EA012807B2 - Catalyst for the oxidative demercaptanization of oil and oil distillates and a method for producing said catalyst - Google Patents

Catalyst for the oxidative demercaptanization of oil and oil distillates and a method for producing said catalyst

Info

Publication number
EA012807B2
EA012807B2 EA200900594A EA200900594A EA012807B2 EA 012807 B2 EA012807 B2 EA 012807B2 EA 200900594 A EA200900594 A EA 200900594A EA 200900594 A EA200900594 A EA 200900594A EA 012807 B2 EA012807 B2 EA 012807B2
Authority
EA
Eurasian Patent Office
Prior art keywords
oil
catalyst
distillates
producing
oxidative
Prior art date
Application number
EA200900594A
Other languages
Russian (ru)
Other versions
EA200900594A3 (en
EA200900594A2 (en
EA012807B1 (en
Inventor
Игорь Валентинович ИСИЧЕНКО
Инна Владимировна ПЛЕТНЕВА
Original Assignee
Ввса Инвестментс Групп Инк.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ввса Инвестментс Групп Инк. filed Critical Ввса Инвестментс Групп Инк.
Priority to EA200900594A priority Critical patent/EA012807B2/en
Priority to PCT/IB2009/006509 priority patent/WO2010136842A1/en
Publication of EA200900594A2 publication Critical patent/EA200900594A2/en
Publication of EA200900594A3 publication Critical patent/EA200900594A3/en
Publication of EA012807B1 publication Critical patent/EA012807B1/en
Publication of EA012807B2 publication Critical patent/EA012807B2/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/08—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of copper chloride
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The invention relates to a method for producing catalysts for the oxidative removal of oil and oil distillates, in particular from furnace fuel oil, and can be used in the oil production industry. The proposed homogeneous catalyst for the oxidative demercaptanization of oil and oil distillates is based on chlorides, acetates or naphthenates of cobalt, nickel or copper or copper oxychloride and nitrogen-containing ligands, i.e. aliphatic amines, with the molar ratio of the above transition metal compound to the nitrogen-containing ligand ranging from 1:1 to 1:4. The method for producing the catalyst involves preparing a water-monoethanolamine mixture at a ratio of 20:80 vol.%, diluting calculated quantities of a transition metal derivative and an aliphatic amine in said mixture, then holding the thus produced homogeneous catalyst at a temperature of 80-95°C for 0.5-1.0 hour and simultaneously blowing air through the catalyst solution. The catalyst makes it possible to produce high-purity oil and oil distillates owing to the complete oxidation of sulphur-containing compounds while improving the technical and economic parameters of the process.
EA200900594A 2009-05-25 2009-05-25 Catalyst for the oxidative demercaptanization of oil and oil distillates and a method for producing said catalyst EA012807B2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EA200900594A EA012807B2 (en) 2009-05-25 2009-05-25 Catalyst for the oxidative demercaptanization of oil and oil distillates and a method for producing said catalyst
PCT/IB2009/006509 WO2010136842A1 (en) 2009-05-25 2009-08-05 Catalyst for the oxidative demercaptanization of oil and oil distillates and a method for producing said catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EA200900594A EA012807B2 (en) 2009-05-25 2009-05-25 Catalyst for the oxidative demercaptanization of oil and oil distillates and a method for producing said catalyst

Publications (4)

Publication Number Publication Date
EA200900594A2 EA200900594A2 (en) 2009-08-28
EA200900594A3 EA200900594A3 (en) 2009-10-30
EA012807B1 EA012807B1 (en) 2009-12-30
EA012807B2 true EA012807B2 (en) 2012-12-28

Family

ID=41127895

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200900594A EA012807B2 (en) 2009-05-25 2009-05-25 Catalyst for the oxidative demercaptanization of oil and oil distillates and a method for producing said catalyst

Country Status (2)

Country Link
EA (1) EA012807B2 (en)
WO (1) WO2010136842A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EA018297B1 (en) * 2012-02-07 2013-06-28 Фролкин, Владимир Владимирович Catalyst for oxidation of hydrogen sulfide, low-molecular and high-molucular mercaptans in hydrocarbon mediums, including oil, gas condensate and refined products
CN115197740A (en) * 2022-06-28 2022-10-18 宁波中一石化科技有限公司 Mercaptan removal alkali liquor oxidation regeneration system and production method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002079373A1 (en) * 2001-03-29 2002-10-10 Framson Limited Alkali-free demercaptanization catalyst for hydrocarbon compositions
US20070227951A1 (en) * 2004-05-31 2007-10-04 Jeyagorwy Thirugnanasampanthar Novel Process for Removing Sulfur from Fuels
RU2326735C2 (en) * 2006-06-01 2008-06-20 Общество с ограниченной ответственностью "Старт-Катализатор" Catalyst for oxidising oil purification gas condensate and oil fractions from mercaptan and method for its producing

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1361305A (en) * 1961-07-21 1964-05-22 Cie De Raffinage Shell Berre Process and catalyst for the preparation of hydrocarbon oils wholly or nearly wholly free of mercaptans
FR2573087B1 (en) * 1984-11-09 1987-07-10 Inst Francais Du Petrole METHOD OF SOFTENING OIL CUTTINGS CARRIED OUT IN THE ABSENCE OF AN ALKALINE COMPOUND

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002079373A1 (en) * 2001-03-29 2002-10-10 Framson Limited Alkali-free demercaptanization catalyst for hydrocarbon compositions
US20070227951A1 (en) * 2004-05-31 2007-10-04 Jeyagorwy Thirugnanasampanthar Novel Process for Removing Sulfur from Fuels
RU2326735C2 (en) * 2006-06-01 2008-06-20 Общество с ограниченной ответственностью "Старт-Катализатор" Catalyst for oxidising oil purification gas condensate and oil fractions from mercaptan and method for its producing

Also Published As

Publication number Publication date
EA200900594A3 (en) 2009-10-30
EA200900594A2 (en) 2009-08-28
WO2010136842A1 (en) 2010-12-02
EA012807B1 (en) 2009-12-30

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Legal Events

Date Code Title Description
DZ4A Eurasian patent assigned for amendment of claims
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM KZ KG TJ TM

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AZ MD

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): BY

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): RU