DK0646106T3 - Process for simultaneous preparation of dicarboxylic acids and diamines by cleavage of polyamides in their monomer stocks - Google Patents
Process for simultaneous preparation of dicarboxylic acids and diamines by cleavage of polyamides in their monomer stocksInfo
- Publication number
- DK0646106T3 DK0646106T3 DK93912919T DK93912919T DK0646106T3 DK 0646106 T3 DK0646106 T3 DK 0646106T3 DK 93912919 T DK93912919 T DK 93912919T DK 93912919 T DK93912919 T DK 93912919T DK 0646106 T3 DK0646106 T3 DK 0646106T3
- Authority
- DK
- Denmark
- Prior art keywords
- dicarboxylic acids
- diamines
- polyamides
- stocks
- cleavage
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
- B01D61/445—Ion-selective electrodialysis with bipolar membranes; Water splitting
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/62—Preparation of compounds containing amino groups bound to a carbon skeleton by cleaving carbon-to-nitrogen, sulfur-to-nitrogen, or phosphorus-to-nitrogen bonds, e.g. hydrolysis of amides, N-dealkylation of amines or quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/06—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/48—Polymers modified by chemical after-treatment
Abstract
Disclosed is a method for the simultaneous preparation of dicarboxylic acids and diamines from (a) polymers based on polyamides made by reacting dicarboxylic acids or derivatives thereof with diamines or (b) compounds containing essentially such polymers, by decomposing these polymers into their constituent monomers by treating the polymers or compounds with a base in an alcoholic solution and subsequently converting electrochemically the dicarboxylic-acid salts thus produced into the corresponding dicarboxylic acids and bases.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4219756A DE4219756A1 (en) | 1992-06-17 | 1992-06-17 | Process for the simultaneous production of dicarboxylic acids and diamines by splitting polyamides into their monomeric components |
PCT/EP1993/001448 WO1993025513A1 (en) | 1992-06-17 | 1993-06-09 | Method for the simultaneous preparation of dicarboxylic acids and diamines by decomposing polyamides into their constituent monomers |
Publications (1)
Publication Number | Publication Date |
---|---|
DK0646106T3 true DK0646106T3 (en) | 1999-06-23 |
Family
ID=6461166
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK93912919T DK0646106T3 (en) | 1992-06-17 | 1993-06-09 | Process for simultaneous preparation of dicarboxylic acids and diamines by cleavage of polyamides in their monomer stocks |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP0646106B1 (en) |
JP (1) | JPH07507555A (en) |
AT (1) | ATE172185T1 (en) |
CA (1) | CA2138024C (en) |
DE (2) | DE4219756A1 (en) |
DK (1) | DK0646106T3 (en) |
ES (1) | ES2123649T3 (en) |
WO (1) | WO1993025513A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2736637B1 (en) * | 1995-07-12 | 1997-08-22 | Rhone Poulenc Fibres & Polymer | PROCESS FOR THE CONVERSION OF POLYAMIDES TO NITROGEN-CONTAINING COMPOUNDS |
FR2754192B1 (en) * | 1996-10-04 | 1998-12-04 | Rhone Poulenc Fibres & Polymer | PROCESS FOR THE EXTRACTION OF AMINE COMPOUNDS FROM A LIQUID MEDIUM |
DE19703426A1 (en) * | 1997-01-30 | 1998-08-06 | Basf Ag | Process for the purification of alpha, beta or gamma substituted carboxylic acids |
WO2024013254A1 (en) * | 2022-07-14 | 2024-01-18 | Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen | Method for producing a monomer from the polymer comprising the monomer |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2840606A (en) * | 1955-04-15 | 1958-06-24 | Du Pont | Nylon hydrolysis |
DE1088063B (en) * | 1958-10-15 | 1960-09-01 | Basf Ag | Process for the recovery of dicarboxylic acids and diamines from polyamides |
NL283077A (en) * | 1961-09-12 | |||
US3964985A (en) * | 1974-10-29 | 1976-06-22 | Ionics, Incorporated | Electrodialysis apparatus and process for ion modification |
US4781809A (en) * | 1986-07-21 | 1988-11-01 | Ionics, Incorporated | Recovering free organic acids from solutions in which they occur with other organic matter |
DE3926634A1 (en) * | 1988-08-11 | 1990-02-15 | Fraunhofer Ges Forschung | Multi-cell electrodialysis appts. - esp. for organic acid recovery from salt |
DE3926642C2 (en) * | 1988-08-11 | 1998-02-26 | Fraunhofer Ges Forschung | Process for obtaining an acid from its salt |
HUT58558A (en) * | 1990-01-18 | 1992-03-30 | Ercros Sa | Process for isolating and purifying acids from their salts by electrodialysis |
US5288378A (en) * | 1990-09-28 | 1994-02-22 | Alliedsignal Inc. | Guard membranes for use in electrodialysis cells |
-
1992
- 1992-06-17 DE DE4219756A patent/DE4219756A1/en not_active Withdrawn
-
1993
- 1993-06-09 EP EP93912919A patent/EP0646106B1/en not_active Expired - Lifetime
- 1993-06-09 CA CA002138024A patent/CA2138024C/en not_active Expired - Fee Related
- 1993-06-09 JP JP6501108A patent/JPH07507555A/en active Pending
- 1993-06-09 AT AT93912919T patent/ATE172185T1/en not_active IP Right Cessation
- 1993-06-09 DE DE59309064T patent/DE59309064D1/en not_active Expired - Lifetime
- 1993-06-09 WO PCT/EP1993/001448 patent/WO1993025513A1/en active IP Right Grant
- 1993-06-09 DK DK93912919T patent/DK0646106T3/en active
- 1993-06-09 ES ES93912919T patent/ES2123649T3/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CA2138024A1 (en) | 1993-12-23 |
EP0646106B1 (en) | 1998-10-14 |
ATE172185T1 (en) | 1998-10-15 |
DE4219756A1 (en) | 1993-12-23 |
DE59309064D1 (en) | 1998-11-19 |
WO1993025513A1 (en) | 1993-12-23 |
JPH07507555A (en) | 1995-08-24 |
CA2138024C (en) | 2000-12-12 |
EP0646106A1 (en) | 1995-04-05 |
ES2123649T3 (en) | 1999-01-16 |
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