DE6730C - Process for the preparation of briquettes using a mixture of magnesia-chloromagnesium as a binder - Google Patents

Process for the preparation of briquettes using a mixture of magnesia-chloromagnesium as a binder

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Publication number
DE6730C
DE6730C DENDAT6730D DE6730DA DE6730C DE 6730 C DE6730 C DE 6730C DE NDAT6730 D DENDAT6730 D DE NDAT6730D DE 6730D A DE6730D A DE 6730DA DE 6730 C DE6730 C DE 6730C
Authority
DE
Germany
Prior art keywords
magnesia
briquettes
binder
mixture
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
DENDAT6730D
Other languages
German (de)
Original Assignee
Dr. AD. GURLT in Bonn
Publication of DE6730C publication Critical patent/DE6730C/en
Active legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/02Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
    • C10L5/06Methods of shaping, e.g. pelletizing or briquetting
    • C10L5/10Methods of shaping, e.g. pelletizing or briquetting with the aid of binders, e.g. pretreated binders
    • C10L5/12Methods of shaping, e.g. pelletizing or briquetting with the aid of binders, e.g. pretreated binders with inorganic binders

Description

1879.1879.

PATENTSCHRIFTPATENT LETTERING

...Klasse....Great.

■■·,, i/T'TVt/ ■■ · ,, i / T'TVt /

AD. GURLT in BONN.AD. GURLT in BONN.

Verfahren zur Bereitung von Briquettes unter Anwendung eines Gemisches von MagnesiaProcess for the preparation of briquettes using a mixture of magnesia

und Chlormagnesium als Bindemittel.and chlorine magnesium as a binder.

Patentirt im Deutschen Reiche vom 14. Februar 1879 ab.Patented in the German Empire on February 14, 1879.

Bei der Fabrikation von künstlichem Brennmaterial, welche zum Zwecke hat, aus sonst werthlosen Abfällen, wie Kohlengrus und Kohlenstaub, ein werthvolles und nützliches Product, die sogenannten Kohlensteine oder Briquettes, in festen Stücken herzustellen, bedient man sich bisher theils organischer Bindemittel, welche mit der Kohle verbrennen, theils unorganischer, die nach der Verbrennung in der Asche zurückbleiben. In the manufacture of artificial fuel, which has the purpose of otherwise worthless waste, such as coals and coal dust, a valuable and useful product, The so-called coal stones or briquettes, made in solid pieces, are used hitherto partly organic binders, which burn with the coal, partly inorganic, which remain in the ashes after burning.

Zu den Bindemitteln der ersten Art gehören besonders Steinkohlentheer, Steinkohlenpech, natürlicher Asphalt, Stärkekleister aus Kartoffeln oder Getreidemehl u. s. w., zu den letzteren Thon, Lehm, Kalk, Alaun mit Kalk, Wasserglas mit Thon u. s. w. Diese Bindemittel oder Kitte werden in gewissen Verhältnissen, kalt oder warm, mit dem Kohlenklein gemengt und dann meist unter kräftigen Pressen bei bedeutendem Drucke zu Blöcken verschiedener Form zusammengeprefst.The binders of the first type include, in particular, coal tar, coal pitch, natural asphalt, starch paste made from potatoes or cereal flour and so on, to the latter Clay, loam, lime, alum with lime, water glass with clay and so on. These binders or In certain proportions, cold or warm, putties are mixed with the coal and then mostly under vigorous pressing with significant pressure to form blocks of various kinds Form pressed together.

Gegen die Anwendung der organischen Kitte tritt besonders ihr hoher Preis in die Schranken, obwohl sie als solche den Heizwerth des Productes nicht beeinträchtigen. Gegen die bisher angewendeten unorganischen Kitte macht sich dagegen theils ihr hoher Preis, theils ihre geringe Bindekraft geltend, weshalb sie in so grofser Menge zugesetzt werden müssen, dafs dadurch der Aschengehalt des Productes wesentlich vermehrt und sein Heizwerth bedeutend beeinträchtigt wird.The use of organic putties is particularly difficult because of their high price. although as such they do not affect the calorific value of the product. Against the so far The inorganic cement used, on the other hand, is partly due to its high price, partly to its own low binding force, which is why they must be added in so great a quantity that thereby the ash content of the product is substantially increased and its calorific value is significant is affected.

