) A 6 E ^a = 85 (E ^c = 37) A 48 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Avena fatua Al 15 5 1.67 85 50 0 (B7.4) glufosinate (CAS 77182-82-2) 150 50 450 20 0 50 Al+ (B7.4) glufosinate (CAS 77182-82-2) 15 + 150 15 + 50 5+450 5 + 150 1.67 + 450 E ^a = 93 (E ^c = 88) A 5 E ^a = 90 (E ^c = 85) A 5 E ^A = 85 (E ^c = 75) A 10 E ^a = 85 (E ^c = 60) A 25 E ^A = 80 (E ^c = 50) A 30 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against EpoMUS sterilis Al 5 1.67 0 0 (B7.4) glufosinate (CAS 77182-82-2) 450 thirty Al+ (B7.4) glufosinate (CAS 77182-82-2) 5+450 1.67 + 450 E ^A = 40(E ^c = 30) A 10 E ^A = 40(E ^c = 30) A 10

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Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Galium aparine Al 5 0 (B7.4) glufosinate (CAS 77182-82-2) 50 0 Al+ (B7.4) glufosinate (CAS 77182-82-2) 5 + 50 E ^a = 20 (E ^c =0) Δ 20 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Hordeum murinum Al 15 5 80 0 (B7.4) glufosinate (CAS 77182-82-2) 450 150 20 10 Al+ (B7.4) glufosinate (CAS 77182-82-2) 15+450 5+450 5 + 150 E ^A = 95 (E ^c = 84) Δ 11 E ^A = 30 (E ^c = 20) Δ 10 E ^A = 30 (E ^c = 10) Δ 20 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Lamium purpureum Al 45 70 (B7.4) glufosinate (CAS 77182-82-2) 50 50 Al+ (B7.4) glufosinate (CAS 77182-82-2) 45 + 50 E ^A = 90 (E ^c = 85) Δ 5 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Lolium rigidum (sensitiver Biotyp) Al 15 0 (B7.4) glufosinate (CAS 77182-82-2) 150 50 0 0 Al+ (B7.4) glufosinate (CAS 77182-82-2) 15 + 150 15 + 50 E ^a = 20 (E ^c = 0) Δ 20 E ^A = 10 (E ^c = 0) Δ 10 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Lolium rigidum (resistenter Biotyp) Al 15 5 0 0 (B7.4) glufosinate (CAS 77182-82-2) 150 50 0 0 Al+ (B7.4) glufosinate (CAS 77182-82-2) 15 + 150 15 + 50 5 + 150 E ^A = 30(E ^c = 0) Δ 30 E ^a = 20 (E ^c = 0) Δ 20 E ^a = 20 (E ^c = 0) Δ 20

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Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Papaver rhoeas Al 5 40 (B7.4) glufosinate (CAS 77182-82-2) 450 50 70 20 Al+ (B7.4) glufosinate (CAS 77182-82-2) 5+450 5+50 E ^A = 95 (E ^c =82) Δ 13 E ^a = 85 (E ^c =52) Δ 33 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Phalaris minor Al 15 5 60 0 (B7.4) glufosinate (CAS 77182-82-2) 450 150 50 450 70 thirty 0 70 Al+ (B7.4) glufosinate (CAS 77182-82-2) 15+450 15 + 150 15 + 50 5+450 5 + 50 E ^a = 95 (E ^c = 88) Δ 7 E ^A = 90 (E ^c = 72) Δ 18 E ^A = 90 (E ^c = 60) Δ 30 E ^A = 85 (E ^c = 70) Δ 15 E ^a = 20 (E ^c = 0) Δ 20 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Roa annua Al 15 5 80 thirty (B7.4) glufosinate (CAS 77182-82-2) 150 50 20 0 Al+ (B7.4) glufosinate (CAS 77182-82-2) 15 + 150 15 + 50 5 + 50 E ^A = 90 (E ^c = 84) Δ 6 E ^A = 90 (E ^c = 80) Δ 10 E ^a = 40 (E ^c = 30) Δ 10 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Polygonum convolvulus Al 15 5 70 0 (B7.4) glufosinate (CAS 77182-82-2) 50 150 0 thirty Al+ (B7.4) glufosinate (CAS 77182-82-2) 15 + 50 5 + 150 5 + 50 E ^a = 90 (E ^c = 70) Δ 20 E ^a = 50 (E ^c = 30) Δ 20 E ^a = 30 (E ^c = 0) Δ 30

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Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Raphanus raphanistrum Al 5 80 (B7.4) glufosinate (CAS 77182-82-2) 150 50 thirty 0 Al+ (B7.4) glufosinate (CAS 77182-82-2) 5 + 150 5 + 50 E ^a = 95 (E ^c = 86) A 9 E ^A = 90 (E ^c = 80) A 10 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Veronica hederifolia Al 5 0 (B7.4) glufosinate (CAS 77182-82-2) 150 70 Al+ (B7.4) glufosinate (CAS 77182-82-2) 5 + 150 E ^A = 80 (E ^c =70) A 10 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Viola tricolor Al 15 5 20 0 (B7.4) glufosinate (CAS 77182-82-2) 450 50 70 0 Al+ (B7.4) glufosinate (CAS 77182-82-2) 15+450 15 + 50 5+450 5 + 50 E ^a = 98 (E ^c =76) A 22 E ^A = 30 (E ^c =20) A 10 E ^A = 80 (E ^c =70) A 10 E ^A = 30 (E ^c =0) A 30 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Brachiaria platyphylla (B7.4) glufosinate (CAS 77182-82-2) 50 thirty A2 15 5 1.7 10 0 0 A2 + (B7.4) glufosinate (CAS 77182-82-2) 15 + 50 5 + 50 1.7 + 50 E ^A = 50 (E ^c = 37) Δ 13 E ^a = 50 (E ^c = 30) A 20 E ^a = 60 (E ^c = 30) A 30 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Digitaria sanguinalis (B7.4) glufosinate (CAS 77182-82-2) 150 50 70 40 A2 5 1.7 0 0 A2 + (B7.4) glufosinate (CAS 77182-82-2) 5 + 150 1.7 + 150 1.7 + 50 E ^A = 80 (E ^c = 70) Δ 10 E ^a = 95 (E ^c = 70) Δ 25 E ^A = 55 (Ε° = 40) Δ 15

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Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Eleusine indica (B7.4) glufosinate (CAS 77182-82-2) 150 50 A2 5 35 A2 + (B7.4) glufosinate (CAS 77182-82-2) 5 + 150 E ^A = 85 (E ^c = 68) A 17 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Kochia scoparia (B7.4) glufosinate (CAS 77182-82-2) 50 10 A2 5 20 A2 + (B7.4) glufosinate (CAS 77182-82-2) 5 + 50 E ^A = 65 (E ^C = 28) A37 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Polygonum convulvulus (B7.4) glufosinate (CAS 77182-82-2) 50 thirty A2 5 80 A2 + (B7.4) glufosinate (CAS 77182-82-2) 5 + 50 E ^A = 97 (E ^c = 86) Δ 11 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Sorghum halepense (B7.4) glufosinate (CAS 77182-82-2) 450 150 50 80 50 20 A2 15 5 1.7 15 0 0 A2 + (B7.4) glufosinate (CAS 77182-82-2) 15+450 5+450 1.7 + 450 1.7 + 150 15 + 50 5 + 50 1.7 + 50 E ^A = 96 (E ^c = 83) Δ 13 E ^a = 100 (E ^c = 80) Δ 20 E ^A = 98 (E ^c = 80) Δ 18 E ^a = 75 (E ^c = 50) Δ 25 E ^A = 45 (E ^c = 32) Δ 13 E ^a = 35 (Ε° = 20)Δ 15 E ^a = 35 (Ε° = 20)Δ 15

- 43 046017

Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Kochia scoparia (B7.4) glufosinate (CAS 77182-82-2) 50 10 AZ 45 15 5 20 10 20 AZ + (B7.4) glufosinate (CAS 77182-82-2) 45 + 50 15 + 50 5 + 50 E ^a = 50 (E ^c = 28) A 22 E ^A = 40 (E ^c = 19) A 21 E ^a = 50 (E ^c = 28) A 22 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Pharbitis purpurea (B7.4) glufosinate (CAS 77182-82-2) 50 40 AZ 5 70 AZ + (B7.4) glufosinate (CAS 77182-82-2) 5 + 50 E ^A = 95 (E ^c = 82) A 13 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Alopecurus myosuroides A4 16 4 1 thirty thirty 10 (B7.4) glufosinate 450 150 50 thirty 20 20 A4 + (B7.4) glufosinate (CAS 77182-82-2) 16 + 450 16 + 150 16 + 50 4 + 450 1+450 Μ Μ Μ Μ Μ > > > > > II II II II II σ, ο οο ο ο 'θ'θ'θ'θ'θ II II II II II s_z > > > > > II II II II II N) — W N) and SO CN CN

Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Alopecurus myosuroides A4 16 10 4 10 1 0 (B7.4) glufosinate 450 10 (CAS 77182-82-2) 150 10 50 0 A4 16 + 450 E ^A = 60 (E ^c = 19) A = 41 + 16 + 150 E ^A = 60 (E ^c = 19) A = 41 (B7.4) glufosinate 16 + 50 E ^a = 80 (E ^c = 10) Δ = 70 (CAS 77182-82-2) 4 + 450 E ^A = 40 (E ^c = 19) Δ = 21 1+450 E ^A = 40 (E ^c = 10) Δ = 30 1 + 150 E ^A = 20 (E ^c = 10) Δ = 10 1+50 E ^A = 20 (E ^c = 0) Δ = 20

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Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against EpoMUS sterilis A4 16 4 1 90 thirty 10 (B7.4) glufosinate (CAS 77182-82-2) 50 450 150 0 10 0 A4 + (B7.4) glufosinate (CAS 77182-82-2) 16 + 50 4 + 450 1+450 1 + 150 1+50 and and and and _ω II II II II ιι and and ω _yu И Μ Μ «Ώ ο ο ο ο ^k q II II II II μ o o yu 3 g >>>>!> II II II II ιι Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Centaurea cyanus A4 4 1 thirty 10 (B7.4) glufosinate (CAS 77182-82-2) 450 150 50 70 70 40 A4 + (B7.4) glufosinate (CAS 77182-82-2) 4 + 450 1+450 1 + 150 1+50 E ^A = 93 (E ^c = 79) Δ = 14 E ^A = 88 (E ^c = 73) Δ = 15 E ^a = 80 (E ^c = 73) Δ = 7 E ^A = 60 (E ^c = 46) Δ = 14 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Centaurea cyanus A4 4 1 30 0 (B7.4) glufosinate (CAS 77182-82-2) 450 150 50 thirty thirty 20 A4 + (B7.4) glufosinate (CAS 77182-82-2) 4 + 450 1+450 1 + 150 1+50 E ^A = 70 (E ^c = 51) Δ = 19 E ^a = 70 (E ^c = 30) Δ = 40 E ^A = 60 (E ^c = 30) Δ = 30 E ^a = 50 (E ^c = 20) Δ = 30 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Galium aparine A4 16 4 1 60 40 thirty (B7.4) glufosinate (CAS 77182-82-2) 150 thirty A4 + (B7.4) glufosinate (CAS 77182-82-2) 16 + 150 4 + 150 1 + 150 E ^a = 80 (E ^c = 72) Δ = 8 E ^a = 70 (E ^c = 58) Δ = 12 E ^A = 70 (E ^c = 51) Δ = 19 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Galium aparine A4 16 20 (B7.4) glufosinate (CAS 77182-82-2) 50 thirty A4 + (B7.4) glufosinate (CAS 77182-82-2) 16 + 50 E ^a = 50 (E ^c = 44) Δ = 6

