DE69506548D1 - Verfahren zur polymerisation unter verwendung von die-enthaltenden katalysatoren - Google Patents

Verfahren zur polymerisation unter verwendung von die-enthaltenden katalysatoren

Info

Publication number
DE69506548D1
DE69506548D1 DE69506548T DE69506548T DE69506548D1 DE 69506548 D1 DE69506548 D1 DE 69506548D1 DE 69506548 T DE69506548 T DE 69506548T DE 69506548 T DE69506548 T DE 69506548T DE 69506548 D1 DE69506548 D1 DE 69506548D1
Authority
DE
Germany
Prior art keywords
polymerizing
containing catalysts
catalysts
diolefins
polymerized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69506548T
Other languages
English (en)
Other versions
DE69506548T2 (de
Inventor
Jasson Patton
David Devore
Francis Timmers
Jorge Soto
Gregory Schmidt
David Wilson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of DE69506548D1 publication Critical patent/DE69506548D1/de
Publication of DE69506548T2 publication Critical patent/DE69506548T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69506548T 1994-06-28 1995-06-23 Verfahren zur polymerisation unter verwendung von diene-enthaltenden katalysatoren Expired - Fee Related DE69506548T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/267,991 US5543480A (en) 1994-06-28 1994-06-28 Polymerization process using diene containing catalysts
PCT/US1995/007946 WO1996000742A1 (en) 1994-06-28 1995-06-23 Polymerization process using diene containing catalysts

Publications (2)

Publication Number Publication Date
DE69506548D1 true DE69506548D1 (de) 1999-01-21
DE69506548T2 DE69506548T2 (de) 1999-07-29

Family

ID=23021001

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69506548T Expired - Fee Related DE69506548T2 (de) 1994-06-28 1995-06-23 Verfahren zur polymerisation unter verwendung von diene-enthaltenden katalysatoren

Country Status (6)

Country Link
US (2) US5543480A (de)
EP (1) EP0767804B1 (de)
JP (1) JPH10502396A (de)
AT (1) ATE174350T1 (de)
DE (1) DE69506548T2 (de)
WO (1) WO1996000742A1 (de)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6030917A (en) 1996-07-23 2000-02-29 Symyx Technologies, Inc. Combinatorial synthesis and analysis of organometallic compounds and catalysts
US6440745B1 (en) 1994-10-18 2002-08-27 Symyx Technologies Combinatorial synthesis and screening of organometallic compounds and catalysts
US6419881B1 (en) 1994-10-18 2002-07-16 Symyx Technologies, Inc. Combinatorial arrays of organometallic compounds and catalysts
WO1996016094A1 (en) * 1994-11-23 1996-05-30 The Dow Chemical Company Preparation of syndiotactic polyolefins from prochiral olefins
US6206922B1 (en) 1995-03-27 2001-03-27 Sdgi Holdings, Inc. Methods and instruments for interbody fusion
US5782919A (en) 1995-03-27 1998-07-21 Sdgi Holdings, Inc. Interbody fusion device and method for restoration of normal spinal anatomy
US5679816A (en) * 1996-01-03 1997-10-21 The Dow Chemical Company Preparation of biscyclopentadienyl diene complexes
EP0925312A1 (de) * 1996-09-12 1999-06-30 BP Chemicals Limited Polymerisationskatalysator
US6720186B1 (en) 1998-04-03 2004-04-13 Symyx Technologies, Inc. Method of research for creating and testing novel catalysts, reactions and polymers
EP0996649A1 (de) 1997-07-08 2000-05-03 BP Chemicals Limited Geträgerter polymerisationskatalysator
US6630545B2 (en) * 1997-09-15 2003-10-07 The Dow Chemical Company Polymerization process
KR20010042509A (ko) 1998-04-07 2001-05-25 그래햄 이. 테일러 개선된 신디오택틱 비닐리덴 방향족 중합체의 중합방법
DE69903850T2 (de) * 1998-10-29 2003-09-11 Dow Chemical Co Herstellung von titan(ii)- oder zirkon(ii)komplexe
US6670299B1 (en) * 1999-07-03 2003-12-30 Northwestern University Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts
JP4122655B2 (ja) 1999-10-05 2008-07-23 住友化学株式会社 遷移金属化合物、付加重合用触媒成分、付加重合用触媒およびオレフィン重合体の製造方法
CA2401694A1 (en) * 2000-03-01 2001-09-07 Shell Internationale Research Maatschappij B.V. Selective, catalytic, thermal functionalization of secondary or aromatic c-h cyclic hydrocarbon bonds
US6451937B1 (en) 2000-03-01 2002-09-17 Shell Oil Company Selective, catalytic, thermal functionalization of primary C-H hydrocarbon bonds
US6966940B2 (en) * 2002-04-04 2005-11-22 Donaldson Company, Inc. Air filter cartridge
EP1737875A1 (de) * 2004-04-23 2007-01-03 Exxonmobil Chemical Patents Inc. Phosphorsubstituierte metallocenverbindungen für die olefinpolymerisation
EP2336204A1 (de) * 2009-12-21 2011-06-22 DSM IP Assets B.V. Boranaktiviertes TI-Katalysatorsystem mit Amidin- und Dienliganden
EP2336205A1 (de) * 2009-12-21 2011-06-22 DSM IP Assets B.V. Boranaktiviertes TI-Katalysatorsystem mit Amidin- und Dienliganden
EP2508539A1 (de) 2011-04-01 2012-10-10 Lanxess Elastomers B.V. Titanium-Katalysatorsystem mit substituierten Cyclopentadienyl-, Guanidin- und Dienliganden
CN115043694B (zh) * 2022-05-23 2023-05-26 万华化学集团股份有限公司 一种制备甲基环戊二烯的方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242099A (en) * 1964-03-27 1966-03-22 Union Carbide Corp Olefin polymerization catalysts
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US4774301A (en) * 1987-06-08 1988-09-27 The Dow Chemical Company Zirconium containing catalysts and method of use
US4808680A (en) * 1987-06-08 1989-02-28 The Dow Chemical Company Polymerization of vinyl aromatic monomers using cyclopentadienyl zirconium catalysts
US5045517A (en) * 1987-06-17 1991-09-03 The Dow Chemical Company Catalyst and process for preparation of syndiotactic polystyrene
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5064918A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Ziegler-Natta polymerization of styrene monomer
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
JP3350561B2 (ja) * 1992-03-12 2002-11-25 三菱化学株式会社 オレフィン重合用遷移金属触媒成分
US5350723A (en) * 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5470993A (en) * 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
EP0705269B1 (de) * 1993-06-24 1997-01-15 The Dow Chemical Company Titan-und zirkoniumkomplexe und diese enthaltende polymerisationskatalysatoren

Also Published As

Publication number Publication date
ATE174350T1 (de) 1998-12-15
US5543480A (en) 1996-08-06
US5646084A (en) 1997-07-08
WO1996000742A1 (en) 1996-01-11
JPH10502396A (ja) 1998-03-03
DE69506548T2 (de) 1999-07-29
EP0767804A1 (de) 1997-04-16
EP0767804B1 (de) 1998-12-09

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee