DE69933658D1 - CATALYTIC PRODUCTION OF HYDROGEN - Google Patents

CATALYTIC PRODUCTION OF HYDROGEN

Info

Publication number
DE69933658D1
DE69933658D1 DE69933658T DE69933658T DE69933658D1 DE 69933658 D1 DE69933658 D1 DE 69933658D1 DE 69933658 T DE69933658 T DE 69933658T DE 69933658 T DE69933658 T DE 69933658T DE 69933658 D1 DE69933658 D1 DE 69933658D1
Authority
DE
Germany
Prior art keywords
hydrogen
hydrocarbon
partial oxidation
steam
generation process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69933658T
Other languages
German (de)
Other versions
DE69933658T2 (en
Inventor
William Carpenter
William Hayes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Publication of DE69933658D1 publication Critical patent/DE69933658D1/en
Application granted granted Critical
Publication of DE69933658T2 publication Critical patent/DE69933658T2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0816—Heating by flames
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1604—Starting up the process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

A process for the catalytic generation of hydrogen by the self-sustaining combination of partial oxidation and steam reforming of a hydrocarbon comprises containing a mixture of the hydrocarbon, an oxygen-containing gas and steam with a catalyst comprising rhodium dispersed on a refractory oxide support material which is a mixture of ceria and zirconia. The hydrocarbons are straight chain or branch chain hydrocarbons having 1 to 15 carbon atoms and include methane, propane, butane, hexane, heptane, normal-octane, iso-octane, naphthas, liquefied petroleum gas and reformulated gasoline petrol and diesel fuels. The hydrogen generation process can be started by feeding the hydrocarbon and air to initiate partial oxidation, before steam is added. The hydrogen generation process can be started by feeding the hydrocarbon and air to initiate partial oxidation, before steam is added. The hydrogen generation process also may be operated in combination with a water-gas shift reaction for the reduction of carbon monoxide in the hydrogen generated.
DE69933658T 1998-03-24 1999-03-23 CATALYTIC PRODUCTION OF HYDROGEN Expired - Lifetime DE69933658T2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB9806199 1998-03-24
GBGB9806199.7A GB9806199D0 (en) 1998-03-24 1998-03-24 Catalytic generation of hydrogen
PCT/GB1999/000753 WO1999048805A1 (en) 1998-03-24 1999-03-23 Catalytic generation of hydrogen

Publications (2)

Publication Number Publication Date
DE69933658D1 true DE69933658D1 (en) 2006-11-30
DE69933658T2 DE69933658T2 (en) 2007-08-23

Family

ID=10829091

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69933658T Expired - Lifetime DE69933658T2 (en) 1998-03-24 1999-03-23 CATALYTIC PRODUCTION OF HYDROGEN

Country Status (10)

Country Link
US (1) US6887455B2 (en)
EP (1) EP1068148B1 (en)
JP (1) JP4597366B2 (en)
AT (1) ATE342872T1 (en)
AU (1) AU3042399A (en)
CA (1) CA2325506C (en)
DE (1) DE69933658T2 (en)
ES (1) ES2273478T3 (en)
GB (1) GB9806199D0 (en)
WO (1) WO1999048805A1 (en)

