DE9409162U1 - Liquid dentifrice with high transparency and high foaming power - Google Patents
Liquid dentifrice with high transparency and high foaming powerInfo
- Publication number
- DE9409162U1 DE9409162U1 DE9409162U DE9409162U DE9409162U1 DE 9409162 U1 DE9409162 U1 DE 9409162U1 DE 9409162 U DE9409162 U DE 9409162U DE 9409162 U DE9409162 U DE 9409162U DE 9409162 U1 DE9409162 U1 DE 9409162U1
- Authority
- DE
- Germany
- Prior art keywords
- weight
- dental care
- care product
- product according
- liquid dental
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007788 liquid Substances 0.000 title claims description 20
- 238000005187 foaming Methods 0.000 title claims description 4
- 239000000551 dentifrice Substances 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 24
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 16
- 239000000600 sorbitol Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- 229940043264 dodecyl sulfate Drugs 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 9
- 239000000230 xanthan gum Substances 0.000 claims description 9
- 235000010493 xanthan gum Nutrition 0.000 claims description 9
- 229920001285 xanthan gum Polymers 0.000 claims description 9
- 229940082509 xanthan gum Drugs 0.000 claims description 9
- 239000012459 cleaning agent Substances 0.000 claims description 8
- 239000003906 humectant Substances 0.000 claims description 7
- 150000002191 fatty alcohols Chemical class 0.000 claims description 6
- 239000013543 active substance Substances 0.000 claims description 5
- -1 polyethylene Polymers 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 150000008051 alkyl sulfates Chemical class 0.000 claims 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 229940074371 monofluorophosphate Drugs 0.000 description 9
- 239000008367 deionised water Substances 0.000 description 8
- 229910021641 deionized water Inorganic materials 0.000 description 8
- 239000000796 flavoring agent Substances 0.000 description 8
- 235000013355 food flavoring agent Nutrition 0.000 description 8
- 229940081974 saccharin Drugs 0.000 description 7
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 7
- IIRDTKBZINWQAW-UHFFFAOYSA-N hexaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCO IIRDTKBZINWQAW-UHFFFAOYSA-N 0.000 description 6
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920002556 Polyethylene Glycol 300 Polymers 0.000 description 2
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 2
- 229920002582 Polyethylene Glycol 600 Polymers 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 230000000675 anti-caries Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- 239000001736 Calcium glycerylphosphate Substances 0.000 description 1
- 208000006558 Dental Calculus Diseases 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- UHHRFSOMMCWGSO-UHFFFAOYSA-L calcium glycerophosphate Chemical compound [Ca+2].OCC(CO)OP([O-])([O-])=O UHHRFSOMMCWGSO-UHFFFAOYSA-L 0.000 description 1
- 229940095618 calcium glycerophosphate Drugs 0.000 description 1
- 235000019299 calcium glycerylphosphate Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 235000010487 tragacanth Nutrition 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- 229940116362 tragacanth Drugs 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Description
P1 ,cABETH JUNG ."..·· .··..·· ., ., P1 ,cABETH JUNG ."..·· .··..·· ., .,
;■ !ürgen scHiRDEWAHN : ::··..·" ::··..·..·:.:.;■ !ürgen schHiRDEWAHN : ::··..·" ::··..·..·:.:.
Ä CLAUS GERNHARDT \.'\.« \.« \.« ..· .·Ä CLAUS GERNHARDT \.'\.« \.« \.« ..· .·
PATENTANWÄLTEPATENT ATTORNEYS
t, tn an803 München
Clemensstr. 30, wöuomu t, tn an803 Munich
Clemensstr. 30, wöuomu
Telefon (089) 345067
Lingner + Fischer GmbH, Bühl, BadenTelephone (089) 345067
Lingner + Fischer GmbH, Bühl, Baden
Flüssiges Zahnpflegemittel mit hoher Transparenz und hohem Ans chäumvermögenLiquid dental care product with high transparency and high foaming capacity
Es ist an sich bekannt, die früher üblichen Zahnpflegemittel in Pulver- oder Pastenform durch flüssige Zubereitungen zu ersetzen, welche sich einfacher dosieren lassen und. daher sparsam im Verbrauch sind.It is well known that the previously common dental care products in powder or paste form can be replaced by liquid preparations, which are easier to dose and therefore economical to use.
