DK150869B - MULTIPLE CELL BLYACUMULATOR AND METHOD FOR PREPARING THE SAME. - Google Patents

MULTIPLE CELL BLYACUMULATOR AND METHOD FOR PREPARING THE SAME. Download PDF

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DK150869B
DK150869B DK342778AA DK342778A DK150869B DK 150869 B DK150869 B DK 150869B DK 342778A A DK342778A A DK 342778AA DK 342778 A DK342778 A DK 342778A DK 150869 B DK150869 B DK 150869B
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electrode
block box
welding
electrodes
support skeleton
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DK342778AA
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Danish (da)
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DK150869C (en
DK342778A (en
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Hans-Joachim Golz
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Varta Batterie
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/06Lead-acid accumulators
    • H01M10/12Construction or manufacture
    • H01M10/125Cells or batteries with wound or folded electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Connection Of Batteries Or Terminals (AREA)
  • Permanent Magnet Type Synchronous Machine (AREA)
  • Fuel Cell (AREA)

Description

i 150869in 150869

Opfindelsen angår en flercellet blyakkumulator med elektrodeblokke i form af siksakagtige til en pakke sammenfoldede positive og negative båndelektroder med mellemliggende separato rer.The invention relates to a multi-cell lead accumulator with electrode blocks in the form of zigzag-like for a package of folded positive and negative band electrodes with intermediate separators.

55

Inden for akkumulatorområdet er de fleste fornyelser kommet det egentlige produkt til gode. Eksempelvis er der udviklet vedi igeholdelsesfri startbatterier.Within the accumulator area, most innovations have benefited the actual product. For example, maintenance-free starter batteries have been developed.

Fremstillingsprocessen er derimod næsten uændret, idet den om- 10 fatter de samme arbejdsprocesser såsom gitterstøbning, bearbejdning, formering, sammenstilling og indbygning af pladeblokke osv. Selv om der findes maskinelle hjælpeindretninger, må mange af disse arbejdsprocesser udføres manuelt og endog på de enkelte elektroder, således at arbejdsforløbet bliver 15 diskontinuert, hvilket begrænser produktionshastigheden.The manufacturing process, on the other hand, is virtually unchanged in that it encompasses the same work processes such as lattice casting, machining, propagation, assembly and incorporation of plate blocks, etc. Although there are mechanical auxiliaries, many of these work processes must be performed manually and even on the individual electrodes, so that the workflow becomes discontinuous, limiting the production speed.

En mere rationel fremstillingsteknik har kun vundet indpas i forbindelse med de såkaldte småakkumulatorer, der uden videre vil kunne massefremst i 11 es. Til disse småakkumulatorer hører 20 alkaliske småakkumu]atorer samt små blyceller med viklede elektrodeenheder. I disse elektrodeenheder er et positivt og et negativt elektrodebånd under indlægning af en separator viklet til en elektrodevikling og anbragt i cellebeholderen. Ved elektrodens rande er der tilslutningsterminaler, der kan føres 25 gennem beholderen. Som følge af vanskelighederne ved terminalgennemføringerne anvendes viklede elektrodeenheder af denne art i almindelighed kun i forbindelse med encellede akkumulatorer, 3Q Også i forbindelse med elektrodepladerne er der tendens til at afløse de svære massebærere, dvs. støbte blygitre med lette skeletstrukturrer, der f.eks. kan udgøres af valset metal. Valset metal kan desuden fremstilles i endeløse bånd.A more rational manufacturing technique has only gained in connection with the so-called small accumulators, which will easily be able to mass advance in 11 es. These small accumulators include 20 alkaline small accumulators as well as small lead cells with wound electrode units. In these electrode units, a positive and a negative electrode band, while inserting a separator, is wound to an electrode winding and placed in the cell container. At the edges of the electrode there are connection terminals which can be passed through the container. Due to the difficulties of terminal feed-throughs, wound electrode units of this kind are generally used only in connection with single-cell accumulators, 3Q. Also, in connection with the electrode plates, the heavy mass carriers tend to be replaced, ie. cast lead grids with light skeletal structures that e.g. can be made of rolled metal. Rolled metal can also be manufactured in endless ribbons.

