DE713589C - Threads, films, coatings, fillers, etc. like - Google Patents

Threads, films, coatings, fillers, etc. like

Info

Publication number
DE713589C
DE713589C DEI62334D DEI0062334D DE713589C DE 713589 C DE713589 C DE 713589C DE I62334 D DEI62334 D DE I62334D DE I0062334 D DEI0062334 D DE I0062334D DE 713589 C DE713589 C DE 713589C
Authority
DE
Germany
Prior art keywords
threads
films
coatings
fillers
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEI62334D
Other languages
German (de)
Inventor
Dr Hans Fikentscher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to DEI62334D priority Critical patent/DE713589C/en
Application granted granted Critical
Publication of DE713589C publication Critical patent/DE713589C/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/08—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/34—Filling pastes
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/16—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated carboxylic acids or unsaturated organic esters, e.g. polyacrylic esters, polyvinyl acetate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Description

Fäden, Filme, Überzüge, Spachtelmassen u. dgl. Das Hauptpatent 685 257 betrifft Fäden, Filme, Überzüge, Spachtehnassen u. dgl., bestehend aus -festen Produkten, die durch Polymerisation von in Wasser unlöslichen Acrylsäureverbindungen oder ihren Homologen im Gemisch mit anderen polymerisierbaren organischen Verbindungen mit ,einer olefinischen Doppelbindung, wie Vinylchlorid, Styrol oder asymmetrischem Dichloräthylen, gewonnen werden, mit Ausnahme der Mischpolym:erisate aus Acrylsäureestern und Vinylestern organischer Säuren.Threads, films, coatings, fillers and the like. The main patent 685 257 relates to threads, films, coatings, Spachtehnassen u Organic compounds with an olefinic double bond, such as vinyl chloride, styrene or asymmetrical dichloroethylene, are obtained, with the exception of mixed polymers: erisate from acrylic acid esters and vinyl esters of organic acids.

Es wurde nun -gefunden, daß man besonders ausgezeichnete Fäden, Filme, Überzüge, Spathtelmassen u. dgl. aus *lVlischpolymerisaten von etwa 8o% Vinylchlorid und etwa 2o0/'o Acrylsäureester herstellen kann. Diese Mischpolymerisate können in der gleichen Weise verarbeitet und verwendet werden, wie im Hauptpatent beschrieben.It has now been found that particularly excellent threads, films, Coatings, spatula masses and the like made from mixed polymers of about 80% vinyl chloride and about 2o0 / 'o can produce acrylic acid esters. These copolymers can processed and used in the same way as described in the main patent.

Beispiel i io Teüe eines durch gemeinsame Polymeris:ation von Acryls,äuremethylester und Vinylchlorid hergestellten Polymerisationsproduktes, enthaltend 2o0!0 Acryisäuremethylester und 8o % Viinylchlorid, werden in einer Mischung aus q.o Teilen Chlorbenzol und 2o Teilen Methylenchlorid gelöst. Man- filtriert die erhaltene Lösung erforderlichenfalls und stellt aus der Lösung nach bekannten Methoden. einen Film her. Der vollkommen getrocknete Film besitzt eine Festigkeit von 6 bis 7 kg/mm2 und eine etwa sechsmal so große Knitterfestigkeit wie ein gleich starker Nitrocellulosefilm. Der erhaltene Film ist vollkommen unbrennbar.Example io part of a joint polymerisation of acrylic, acid methyl ester and vinyl chloride produced polymerization product containing 2o0! 0 methyl acrylate and 8o% Viinylchlorid, are in a mixture of q.o parts and chlorobenzene 2o parts of methylene chloride dissolved. The solution obtained is filtered if necessary and puts out of the solution according to known methods. made a movie. The perfect dried film has a strength of 6 to 7 kg / mm2 and about six times as strong as a nitrocellulose film of the same thickness. The received Film is completely incombustible.

Beispiel Aus einem Mischpolymerisat, das durch Polymerisation von 82 Teilen Vinylchlorid und 18 Teilen Acrylsäuremethylester erhalten wird, wird eine zoo'oige Lösung in Methylenchloridaceton (im Verhältnis .4: i) hergestellt und diese Lösung unter einem Druck von 2o bis 3o Atm. und einer Schaclittempera.tur-von 8o bis ioo' bei einer Geschwindigheit von 8o bis ioo m 'Min. nach dem Trokkenspinnverfahren versponnen. Man erhält glänzende Fäden mit einer Bruchdehnung von 8 0`o und einer Festigkeit von i 5o bis Zoo g pro ioo -deniers. BeispiÜl 3 12 Teile eines Mischpolymerisationsproduktes aus 2o% Acrylsäuremethylester und 8o0'o Vinylchlorid vom K-Wert 50 werden in einer Mischung von 35,6 Teilen Methylenchlori:d, 13,2 Teilen Butylacetat (ioo%ig) und .a.3,4 Teilen Äthylacetat gelöst. Der so hergestellte Lack kann in gewohnter Weise durch Tauchen, Streichen oder gegebenenfalls nach weiterem Verdünnen durch Spritzen verarbeitet werden und gibt, auf Holz oder Metall aufgetragen, Filme, die eine ausgezeichnete Witterungsbeständigkeit besitzen und auch gegen chemische Einflüsse eine bemerkenswerte Widerstandsfähigkeit aufweisen. Der Lack kann in bekannter «'eise mit Pigment angerieben «-.erden.EXAMPLE A mixed polymer obtained by polymerizing 82 parts of vinyl chloride and 18 parts of methyl acrylate is used to prepare a zoo'oige solution in methylene chloride acetone (in a ratio of .4: i) and this solution is prepared under a pressure of 20 to 3o atm. and a schaclite temperature of 8o to 100 'at a speed of 8o to 100 m' min. spun using the dry spinning process. Shiny threads are obtained with an elongation at break of 80% and a strength of 150 to 100 g per 100 deniers. Example 3 12 parts of a copolymerization product of 2o% methyl acrylate and 8o0'o vinyl chloride with a K value of 50 are added in a mixture of 35.6 parts of methylene chloride, 13.2 parts of butyl acetate (100%) and .a.3,4 Part of ethyl acetate dissolved. The varnish produced in this way can be processed in the usual way by dipping, painting or, if necessary, after further thinning by spraying and, when applied to wood or metal, gives films that have excellent weather resistance and are also remarkably resistant to chemical influences. The varnish can be grounded in the familiar “ice rubbed with pigment”.