- 45 046017

Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Lamium purpureum L. A4 4 1 thirty thirty (B7.4) glufosinate (CAS 77182-82-2) 450 80 A4 + (B7.4) glufosinate (CAS 77182-82-2) 4 + 450 1+450 E ^a = 98 (E ^c = 86) A = 12 E ^a = 95 (E ^c = 86) A = 9 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Lamium purpureum L. A4 4 1 20 20 (B7.4) glufosinate (CAS 77182-82-2) 450 60 A4 + (B7.4) glufosinate (CAS 77182-82-2) 4 + 450 1+450 E ^A = 99 (E ^c = 68) A = 31 E ^a = 80 (E ^c = 68) A = 12 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Lolium rigidum (resistenter Biotyp) A4 1 0 (B7.4) glufosinate (CAS 77182-82-2) 450 20 A4 + (B7.4) glufosinate (CAS 77182-82-2) 1+450 E ^A = 30 (E ^c = 20) A = 10 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Poa annua L. A4 16 40 (B7.4) glufosinate (CAS 77182-82-2) 450 40 A4 + (B7.4) glufosinate (CAS 77182-82-2) 16 + 450 E ^A = 70 (E ^c = 64) A = 6 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Viola tricolor A4 16 4 1 40 thirty thirty (B7.4) glufosinate (CAS 77182-82-2) 150 450 50 70 A4 + (B7.4) glufosinate (CAS 77182-82-2) 16 + 150 4 + 450 4 + 150 1+450 1 + 150 E ^A = 85 (E ^c = 70) A = 15 E ^a = 88 (E ^c = 79) A = 9 E ^A = 70 (E ^c = 65) A = 5 E ^a = 85 (E ^c = 79) A = 6 E ^A = 80 (E ^c = 65) A = 15

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Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Viola tricolor A4 16 10 4 0 1 0 (B7.4) glufosinate 150 thirty 50 20 450 40 A4 16 + 150 E ^A = 70 (E ^c = 37) Δ = 33 + 16 + 50 E ^a = 50 (E ^c = 28) Δ = 22 (B7.4) glufosinate 4 + 450 E ^A = 70 (E ^c = 40) Δ = 30 4 + 150 E ^a = 50 (E ^c = 30) Δ = 20 4 + 50 E ^A = 40 (E ^c = 20) Δ = 20 1+450 E ^A = 75 (E ^c = 40) Δ = 35 1 + 150 E ^a = 70 (E ^c = 30) Δ = 40 1+50 E ^A = 40 (E ^c = 20) Δ = 20 Current Consumption rate Herbicidal effect in [%] 14 DAT substance/substances [g a.i./ha] against Alopecurus myosuroides A5 16 ΊΟ 4 50 1 thirty (B7.4) glufosinate 450 thirty (CAS 77182-82-2) 150 20 50 20 A5 16 + 450 E ^A = 100 (E ^c = 79) Δ = 21 + 16 + 150 E ^A = 95 (E ^c = 76) Δ = 19 (B7.4) glufosinate 16 + 50 E ^a = 85 (E ^c = 76) Δ = 9 (CAS 77182-82-2) 4 + 450 E ^A = 75 (E ^c = 65) Δ = 10 4 + 150 E ^A = 70 (E ^c = 60) Δ = 10 1+450 E ^A = 70 (E ^c = 51) Δ = 19 Current Consumption rate Herbicidal effect in [%] 28 DAT substance/substances [g a.i./ha] against Alopecurus myosuroides A5 16 40 4 40 (B7.4) glufosinate 450 10 (CAS 77182-82-2) 150 10 50 0 A5 16 + 450 E ^A = 100 (E ^c = 46) Δ = 54 + 16 + 150 E ^A = 100 (E ^c = 46) Δ = 54 (B7.4) glufosinate 16 + 50 E ^A = 70 (E ^c = 40) Δ = 30 (CAS 77182-82-2) 4 + 450 E ^A = 60 (E ^c = 46) Δ = 14 Current Consumption rate Herbicidal effect in [%] 14 DAT substance/substances [g a.i./ha] against EpoMUS sterilis A5 16 85 1 20 (B7.4) glufosinate 450 thirty (CAS 77182-82-2) 150 20 50 20 A5 16 + 450 E ^A = 95 (E ^c = 90) Δ = 5 + 16 + 150 E ^A = 93 (E ^c = 88) Δ = 5 (B7.4) glufosinate 16 + 50 E ^A = 93 (E ^c = 88) Δ = 5 (CAS 77182-82-2) 1+450 E ^A = 60 (E ^c = 44) Δ = 16

- 47 046017

Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Epomus sterilis A5 4 60 (B7.4) glufosinate (CAS 77182-82-2) 450 10 A5+ (B7.4) glufosinate (CAS 77182-82-2) 4 + 450 E ^A = 80 (E ^c = 64) Δ = 16 Wirkung Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Centaurea cyanus A5 16 1 ΊΟ 40 (B7.4) glufosinate (CAS 77182-82-2) 450 150 70 70 A5+ (B7.4) glufosinate (CAS 77182-82-2) 16 + 450 1 + 150 E ^A = 97 (E ^c = 91) Δ = 6 E ^A = 98 (E ^c = 82) Δ = 16 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Centaurea cyanus A5 16 1 50 10 (B7.4) glufosinate (CAS 77182-82-2) 450 50 thirty 20 A5 + (B7.4) glufosinate (CAS 77182-82-2) 16 + 450 1+450 1 +50 E ^A = 70 (E ^c = 65) Δ = 5 E ^a = 60 (E ^c =37) Δ = 23 E ^a = 50 (E ^c =28) Δ = 22 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Galium aparine A5 1 50 (B7.4) glufosinate (CAS 77182-82-2) 150 thirty A5+ (B7.4) glufosinate (CAS 77182-82-2) 1 + 150 E ^A = 70 (E ^c = 65) Δ = 5 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Lamium purpureum L. A5 1 60 (B7.4) glufosinate (CAS 77182-82-2) 450 80 A5+ (B7.4) glufosinate (CAS 77182-82-2) 1+450 E ^A = 97 (E ^c = 92) Δ = 5 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Lamium purpureum L. A5 1 40 (B7.4) glufosinate (CAS 77182-82-2) 450 60 A5 + (B7.4) glufosinate (CAS 77182-82-2) 1+450 E ^a = 85 (E ^c = 76) Δ = 9