Es sind weiterhin gelförmige Zahnpflegemittel bekannt, welche eine gewisse Transparenz aufweisen und daher ein besonders ansprechendes Aussehen haben, was sich insbesondere vorteilhaft für die Hygieneerziehung von Kindern und Jugendlichen erwiesen hat.Furthermore, gel-like dental care products are known which have a certain degree of transparency and therefore a particularly attractive appearance, which has proven particularly advantageous for the hygiene education of children and young people.
In der Praxis haben sich jedoch Schwierigkeiten ergeben bei dem Bemühen, lagerfähige hochtransparente flüssige Zahnpflegemittel herzustellen, welche ausreichende Mengen an Putzkörper enthalten, und außerdem das von Pastenpräparaten her gewohnte Schaumvolumen zu bilden, welches vom Verbraucher auch als "Mundgefühl" wahrgenommen wird.In practice, however, difficulties have arisen in the attempt to produce storable, highly transparent liquid dental care products that contain sufficient amounts of abrasives and also produce the foam volume that is usual for paste preparations and that is also perceived by the consumer as a "mouth feel".
Diese bisher einer allgemeinen Akzeptanz entgegenstehenden Nachteile von flüssigen Zahnpflegemitteln werden erfindungsgemäß durch eine spezielle Kombination von Einzelkomponenten behoben.These disadvantages of liquid dental care products, which have so far prevented general acceptance, are remedied according to the invention by a special combination of individual components.
Das erfindungsgemäße flüssige Zahnpflegemittel mit hoher Transparenz und hohem Anschäumvermögen auf der Basis eines Verdickungsmittels, eines Feuchthaltemittels, eines Putzkörpers und von Tensiden ist dadurch gekennzeichnet, daßThe liquid dental care product according to the invention with high transparency and high foaming capacity based on a thickener, a humectant, an abrasive and surfactants is characterized in that
a) das Feuchthaltemittel aus einer Kombination von Sorbit in einer Menge von 40 bis 60 Gew%, bezogen auf die Zusammensetzung, und einem Polyethylenglycol mit einem Durchschnittsmolekulargewicht von 200 bis 600 in einer Menge von 0,5 bis 10 Gew%, bezogen auf die Zusammensetzung (jeweils bezogen auf 100% aktiven Stoff) besteht; daßa) the humectant consists of a combination of sorbitol in an amount of 40 to 60% by weight, based on the composition, and a polyethylene glycol with an average molecular weight of 200 to 600 in an amount of 0.5 to 10% by weight, based on the composition (each based on 100% active substance); that
b) der Putzkörper in einer Menge von 8 bis 20 Gew% in der Gesamtzusammensetzung vorliegt, und daß diesesb) the cleaning agent is present in an amount of 8 to 20% by weight in the total composition, and that this
c) ein Tensidsystem in Form einer Mischung aus einem l8~A-'-^ylsu-'-fa't: und einem (Cg-ig) Fettalkoholpolyglycosid enthält.c) a surfactant system in the form of a mixture of a ( C 8 -C 12 ) fatty alcohol polyglycoside and a (C 10 -C 14 ) fatty alcohol polyglycoside.
Überraschenderweise hat sich beispielsweise gezeigt, daß das nur aus Sorbit und relativ niedrigmolekularen Polyethylenglycolen bestehende Feuchthaltemittel, das nicht den sonst üblichen Polyalkohol Glycerin enthält, es ermöglicht, in dem angegebenen Konzentrationsbereich auch bei Mengen an Putzkörper, vor allem feinteiliger Kieselsäure, die bis zu 20 Gew% betragen können, noch eine hohe Transparenz zu gewährleisten.Surprisingly, it has been shown, for example, that the humectant, which consists only of sorbitol and relatively low molecular weight polyethylene glycols and does not contain the otherwise usual polyalcohol glycerine, makes it possible to ensure a high level of transparency in the specified concentration range even with quantities of cleaning agents, especially finely divided silica, which can amount to up to 20% by weight.
Außerdem hat sich überraschenderweise gezeigt, daß das Tensidsystem gemäß Merkmal (c) zu einer verstärkten Schaumbildung führt, während gleichzeitig die dermatologische Verträglichkeit verbessert wird.Furthermore, it has surprisingly been shown that the surfactant system according to feature (c) leads to increased foam formation, while at the same time improving dermatological compatibility.