Families Citing this family (66)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1077198A3 (en) * 1999-08-19 2001-03-07 Haldor Topsoe A/S Process for pre-reforming of oxygen-containing gas
JP4045564B2 (en) 1999-10-20 2008-02-13 株式会社日本ケミカル・プラント・コンサルタント Self-oxidation internal heating type reformer and method
US6902717B2 (en) * 1999-12-21 2005-06-07 Shell Oil Company Process for the catalytic partial oxidation of a hydrocarbonaceous feedstock
US6458334B1 (en) 2000-03-02 2002-10-01 The Boc Group, Inc. Catalytic partial oxidation of hydrocarbons
EP1134188A3 (en) * 2000-03-02 2004-06-09 The Boc Group, Inc. Catalytic partial oxidation of hydrocarbons
DE10013895A1 (en) * 2000-03-21 2001-10-04 Dmc2 Degussa Metals Catalysts Cerdec Ag Water gas shift reaction, useful in mobile unit in vehicle for removing carbon monoxide from gas mixture containing hydrogen for fuel cell, uses catalyst based on noble metal coating on inert carrier
EP1274650A1 (en) 2000-04-17 2003-01-15 Shell Internationale Researchmaatschappij B.V. Fuel processor
DE10025032A1 (en) 2000-05-20 2001-11-29 Dmc2 Degussa Metals Catalysts Process for the autothermal, catalytic steam reforming of hydrocarbons
US6436363B1 (en) 2000-08-31 2002-08-20 Engelhard Corporation Process for generating hydrogen-rich gas
EP1315670B1 (en) * 2000-09-05 2007-07-25 Conocophillips Company Process for producing synthesis gas with lanthanide-promoted rhodium catalysts
WO2002028770A1 (en) 2000-10-02 2002-04-11 Chevron U.S.A. Inc. Process for reducing coke formation in hydrocarbon processing by application of radio frequency electromagnetic radiation
US7922781B2 (en) * 2001-03-02 2011-04-12 Chellappa Anand S Hydrogen generation apparatus and method for using same
JP4267325B2 (en) 2001-03-02 2009-05-27 インテリジェント・エネルギー・インコーポレーテッド Ammonia-based hydrogen generator and method of using the same
US7811529B2 (en) * 2001-04-23 2010-10-12 Intelligent Energy, Inc. Hydrogen generation apparatus and method for using same
US6455182B1 (en) * 2001-05-09 2002-09-24 Utc Fuel Cells, Llc Shift converter having an improved catalyst composition, and method for its use
JP4648566B2 (en) * 2001-05-11 2011-03-09 Ｊｘ日鉱日石エネルギー株式会社 Autothermal reforming catalyst and method for producing fuel gas for fuel cell
DE10157155A1 (en) 2001-11-22 2003-06-12 Omg Ag & Co Kg Process for the catalytic autothermal steam reforming of higher alcohols, especially ethanol
EP1458960B1 (en) 2001-12-20 2011-02-09 Johnson Matthey Public Limited Company Improvements in selective catalytic reduction
US7303606B2 (en) 2002-01-08 2007-12-04 The Boc Group, Inc. Oxy-fuel combustion process
WO2003072491A1 (en) 2002-02-22 2003-09-04 Chevron U.S.A. Inc. Process for reducing metal catalyzed coke formation in hydrocarbon processing
US7056488B2 (en) 2002-03-13 2006-06-06 Conocophillips Company Controlled-pore catalyst structures and process for producing synthesis gas
US20040147394A1 (en) * 2002-03-28 2004-07-29 Wagner Jon P. Catalyst for production of hydrogen
US8172913B2 (en) 2002-04-23 2012-05-08 Vencill Thomas R Array of planar membrane modules for producing hydrogen
JP3999557B2 (en) * 2002-04-30 2007-10-31 株式会社日本触媒 Catalyst for partial oxidation of hydrocarbon and method for producing hydrogen-containing gas using the catalyst
EP1393804A1 (en) 2002-08-26 2004-03-03 Umicore AG & Co. KG Multi-layered catalyst for autothermal steam reforming of hydrocarbons and its use
US20040048116A1 (en) * 2002-09-06 2004-03-11 Ord Jason S. Hydrogen generating apparatus
US7459224B1 (en) 2002-11-26 2008-12-02 General Motors Corporation Methods, apparatus, and systems for producing hydrogen from a fuel
US7156887B1 (en) 2002-11-26 2007-01-02 General Motors Corporation Methods, apparatus, and systems for producing hydrogen from a fuel
US7105148B2 (en) 2002-11-26 2006-09-12 General Motors Corporation Methods for producing hydrogen from a fuel
GB0227582D0 (en) * 2002-11-27 2002-12-31 Johnson Matthey Plc Reforming catalyst
WO2004051060A1 (en) 2002-12-03 2004-06-17 Shell Internationale Research Maatschappij B.V. Process and apparatus for controlling the performance of a homogeneous charge compression ignition (hcci) engine
US7090826B2 (en) 2002-12-23 2006-08-15 The Boc Group, Inc. Monolith based catalytic partial oxidation process for syngas production