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Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Lolium rigidum A5 16 thirty (B7.4) glufosinate (CAS 77182-82-2) 150 50 20 10 A5+ (B7.4) glufosinate (CAS 77182-82-2) 16 + 150 16 + 50 E ^a = 50 (E ^c = 44) A = 6 E ^A = 50 (E ^c = 37) A = 13 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Lolium rigidum (resistenter Biotyp) A5 16 thirty (B7.4) glufosinate (CAS 77182-82-2) 450 150 50 thirty 20 10 A5+ (B7.4) glufosinate (CAS 77182-82-2) 16 + 450 16 + 150 16 + 50 E ^A = 60 (E ^c = 51) A = 9 E ^a = 70 (E ^c = 44) A = 26 E ^a = 60 (E ^c = 37) A = 23 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Phalaris minor A5 16 40 (B7.4) glufosinate (CAS 77182-82-2) 450 150 thirty 20 A5+ (B7.4) glufosinate (CAS 77182-82-2) 16 + 450 16 + 150 E ^A = 70 (E ^c = 58) A = 12 E ^A = 60 (E ^c = 52) A = 8 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Poa annua L. A5 16 thirty (B7.4) glufosinate (CAS 77182-82-2) 450 150 50 40 thirty 20 A5+ (B7.4) glufosinate (CAS 77182-82-2) 16 + 450 16 + 150 16 + 50 E ^a = 80 (E ^c = 58) A = 22 E ^A = 60 (E ^c = 51) A = 9 E ^a = 50 (E ^c = 44) A = 6 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Poa annua L. A5 16 20 (B7.4) glufosinate (CAS 77182-82-2) 450 thirty A5 + (B7.4) glufosinate (CAS 77182-82-2) 16 + 450 E ^a = 50 (E ^c = 44) A = 6

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Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Viola tricolor A5 16 4 1 thirty 20 thirty (B7.4) glufosinate (CAS 77182-82-2) 150 50 450 50 thirty 70 A5+ (B7.4) glufosinate (CAS 77182-82-2) 16 + 150 16 + 50 4 + 450 4 + 150 4 + 50 1 + 150 1 +50 E ^A = 80 (E ^c = 65) Δ = 15 E ^A = 60 (E ^c = 51) Δ = 9 E ^A = 90 (E ^c = 76) Δ = 14 E ^a = 80 (E ^c = 60) Δ = 20 E ^a = 70 (E ^c = 44) Δ = 26 E ^A = 70 (E ^c = 65) Δ = 5 E ^A = 60 (E ^c = 51) Δ = 9 Active substance/substances Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Viola tricolor A5 16 4 1 10 0 0 (B7.4) glufosinate (CAS 77182-82-2) 150 450 50 thirty 40 20 A5+ (B7.4) glufosinate (CAS 77182-82-2) 16 + 150 4 + 450 4 + 150 4 + 50 1+450 1 + 150 1+50 E ^a = 60 (E ^c =37) Δ = 23 E ^A = 70 (E ^c = 40) Δ = 30 E ^a = 50 (E ^c =30) Δ = 20 E ^a = 60 (E ^c =20) Δ = 40 Е ^А = 50 (Е ^с = 40) Δ = 10 Е ^А = 40 (Е ^с = 30) Δ = 10 Е ^а = 40 (Е ^с =20) Δ = 20 Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Digitaria sanguinalis (B7.5) glyphosate (CAS 38641-94-0) 50 45 Al 15 thirty Al+ (B7.5) glyphosate (CAS 38641-94-0) 15 + 50 E ^A = 80 (E ^c = 62) Δ19 Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Sorghum halepense (B7.5) glyphosate (CAS 38641-94-0) 50 thirty Al 15 1.67 45 0 Al+ (B7.5) glyphosate (CAS 38641-94-0) 15 + 50 1.67 + 50 E ^A = 85 (E ^c = 63) Δ24 E ^A = 40 (E ^c = 30) Δ 10

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Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Setaria viridis (B7.5) glyphosate (CAS 38641-94-0) 450 95 A1 1.67 10 A1 + (B7.5) glyphosate (CAS 38641-94-0) 1.67 + 450 E ^a = 100 (E ^c = 95) A 5 Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Abutilon theophrasti (B7.5) glyphosate (CAS 38641-94-0) 450 85 Al 5 0 Al+ (B7.5) glyphosate (CAS 38641-94-0) 5+450 E ^A = 98 (E ^c = 85) A 13 Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Euphorbia heterophylla (B7.5) glyphosate (CAS 38641-94-0) 450 150 50 70 35 10 Al 45 15 5 35 10 0 Al+ (B7.5) glyphosate (CAS 38641-94-0) 45 +450 45 + 150 45 + 50 15+450 5+450 5 + 150 15 + 50 E ^a = 85 (E ^c = 80) A 5 E ^A = 65 (E ^c = 58) A 7 E ^A = 50 (E ^c = 41) A 9 E ^A = 90 (E ^c = 73) A 17 E ^A = 95 (E ^c = 70) A 25 E ^A = 60 (E ^c = 35) A 25 E ^a = 35 (E ^c = 19) A 16

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Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Ipomoea purpurea (B7.5) glyphosate (CAS 38641-94-0) 450 150 50 65 50 15 Al 45 15 5 100 0 Al+ (B7.5) glyphosate (CAS 38641-94-0) 45 +450 45 + 50 15+450 15 + 150 15 + 50 5+450 5 + 150 5 + 50 Мйш1т11т11т1|т|й > >> > > >> > II II II II II II II II Ώ and Ώ Ώ d II II II II II II II II — Ui Qx — Ui О+ [xj from O from 'from O from 4^ 0 >>>>>>>> and and 'l and W „ and o 'l 'l o S'so Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Polygonum convulvulus (B7.5) glyphosate (CAS 38641-94-0) 450 150 50 40 10 0 Al 15 5 93 50 Al+ (B7.5) glyphosate (CAS 38641-94-0) 15 + 150 5+450 5 + 150 5 + 50 E ^A = 98 (E ^c = 94) Δ 4 E ^A = 75 (E ^c = 70) Δ 5 E ^A = 97 (E ^c = 55) Δ42 E ^A = 65 (E ^c = 50) Δ 15 Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Alopecurus myosuroides (sensitive! Biotyp) Al 15 5 60 0 (B7.5) glyphosate (CAS 38641-94-0) 150 50 20 0 Al+ (B7.5) glyphosate (CAS 38641-94-) 15 + 150 5 + 50 E ^A = 80 (E ^c = 68) Δ 12 E ^a = 20 (E ^c = 0) Δ 20 Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Alopecurus myosuroides (resistenter Biotyp) Al 15 60 (B7.5) glyphosate (CAS 38641-94-0) 150 0 Al+ (B7.5) glyphosate (CAS 38641-94-0) 15 + 150 E ^A = 70 (E ^c = 60) Δ 10