Claims (1)

PATENTANSPRUCH: Fäden,. Filme, Überzüge, Spachtehnassen u. dgl., bestehend aus Mi@schpolymerisaten von etwa 8o0-!o Vinylchlorid und etwa 2o0'o Acrylsäureester.PATENT CLAIM: threads ,. Films, coatings, spatulas and the like, consisting of from mixed polymers of about 8o0-! o vinyl chloride and about 2o0'o acrylic acid esters.
DEI62334D 1930-05-27 1931-10-22 Threads, films, coatings, fillers, etc. like Expired DE713589C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEI62334D DE713589C (en) 1930-05-27 1931-10-22 Threads, films, coatings, fillers, etc. like

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE685257T 1930-05-27
DEI62334D DE713589C (en) 1930-05-27 1931-10-22 Threads, films, coatings, fillers, etc. like

Publications (1)

Publication Number Publication Date
DE713589C true DE713589C (en) 1941-11-11

Family

ID=31994911

Family Applications (1)

Application Number Title Priority Date Filing Date
DEI62334D Expired DE713589C (en) 1930-05-27 1931-10-22 Threads, films, coatings, fillers, etc. like

Country Status (1)

Country Link
DE (1) DE713589C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2873703A1 (en) * 2013-11-18 2015-05-20 BASF Coatings GmbH Mixing system for the production of top coat compositions and coating compositions used as filler

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2873703A1 (en) * 2013-11-18 2015-05-20 BASF Coatings GmbH Mixing system for the production of top coat compositions and coating compositions used as filler
WO2015071489A1 (en) * 2013-11-18 2015-05-21 Basf Coatings Gmbh Mixing system for producing both topcoat compositions and coating compositions for use as a knifing filler
US10427187B2 (en) 2013-11-18 2019-10-01 Basf Coatings Gmbh Mixer system for producing topcoat compositions and coating compositions used as filler

Similar Documents

Publication Publication Date Title
DE1220613B (en) Process for the production of polymer emulsions
DE1520493B2 (en) PROCESS FOR MANUFACTURING AETHYLENE COPOLYMERISATES
DE1495694B2 (en) Process for the production of polymers of vinyl chloride
DE1208496B (en) Process for the production of mixed polymers
DE1519261A1 (en) Paint
DE929876C (en) Process for the preparation of copolymerization products
DE1210115B (en) Coating agents and varnishes
DE1720593A1 (en) Film-forming emulsions made from copolymers
DE2204429A1 (en) Thermoplastic coating compounds
DE1644783A1 (en) Heat-curable, liquid coating binders
DE2047182C3 (en) Polychloroprene-based adhesive
DE713589C (en) Threads, films, coatings, fillers, etc. like
DE1495801A1 (en) Process for the production of graft polymers of vinyl chloride
DE2003819A1 (en) Process for synthetic resin coating of surfaces and synthetic mixtures for this which can be hardened by irradiation based on polyvinyl chloride
DE2547970A1 (en) FILM FORMING Aqueous PLASTIC DISPERSIONS AND THEIR USE AS BINDERS FOR PAINTING
DE1922942B2 (en) Use of a linear, thermosetting copolymer for surface gelling of wood-based panels !!
DE3303930A1 (en) USE OF AQUEOUS POLY (METH) ACRYLATE SECONDARY DISPERSION AS A THICKENING Binder FOR COLORED STONE PLASTER
DE941575C (en) Process for the preparation of copolymers of vinyl compounds and vinylidene compounds by emulsion polymerization
DE685257C (en) Threads, films, coatings or fillers
DE2536312C3 (en) Method of making a thermosetting film
DE1745318A1 (en) Heterogeneous mixed polymers
DE2217375A1 (en) Stable polyvinylidene fluoride solns - produced at low temps using acetone as solvent
DE1745089C2 (en) Fluorine-containing copolymer, a process for its production and its use for reverse side coatings with low adhesion in pressure-sensitive adhesive strips
DE677433C (en) Process for the production of rubbery polymerization products from butadiene or its substitution products
DE1546891C3 (en) Process for coating metal surfaces with polyvinyl fluoride