Mein Verfahren besteht nun in der Anwendung eines wohlfeilen, unorganischen Bindemittels von sehr grofser Bindekraft, nämlich des Magnesiakittes, von dem 1 Gewichtstheil bis zu 20 Gewichtstheilen anderer Substanzen zu festen und harten Blöcken zusammenzukitten vermag, die einen Druck von über 500 kg auf einen Quadratcentimeter Fläche aushalten, ohne zu zerbrechen. Daher sind die nach meiner Methode hergestellten Kohlensteine besonders geeignet, einen weiten Transport zu Lande und zur See auszuhalten. Ferner ist auch bei der grofsen Bindekraft des Magnesiakittes die Vermehrung der Asche sehr bedeutend und daher die Beeinträchtigung der Heizkraft sehr gering. Der Magnesiakitt wird bereitet aus einer Lösung von Chlormagnesium von 20 bis 35 ° Baume", die mit unter der Weifsglühhitze geglühter Magnesia in Pulverform, theils aus Magnesit, theils aus trockenem Chlormagnesium erhalten, in solcher Menge gemischt wird, dafs sich ein plastischer Kitt bildet, welcher je nach der Temperatur und Concentration schneller oder langsamer erhärtet, indem sich dabei wahrscheinlich ein basisches Chlormagnesiumhydrat bildet. Der Magnesiakitt wird dann mit Kohlenklein in einer Mengtrommel oder auf eine andere geeignete Weise kalt oder warm angemengt, so dafs je nach der Beschaffenheit der Kohle die Masse von 5 bis 10 pCt. Kitt enthält. Als Grundsatz gilt, dafs bei sehr magerer Kohle und kalter Mengung die Menge des Bindemittels grofser, bei backender Kohle und zuvoriger Erwärmung derselben bis zum Anfange der Theerbildung kleiner genommen wird. Das so erhaltene Gemenge kann dann mit der Hand wie gewöhnliche Ziegelsteine geformt werden. Wird aber grofse Festigkeit der Kohlensteine verlangt, so mufs es unter einer kräftigen Presse in Formen geprefst werden, wie das auch heute bei anderen Methoden der Briquettefabrikation geschieht.My method now consists in the use of an inexpensive, inorganic binder of very great binding power, namely of magnesia cement, from 1 part by weight up to 20 parts by weight of other substances can cement together into solid and hard blocks, that can withstand a pressure of more than 500 kg on a square centimeter of area without to break. Therefore, the carbon stones made according to my method are particularly suitable, to endure long transport by land and sea. Furthermore, the because of the great binding power of the magnesia cement, the increase in the ashes is very significant, and therefore very significant the impairment of the heating power is very low. The magnesia putty is prepared from a Solution of chlorine magnesium from 20 to 35 ° Baume ", which is annealed with white glow heat Magnesia in powder form, obtained partly from magnesite, partly from dry chlorine magnesium, is mixed in such a quantity that a plastic cement is formed, which depending on the The temperature and concentration hardened faster or slower, probably by doing so forms a basic chlorine magnesium hydrate. The magnesia putty is then made with coal in a drum or in another suitable way mixed cold or warm, so that, depending on the nature of the charcoal, the mass is from 5 to 10 pCt. Contains putty. The basic principle is that with very lean coal and cold mix the amount of binding agent larger, with baking coal and prior heating of the same up to the beginning the tar formation is taken smaller. The mixture obtained in this way can then by hand how ordinary bricks are shaped. But the coal stones become very firm if required, it must be pressed into molds under a powerful press, as it is today happens with other methods of briquette production.

Claims (1)

Patent-Anspruch:Patent claim: Zum Zweck der Herstellung von künstlichem Brennmaterial die Anwendung des Magnesiakittes als Kitt oder Bindemittel zum festen Zusammenhalten der Kohlentheilchen, gleichgültig, ob die Fabrikation kalt oder warm, mit oder ohne Pressung geschieht.The use of magnesia putty for the production of artificial fuel as putty or binding agent to hold the coal particles firmly together, indifferent, whether the production is cold or warm, with or without pressing.
DENDAT6730D Process for the preparation of briquettes using a mixture of magnesia-chloromagnesium as a binder Active DE6730C (en)

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DENDAT16792D Active DE16792C (en) Process for the production of briquettes using a mixture of burnt dolomite or other magnesia-containing bodies and chlorine magnesium

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE745934C (en) * 1933-12-30 1944-05-30 Rodolphe Spatz Process for the production of pellets from vegetable fuels

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3066535A (en) * 1957-05-28 1962-12-04 Philips Corp Device for measuring low pressures
US3066536A (en) * 1958-02-21 1962-12-04 Philips Corp Apparatus for measuring low pressures
US4506667A (en) * 1983-04-06 1985-03-26 Figgie Int Inc Self-contained ventilator/resuscitator

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE745934C (en) * 1933-12-30 1944-05-30 Rodolphe Spatz Process for the production of pellets from vegetable fuels

Also Published As

Publication number Publication date
DE16792C (en)

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