DE69424540T2 - A stable and active nickel catalyst for the carbon dioxide reforming of methane to synthesis gas - Google Patents
A stable and active nickel catalyst for the carbon dioxide reforming of methane to synthesis gasInfo
- Publication number
- DE69424540T2 DE69424540T2 DE69424540T DE69424540T DE69424540T2 DE 69424540 T2 DE69424540 T2 DE 69424540T2 DE 69424540 T DE69424540 T DE 69424540T DE 69424540 T DE69424540 T DE 69424540T DE 69424540 T2 DE69424540 T2 DE 69424540T2
- Authority
- DE
- Germany
- Prior art keywords
- la2o3
- methane
- carbon dioxide
- nickel
- stable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
- Carbon And Carbon Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
This invention refers to a novel nickel-based catalyst which exhibits excellent activity and stability for carbon dioxide reforming of natural gas (methane) to synthesis gas. The catalyst consists of nickel crystallites in contact with La2O3 carrier or in the form of nickel supported on La2O3 carrier or in the form of nickel on La2O3 particles dispersed on a conventional carrier such as gamma -Al2O3. The stable and active surface of Ni/La2O3 is formed, following two hours of the reaction of carbon dioxide reforming of methane at temperatures higher than 600 DEG C. In contrast to conventional nickel-based catalysts, e.g. Ni/ gamma -Al2O3, the new Ni/La2O3 catalysts (at the stable state) are not prone to coking in the temperature range of 550-850 DEG C, exhibiting excellent stability. Near complete conversion of methane and carbon dioxide, and around 100% selectivity to carbon monoxide and hydrogen are achieved over the Ni/La2O3 catalysts under stoichiometric conditions at temperatures in the neighbourhood of 8oo DEG C and a superficial contact time of ca. 0.02 seconds. <MATH>
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP94600005A EP0692451B1 (en) | 1994-07-13 | 1994-07-13 | A stable and active nickel catalyst for carbon dioxide reforming of methane to synthesis gas |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69424540D1 DE69424540D1 (en) | 2000-06-21 |
DE69424540T2 true DE69424540T2 (en) | 2001-02-08 |
Family
ID=8218181
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69424540T Expired - Fee Related DE69424540T2 (en) | 1994-07-13 | 1994-07-13 | A stable and active nickel catalyst for the carbon dioxide reforming of methane to synthesis gas |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0692451B1 (en) |
AT (1) | ATE192997T1 (en) |
DE (1) | DE69424540T2 (en) |
DK (1) | DK0692451T3 (en) |
ES (1) | ES2148301T3 (en) |
PT (1) | PT692451E (en) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GR1003235B (en) | 1998-05-22 | 1999-10-13 | Process for the production of hydrogen and electricity generation by bio-ethanol reforming with the use of fuel cells and without emission of pollutants | |
KR100406363B1 (en) * | 1998-12-11 | 2004-01-24 | 주식회사 포스코 | A method for preparation of nickel-alumina catalyst, a nickel-alumina catalyst prepared thereby and a method for refor ming carbon dioxide with methan by using the same |
US6287393B1 (en) | 1999-09-03 | 2001-09-11 | Air Products And Chemicals, Inc. | Process for producing carburizing atmospheres |
KR100395095B1 (en) * | 1999-12-24 | 2003-08-21 | 재단법인 포항산업과학연구원 | A method for preparing of catalyst for reforming of methane and catalyst preparred by the method and a method for reforming of methan by using the catalyst |
WO2005097319A1 (en) | 2004-04-08 | 2005-10-20 | Sulzer Metco (Canada) Inc. | Supported catalyst for steam methane reforming and autothermal reforming reactions |
CN104549285B (en) * | 2013-10-15 | 2017-07-11 | 中国石油化工股份有限公司 | Nano-composite catalyst of synthesizing gas by reforming methane with co 2 and preparation method thereof |
FR3020356A1 (en) | 2014-04-29 | 2015-10-30 | Univ Lille Sciences Tech | METHOD FOR DRY REFORMING AT LEAST ONE ALKANE |
CN104475115A (en) * | 2014-11-20 | 2015-04-01 | 西南化工研究设计院有限公司 | Gaseous hydrocarbon pre-conversion catalyst and preparation method thereof |
CN105680057B (en) * | 2016-01-12 | 2018-03-16 | 山东联星能源集团有限公司 | A kind of preparation method of metal-air battery electrode graphite alkene catalyst |
US10046309B2 (en) | 2016-06-28 | 2018-08-14 | Yasin Khani | Supported nanocatalyst for catalytic reforming reactions |
CN106824200A (en) * | 2016-12-27 | 2017-06-13 | 武汉科技大学 | A kind of carbon load nickel metallic catalyst and preparation method thereof |
CN110026199B (en) * | 2019-04-02 | 2022-01-28 | 天津大学 | Lanthanum oxycarbonate modified aluminum oxide loaded nickel-based catalyst and preparation method thereof |
CN113019383A (en) * | 2021-03-10 | 2021-06-25 | 中国科学院兰州化学物理研究所 | Nickel/lanthanum oxide catalyst and preparation method and application thereof |
CN112897463B (en) * | 2021-04-21 | 2022-12-20 | 山东大学 | Device and method for preparing synthesis gas by electrocatalysis of methane-carbon dioxide |
CN114917915B (en) * | 2022-05-19 | 2023-12-15 | 华南理工大学 | Alkaline earth metal doped lanthanum oxide supported nickel-based catalyst and preparation and application thereof |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3395004A (en) * | 1964-01-20 | 1968-07-30 | Exxon Research Engineering Co | Low-temperature, high-pressure, catalytic, partial conversion of naphtha hydrocarbons to hydrogen |
DE1792795A1 (en) * | 1968-08-13 | 1977-06-23 | Metallgesellschaft Ag | METHOD FOR GENERATING A SYNTHESIS GAS RICH IN CARBON MONOXIDE |
EP0084273A3 (en) * | 1982-01-04 | 1984-05-23 | The Standard Oil Company | Production of synthesis gas |
-
1994
- 1994-07-13 PT PT94600005T patent/PT692451E/en unknown
- 1994-07-13 AT AT94600005T patent/ATE192997T1/en not_active IP Right Cessation
- 1994-07-13 DE DE69424540T patent/DE69424540T2/en not_active Expired - Fee Related
- 1994-07-13 ES ES94600005T patent/ES2148301T3/en not_active Expired - Lifetime
- 1994-07-13 EP EP94600005A patent/EP0692451B1/en not_active Expired - Lifetime
- 1994-07-13 DK DK94600005T patent/DK0692451T3/en active
Also Published As
Publication number | Publication date |
---|---|
DE69424540D1 (en) | 2000-06-21 |
ATE192997T1 (en) | 2000-06-15 |
EP0692451A1 (en) | 1996-01-17 |
PT692451E (en) | 2000-10-31 |
EP0692451B1 (en) | 2000-05-17 |
DK0692451T3 (en) | 2000-09-25 |
ES2148301T3 (en) | 2000-10-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8327 | Change in the person/name/address of the patent owner |
Owner name: ELIBIO .S.A.HYDROGEN AND ENERGY PRODUCTION SYS, GR Owner name: ZHANG, ZHAOLONG, XIAMEN, CN |
|
8381 | Inventor (new situation) |
Inventor name: ZHANG, ZHAOLONG, XIAMEN 361005, CN Inventor name: VERYKIOS, XENOPHON E., AGIOS BASILIOS, PATRAS, GR |
|
8339 | Ceased/non-payment of the annual fee |