Bevorzugte Ausführungsformen der flüssigen Zahnpflegemittel gemäß vorliegender Neuerung enthaltenPreferred embodiments of the liquid dental care products according to the present invention contain
a) 50 bis 55 Gew% Sorbit und 0,5 bis 3 Gew% der PoIyethylenkomponente (MG 200 bis 600), jeweils bezogen auf 100% aktiven Stoff;a) 50 to 55% by weight of sorbitol and 0.5 to 3% by weight of the polyethylene component (MW 200 to 600), each based on 100% active substance;
b) 10 bis 15 Gew% eines Putzkörpers undb) 10 to 15% by weight of a cleaning agent and
c) 0,5 bis 5,0 Gew% des Tensidsystems.c) 0.5 to 5.0 wt% of the surfactant system.
Als Putzkörper eignet sich vor allem jede feinteilige Kieselsäure, wie Fällungssäure oder Kieselsäuregele, &zgr;. &Bgr;. Xerogele. Der Putzkörper hat zweckmäßig eine Durchschnittsteilchengröße zwischen 1 und 20 &mgr;&pgr;&igr;, bevorzugt zwischen 1 und 15 [xm. Die Oberflächenausdehnung beträgt vorzugsweise 50 bis 100 m^/.g und insbesondere 70 bis 90 m^/g (bestimmt nach der BET-Methode, DIN 66 131).Any finely divided silica, such as precipitated acid or silica gels, z, B, xerogels, is particularly suitable as a cleaning agent. The cleaning agent preferably has an average particle size of between 1 and 20 μιδ, preferably between 1 and 15 [μm. The surface area is preferably 50 to 100 m2/g and in particular 70 to 90 m2/g (determined according to the BET method, DIN 66 131).
Als Verdickungsmittel können natürlich vorkommende Gummi sowie Traganth und Alkalimetallalginate, wie Natriumalginat, verwendet werden. Sehr gut geeignet für diesen Zweck ist Xanthat-Gummi (vgl. US-PS 3 067 038). Das Verdickungsmittel liegt zweckmäßig in Mengen von 0,01 bis 3 Gew%, vorzugsweise in Mengen von 0,01 bis 2 Gew%, bezogen auf die Gesamtzusammensetzung, vor.Naturally occurring gums, as well as tragacanth and alkali metal alginates such as sodium alginate, can be used as thickeners. Xanthate gum is very suitable for this purpose (see US Patent 3,067,038). The thickener is suitably present in amounts of 0.01 to 3% by weight, preferably in amounts of 0.01 to 2% by weight, based on the total composition.
Der als eine Komponente des Feuchthaltemittels verwendete Sorbit wird im allgemeinen in Form einer 70%igen wässrigen Lösung eingesetzt. Wenn diese Lösung in Mengen von ca. 71 bis 79 Gew% verwendet wird, so entspricht das einem Gehalt von 49,7 bis 55,3 Gew% an Sorbit, bezogen auf 100% aktiven Stoff.The sorbitol used as a component of the humectant is generally used in the form of a 70% aqueous solution. If this solution is used in amounts of approximately 71 to 79% by weight, this corresponds to a content of 49.7 to 55.3% by weight of sorbitol, based on 100% active substance.
Die zweite Komponente des Feuchthaltemittels ist ein Polyethylenglycol, dessen Durchschnittsmolekulargewicht vorzugsweise 200 bis 400 beträgt. Solche Produkte sind im Handel unter der Bezeichnung PEG 200 (PEG4), PEG 300 (PEG6), PEG 400 (PEG8) sowie PEG 600 (PEG12) erhältlich.The second component of the humectant is a polyethylene glycol, the average molecular weight of which is preferably 200 to 400. Such products are commercially available under the names PEG 200 (PEG4), PEG 300 (PEG6), PEG 400 (PEG8) and PEG 600 (PEG12).
Das Natriumalkylsulfat im Tensidsystem (c) weist eine Alkylgruppe mit 12 bis 18 Kohlenstoffatomen auf, wobei die Verbindung Na-Laurylsulfat bevorzugt ist.The sodium alkyl sulfate in the surfactant system (c) has an alkyl group with 12 to 18 carbon atoms, with the compound Na-lauryl sulfate being preferred.