US7230035B2 (en) 2002-12-30 2007-06-12 Conocophillips Company Catalysts for the conversion of methane to synthesis gas
US7220390B2 (en) 2003-05-16 2007-05-22 Velocys, Inc. Microchannel with internal fin support for catalyst or sorption medium
US7153334B2 (en) 2003-05-21 2006-12-26 General Motors Corporation Fuel reforming system and method of operation
US7066984B2 (en) 2003-09-25 2006-06-27 The Boc Group, Inc. High recovery carbon monoxide production process
US7214331B2 (en) 2004-02-26 2007-05-08 The Boc Group, Inc. Catalyst configuration and methods for syngas production
US7427388B2 (en) 2004-03-19 2008-09-23 Air Products And Chemicals, Inc. Process for improving prereforming and reforming of natural gas containing higher hydrocarbons along with methane
US7309480B2 (en) * 2004-04-16 2007-12-18 H2Gen Innovations, Inc. Catalyst for hydrogen generation through steam reforming of hydrocarbons
US9150494B2 (en) 2004-11-12 2015-10-06 Velocys, Inc. Process using microchannel technology for conducting alkylation or acylation reaction
WO2006055326A1 (en) * 2004-11-18 2006-05-26 Praxair Technology, Inc. Steam methane reforming method
US7037485B1 (en) * 2004-11-18 2006-05-02 Praxair Technology, Inc. Steam methane reforming method
US7351275B2 (en) 2004-12-21 2008-04-01 The Boc Group, Inc. Carbon monoxide production process
WO2006127889A2 (en) 2005-05-25 2006-11-30 Velocys Inc. Support for use in microchannel processing
US8115373B2 (en) * 2005-07-06 2012-02-14 Rochester Institute Of Technology Self-regenerating particulate trap systems for emissions and methods thereof
US20070083073A1 (en) * 2005-09-02 2007-04-12 Ebrahim Bagherzadeh Catalyst and method for converting low molecular weight paraffinic hydrocarbons into alkenes and organic compounds with carbon numbers of 2 or more
FR2892323B1 (en) * 2005-10-20 2008-08-15 Cie D Etudes Des Technologies CATALYST FOR THE PRODUCTION OF HYDROGEN RICH GAS
GB0605232D0 (en) 2006-03-16 2006-04-26 Johnson Matthey Plc Oxygen removal
US7879256B2 (en) * 2006-03-31 2011-02-01 E. I. Du Pont De Nemours And Company Liquid crystal compositions, polymer networks derived therefrom and process for making the same
US7914700B2 (en) * 2006-03-31 2011-03-29 E. I. Du Pont De Nemours And Company Liquid crystal compositions and polymer networks derived therefrom
US20070256359A1 (en) * 2006-04-19 2007-11-08 Wiltowski Tomasz S Process for recovery of hydrogen from coal gasification products
GB0612092D0 (en) 2006-06-20 2006-07-26 Johnson Matthey Plc Oxygen removal
KR20090095653A (en) 2006-12-21 2009-09-09 존슨 맛쎄이 퍼블릭 리미티드 컴파니 Apparatus comprising lean burn ic engine and exhaust system therefor
ES2304889B1 (en) 2007-04-13 2009-10-30 INSTITUTO NACIONAL DE TECNICA AEROESPACIAL "ESTEBAN TERRADAS" PROCEDURE FOR OBTAINING HYDROGEN.
WO2008134484A2 (en) * 2007-04-25 2008-11-06 Hrd Corp. Catalyst and method for converting natural gas to higher carbon compounds
WO2009023759A2 (en) * 2007-08-15 2009-02-19 E. I. Du Pont De Nemours And Company Chiral compounds, liquid crystal compositions and polymer networks derived therefrom
EP2179007B1 (en) * 2007-08-15 2012-10-17 E. I. du Pont de Nemours and Company Alkaloid monomers, liquid crystal compositions and polymer networks derived therefrom
JP2009196869A (en) * 2008-02-25 2009-09-03 Nippon Suiso Kk Method for reforming hydrocarbon by oxyhydrogen flame using two burners
FR2942151B1 (en) * 2009-02-13 2011-08-05 Peugeot Citroen Automobiles Sa CATALYST FOR VAPORIZING HYDROCARBONS
US8034255B2 (en) * 2009-06-08 2011-10-11 E. I. Du Pont De Nemours And Company Liquid crystal compositions
US8044228B2 (en) 2009-06-08 2011-10-25 E.I. Du Pont De Nemours And Company Liquid crystal compositions
US20100308268A1 (en) * 2009-06-08 2010-12-09 E. I. Du Pont De Nemours And Company Liquid crystal compositions
US8067068B2 (en) * 2009-06-08 2011-11-29 E.I. Du Pont De Nemours And Company Liquid crystal compositions
RU2650142C2 (en) 2013-02-04 2018-04-09 Джонсон Мэтти Паблик Лимитед Компани Exhaust system reforming catalyst
WO2017004551A1 (en) * 2015-07-02 2017-01-05 Exen Holdings, Llc Hydrogen production method and system
EP3340349A1 (en) 2016-12-21 2018-06-27 sunfire GmbH Sulfur tolerant catalyst for solid oxide fuel cell and production method

