DE955093C - Hair and skin care products - Google Patents
Hair and skin care productsInfo
- Publication number
- DE955093C DE955093C DEJ8945A DEJ0008945A DE955093C DE 955093 C DE955093 C DE 955093C DE J8945 A DEJ8945 A DE J8945A DE J0008945 A DEJ0008945 A DE J0008945A DE 955093 C DE955093 C DE 955093C
- Authority
- DE
- Germany
- Prior art keywords
- hair
- skin care
- chloride
- care products
- amino
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/673—Vitamin B group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q7/00—Preparations for affecting hair growth
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Mycology (AREA)
- Microbiology (AREA)
- Botany (AREA)
- Biotechnology (AREA)
- Engineering & Computer Science (AREA)
- Dermatology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Cosmetics (AREA)
Description
Haar- und Hautpflegemittel Die Anwendung der Aminosäuren, der Pantothensäure und des Panthothenols in der Kosmetik ist bekannt. Ihre Wirkung auf das Haarwachstum ist umstritten. Zur Kennzeichnung des derzeitigen Standes der Technik dienen die schweizerischen Patentschriften 238 597, 245 584 und 245 907.Hair and skin care products The use of amino acids, pantothenic acid and panthothenol in cosmetics is known. Their effect on hair growth is controversial. The are used to identify the current state of the art Swiss patents 238 597, 245 584 and 245 907.
Auch einfache Mischungen der Aminosäuren mit der Pantothensäure einschließlich ihrer Salze oder mit dem Pantothenol ergeben keine nennenswerten Effekte. Der geschwächte Haarboden ist nur in vereinzelten Fällen ansprechbar. Also including simple mixtures of amino acids with pantothenic acid Their salts or with pantothenol do not produce any noteworthy effects. The weakened one The scalp is only accessible in isolated cases.
Im Gegensatz hierzu wurde nun gefunden, daß die Umsetzungsprodukte der Pantothensäure bzw. ihrer Salze mit den Chloriden der Aminosäuren oder den Aminoalkoholen, die aus den Aminosäuren herstellbar sind, wirksame, den Haarwuchs fördernde Mittel ergeben und darüber hinaus ausgeprägt hautfreundliche Eigenschaften entfalten. Von den Aminosäurechloriden sind beispielsweise Cysteinylchlorid und Methioninylchlorid zu erwähnen. In contrast, it has now been found that the reaction products the pantothenic acid or its salts with the chlorides of the amino acids or the amino alcohols, which can be produced from the amino acids, effective means that promote hair growth and also develop pronounced skin-friendly properties. from the amino acid chlorides are, for example, cysteinyl chloride and methioninyl chloride to mention.
Die Aminosäuren können als reine Produkte vorliegen oder aber als Gemisch, wie man sie beim Abbau des Haarkeratins erhält. Diese Produkte dienen dann zur Herstellung der Säurechloride. Beispielsweise wird Cysteinylchlorid nach der Methode von E. Fischer gewonnen (Ber. d. d. ch. Ges., 38, 605 [I905]). Cystein wird dabei trocken und feinst verteilt in der zehnfachen Menge Acetylchlorid dispergiert und mit der berechneten Menge Phosphorpentachlorid bei o bis 200 umgesetzt. Das erhal- tene Chlorid wird anschließend init der berechneten Menge Natriumpantothenat im inerten Medium umgesetzt. Das erhaltene Kondensationsprodukt kann sogleich oder nach der Reinigung Verwendung finden.The amino acids can be present as pure products or as Mixture as obtained from the breakdown of hair keratin. These products then serve for the production of acid chlorides. For example, cysteinyl chloride is used according to the Method obtained from E. Fischer (Ber. D. D. Ch. Ges., 38, 605 [I905]). Cysteine will while dry and finely dispersed in ten times the amount of acetyl chloride and reacted with the calculated amount of phosphorus pentachloride at 0 to 200. That receive tene chloride is then used in the calculated amount Sodium pantothenate implemented in the inert medium. The condensation product obtained can be used immediately or after cleaning.