Elektrodeplader fremstillet af valset metal, og som er pakket 3 5 på konventionel måde og indsat i opadtil åbne beholdere, indebærer imidlertid ikke noget væsentligt fremskridt for så vidt angår fremstillingsprocessen.However, electrode sheets made of rolled metal, which are packed in conventional manner and inserted into upwardly open containers, do not represent any significant progress in the manufacturing process.

2 1508692 150869

Man har søgt at tilvejebringe en mere bekvem forbindelse imellem de enkelte akkumulatorceller ved at give afkald på den ene overflade af den enkelte celle af et antal indbyrdes forbundne celler - jf. US-patentskrift nr. 3.844.841. Denne forbindelse 5 er muliggjort ved hjælp af en svagt bægerformet udvidelse af sidevæggene, hvorved sidevæggene med den udvidede rand kan gribe ind over en tilsvarende udvidet nabocelle. Den resulterende stikforbindelse er imidlertid ikke helt tilfredsstillende i henseende til kontaktering og elektrolyttæthed af 10 huset.An attempt has been made to provide a more convenient connection between the individual accumulator cells by renouncing on one surface of the individual cell a number of interconnected cells - cf. U.S. Patent No. 3,844,841. This connection 5 is made possible by a slight cup-shaped extension of the side walls, whereby the side walls with the extended edge can intervene over a corresponding extended neighbor cell. However, the resulting plug connection is not entirely satisfactory in terms of contact and electrolyte density of the housing.

Formålet med opfindelsen er at tilvejebringe en blyakkumulator, der er bedre egnet til massefremstilling end hidtil kendt, og dette formål er ifølge opfindelsen opnået ved at ved siden af hinanden liggende akkumulatorceller er elektrisk forbundet via et storfladet, gennem skillevæggen ført bæreskelet for en af båndelektroderne, og ved at blokkassens låg dannes af en sidevæg, der står vinkelret på elektrodernes plan.The object of the invention is to provide a lead accumulator which is better suited for mass production than hitherto known, and this object is achieved according to the invention by adjacent accumulator cells being electrically connected via a large surface, through the partition, carrying the support skeleton for one of the tape electrodes, and by forming the cap of the block box by a side wall perpendicular to the plane of the electrodes.

I en foretrukken udførelsesform for akkumulatoren består hver 20 af de til en celle hørende pladeblokke af siksakformede, til en pakke sammenfoldede, positive og negative båndelektroder med mellemliggende båndformede separatorer. Både indbyrdes forbindelser mellem cellerne og ydre elektriske tilslutninger etableres via storfladede, over skillevæggene henholdsvis 25 ydervæggene førte områder af et af de to elektrodebæregitre. Disse områder ligger samtidigt i lukkeplanet af blokkassen, der lukkes væsketæt af en sidevæg ved en spejlsvejsning.In a preferred embodiment of the accumulator, each of the one-cell plate blocks consists of zigzag-shaped, folded, positive and negative band electrodes with intermediate band-shaped separators. Both interconnections between the cells and external electrical connections are established via large-flat areas, across the partitions and 25 outer walls, respectively, areas of one of the two electrode support grids. These areas are at the same time in the closing plane of the block box, which is closed liquid-tight by a side wall by a mirror welding.