Die zweite Komponente des Tensidsystems enthält vorzugsweise 8 bis 16, insbesondere 12 bis 16, Kohlenstoffatome im Fettalkoholrest. Die betreffenden Polyglycoside sind im Handel erhältlich.The second component of the surfactant system preferably contains 8 to 16, in particular 12 to 16, carbon atoms in the fatty alcohol residue. The polyglycosides in question are commercially available.
Das flüssige Zahnpflegemittel enthält außer dem durch die Sorbitlösung eingebrachten Wasseranteil in der Regel noch zusätzliche Wassermengen bis zu einem Gesamtwassergehalt von 15 bis 40 Gew%, vorzugsweise von 20 bis 35 Gew%, bezogen auf die Gesamtzusammensetzung.In addition to the water content introduced by the sorbitol solution, the liquid dental care product generally contains additional amounts of water up to a total water content of 15 to 40% by weight, preferably 20 to 35% by weight, based on the total composition.
Das flüssige Zahnpflegemittel kann gegebenenfalls noch spezielle Wirkstoffe enthalten, wie eine Quelle von Fluorionen, wodurch die Antikarieswirkung verstärkt wird. Solche fluorhaltigen Wirkstoffe, wie NaF und Na-Monofluorphosphat, werden üblicherweise in Mengen mit verwendet, welche 250 bis 2000 TpM und vorzugsweise 500 bis 1500 TpM Fluorion entsprechen. Diese Antikarieswirkung kann durch gleichzeitigen Zusatz von Kalziumglycerophosphat noch intensiviert werden.The liquid dental care product may optionally contain special active ingredients, such as a source of fluorine ions, which enhances the anti-caries effect. Such fluorine-containing active ingredients, such as NaF and Na monofluorophosphate, are usually used in amounts corresponding to 250 to 2000 ppm and preferably 500 to 1500 ppm fluorine ion. This anti-caries effect can be further intensified by the simultaneous addition of calcium glycerophosphate.
Auch Antizahnsteinmittel, Mittel zum Einstellen des pH-Wertes sowie Aromastoffe und pharmakologisch zulässige Farbstoffe können mitverwendet werden.Anti-tartar agents, pH adjusters, flavorings and pharmacologically acceptable colorants can also be used.
Um die Attraktivität der neuen flüssigen Zahnpflegemittel, insbesondere bei Kindern, noch zu verstärken, können diese zusätzlich z. B. Glimmerteilchen enthalten, wodurch eine Art Glitzereffekt hervorgerufen wird. Vorzugsweise sind solche Glimmerteilchen in Mengen von 0,01 bis 0,1 Gew%, insbesondere von etwa 0,05 Gew%, in der Gesamtzusammensetzung vorhanden.In order to increase the attractiveness of the new liquid dental care products, especially for children, they can additionally contain, for example, mica particles, which create a kind of glitter effect. Preferably, such mica particles are present in amounts of 0.01 to 0.1% by weight, in particular of about 0.05% by weight, in the overall composition.
Die neuen flüssigen Zahnpflegemittel werden durch die
nachstehenden Beispiele näher erläutert. Der in Beispiel 2 angegebene Trübungswert ist mittels eines HACH-Ratio XR Turbimeters
bestimmt worden. Werte unter 40 entsprechen dabei einem klaren Produkt.
Beispiel 1 The new liquid dental care products are explained in more detail in the following examples. The turbidity value given in example 2 was determined using a HACH Ratio XR Turbimeter. Values below 40 correspond to a clear product.