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Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Avena fatua Al 5 50 (B7.5) glyphosate (CAS 38641-94-0) 150 20 Al+ (B7.5) glyphosate (CAS 38641-94-0) 5 + 150 E ^a = 80 (E ^c = 60) A 20 Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against EpoMUS sterilis Al 5 0 (B7.5) glyphosate (CAS 38641-94-0) 50 0 Al+ (B7.5) glyphosate (CAS 38641-94-0) 5 + 50 E ^a = 10 (E ^c = 0) A 10 Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Centaurea cyanus Al 15 5 thirty 20 (B7.5) glyphosate (CAS 38641-94-0) 450 60 Al+ (B7.5) glyphosate (CAS 38641-94-0) 15+450 5+450 E ^a = 80 (E ^c = 72) A 8 E ^A = 85 (E ^c = 68) A 17 Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Galium aparine Al 45 15 5 50 thirty 0 (B7.5) glyphosate (CAS 38641-94-0) 450 150 50 50 20 0 Al+ (B7.5) glyphosate (CAS 38641-94-0) 45 +450 15+450 5+450 5 + 150 5 + 50 E ^A = 80 (E ^c = 75) A 5 E ^A = 80 (E ^c = 65) A 15 E ^a = 70 (E ^c = 50) A 20 E ^A = 30 (E ^c = 20) A 10 E ^a = 10(E ^c = 0) A 10 Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Hordeum murinum Al 5 0 (B7.5) glyphosate (CAS 38641-94-0) 50 10 Al+ (B7.5) glyphosate (CAS 38641-94-0) 5 + 50 E ^a = 20 (E ^c = Yu) Δ 10

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Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Lamium purpureum Al 15 5 50 20 (B7.5) glyphosate (CAS 38641-94-0) 150 450 60 80 Al+ (B7.5) glyphosate (CAS 38641-94-0) 15 + 150 5+450 E ^A = 90 (E ^c = 80) Δ 10 E ^A = 90 (E ^c = 84) Δ 6 Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Lolium rigidum (sensitiver Biotyp) Al 15 5 1.67 0 0 0 (B7.5) glyphosate (CAS 38641-94-0) 450 150 50 0 Al+ (B7.5) glyphosate (CAS 38641-94-0) 15+450 15 + 150 5+450 1.67 + 450 E ^A = 80 (E ^c = 50) Δ 30 E ^A = 20 (E ^c = 0) Δ 20 E ^A = 60 (E ^c = 50) Δ 10 E ^A = 70 (E ^c = 50) Δ 20 Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Lolium rigidum (resistenter Biotyp) Al 15 5 1.67 0 0 0 (B7.5) glyphosate (CAS 38641-94-0) 450 150 50 20 0 0 Al+ (B7.5) glyphosate (CAS 38641-94-0) 15+450 15 + 150 15 + 50 5+450 5 + 150 1.67 + 450 E ^A = 50(E ^c = 20) Δ 30 E ^A = 20 (E ^c = 0) Δ 20 E ^A = 20 (E ^c = 0) Δ 20 E ^A = 60(E ^c = 20) Δ 40 E ^A = 10(E ^c = 0) Δ 10 E ^A = 70(E ^c = 20) Δ 50 Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Phalaris minor Al 15 5 60 0 (B7.5) glyphosate (CAS 38641-94-0) 150 50 10 0 Al+ (B7.5) glyphosate (CAS 38641-94-0) 15 + 150 5 + 150 5 + 50 E ^a = 90 (E ^c = 64) Δ 26 E ^A = 30 (E ^c = 10) Δ 20 E ^a = 20 (E ^c = 0) Δ 20

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Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Polygonum convolvulus Al 15 5 70 0 (B7.5) glyphosate (CAS 38641-94-0) 450 150 50 0 0 0 Al+ (B7.5) glyphosate (CAS 38641-94-0) 15+450 15 + 150 15 + 50 5+450 5 + 150 5 + 50 E ^a = 90 (E ^c = 70) A 20 E ^a = 90 (E ^c = 70) A 20 E ^a = 90 (E ^c = 70) A 20 E ^a = 40 (E ^c = 0) A 40 E ^A = 80 (E ^c = 0) A 80 E ^A = 70 (E ^c = 0) A 70 Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Raphanus raphanistrum Al 5 80 (B7.5) glyphosate (CAS 38641-94-0) 450 50 thirty 0 Al+ (B7.5) glyphosate (CAS 38641-94-0) 5+450 5+50 E ^a = 95 (E ^c = 86) A 9 E ^a = 85 (E ^c = 80) A 5 Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Stellaria media Al 5 0 (B7.5) glyphosate (CAS 38641-94-0) 450 85 Al+ (B7.5) glyphosate (CAS 38641-94-0) 5+450 E ^a = 93 (E ^c = 85) A 8 Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Veronica hederifolia Al 5 0 (B7.5) glyphosate (CAS 38641-94-0) 450 150 85 85 Al+ (B7.5) glyphosate (CAS 38641-94-0) 5+450 5 + 150 E ^A = 95 (E ^c = 85) A 10 E ^A = 90 (E ^c = 85) A 5