Man kann ferner aus den Aminosäuren oder deren Estern durch Reduktion mit Natrium oder mittels Lithiumaluminiumhydrid in bekannter Weise den Aminoalkohol bereiten, diesen in bekannter Art mittels Thionylchlorid in ds Chlorid umwandeln und dieses mit trockenem Calciumpantothenat zur Reaktion bringen. So erhält man beispielsweise aus Leucin über den Methylester durch Reduktion mit Natrium das Leucinol, und das Leucinolchlorid wird wieder mit Calciumpantothenat umgesetzt. You can also from the amino acids or their esters by reduction with sodium or by means of lithium aluminum hydride in a known manner the amino alcohol prepare to convert this into the chloride in the known way using thionyl chloride and react this with dry calcium pantothenate. So you get For example, from leucine via the methyl ester by reduction with sodium the leucinol, and the leucinol chloride is reacted with calcium pantothenate.
Die erhaltene Verbindung hat haarwuchsfördernde Eigenschaften, wird aber von dem Kondensationsprodukt aus Cysteinylchlorid mit Calciumpantothenat noch übertroffen.The compound obtained has hair growth-promoting properties but of the condensation product of cysteinyl chloride with calcium pantothenate exceeded.
Die Herstellung der Aminosäurechloride und der Aminoalkohole ist nicht Gegenstand des Patents. The manufacture of amino acid chlorides and amino alcohols is not subject of the patent.
Die Erfindung betrifft nur die Verwendung der Kondensationsverbindungen, die aus den Aminosäurechloriden mit Pantothensäure bzw. mit deren Salzen erhalten werden, oder der Kondensationsverbindungen, die aus den Aminoalkoholen und der Pantothensäure in bereits erwähnter Art entstehen. The invention relates only to the use of the condensation compounds, obtained from the amino acid chlorides with pantothenic acid or with its salts be, or the condensation compounds, which from the amino alcohols and pantothenic acid arise in the manner already mentioned.
Von den Aminosäuren kommen vorzugsweise jene in Betracht, die als Bestandteile der Eiweißstoffe erkanat wurden.Of the amino acids, those preferably come into consideration as Components of the protein substances were erkanat.
Den Haar- und Hautpflegemitteln, die gemäß der Erfindung mittels der neuen Kondensationsverbindungen hergestellt werden, können in sonst bekannter Weise andere Substanzen, wie Alkohole, Glycerin, Glykole, Salicylsäure, Kampfer, Thymol, Teerfraktionenfl pflanzliche Auszüge, Fette und Ole, Wachse, Kohlenwasserstoffe, Emulgatoren, Schwefel u. dgl. zugefügt werden. The hair and skin care products according to the invention by means of the new condensation compounds can be produced in otherwise known Way other substances, such as alcohols, glycerin, glycols, salicylic acid, camphor, Thymol, tar fractions, vegetable extracts, fats and oils, waxes, hydrocarbons, Emulsifiers, sulfur and the like can be added.
In Mengen von 0,2 bis 0,5 0/o erweisen sich die neuen Kondensationsverbindungen als wirksam, d. h. sie fördern den Haarwuchs und üben eine wohltuende Wirkung auf die Haut aus. The new condensation compounds are found in amounts of 0.2 to 0.5% as effective, d. H. they promote hair growth and have a beneficial effect the skin off.
Im Gegensatz hierzu sind die Aminosäuren allein oder in Mischung mit Pantothensäure oder Pantophenol von sehr unsicherer Wirkung und ebenso die Pantothensäure für sich. In contrast, the amino acids are alone or in a mixture with pantothenic acid or pantophenol of very uncertain effect and also pantothenic acid for themselves.
