DE8707760U1 - Filter mat for flue gas detoxification - Google Patents
Filter mat for flue gas detoxificationInfo
- Publication number
- DE8707760U1 DE8707760U1 DE8707760U DE8707760U DE8707760U1 DE 8707760 U1 DE8707760 U1 DE 8707760U1 DE 8707760 U DE8707760 U DE 8707760U DE 8707760 U DE8707760 U DE 8707760U DE 8707760 U1 DE8707760 U1 DE 8707760U1
- Authority
- DE
- Germany
- Prior art keywords
- filter mat
- particles
- adhesive layer
- base body
- sulfur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003546 flue gas Substances 0.000 title claims description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims description 7
- 238000001784 detoxification Methods 0.000 title claims description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 20
- 239000002245 particle Substances 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- 239000012790 adhesive layer Substances 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 239000005864 Sulphur Substances 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- 239000011593 sulfur Substances 0.000 claims description 7
- 239000010419 fine particle Substances 0.000 claims description 3
- 239000004071 soot Substances 0.000 claims description 2
- 239000002250 absorbent Substances 0.000 claims 1
- 230000002745 absorbent Effects 0.000 claims 1
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 244000309464 bull Species 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000006262 metallic foam Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002984 plastic foam Substances 0.000 description 1
- 230000010152 pollination Effects 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/64—Heavy metals or compounds thereof, e.g. mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28042—Shaped bodies; Monolithic structures
- B01J20/28045—Honeycomb or cellular structures; Solid foams or sponges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28052—Several layers of identical or different sorbents stacked in a housing, e.g. in a column
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Treating Waste Gases (AREA)
Description
■■ ■ ■ ·»'· r*■■ ■ ■ ·»'· r*
})■ ·· &agr; ui})■ ·· α ui
) &igr;* tatet «#) &igr;* tatet «#
EDT Technik-Consult und Umweltsysteme GmbH : Privates Institut für UmweltschutzEDT Technik-Consult und Umweltsysteme GmbH : Private Institute for Environmental Protection
6300 Gießen
Filtermatte für die Rauchaasentaiftuna 6300 Giessen
Filter mat for the smoke extractor
," Die Neuerung betrifft, eine Filtermatte für die Rauchgas-," The innovation concerns a filter mat for the flue gas
,' "* entgiftung, bestehend aus einem schwammartigen, porösen oder vernetzten! Grundkörper mit einer mit der Oberfläche des Grundkörpers verbundenen, aktiven, trockenen Substanz. ,' "* detoxification, consisting of a sponge-like, porous or cross-linked! base body with an active, dry substance connected to the surface of the base body.
!
&kgr; Es ist bekannt, die Rauchgasentgiftung, insbesondere die!
&kgr; It is known that smoke gas detoxification, especially the
:j Desorption oder chemische Adsorption (Chemiesorption):j Desorption or chemical adsorption (chemosorption)
T< 20 mit Hilfe von Aktivkohle, der weitere aktive Bestandteile, wie beispielsweise Elementarschwefel, beigemischt f.st, zu bewirken. Es zeigt sich, daß das Strömungs- und Fließverhalten der Rauchgase in den trockenen Substanzen, aber auch das Schüttverhalten dieser Substanzen ' _ 25 selbst, in vielen Fällen keine optimale Kontaktierung der Gase mit den festen Substanzen ermöglicht. T< 20 with the aid of activated carbon, to which other active components, such as elemental sulphur, are added. It is evident that the flow and flow behaviour of the flue gases in the dry substances, but also the pouring behaviour of these substances themselves, in many cases do not allow optimum contact between the gases and the solid substances.
y Für die Neuerung stellt sich daher die Aufgabe, bekannte y The innovation therefore has the task of identifying known
&igr; ' Filtermatten so zu präparieren, daß sie insbesondere für&igr; ' Filter mats to be prepared in such a way that they are particularly suitable for
die Schwermetall-Entgiftung ent«&igr; Zuhilfenahme von elementarem Schwefel optimal geeignet sind.which are ideal for heavy metal detoxification with the help of elemental sulfur.
y. Diese Aufgabe witd gelöst mit einer Filtermatte für die y. This task is solved with a filter mat for the
Rauchgasentc/iftung der eingangs genannten Art, bei der die aktive, ttfockene Substanz aus feinen Partikeln das reinem, elementarem Schwefel besteht, i> B1 gemahlener Schwefelblüte Oder sublimieiitem Schwefel, beöteht, dieFlue gas degassing of the type mentioned above, in which the active, volatile substance consists of fine particles of pure, elemental sulphur, i> B 1 ground sulphur bloom or sublimed sulphur, which
III· · } · « i<«a * »* IUIIII· · } · « i<«a * »* IUI
ti· it» ti <ti· it» ti <
ti · · &igr; i-iu # t ·ti · · &igr; i-iu # t ·
«its « * t ft * ft«its « * t ft * ft
ce Ii «»4>t »&igr; .ce Ii «»4>t »&igr; .
