DK2294162T3 - PROCEDURE FOR USING A FISCHER-TROPSCH SYNTHESE - Google Patents

PROCEDURE FOR USING A FISCHER-TROPSCH SYNTHESE

Info

Publication number
DK2294162T3
DK2294162T3 DK09765475.0T DK09765475T DK2294162T3 DK 2294162 T3 DK2294162 T3 DK 2294162T3 DK 09765475 T DK09765475 T DK 09765475T DK 2294162 T3 DK2294162 T3 DK 2294162T3
Authority
DK
Denmark
Prior art keywords
fischer
gas
tropsch synthesis
tropsch
fed
Prior art date
Application number
DK09765475.0T
Other languages
Danish (da)
Inventor
Johannes Menzel
Original Assignee
Thyssenkrupp Uhde Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Thyssenkrupp Uhde Gmbh filed Critical Thyssenkrupp Uhde Gmbh
Application granted granted Critical
Publication of DK2294162T3 publication Critical patent/DK2294162T3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
    • C10K1/004—Sulfur containing contaminants, e.g. hydrogen sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415—Purification by absorption in liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/86—Carbon dioxide sequestration
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1618—Modification of synthesis gas composition, e.g. to meet some criteria
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1659—Conversion of synthesis gas to chemicals to liquid hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Industrial Gases (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Fats And Perfumes (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention relates to a method and a system for operating a Fischer-Tropsch synthesis, wherein a feed gas comprising CO and H2 from coal gasification (1) is desulfurized and subsequently fed into a Fischer-Tropsch synthesis as an input gas, wherein hydrocarbons are formed from carbonic oxides and hydrogen by catalytic reactions. The hydrocarbons are separated as liquid products (4), and a gas flow comprising CO and CO2 exiting the Fischer-Tropsch synthesis unit (3) is compressed and fed into a conversion stage, wherein CO and steam are transformed into H2 and CO2. In the method according to the invention, the gas exiting the conversion stage is fed back into the Fischer-Tropsch synthesis unit as a gas rich in H2, together with the desulfurized input gas, after the gas is prepared in that CO2 and/or further components other than H2 are removed.
DK09765475.0T 2008-05-28 2009-05-07 PROCEDURE FOR USING A FISCHER-TROPSCH SYNTHESE DK2294162T3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008025577A DE102008025577A1 (en) 2008-05-28 2008-05-28 Method for operating a Fischer-Tropsch synthesis
PCT/EP2009/003250 WO2009152895A1 (en) 2008-05-28 2009-05-07 Method for operating a fischer-tropsch synthesis

Publications (1)

Publication Number Publication Date
DK2294162T3 true DK2294162T3 (en) 2012-05-07

Family

ID=41112529

Family Applications (1)

Application Number Title Priority Date Filing Date
DK09765475.0T DK2294162T3 (en) 2008-05-28 2009-05-07 PROCEDURE FOR USING A FISCHER-TROPSCH SYNTHESE

Country Status (16)

Country Link
US (1) US8741971B2 (en)
EP (1) EP2294162B1 (en)
JP (1) JP5607612B2 (en)
KR (1) KR20110021940A (en)
CN (1) CN102066526A (en)
AT (1) ATE541914T1 (en)
AU (1) AU2009259740A1 (en)
BR (1) BRPI0913206A2 (en)
CA (1) CA2725898A1 (en)
DE (1) DE102008025577A1 (en)
DK (1) DK2294162T3 (en)
ES (1) ES2382173T3 (en)
PL (1) PL2294162T3 (en)
RU (1) RU2503706C2 (en)
WO (1) WO2009152895A1 (en)
ZA (1) ZA201008544B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2530136B1 (en) * 2011-05-30 2020-04-01 Neste Oyj Method of producing a hydrocarbon composition
CN102746870B (en) * 2012-06-19 2014-07-09 中国石油化工股份有限公司 FT synthesis technology
CN105460890B (en) * 2015-12-03 2018-03-13 东华工程科技股份有限公司 A kind of method of UF membrane impermeable gas reforming hydrogen manufacturing of the coal liquifaction project oil wash dry gas after UF membrane
CN112410078A (en) * 2020-11-04 2021-02-26 山东义丰环保机械股份有限公司 A sweetener for coal gas
JP7361142B2 (en) * 2022-01-12 2023-10-13 本田技研工業株式会社 fuel synthesis device

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6306917B1 (en) 1998-12-16 2001-10-23 Rentech, Inc. Processes for the production of hydrocarbons, power and carbon dioxide from carbon-containing materials
US6740683B2 (en) * 2001-05-23 2004-05-25 Sasol Technology (Proprietary) Limited Chemicals from synthesis gas
US6976362B2 (en) * 2001-09-25 2005-12-20 Rentech, Inc. Integrated Fischer-Tropsch and power production plant with low CO2 emissions
US20030083390A1 (en) * 2001-10-23 2003-05-01 Shah Lalit S. Fischer-tropsch tail-gas utilization
GB0200891D0 (en) * 2002-01-16 2002-03-06 Ici Plc Hydrocarbons
MY134279A (en) * 2002-06-05 2007-11-30 Shell Int Research Process for the production of hydrocarbons from gaseous hydrocarbonaceous feed
FR2853904B1 (en) * 2003-04-15 2007-11-16 Air Liquide PROCESS FOR THE PRODUCTION OF HYDROCARBON LIQUIDS USING A FISCHER-TROPSCH PROCESS
WO2005019384A1 (en) * 2003-08-22 2005-03-03 Sasol Technology (Proprietary) Limited Process for synthesising hydrocarbons
US7300642B1 (en) * 2003-12-03 2007-11-27 Rentech, Inc. Process for the production of ammonia and Fischer-Tropsch liquids
US7166643B2 (en) * 2004-03-08 2007-01-23 Chevron U.S.A. Inc. Hydrogen recovery from hydrocarbon synthesis processes
US7405243B2 (en) * 2004-03-08 2008-07-29 Chevron U.S.A. Inc. Hydrogen recovery from hydrocarbon synthesis processes
GB2442646A (en) 2005-06-14 2008-04-09 Sasol Tech Pty Ltd Process for the preparation and conversion of synthesis gas
US7879919B2 (en) 2005-12-15 2011-02-01 Sasol Technology (Proprietary) Limited Production of hydrocarbons from natural gas
EP1860063A1 (en) 2006-05-22 2007-11-28 Shell Internationale Researchmaatschappij B.V. Process for preparing a paraffin product
EP1935845A1 (en) * 2006-12-22 2008-06-25 Shell Internationale Researchmaatschappij B.V. Process for producing hydrocarbons from a hydrocarbonaceous feedstock

Also Published As

Publication number Publication date
WO2009152895A1 (en) 2009-12-23
CN102066526A (en) 2011-05-18
EP2294162B1 (en) 2012-01-18
BRPI0913206A2 (en) 2016-01-12
JP2011521089A (en) 2011-07-21
ES2382173T3 (en) 2012-06-06
US8741971B2 (en) 2014-06-03
ZA201008544B (en) 2012-03-28
PL2294162T3 (en) 2012-08-31
ATE541914T1 (en) 2012-02-15
US20110118366A1 (en) 2011-05-19
KR20110021940A (en) 2011-03-04
CA2725898A1 (en) 2009-12-23
DE102008025577A1 (en) 2009-12-03
RU2503706C2 (en) 2014-01-10
JP5607612B2 (en) 2014-10-15
AU2009259740A1 (en) 2009-12-23
EP2294162A1 (en) 2011-03-16
RU2010153594A (en) 2012-07-10

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