Opfindelsen angår også en fremgangsmåde til fremstilling af en 30 flercellet blyakkumulator, ved hvilken fremgangsmåde elektrodeblokkene bestående af postive og negative båndelektroder og mellemliggende separatorer sammenfoldes til en siksakformet pakke og indsættes i blokkassen. Fremgangsmåde er ejendommelig ved, at det storfladede elektrodebæreskelet, der føres gennem 35 skillevæggen eller ydervæggen af blokkassen, er forsynet med tilsvarende opdelte områder, der er fri for aktiv masse, at de tilsvarende paral lelafsnit af modelektroden helt fjernes, og at sideåbningerne af blokkassen derefter lukkes væsketæt ved 150869 3 påsvejsning af en sidevæg. Derved opnås en særlig hensigtsmæssig fremgangsmåde til fremstilling af en flercellet blyakkumulator.The invention also relates to a method of producing a multi-cell lead accumulator in which the electrode blocks consisting of positive and negative tape electrodes and intermediate separators are folded into a zigzag-shaped package and inserted into the block box. The method is characterized in that the large-flat electrode support skeleton passing through the partition or outer wall of the block box is provided with correspondingly divided areas free of active mass, that the corresponding parallel sections of the model electrode are completely removed and that the lateral openings of the block box are then removed. liquid-tight is closed by welding a sidewall. Thereby, a particularly convenient method is obtained for the preparation of a multi-cell lead accumulator.

5 Opfindelsen skal nærmere forklares i det følgende under henvisning til tegningen, hvorThe invention will be explained in more detail below with reference to the drawings, wherein

Fig. 1 viser en blyakkumulator ifølge opfindelsen, idet de enkelte dele er trukket ud fra hinanden og 10 Fig. 2 samme set i perspektiv.FIG. 1 shows a lead accumulator according to the invention, the individual parts being pulled apart and FIG. 2 the same in perspective.

Det i fig. 1 viste elektrodesæt består af en båndelektrode 12, en båndelektrode 13 og et mellemliggende separatorbånd 4 med ribber eller forbindelsesstykker. Båndelektroderne 12, 13 og jg separatorbåndet 4 er siksakagtigt foldet til pakker og er pakkevis skubbet sideværts ind i cellerne af en blokkasse. Foldekanterne 6 af elektrodepakkerne står vinkelret på akkumulatorens anlægsflade, således at gasbobler uhindret kan stige op imellem elektroderne 12, 13.The FIG. 1, a strip electrode 12, a tape electrode 13 and an intermediate separator band 4 with ribs or connectors are provided. The band electrodes 12, 13 and the separator band 4 are zigzagically folded into packets and are packaged laterally laterally into the cells of a block box. The folding edges 6 of the electrode packages are perpendicular to the abutment surface of the accumulator, so that gas bubbles can rise freely between the electrodes 12, 13.

2020

Ifølge opfindelsen etableres både de ydre tilledninger og de indbyrdes forbindelser imellem cellerne via storfladede, over skillevæggene 7 eller ydervæggene 8 af blokkassen førte områder 9 af elektrodebæreskelettet 2,3 af en båndelektrode. IAccording to the invention, both the outer leads and the interconnections between the cells are established via large flat, overlying partitions 7 or outer walls 8 of the block box, areas 9 of the electrode support skeleton 2,3 by a tape electrode. IN

fig. 1 udgøres de ydre tilledninger 16 og 17 af elektrodebæ-25 reskelettet 2 af båndelektroden 12, mendes forbindelsen imellem cellerne tilvejebringes ved hjælp af elektrodebæreskelettet 3 af båndelektroden 13.FIG. 1, the outer leads 16 and 17 of the electrode support skeleton 2 are formed by the band electrode 12, the connection between the cells is provided by means of the electrode support skeleton 3 of the band electrode 13.

Den enkelte båndelektrode kan ved enden også vikles over en 30 blystift og forbindes til denne, eksempelvis ved tryksvejsning.The individual tape electrode can also be wound at the end over a lead pin and connected to it, for example by pressure welding.

Modelektroden og separatorbåndet er afbrudt i overgangsområderne mellem cellerne.The model electrode and the separator band are interrupted in the transition regions between the cells.