jeweils mit einem geringen Teil ihrer Oberfläche in einer auf dem GCUndkörper befindlichen Klebschicht gebunden sind,each of which is bonded with a small part of its surface in an adhesive layer located on the GC and body,
Die Auswahl des Gründkörpers, wobei vorausgesetzt sind, daß hier entsprechende Gründkörper an sich bekannt sind/ unterliegt den Kriterien, die dem Fachmann bekannt sind. Insbesondere ist bei der Auswahl der Grundkörper der Temperaturbereich des Einsatzfalles, die AggressivitätThe selection of the base body, whereby it is assumed that appropriate base bodies are known per se/ is subject to the criteria known to the expert. In particular, when selecting the base body, the temperature range of the application, the aggressiveness
iö der auftretenden Gase, der Sauerstoffgehalt und ähnliches zu berücksichtigen. Die Grundkörper-Filtermatten können beispielsweise aus keramischen Schäumen, aus porösen Feststoffen, aus Metallschäumen und Drahtgeflechten aus Kunststoffschäumen, z. B. Polyurethan-Schäumen und dergleichen, bestehent Ihre Konsistenz kann starr sein, sie kann schwach eindrückbar bis zu sehr weich sein. Üblicherweise werden Matten von 1 qm Grundfläche verwendet bei etwa 10 mm Dicke. Die Porendichte, gemessen im üblichen Maß Pore pro Inch = ppi, liegt beispielsweise zwischen 10 - 60 ppi. Wesentlich ist, daß die gesamte äußere und innere, zugängliche Oberfläche des Grundkörpers mit der Klebschicht und entsprechend mit den feinen Partikeln belegt ist. Das Aufbringen der Partikel kann beispielsweise durch Bestäuben, Berieseln und anschließendes Schütteln, aber auch durch Sublimieren aus einem Schwefeldampf heraus, erfolgen.iö of the gases occurring, the oxygen content and similar must be taken into account. The base body filter mats can consist, for example, of ceramic foams, of porous solids, of metal foams and wire mesh made of plastic foams, e.g. polyurethane foams and the like. Their consistency can be rigid, it can be slightly pressed in or very soft. Usually mats with a base area of 1 square meter and a thickness of around 10 mm are used. The pore density, measured in the usual measure of pore per inch = ppi, is for example between 10 - 60 ppi. It is essential that the entire outer and inner, accessible surface of the base body is covered with the adhesive layer and accordingly with the fine particles. The particles can be applied, for example, by dusting, sprinkling and then shaking, but also by sublimation from a sulfur vapor.
Neben den Schwefelpartikeln können auch feingemahlene Aktivkohle- oder Rußteilchen in der Klebeschicht gebunden sein. Es sei auch nicht ausgeschlossen, daß weitere inerte oder aktive Partikel, z. B. Feuchtigkeitsadsorbentien, in die Klebeschicht zusätzlich eingebettet sind.In addition to the sulfur particles, finely ground activated carbon or soot particles can also be bound in the adhesive layer. It cannot be ruled out that other inert or active particles, e.g. moisture adsorbents, are also embedded in the adhesive layer.
Die Dicke des Materials, d. h. die von dem zu entgiftenden Rauchgas zu durchdringende Mächtigkeit, richtet sich im wesentlichen nach Wünschen#,bekannten Kriterien. EsThe thickness of the material, i.e. the thickness through which the flue gas to be decontaminated must penetrate, depends essentially on known criteria.
t f t e it &iacgr; &Idigr; F &iacgr;t f t e it &iacgr;&Idigr; F &iacgr;
rl Ii ·&igr;··&igr; ar t rl Ii ·&igr;··&igr; ar t
zeigt sich, daft bei Durchlässigkeit füt das Rauchgas auch eine Bestäubung" Und Beschickung möglich ist.It turns out that if the flue gas is permeable, pollination and feeding are also possible.