- 55 046017

Active substance/substances (Z20) Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Viola tricolor Al 15 5 20 0 (B7.5) glyphosate (CAS 38641-94-0) 450 50 thirty 0 Al+ (B7.5) glyphosate (CAS 38641-94-0) 15+450 5+450 5 + 50 E ^a = 70 (E ^c = 44) A 26 E ^a = 80 (E ^c = 30) A 50 E ^a = 20 (E ^c = 0) A 20 Active substance/substances Z49 Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Amaranthus palmeri (res.) (B7.5) glyphosate (CAS 38641-94-0) 450 150 50 35 20 10 A2 15 5 65 15 A2 + (B7.5) glyphosate (CAS 38641-94-0) 15+450 5 + 150 15 + 50 5 + 50 O', SP — — — C-I < < < < (G s7 o/ A G' sp ό οι II II II II O' pG oo nlll II II II < < < < I I I Active substance/substances Z49 Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Brachiaria platyphylla (B7.5) glyphosate (CAS 38641-94-0) 50 80 A2 1.7 0 A2 + (B7.5) glyphosate (CAS 38641-94-0) 1.7 + 50 E ^A = 93 (E ^c = 80) A 13 Active substance/substances Z49 Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Digitaria sanguinalis (B7.5) glyphosate (CAS 38641-94-0) 50 65 A2 15 5 1.7 10 0 0 A2 + (B7.5) glyphosate (CAS 38641-94-0) 15 + 50 5 + 50 1.7 + 50 E ^A = 85 (E ^c = 69) A 16 E ^a = 98 (E ^c = 65) A 33 E ^a = 96 (E ^c = 65) A 31

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Active substance/substances Z49 Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Echinochloa crus-galli (B7.5) glyphosate (CAS 38641-94-0) 50 20 A2 5 1.7 20 10 A2 + (B7.5) glyphosate (CAS 38641-94-0) 5 + 50 1.7 + 50 E ^a = 80 (E ^c = 36) Δ 44 E ^a = 55 (E ^c = 28) Δ 27 Active substance/substances Z49 Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Eleusine indica (B7.5) glyphosate (CAS 38641-94-0) 150 50 80 40 A2 15 5 1.7 45 35 thirty A2 + (B7.5) glyphosate (CAS 38641-94-0) 5 + 150 15 + 50 5 + 50 1.7 + 50 E ^A = 100(Ε° = 87)Δ 13 E ^A = 98 (E° = 67)Δ31 E ^a = 75 (E ^c = 61) Δ 14 E ^a = 85 (E ^c = 58) Δ 27

Active substance/substances Ζ49 Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Kochia scoparia (B7.5) glyphosate (CAS 38641-94-0) 50 20 A2 15 5 20 20 A2 + (B7.5) glyphosate (CAS 38641-94-0) 15 + 50 5 + 50 E ^a = 75 (E ^c = 36) Δ 39 E ^a = 60 (E ^c = 36) Δ 24 Active substance/substances Z49 Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Pharbitis purpurea (B7.5) glyphosate (CAS 38641-94-0) 50 40 A2 5 75 A2 + (B7.5) glyphosate (CAS 38641-94-0) 5 + 50 E ^A = 96 (E ^c = 85) Δ 11

- 57 046017

Active substance/substances Z49 Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Polygonum convolvulus (B7.5) glyphosate (CAS 38641-94-0) 50 20 A2 5 80 A2 + (B7.5) glyphosate (CAS 38641-94-0) 5 + 50 E ^a = 96 (E ^c = 84) A 12 Active substance/substances Z49 Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Sorghum halepense (B7.5) glyphosate (CAS 38641-94-0) 50 thirty A2 15 5 1.7 15 0 0 A2 + (B7.5) glyphosate (CAS 38641-94-0) 15 + 50 5 + 50 1.7 + 50 E ^a = 99 (E ^c = 41) A 59 E ^a = 93 (E ^c = 30) A 63 E ^a = 80 (E ^c = 30) A 50 Active substance/substances Z78 Consumption rate [g a.i./ha] Herbicidal effect 28 DAT [%] against Amaranthus palmeri (res.) (B7.5) glyphosate (CAS 38641-94-0) 450 150 35 20 AZ 45 15 20 10 AZ + (B7.5) glyphosate (CAS 38641-94-0) 15+450 45 + 150 E ^a = 75 (E ^c = 42) A 33 E ^a = 50 (E ^c = 36) A 14 Active substance/substances Z78 Consumption rate [g a.i./ha] Herbicidal effect of 28 DAT [%] against Kochia scoparia (B7.5) glyphosate (CAS 38641-94-0) 50 20 AZ 45 20 AZ + (B7.5) glyphosate (CAS 38641-94-0) 45 + 50 E ^a = 50 (E ^c = 36) A 14 Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Alopecurus myosuroides A4 16 1 thirty 10 (B7.5) glyphosate (CAS 38641-94-0) 50 150 thirty 60 A4 + (B7.5) glyphosate (CAS 38641-94-0) 16 + 50 1 + 150 E ^A = 70 (E ^c = 51) A = 19 E ^A = 70 (E ^c = 64) A = 6

- 58 046017

Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Alopecurus myosuroides A4 1 0 (B7.5) glyphosate (CAS 38641-94-0) 150 thirty A4 + (B7.5) glyphosate (CAS 38641-94-0) 1 + 150 E ^A = 40 (E ^c = 30) Δ = 10 Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Epomus sterilis A4 1 20 (B7.5) glyphosate (CAS 38641-94-0) 150 50 A4 + (B7.5) glyphosate (CAS 38641-94-0) 1 + 150 E ^a = 80 (E ^c = 60) Δ = 20 Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Epomus sterilis A4 4 1 thirty 10 (B7.5) glyphosate (CAS 38641-94-0) 450 150 60 20 A4 + (B7.5) glyphosate (CAS 38641-94-0) 4 + 450 1+450 1 + 150 E ^a = 80 (E ^c = 72) Δ = 8 E ^A = 85 (E ^c = 64) Δ = 21 E ^A = 40 (E ^c = 28) Δ = 12 Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Centaurea cyanus A4 16 4 40 thirty (B7.5) glyphosate (CAS 38641-94-0) 50 50 A4 + (B7.5) glyphosate (CAS 38641-94-0) 16 + 50 4 + 50 E ^A = 80 (E ^c = 70) Δ = 10 E ^A = 75 (E ^c = 65) Δ = 10 Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Galium aparine A4 16 20 (B7.5) glyphosate (CAS 38641-94-0) 450 150 50 40 A4 + (B7.5) glyphosate (CAS 38641-94-0) 16 + 450 16 + 150 E ^a = 80 (E ^c = 60) Δ = 20 E ^a = 60 (E ^c = 52) Δ = 8