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2907106C2 (en) 1979-02-23 1985-12-19 Degussa Ag, 6000 Frankfurt Catalytic converter and its use for cleaning exhaust gases from internal combustion engines
JPS59199042A (en) * 1983-04-28 1984-11-12 Nissan Motor Co Ltd Catalyst for reforming methanol
CA1213874A (en) 1983-05-12 1986-11-12 Tomohisa Ohata Process for producing honeycomb catalyst for exhaust gas conversion
JPH0790169B2 (en) * 1988-03-12 1995-10-04 哲 五十嵐 Hydrocarbon steam reforming catalyst
JPH064135B2 (en) * 1988-08-04 1994-01-19 哲 五十嵐 Hydrocarbon steam reforming catalyst
ZA859580B (en) * 1985-04-25 1986-08-27 Westinghouse Electric Corp Apparatus for hydrocarbon fuel processing
GB8521953D0 (en) 1985-09-04 1985-10-09 Johnson Matthey Plc Catalytic hydrogen generator
DE3533250C1 (en) 1985-09-18 1986-12-04 Hoechst Ag, 6230 Frankfurt Process for the production of a carrier catalyst
GB8623482D0 (en) * 1986-09-30 1986-11-05 Johnson Matthey Plc Catalytic generation of hydrogen
EP0495534A3 (en) * 1988-03-12 1992-10-07 Akira C/O Kohgakuin University Igarashi Catalyst for steam reforming of hydrocarbon
JPH0653229B2 (en) * 1988-03-24 1994-07-20 トヨタ自動車株式会社 Exhaust gas purification catalyst
CA1334962C (en) 1988-04-14 1995-03-28 Tomohisa Ohata Catalyst for purifying exhaust gas and method for production thereof
DE3830318A1 (en) * 1988-09-07 1990-03-15 Degussa EXHAUST GAS CATALYST WITH REDUCED INCLINATION FOR STORAGE OF SULFUR OXIDE AND SULFUR EMISSION
JP2716092B2 (en) * 1989-05-16 1998-02-18 財団法人石油産業活性化センター Hydrocarbon steam reforming method
US5134109A (en) 1989-07-07 1992-07-28 Idemitsu Kosan Company Limited Catalyst for reforming hydrocarbon with steam
JPH0640963B2 (en) * 1989-07-07 1994-06-01 財団法人石油産業活性化センター Hydrocarbon steam reforming catalyst
US5010051A (en) * 1989-11-08 1991-04-23 Engelhard Corporation Staged three-way conversion catalyst and method of using the same
EP0551342A1 (en) 1990-09-27 1993-07-21 Engelhard Corporation Catalyst composition containing base metal oxide-promoted rhodium
NZ245394A (en) * 1991-12-20 1995-03-28 Idemitsu Kosan Co Preparation process for synthesis gases using methane, oxygen and a catalyst
JPH05221602A (en) * 1991-12-20 1993-08-31 Idemitsu Kosan Co Ltd Production of synthesis gas
EP0640561B1 (en) * 1993-08-24 1998-11-11 Shell Internationale Researchmaatschappij B.V. Process for the catalytic partial oxidation of hydrocarbons
NZ264173A (en) * 1993-08-24 1995-09-26 Shell Int Research Catalytic process for the partial oxidation of hydrocarbons
CO4370053A1 (en) * 1993-11-29 1996-10-07 Shell Int Research PROCESS FOR PARTIAL CATALYTIC OXIDATION OF HYDROCARBONS
GB9412786D0 (en) * 1994-06-24 1994-08-17 Johnson Matthey Plc Improved reformer
ZA9510014B (en) * 1994-11-28 1996-06-04 Shell Int Research Process for preparation of supports
US5945369A (en) 1994-12-09 1999-08-31 Kabushiki Kaisha Toyota Chuo Kenkyusho Catalyst for purifying exhaust gases and process for producing the same
JP3389412B2 (en) * 1996-05-16 2003-03-24 東洋エンジニアリング株式会社 Improved steam reforming catalyst for lower hydrocarbons
US5980840A (en) * 1997-04-25 1999-11-09 Bp Amoco Corporation Autothermic reactor and process using oxygen ion--conducting dense ceramic membrane
GB9806198D0 (en) * 1998-03-24 1998-05-20 Johnson Matthey Plc Ctalytic generation of hydrogen
JP4488321B2 (en) * 1998-04-17 2010-06-23 Ｊｆｅスチール株式会社 Synthesis gas production catalyst and synthesis gas production method