Das Aktivierüngsprinzip der Filtermatte geht ab von üblichen Verfahren, bei dein in die Klebstoffmasse selbst die feingemahlene Grundsubstanz eingerührt und anschließend durch Tauchen in der Klebstoffmasse auf dem Grundkörper befestigt wird. Diese Auftragmethode hat den großen Nachteil, daß die feinen, aktiven Partikel von der Klebstoffschicht umhüllt bleiben und damit wesentlich weniger aktive Austauschzone zwischen dem Rauchgas und dem Partikel selbst ergeben. Es kommt also darauf an, daß nur ein geringer Teil der Oberfläche in der : "" Klebschicht eingebunden ist. Als Schwefelpulver eignet &igr; 15 sich beispielsweise ein solches, das nach DAB (Deutsches &igr; Arzheimittelbuch) Nr. 6 als "Schwefeipulver" definiertThe activation principle of the filter mat differs from the usual method, in which the finely ground base substance is stirred into the adhesive mass itself and then attached to the base body by dipping it into the adhesive mass. This application method has the major disadvantage that the fine, active particles remain covered by the adhesive layer and thus result in a much smaller exchange zone between the flue gas and the particle itself. It is therefore important that only a small part of the surface is incorporated into the adhesive layer. A suitable sulfur powder is, for example, one that is defined as "sulfur powder" according to DAB (German Pharmacopoeia) No. 6.
ist. Andere geeignete Schwefelpulver sind beispielsweise "Grystex N" der Firma EMW. Der feingemahlene SchwefelOther suitable sulphur powders are, for example, "Grystex N" from EMW. The finely ground sulphur
] kann beispielsweise in einem Verhältnis von 10 : 2] can be used in a ratio of 10 : 2
20 (Schwefel zu Aktivkohle) mit feingemahlener Aktivkohle20 (sulphur to activated carbon) with finely ground activated carbon
..
j vermischt sein. Als Kleber eigne» sich beispielsweisej mixed. For example,
Mowilith DM 122.Mowilith DM 122.
&igr; Die Figur zeigt ein Ausführungsbeispiel. Ein grobporiger&igr; The figure shows an example. A coarse-pored
25 Stoff mit der Porösität 35 ppi, mit 10 mm Stärke aus geschäumtem Polyurethan. Die Grundplatte wird mit einem Kleber getränkt; überschüssiger Kleber wird abgequetscht. Das Gewicht beträgt nunmehr 638 g. Der getränkte Schaumstoff wurde von beiden Seiten mit feingemahlenem Schwefel gemäß DAB 6 gepudert und gesprüht, bis die Masse insgesamt 1990 g beträgt. D. h. 752 g Schwefel befinden sich auf 1 qm. Die Platte wird bis zur Wasserfreihext getrocknet. Nicht fixierter bzw. nicht haftender Schwefel und andere Teilchen werden abgeschlagen. Schwermetall, insbesondere quecksilberhaltige Dämpfe, werden durch die Substanz hindurchgeschickt und25 fabric with a porosity of 35 ppi, 10 mm thick, made of foamed polyurethane. The base plate is soaked with an adhesive; excess adhesive is squeezed off. The weight is now 638 g. The soaked foam was powdered and sprayed on both sides with finely ground sulfur in accordance with DAB 6 until the total mass is 1990 g. This means that 752 g of sulfur are in 1 square meter. The plate is dried until it is anhydrous. Unfixed or non-adhering sulfur and other particles are knocked off. Heavy metals, especially mercury-containing vapors, are passed through the substance and
! reagieren mit den freiliegenden Teilchen. Derartige! react with the exposed particles. Such
• · &igr; &igr; &pgr; ■ nit &igr;«• · &igr;&igr;&pgr; ■ nit &igr;«
( 1 -) F lilt <·( 1 -) F lilt <·
• i > · S ·• i > · S ·
! " ·■ ! " ·■ tiftif
SchaUiristo££platten können auch zu mehreren in Kassetten-Filtergehäusen Und dergleiehen (nicht dargestellt) zusammengefaßt werden. Die Figur zeigt in vergrößerter Darstellung den Bereich der Poren mit der Klebstoffschicht und eingebetteten Partikeln aus elementarem Schwefel.Soundproofing plates can also be combined in groups in cassette filter housings and the like (not shown). The figure shows an enlarged view of the area of the pores with the adhesive layer and embedded particles of elemental sulfur.
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE8707760U DE8707760U1 (en) | 1986-06-02 | 1987-05-30 | Filter mat for flue gas detoxification |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19868614516 DE8614516U1 (en) | 1986-06-02 | 1986-06-02 | Filter mat for flue gas detoxification |
DE8707760U DE8707760U1 (en) | 1986-06-02 | 1987-05-30 | Filter mat for flue gas detoxification |
Publications (1)
Publication Number | Publication Date |
---|---|
DE8707760U1 true DE8707760U1 (en) | 1988-01-14 |
Family
ID=25950899
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE8707760U Expired DE8707760U1 (en) | 1986-06-02 | 1987-05-30 | Filter mat for flue gas detoxification |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE8707760U1 (en) |
-
1987
- 1987-05-30 DE DE8707760U patent/DE8707760U1/en not_active Expired
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