Beispiel Haarwasser 0,2 bis o,50/a des Umsetzungsproduktes, gewonnen aus Cysteinylchlorid mit Na- oder Ca-pantothenat, 3 his 5 ovo Arnikatinktur, 0,I °/0 Salicylsäure, 0,1 0/o Kampfer oder Menthol, 0,1 0/o Polyvinylpyrrolidon, 45 ovo Äthylalkohol, Wasser auf IooTeile. Example hair lotion 0.2 to 0.50 / a of the reaction product obtained from cysteinyl chloride with Na or Ca pantothenate, 3 to 5 ovo arnica tincture, 0, I. ° / 0 salicylic acid, 0.1% camphor or menthol, 0.1% polyvinylpyrrolidone, 45 ovo ethyl alcohol, water to 100 parts.
Riechstoffe, Farbstoffe und Lösungsvermittler können nach Bedarf zugefügt werden, desgleichen antiseptisch wirkende Stoffe. Fragrances, dyes and solubilizers can be used as required are added, as well as antiseptic substances.
An Stelle des Umsetzungsproduktes von Cysteinylchlorid mit Natrium oder Ca;lcium-pantothenat kann beispielsweise das Umsetzungsprodukt aus Ieucinolchlorid und Natrium- oder Calcium- pantothenat Verwendung finden. Instead of the reaction product of cysteinyl chloride with sodium or calcium pantothenate can, for example, be the reaction product of ieucinol chloride and sodium or calcium pantothenate are used.
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEJ8945A DE955093C (en) | 1954-07-23 | 1954-07-23 | Hair and skin care products |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEJ8945A DE955093C (en) | 1954-07-23 | 1954-07-23 | Hair and skin care products |
Publications (1)
Publication Number | Publication Date |
---|---|
DE955093C true DE955093C (en) | 1956-12-27 |
Family
ID=7198769
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEJ8945A Expired DE955093C (en) | 1954-07-23 | 1954-07-23 | Hair and skin care products |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE955093C (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0035919A2 (en) * | 1980-03-05 | 1981-09-16 | Sophie Frajdenrajch | Composition for treating the hair |
US4478853A (en) * | 1982-05-17 | 1984-10-23 | S. C. Johnson & Son, Inc. | Skin conditioning composition |
EP0200208A2 (en) * | 1985-04-29 | 1986-11-05 | Richardson-Vicks, Inc. | Pantethine component for hair permanent waving |
US4970220A (en) * | 1982-05-17 | 1990-11-13 | S. C. Johnson & Son, Inc. | Skin conditioning composition |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH238597A (en) * | 1942-09-29 | 1945-07-31 | Hoffmann La Roche | Process for the production of a cosmetic agent. |
-
1954
- 1954-07-23 DE DEJ8945A patent/DE955093C/en not_active Expired
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH238597A (en) * | 1942-09-29 | 1945-07-31 | Hoffmann La Roche | Process for the production of a cosmetic agent. |
CH245584A (en) * | 1942-09-29 | 1946-11-15 | Hoffmann La Roche | Process for the production of a cosmetic agent. |
CH245907A (en) * | 1942-09-29 | 1946-11-30 | Hoffmann La Roche | Process for the production of a cosmetic agent. |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0035919A2 (en) * | 1980-03-05 | 1981-09-16 | Sophie Frajdenrajch | Composition for treating the hair |
EP0035919A3 (en) * | 1980-03-05 | 1982-12-08 | Sophie Frajdenrajch | Composition for treating the hair |
US4478853A (en) * | 1982-05-17 | 1984-10-23 | S. C. Johnson & Son, Inc. | Skin conditioning composition |
US4970220A (en) * | 1982-05-17 | 1990-11-13 | S. C. Johnson & Son, Inc. | Skin conditioning composition |
EP0200208A2 (en) * | 1985-04-29 | 1986-11-05 | Richardson-Vicks, Inc. | Pantethine component for hair permanent waving |
EP0200208A3 (en) * | 1985-04-29 | 1987-03-18 | Richardson-Vicks, Inc. | Pantethine component for hair permanent waving |
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