Til fremstilling af en siksakagtigt foldet elektrodepakke til en flercellet akkumulator går man fortrinsvis ud fra elektro-debæreskeletter, der er viklet som endeløse bånd på ruller 10, 35 4 150869 11, og som kan have form af gitter skeletter af bly eller valset metal, idet den enkelte båndelektrode i givet fald har et gennemgående forbindelsesstykke ved randen. I disse gitterskeletter indklistres som aktivt materiale en ensartet masse.For the manufacture of a zigzag-folded electrode package for a multi-cell accumulator, it is preferable to use electrode skeletons wound as endless bands on rollers 10, 35, 4 and which may be in the form of lattice skeletons of lead or rolled metal, the individual tape electrode, if any, has a continuous connector at the rim. In these lattice skeletons a uniform mass is pasted as active material.

5 Oette er fordelagtigt, eftersom de færdige båndelektroder under batteriets drift veksler i polaritet fra celle til celle. Elektrodebæreskeletterne 2, 3 går således over i båndelektroderne 12, 13.5 This is advantageous since the finished tape electrodes during the battery operation alternate in polarity from cell to cell. Thus, the electrode support skeletons 2, 3 pass into the band electrodes 12, 13.

Under indlæggelse af et højporøst separatorbånd, der er ret ufølsomt over for tryk, og som afvikles fra en rulle 14, løber båndelektroderne via en venderulle 15 sammen, hvorefter de kan foldes.During the insertion of a highly porous separator band which is quite insensitive to pressure and wound from a roller 14, the band electrodes run together via a turning roller 15, after which they can be folded.

Umiddelbart inden foldningen bliver der skåret nogle områder 9 15 ud af båndelektroderne 12, 13 og separatoren 4, hvilke områder efter indføring i blokkassen ellers ville forløbe over en af skillevæggene 7 eller 8 og være tilovers, når bortses fra det elektrodebæreskelet, der er nødvendigt til overgangen over en skillevæg.Immediately prior to folding, some areas 9 15 are cut out of the tape electrodes 12, 13 and separator 4, which areas, after insertion into the block box, would otherwise extend over one of the partitions 7 or 8 and be left over, except for the electrode support skeleton needed for the transition over a partition.

2020

Til færdiggørelse af akkumulatoren er det nu kun nødvendigt at lukke blokkassen, hvilket kan ske ved en spej1 svejsn ing, ved hvilken en sidevæg 18 påsvejses, idet sidevæggen står vinkelret på elektrodernes plan. Gennem varmepåvirkningen trænger 25 formstoffet af såvel skillevæggen 7 og ydervæggen 8 af blokkassen som de tilsvarende fortsættelser 19 henholdsvis 20 ind i sidevæggen 18 gennem skelettet af elektroden, således at der opnås en fast og væsketæt forbindelse. Inden påsvejsningen af et låg kan elektrodebæreskelettet ved hjælp af et stempel 30 trykkes mod skillevæggen, og der kan i givet fald foretages en yderligere opvarmning til opnåelse af en vis indtrængning af elektrodebæreskelettet i kanten af skillevæggen 7 inden den endelige påsvejsning af låget.To complete the accumulator, it is now only necessary to close the block case, which can be done by a mirror weld at which a sidewall 18 is welded, the sidewall being perpendicular to the plane of the electrodes. Through the heat effect, the resin penetrates both the partition wall 7 and the outer wall 8 of the block box as well as the corresponding extensions 19 and 20 respectively into the side wall 18 through the skeleton of the electrode, so that a solid and liquid-tight connection is obtained. Prior to welding a lid, the electrode support skeleton may be pressed against the partition by means of a plunger 30 and further heating may be provided to obtain some penetration of the electrode support skeleton at the edge of the partition 7 prior to final welding of the lid.

3g På oversiden af blokkassen kan der derefter tilvejebringes indfyldnings- og udluftningsåbninger.3g Fill and vent openings can then be provided on the upper side of the block box.

Parallelt med afbildningsplanet ligger også planet af elektrolytspejlet, medens lukkeplanet, der er angivet ved hjælp af sporet A-A, står vinkelret på elektrolytspejlet.Parallel to the imaging plane is also the plane of the electrolyte mirror, while the closing plane indicated by the groove A-A is perpendicular to the electrolyte mirror.

