DK452079A - MODIFIED HIGH-RESISTANCE THERMOPLASTIC ABS POLYMERS - Google Patents

MODIFIED HIGH-RESISTANCE THERMOPLASTIC ABS POLYMERS

Info

Publication number
DK452079A
DK452079A DK452079A DK452079A DK452079A DK 452079 A DK452079 A DK 452079A DK 452079 A DK452079 A DK 452079A DK 452079 A DK452079 A DK 452079A DK 452079 A DK452079 A DK 452079A
Authority
DK
Denmark
Prior art keywords
weight
mixture
acrylonitrile
units
styrene
Prior art date
Application number
DK452079A
Other languages
Danish (da)
Inventor
E Priebe
J Swoboda
F Brandstetter
B Scharf
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of DK452079A publication Critical patent/DK452079A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C08L25/12—Copolymers of styrene with unsaturated nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1. A mixture which consists essentially of (A) a hard component consisting of one or more copolymers of styrene and/or alpha-methylstyrene with acrylonitrile, the said copolymers containing from 20 to 40 % by weight of acrylonitrile as copolymerized units, (B) a first graft copolymer consisting of (B1 ) from 40 to 80 % by weight, based on (B), of a butadiene polymer consisting of partially agglomerated particles, more than 50 % of the particles (number distribution) being present in the non-agglomerated state, and having a mean particle size (d50 value of the cumulative mass distribution) of from 0.20 to 0.45 mu m, onto which is grafted (B2 ) from 20 to 60 % by weight, based on (B), of a mixture of styrene and acrylonitrile in a weight ratio of from 75:25 to 65:35, (C) a second, separately prepared graft copolymer which consists of (C1 ) from 50 to 85 % by weight, based on (C), of a copolymer which itself consists of from 30 to 77 % by weight of butyl acrylate and/or ethylhexyl acrylate units, from 20 to 40 % by weight of butadiene units and from 3 to 30 % by weight of vinyl alkyl ether units, where alkyl is of 1 to 8 carbon atoms, the percentages of the said three monomer constituents together being 100, with a mean particle size (d50 value of the cumulative mass distribution) of less than 0.15 mu m, onto which has been grafted (C2 ) from 15 to 50 % by weight, based on (C), of a mixture of styrene and acrylonitrile in a weight ratio of from 75:25 to 65:35, the weight ratio of the grafting bases (B1 ) and (C1 ) in the mixture of [(A)+(B)+(C)] being from 70:30 to 30:70, and the sum of the two grafting bases (B1 and C1 ) being from about 10 to 35 % by weight, based on the total mixture [(A)+(B)+(C)].
DK452079A 1978-10-27 1979-10-26 MODIFIED HIGH-RESISTANCE THERMOPLASTIC ABS POLYMERS DK452079A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19782846754 DE2846754A1 (en) 1978-10-27 1978-10-27 IMPACT TOE THERMOPLASTIC PLASTICS

Publications (1)

Publication Number Publication Date
DK452079A true DK452079A (en) 1980-04-28

Family

ID=6053244

Family Applications (1)

Application Number Title Priority Date Filing Date
DK452079A DK452079A (en) 1978-10-27 1979-10-26 MODIFIED HIGH-RESISTANCE THERMOPLASTIC ABS POLYMERS

Country Status (6)

Country Link
EP (1) EP0011158B1 (en)
JP (1) JPS5560547A (en)
AT (1) ATE1627T1 (en)
DE (2) DE2846754A1 (en)
DK (1) DK452079A (en)
ES (1) ES485418A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3044110A1 (en) * 1980-11-24 1982-06-24 Basf Ag, 6700 Ludwigshafen THERMOPLASTIC MOLDING AND MOLDING PARTS THEREOF
DE3135251A1 (en) * 1981-09-05 1983-03-17 Basf Ag, 6700 Ludwigshafen THERMOPLASTIC MOLDING
DE3206136A1 (en) * 1982-02-20 1983-09-01 Basf Ag, 6700 Ludwigshafen METHOD FOR PRODUCING THERMOPLASTIC MOLDS
DE19639592A1 (en) 1996-09-26 1998-04-02 Basf Ag Thermoplastic molding compounds

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2420357B2 (en) * 1974-04-26 1980-02-07 Bayer Ag, 5090 Leverkusen Molding compounds
US3931356A (en) * 1974-04-26 1976-01-06 Monsanto Company Continuous process for the preparation of ABS type polyblends
DE2420358B2 (en) * 1974-04-26 1980-02-07 Bayer Ag, 5090 Leverkusen Molding compounds
DE2503966B1 (en) * 1975-01-31 1975-08-07 Basf Ag Impact-resistant thermoplastic molding compounds

Also Published As

Publication number Publication date
DE2963819D1 (en) 1982-11-11
ES485418A1 (en) 1980-05-16
JPS5560547A (en) 1980-05-07
DE2846754A1 (en) 1980-05-08
EP0011158A1 (en) 1980-05-28
ATE1627T1 (en) 1982-10-15
EP0011158B1 (en) 1982-10-06

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Legal Events

Date Code Title Description
AHS Application shelved for other reasons than non-payment