- 59 046017

Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Lamium purpureum L. A4 4 thirty (B7.5) glyphosate (CAS 38641-94-0) 150 50 60 50 A4 + (B7.5) glyphosate (CAS 38641-94-0) 4 + 150 4 + 50 E ^a = 80 (E ^c = 72) A = 8 E ^A = 70 (E ^c = 65) A = 5 Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Lamium purpureum L. A4 1 20 (B7.5) glyphosate (CAS 38641-94-0) 450 80 A4 + (B7.5) glyphosate (CAS 38641-94-0) 1+450 E ^A = 95 (E ^c = 84) A = 11 Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Lolium rigidum A4 4 10 (B7.5) glyphosate (CAS 38641-94-0) 450 40 A4 + (B7.5) glyphosate (CAS 38641-94-0) 4 + 450 E ^A = 65 (E ^c = 46) A = 19 Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Lolium rigidum (resistenter Biotyp) A4 4 1 10 10 (B7.5) glyphosate (CAS 38641-94-0) 450 150 40 thirty A4 + (B7.5) glyphosate (CAS 38641-94-0) 4 + 450 4 + 150 1+450 1 + 150 E ^A = 60 (E ^c = 46) A = 14 E ^A = 50 (E ^c = 37) A = 13 E ^A = 70 (E ^c = 46) A = 24 E ^A = 50 (E ^c = 37) A = 13 Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Lolium rigidum (resistenter Biotyp) A4 4 0 (B7.5) glyphosate (CAS 38641-94-0) 450 150 50 thirty 20 10 A4 + (B7.5) glyphosate (CAS 38641-94-0) 4 + 450 4 + 150 4 + 50 E ^A = 40 (E ^c = 30) A = 10 E ^A = 30 (E ^c = 20) A = 10 E ^A = 20 (E ^c = 10) A = 10

- 60 046017

Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Matricaria inodora A4 4 1 thirty 40 (B7.5) glyphosate (CAS 38641-94-0) 150 50 88 40 A4 + (B7.5) glyphosate (CAS 38641-94-0) 4 + 150 4 + 50 1+50 E ^A = 97 (E ^c = 92) A = 5 E ^A = 80 (E ^c = 58) A = 22 E ^A = 70 (E ^c = 64) A = 6 Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Matricaria inodora A4 4 1 10 10 (B7.5) glyphosate (CAS 38641-94-0) 450 150 50 80 75 20 A4 + (B7.5) glyphosate (CAS 38641-94-0) 4 + 450 4 + 150 4 + 50 1+50 E ^a = 90 (E ^c = 82) A = 8 E ^a = 85 (E ^c = 78) A = 7 E ^A = 60 (E ^c = 28) A = 32 E ^a = 50 (E ^c = 28) A = 22 Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Phalaris minor A4 4 10 (B7.5) glyphosate (CAS 38641-94-0) 450 150 60 40 A4 + (B7.5) glyphosate (CAS 38641-94-0) 4 + 450 4 + 150 E ^A = 70 (E ^c = 64) A = 6 E ^A = 60 (E ^c = 46) A = 14 Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Roa annua L. A4 16 1 40 20 (B7.5) glyphosate (CAS 38641-94-0) 50 20 A4 + (B7.5) glyphosate (CAS 38641-94-0) 16 + 50 1+50 E ^a = 60 (E ^c = 52) A = 8 E ^A = 50 (E ^c = 36) A = 14 Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Viola tricolor A4 4 1 thirty thirty (B7.5) glyphosate (CAS 38641-94-0) 450 50 60 50 A4 + (B7.5) glyphosate (CAS 38641-94-0) 4 + 450 1+50 E ^A = 85 (E ^c = 72) A = 13 E ^A = 75 (E ^c = 65) A = 10

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Active substance/substances (Z107) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Viola tricolor A4 4 1 0 0 (B7.5) glyphosate (CAS 38641-94-0) 450 150 50 20 20 20 A4 + (B7.5) glyphosate (CAS 38641-94-0) 4 + 450 4 + 150 4 + 50 1+450 1 + 150 1+50 tn tn tn tn tn tn >>>>>> II II II II II II o o o o o o and Έτί Έτί Έτί tn Έπϊ II II II II II II and and and and '--' ---- ' ----' ----' ----' ----' >>>>>> II II II II II II Active substance/substances (Z136) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Alopecurus myosuroides A5 16 ΊΟ (B7.5) glyphosate (CAS 38641-94-0) 50 thirty A5 + (B7.5) glyphosate (CAS 38641-94-0) 16 + 50 E ^A = 95 (E ^c = 79) A = 16 Active substance/substances (Z136) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Alopecurus myosuroides A5 16 40 (B7.5) glyphosate (CAS 38641-94-0) 150 50 thirty 20 A5 + (B7.5) glyphosate (CAS 38641-94-0) 16 + 150 16 + 50 E ^A = 75 (E ^c = 58) A = 17 E ^A = 98 (E ^c = 52) A = 46 Active substance/substances (Z136) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Centaurea cyanus A5 16 4 1 50 20 10 (B7.5) glyphosate (CAS 38641-94-0) 150 450 50 70 80 thirty A5 + (B7.5) glyphosate (CAS 38641-94-0) 16 + 150 4 + 450 4 + 150 4 + 50 1+450 1 + 150 E ^A = 100 (E ^c = 85) A = 15 E ^A = 100 (E ^c = 84) A = 16 E ^A = 95 (E ^c = 76) A = 19 E ^A = 60 (E ^c = 44) A = 16 EA ^A = 100 (E ^s = 82) A = 18 EA ^A = 85 (E ^s = 73) A = 12 Active substance/substances (Z136) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Galium aparine A5 1 thirty (B7.5) glyphosate (CAS 38641-94-0) 450 50 A5 + (B7.5) glyphosate (CAS 38641-94-0) 1+450 E ^A = 70 (E ^c = 65) A = 5