example 1
Sorbit (70%ig in Wasser) 74,8Sorbitol (70% in water) 74.8
Polyethylenglycol 200 (PEG4) 2,0Polyethylene glycol 200 (PEG4) 2.0
Fällungskieselsäure 12,0Precipitated silica 12.0
Na-Laurylsulfat 1,7Na-lauryl sulfate 1.7
Cg-^-PoiycfiycOsici 0,8Cg-^-PoiycfiycOsici 0.8
Xanthan-Gummi 0,1Xanthan gum 0.1
Na-Monofluorphosphat 0,75Na-monofluorophosphate 0.75
Ca-Glycerophosphat 0,13Ca-glycerophosphate 0.13
Geschmacksgebender Stoff 0,80Flavouring agent 0.80
Farbstoff 0,003Dye 0.003
Entionisiertes Wasser Rest ad 100%Deionized water rest ad 100%
Sorbit (70%ig in Wasser) PEG-6Sorbitol (70% in water) PEG-6
KieselsäureSilica
Na-LaurylsulfatNa-lauryl sulfate
Xanthan-GummiXanthan gum
Na-Monofluorphosphat Ca-Glycerophosphat Geschmacksgebender Stoff Na-SaccharinNa-monofluorophosphate Ca-glycerophosphate Flavouring agent Na-saccharin
Farbstoffdye
Entionisiertes WasserDeionized water
74,4774.47
2,00 12,00 1,70 1,00 0,10 0,75 0,13 0,80 0,252.00 12.00 1.70 1.00 0.10 0.75 0.13 0.80 0.25
0,003 Rest ad 100%0.003 remainder to 100%
Trübungswert: 26,2Turbidity value: 26.2
Sorbit (70%ig in Wasser) PEG-6Sorbitol (70% in water) PEG-6
KieselsäureSilica
Na-LaurylsulfatNa-lauryl sulfate
Xanthan-GummiXanthan gum
Na-Monofluorphosphat Ca-Glycerophosphat Geschmacksgebender Stoff Na-SaccharinNa-monofluorophosphate Ca-glycerophosphate Flavouring agent Na-saccharin
Farbstoffdye
Entionisiertes WasserDeionized water
70,0070,00
3,00 12,00 1,70 1,00 0,10 0,75 0,13 0,80 0,253.00 12.00 1.70 1.00 0.10 0.75 0.13 0.80 0.25
0,003 Rest ad 100%0.003 remainder to 100%
Sorbit (70%ig in Wasser) PEG-6Sorbitol (70% in water) PEG-6
KieselsäureSilica
Na-LaurylsulfatNa-lauryl sulfate
Xanthan-GummiXanthan gum
Na-Monofluorphosphat Ca-Glycerophosphat Geschmacksgebender Stoff Na-SaccharinNa-monofluorophosphate Ca-glycerophosphate Flavoring agent Na-saccharin
Farbstoffdye
Entionisiertes WasserDeionized water
72,0072.00
4,00 13,00 1,70 1,00 0,08 0,75 0,13 0,80 0,254.00 13.00 1.70 1.00 0.08 0.75 0.13 0.80 0.25
0,003 Rest ad 100%0.003 remainder to 100%
Sorbit (70%ig in Wasser) PEG-4Sorbitol (70% in water) PEG-4
KieselsäureSilica
Na-LaurylsulfatNa-lauryl sulfate
Xanthan-GummiXanthan gum
Na-Monofluorphosphat Ca-Glycerophosphat Geschmacksgebender Stoff Na-SaccharinNa-monofluorophosphate Ca-glycerophosphate Flavouring agent Na-saccharin
Farbstoffdye
Entionisiertes WasserDeionized water
73,5073.50
2,00 15,00 1,70 1,00 0,05 0,75 0,13 0,80 0,252.00 15.00 1.70 1.00 0.05 0.75 0.13 0.80 0.25
0,003 Rest ad 100%0.003 remainder to 100%
Sorbit (70%ig in Wasser) PEG-6Sorbitol (70% in water) PEG-6
Kieselsäure
Na-Laurylsulfat c &khgr; 2 -16 ~ Po -"-y91 yco s ^ ^
Xanthan-GummiSilica
Na-lauryl sulfate c &khgr; 2 -16 ~ Po -"-y91 y co s ^ ^ Xanthan gum
Na-Monof luorphosphat:Na-monofluorophosphate:
Ca-Glycerophosphat Geschmacksgebender Stoff Na-SaccharinCa-Glycerophosphate Flavoring agent Na-Saccharin
Farbstoffdye
Entionisiertes WasserDeionized water
78,0078.00
2,50 12,00 1,70 1,00 0,10 0,75 0,13 0,80 0,252.50 12.00 1.70 1.00 0.10 0.75 0.13 0.80 0.25
0,003 Rest ad 100%0.003 remainder to 100%
Sorbit (70%ig in Wasser) PEG-6Sorbitol (70% in water) PEG-6
Kieselsäure
Na-LaurylsulfatSilica
Na-lauryl sulfate
Xanthan-GummiXanthan gum
Na-Monofluorphosphat Ca-Glycerophosphat Geschmacksgebender Stoff Na-SaccharinNa-monofluorophosphate Ca-glycerophosphate Flavoring agent Na-saccharin