Claims (9)

150869 De nødvendige endepoltilslutninger kan tilvejebringes inde i eller uden for cellen via udragende elektrodedele, eksempelvis ved påsvejsning af en endepol.The necessary end pole connections can be provided inside or outside the cell via protruding electrode parts, for example by welding an end pole. 1. Flercellet blyakkumulator med elektrodeblokke i form af siksakagtige til en pakke sammenfoldede positive og negative båndelektroder (12, 13) med mellemliggende separatorer (4), 2ø kendetegnet ved, at ved siden af hinanden liggende akkumulatorceller er elektrisk forbundet via et storfladet, gennem cellevæggen (7) ført bæreskelet (3) for en af båndelektroderne (12, 13), og at blokkassens låg dannes af en sidevæg (18), der står vinkelret på elektrodernes plan. 251. Multi-cell lead accumulator with electrode blocks in the form of zigzag-like for a package folded positive and negative band electrodes (12, 13) with intermediate separators (4), 2 o, characterized in that adjacent accumulator cells are electrically connected via a large surface, through the cell wall (7) guided the support skeleton (3) for one of the tape electrodes (12, 13) and the cover of the block box is formed by a side wall (18) perpendicular to the plane of the electrodes. 25 2. Blyakkumulator ifølge krav 1, kendetegnet ved, at bæreskelettet (2, 3) udgøres af endeløse bånd af valset metal.Lead accumulator according to claim 1, characterized in that the support skeleton (2, 3) is made of endless ribbons of rolled metal. 3. Blyakkumulator ifølge krav 1 og 2, kendetegnet 30 ved, at båndene af elektrodeblokkene er forbundet med stiftformede blystave, f.eks. ved omvikling og tryksvejsning, og at disse stifter danner basis for polgennemføringerne.Lead accumulator according to claims 1 and 2, characterized in that the bands of the electrode blocks are connected to pin shaped lead rods, e.g. by wrapping and pressure welding, and that these pins form the basis for the pin holes. 4. Blyakkumulator ifølge krav 1 og 2, kendetegnet 35 ved, at de ydre elektriske tilslutninger (16, 17) dannes af det storfladede, gennem blokkassens (1) ydervæg (8) førte elektro-debæreskelet (2 eller 3) eller en af båndelektroderne (12 henholdsvis 13). 150869Lead accumulator according to claims 1 and 2, characterized in that the outer electrical connections (16, 17) are formed by the large surface, which passes through the outer wall (8) of the block box (1) the electrode skeleton (2 or 3) or one of the tape electrodes. (12 and 13, respectively). 150869 5. Fremgangsmåde til fremstilling af en flercellet blyakkumulator, ved hvilken fremgangsmåde elektrodeblokkene bestående af positive og negative båndelektroder og mellemliggende separatorer (4) sammenfoldes til en siksakformet pakke og indsæt- 5 tes i blokkassen, kendetegnet ved, at det storfla-dede elektrodebæreskelet, der føres gennem skillevæggen eller ydervæggen af blokkassen, er forsynet med tilsvarende opdelte områder, der er fri for aktiv masse, at de tilsvarende parallelafsnit af modelektroden helt fjernes, og at sideåbningerne 10 derefter lukkes væsketæt ved påsvejsning af en sidevæg (18).A method of producing a multi-cell lead accumulator, in which the electrode blocks consisting of positive and negative band electrodes and intermediate separators (4) are folded into a zigzag-shaped package and inserted into the block box, characterized in that the large-scale electrode carrier framework which passed through the partition or outer wall of the block box, is provided with correspondingly divided areas free of active mass, that the corresponding parallel sections of the model electrode are completely removed, and that the side openings 10 are then closed tightly by welding a side wall (18). 5 Det er indlysende, at de sædvanlige behandlingsprocesser, såsom lagring, ombrydning, konservering (såsom borsyrebehandling) kan foretages uden for blokkassen. Af hensyn til fremstillingsprocessens kontinuitet er det imidlertid fordelagtigt, hvis behandlingerne efter elektrodepakkens indsætning i 10 blokkassen udføres i denne. Fordelen ved den beskrevne akkumulator er, at dens fremstillingsproces muliggør en mere hensigtsmæssig materialestrøm. Patentkrav. 15 ---------------------It is obvious that the usual processing processes, such as storage, wrapping, preservation (such as boric acid treatment) can be carried out outside the block box. However, for the continuity of the manufacturing process, it is advantageous if the treatments after insertion of the electrode package into the block box are carried out therein. The advantage of the described accumulator is that its manufacturing process enables a more appropriate flow of material. Claims. 15 --------------------- 6. Fremgangsmåde ifølge krav 5, kendetegnet ved, at lukningen sker ved en spejlsvejsning, og at den ene båndelektrode inden svejsningen af elektrodebæreskelettet uden aktiv masse indføres en smule i skillevæggen eller ydervæggen ved en trykpåvirkning.Method according to claim 5, characterized in that the closure is effected by a mirror welding and that one tape electrode is inserted slightly into the partition or outer wall by a pressure effect before welding the electrode support skeleton without welding. 7. Fremgangsmåde ifølge krav 6, kendetegnet ved, at det område af elektrodebæreskelettet, der skal indføres, opvarmes inden trykpåvirkningen. 20Method according to claim 6, characterized in that the area of the electrode support skeleton to be introduced is heated before the pressure effect. 20 8. Fremgangsmåde ifølge krav 5-7, kendetegnet ved, at elektrodebæreskelettet (2, 3) klistres sammen med en ensartet aktiv masse.Method according to claims 5-7, characterized in that the electrode support skeleton (2, 3) is glued together with a uniformly active mass. 9. Fremgangsmåde ifølge krav 5-8, kendetegnet ved, at båndelektroderne i blokkassen underkastes en formeringsbehandling, hvorefter blokkassen lukkes fra siden.Method according to claims 5-8, characterized in that the band electrodes in the block box are subjected to a propagation treatment, after which the block box is closed from the side.
DK342778A 1977-08-23 1978-08-02 MULTIPLE CELL BLYACUMULATOR AND METHOD FOR PREPARING THE SAME. DK150869C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2737837A DE2737837C3 (en) 1977-08-23 1977-08-23 Design and method for manufacturing a multi-cell lead-acid battery
DE2737837 1977-08-23