- 62 046017

Active substance/substances (Z136) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Lamium purpureum L. A5 16 1 60 40 (B7.5) glyphosate (CAS 38641-94-0) 150 50 50 thirty A5 + (B7.5) glyphosate (CAS 38641-94-0) 16 + 150 16 + 50 1 + 150 E ^a = 85 (E ^c =80) Δ = 5 E ^a = 80 (E ^c =72) Δ = 8 E ^A = 75 (E ^c = 70) Δ = 5 Active substance/substances (Z136) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Lolium rigidum A5 16 60 (B7.5) glyphosate (CAS 38641-94-0) 50 10 A5+ 16 + 50 E ^A = 70 (E ^c = 64) Δ = 6 (B7.5) glyphosate (CAS 38641-94-0) Active substance/substances (Z136) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Lolium rigidum (resistenter Biotyp) A5 16 4 1 thirty 20 10 (B7.5) glyphosate (CAS 38641-94-0) 450 50 150 40 10 thirty A5 + (B7.5) glyphosate (CAS 38641-94-0) 16 + 450 16 + 50 4 + 450 4 + 150 1+450 ΓΙ T - ~ G | - G| II II II II II < < < < < OO G' CT Tf- Ό II II II II II sch sch sch sch ---- .--- .--- .--· ° ° g § θ II II II II II < < < < < sch sch sch sch Active substance/substances (Z136) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Matricaria inodora A5 16 4 1 50 50 thirty (B7.5) glyphosate (CAS 38641-94-0) 50 40 A5 + (B7.5) glyphosate (CAS 38641-94-0) 16 + 50 4 + 50 1+50 E ^A = 75 (E ^c = 70) Δ = 5 E ^A = 80 (E ^c = 70) Δ = 10 E ^A = 70 (E ^c = 58) Δ = 12 Active substance/substances (Z136) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Matricaria inodora A5 16 4 1 20 10 0 (B7.5) glyphosate (CAS 38641-94-0) 50 450 20 80 A5 + (B7.5) glyphosate (CAS 38641-94-0) 16 + 50 4 + 450 4 + 50 1+50 E ^A = 60 (E ^c = 36) Δ = 24 E ^A = 95 (E ^c = 82) Δ = 13 E ^a = 50 (E ^c = 28) Δ = 22 E ^A = 40 (E ^c = 20) Δ = 20

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Active substance/substances (Z136) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Phalaris minor A5 16 4 40 thirty (B7.5) glyphosate (CAS 38641-94-0) 50 450 150 20 60 40 A5 + (B7.5) glyphosate (CAS 38641-94-0) 16 + 50 4 + 450 4 + 150 E ^a = 80 (E ^c = 52) A = 28 E ^A = 85 (E ^c = 72) A = 13 E ^A = 75 (E ^c = 58) A = 17 Active substance/substances (Z136) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Roa annua L. A5 16 thirty (B7.5) glyphosate (CAS 38641-94-0) 50 20 A5 + (B7.5) glyphosate (CAS 38641-94-0) 16 + 50 E ^A = 70 (E ^c = 44) A = 26 Active substance/substances (Z136) Consumption rate [g a.i./ha] Herbicidal effect in [%] 14 DAT against Viola tricolor A5 4 1 20 thirty (B7.5) glyphosate (CAS 38641-94-0) 450 50 60 50 A5 + (B7.5) glyphosate (CAS 38641-94-0) 4 + 450 4 + 50 1+450 E ^a = 88 (E ^c = 68) A = 20 E ^A = 65 (E ^c = 60) A = 5 E ^A = 88 (E ^c = 72) A = 16 Active substance/substances (Z136) Consumption rate [g a.i./ha] Herbicidal effect in [%] 28 DAT against Viola tricolor A5 16 4 1 10 0 0 (B7.5) glyphosate (CAS 38641-94-0) 450 150 50 20 20 20 A5 + (B7.5) glyphosate (CAS 38641-94-0) 16 + 450 16 + 150 4 + 450 4 + 150 4 + 50 1+450 1 + 150 1+50 ci ci κ. o o o o o o- GS 'G. GS S1 'G. 'G. GS II II II II II II II II <<<<<<I<I< oooooooooooooooooo S| C| C| C| C| C| C| C| II II II II II II II II - .—, . . . . . · . θθ,Γθθθθθ II II II II II II II II <<<<<<<<

Claims (9)

1. A herbicidal composition containing herbicidal compounds (A) and (B), wherein component (A) is selected from A1, A2, A3, A4 and A5, or an agrochemically acceptable salt of these compounds, wherein A1-A5 have the following definitions: and component (B) is selected from (B2.18) diflufenican; (B7.4) glyphosinate; (B7.5) glyphosate. 2. Herbicidal composition according to claim 1, characterized in that the components of the active substances (A) and (B) are contained in a mass ratio of 1:15000-500:1. 3. Herbicidal composition according to claim 1 or 2, additionally containing one or more additives common in plant protection. 4. A method of controlling weeds, characterized in that the components of the active ingredients of the herbicidal composition according to one of claims 1-3 are applied to plants, parts of plants, plant seeds or crop area. 5. The method according to claim 4, characterized in that the components of the active ingredients of the herbicidal composition, together or separately, in the pre-emergence period, post-emergence period or in the pre- and post-emergence period are applied to plants, parts of plants, plant seeds or the sown area. 6. The method according to claim 5, characterized in that the herbicidal component (A) is applied at a consumption rate of 0.01-1000 g a.i./ha. 7. The method according to claim 5, characterized in that the herbicidal component (B) is applied at a consumption rate of 0.01-4000 g a.i./ha. 8. A method according to one of claims 5-7 for controlling weeds by treating them before sowing cultivated plants and in plantation crops, as well as on uncultivated soils. 9. Use of a herbicidal composition according to one of claims 1-3 to control weeds.