Farbstoffdye
Entionisiertes WasserDeionized water
78,0078.00
2,00 10,00 1,70 1,00 0,10 0,75 0,13 0,80 0,252.00 10.00 1.70 1.00 0.10 0.75 0.13 0.80 0.25
0,003 Rest ad 100%0.003 remainder to 100%
Sorbit (70%ig in Wasser) PEG-6Sorbitol (70% in water) PEG-6
Kieselsäure
Na-LaurylsulfatSilica
Na-lauryl sulfate
Xanthan-GummiXanthan gum
Na-Monofluorphosphat Ca-Glycerophosphat Geschmacksgebender Stoff Na-SaccharinNa-monofluorophosphate Ca-glycerophosphate Flavoring agent Na-saccharin
Farbstoffdye
Entionisiertes WasserDeionized water
• f• f
• ··
74,4774.47
2,00 12,00 1,70 1,00 0,10 0,75 0,13 0,80 0,252.00 12.00 1.70 1.00 0.10 0.75 0.13 0.80 0.25
0,003 Rest ad 100%0.003 remainder to 100%
Claims (9)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE9409162U DE9409162U1 (en) | 1994-06-06 | 1994-06-06 | Liquid dentifrice with high transparency and high foaming power |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE9409162U DE9409162U1 (en) | 1994-06-06 | 1994-06-06 | Liquid dentifrice with high transparency and high foaming power |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE9409162U1 true DE9409162U1 (en) | 1994-09-01 |
Family
ID=6909507
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE9409162U Expired - Lifetime DE9409162U1 (en) | 1994-06-06 | 1994-06-06 | Liquid dentifrice with high transparency and high foaming power |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE9409162U1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995022958A2 (en) * | 1994-02-24 | 1995-08-31 | Lingner + Fischer Gmbh | Transparent liquid dentifrice |
| WO1997025966A1 (en) * | 1996-01-15 | 1997-07-24 | Henkel Kommanditgesellschaft Auf Aktien | Dental hygiene agents |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3131850C2 (en) * | 1980-08-19 | 1990-11-08 | Colgate-Palmolive Co., New York, N.Y., Us | |
| WO1993007160A1 (en) * | 1991-10-10 | 1993-04-15 | Henkel Corporation | Preparation of alkylpolyglycosides |
| WO1993007249A1 (en) * | 1991-10-10 | 1993-04-15 | Henkel Corporation | Preparation of improved alkylpolyglycoside surfactant mixtures |
| EP0550281A2 (en) * | 1991-12-31 | 1993-07-07 | Unilever Plc | Compositions comprising nonionic glycolipid surfactants |
-
1994
- 1994-06-06 DE DE9409162U patent/DE9409162U1/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3131850C2 (en) * | 1980-08-19 | 1990-11-08 | Colgate-Palmolive Co., New York, N.Y., Us | |
| WO1993007160A1 (en) * | 1991-10-10 | 1993-04-15 | Henkel Corporation | Preparation of alkylpolyglycosides |
| WO1993007249A1 (en) * | 1991-10-10 | 1993-04-15 | Henkel Corporation | Preparation of improved alkylpolyglycoside surfactant mixtures |
| EP0550281A2 (en) * | 1991-12-31 | 1993-07-07 | Unilever Plc | Compositions comprising nonionic glycolipid surfactants |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995022958A2 (en) * | 1994-02-24 | 1995-08-31 | Lingner + Fischer Gmbh | Transparent liquid dentifrice |
| WO1995022958A3 (en) * | 1994-02-24 | 1995-09-21 | Lingner & Fischer Gmbh | Transparent liquid dentifrice |
| WO1997025966A1 (en) * | 1996-01-15 | 1997-07-24 | Henkel Kommanditgesellschaft Auf Aktien | Dental hygiene agents |
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