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DK342778A DK342778A (en) 1979-02-24
DK150869B true DK150869B (en) 1987-07-06
DK150869C DK150869C (en) 1988-01-25

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AT363531B (en) 1981-08-10
BE869893A (en) 1978-12-18
NO147463C (en) 1983-04-13
CA1107816A (en) 1981-08-25
GB2002949B (en) 1982-05-26
GR64038B (en) 1980-01-19
FI71633B (en) 1986-10-10
IT7826953A0 (en) 1978-08-23
FR2408918B1 (en) 1981-09-11
TR21181A (en) 1983-12-05
DE2737837C3 (en) 1980-11-13
NL7807418A (en) 1979-02-27
FI71633C (en) 1987-01-19
GB2002949A (en) 1979-02-28
DK150869C (en) 1988-01-25
DK342778A (en) 1979-02-24
FI781971A (en) 1979-02-24
IT1113094B (en) 1986-01-20
NL178109C (en) 1986-01-16
ES244800Y (en) 1980-05-16
NO782386L (en) 1979-02-26
JPS5445752A (en) 1979-04-11
DE2737837B2 (en) 1980-03-27
SE442565B (en) 1986-01-13
ATA425778A (en) 1981-01-15
FR2408918A1 (en) 1979-06-08
DE2737837A1 (en) 1979-03-01
SE7808102L (en) 1979-02-24
NO147463B (en) 1983-01-03
ES244800U (en) 1979-11-16
AR215949A1 (en) 1979-11-15
CH641914A5 (en) 1984-03-15
BR7805416A (en) 1979-04-17

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