Also Published As

Publication number Publication date
US20020127445A1 (en) 2002-09-12
JP2002507535A (en) 2002-03-12
CA2325506A1 (en) 1999-09-30
EP1068148A1 (en) 2001-01-17
GB9806199D0 (en) 1998-05-20
EP1068148B1 (en) 2006-10-18
AU3042399A (en) 1999-10-18
ES2273478T3 (en) 2007-05-01
ATE342872T1 (en) 2006-11-15
CA2325506C (en) 2009-06-02
WO1999048805A1 (en) 1999-09-30
JP4597366B2 (en) 2010-12-15
US6887455B2 (en) 2005-05-03
DE69933658T2 (en) 2007-08-23

Similar Documents

Publication Publication Date Title
DE69933658D1 (en) CATALYTIC PRODUCTION OF HYDROGEN
KR101419567B1 (en) Oil-based thermo-neutral reforming with a multi-component catalyst
Aasberg-Petersen et al. Recent developments in autothermal reforming and pre-reforming for synthesis gas production in GTL applications
AU2006221822B2 (en) A fuel processor for a fuel cell arrangement and a method of operating a fuel processor for a fuel cell arrangement
Navarro Yerga et al. Catalysts for hydrogen production from heavy hydrocarbons
AU6858694A (en) Process for the production of hydrogen/carbon monoxide mixtures or hydrogen from methane
Newson et al. Low-temperature catalytic partial oxidation of hydrocarbons (C1–C10) for hydrogen production
MY151832A (en) Reformed gas production method and reformed gas production apparatus
US7998456B2 (en) Process for the production of hydrogen
Shekhawat et al. Catalytic reforming of liquid hydrocarbon fuels for fuel cell applications
KR950000844A (en) Catalytic Partial Oxidation of Hydrocarbons
EP1269006B1 (en) Gas powered engine having improved emissions
CA2374852A1 (en) Catalytic partial oxidation with ignition system
AR245685A1 (en) Production of methanol from hydrocarbonaceous feedstock
RU2266946C2 (en) Method of producing hydrogen- and/or carbon monoxide-enriched gas
RU2001100538A (en) METHOD AND REACTOR FOR PRODUCING GAS ENRICHED WITH HYDROGEN AND CARBON OXIDE.
US20020174603A1 (en) Method for generating hydrogen for fuel cells
Pereira et al. Liquid fuel reformer development
CA3090983A1 (en) Integration of a hot oxygen burner with an auto thermal reformer
GB1430121A (en) Steam hydrocarbon reforming process
AU4477696A (en) Direct conversion of methane to hythane
GB1434103A (en) Process for making fuel gas

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8328 Change in the person/name/address of the agent

Representative=s name: KROHER, STROBEL RECHTS- UND PATENTANWAELTE, 80336

8328 Change in the person/name/address of the agent

Representative=s name: DR. SCHOEN & PARTNER, 80336 MUENCHEN